Paraffin–CaCl_(2)·6H_(2)O dosage effects on the strength and heat transfer characteristics of cemented tailings backfill

The challenge of high temperatures in deep mining remains harmful to the health of workers and their production efficiency The addition of phase change materials (PCMs) to filling slurry and the use of the cold storage function of these materials to reduce downhole temperatures is an effective approach to alleviate the aforementioned problem.Paraffin–CaCl_(2)·6H_(2)O composite PCM was prepared in the laboratory.The composition,phase change latent heat,thermal conductivity,and cemented tailing backfill (CTB) compressive strength of the new material were studied.The heat transfer characteristics and endothermic effect of the PCM were simulated using Fluent software.The results showed the following:(1) The new paraffin–CaCl_(2)·6H_(2)O composite PCM improved the thermal conductivity of native paraffin while avoiding the water solubility of CaCl_(2)·6H_(2)O.(2) The calculation formula of the thermal conductivity of CaCl_(2)·6H_(2)O combined with paraffin was deduced,and the reasons were explained in principle.(3) The“enthalpy–mass scale model”was applied to calculate the phase change latent heat of nonreactive composite PCMs.(4)The addition of the paraffin–CaCl_(2)·6H_(2)O composite PCM reduced the CTB strength but increased its heat absorption capacity.This research can give a theoretical foundation for the use of heat storage backfill in green mines.

Numerical simulation research on surface radiation heat calculation of spacecraft in orbit whole course

The surface radiation heat simulation program based on Microsoft VC++ 6.0 for spacecraft in whole orbit course was presented.Due to complexity of spacecraft structure,the spacecraft structures were decomposed to relatively regular parts.Automatic generation of calculation grid was conducted by using structured grid and unstructured technology.Simulation mainly solved automatic grid generation for arbitrary surface and data transmission between arbitrary shape interfaces,and the geometry structure,physical process,calculation accuracy and efficiency were considered.View factors and radiation transfer coefficients were calculated by combining finite element method and ray uniform distribution.According to the position of surface cells,external heat flux was calculated with integral method for non-shaded surface and with ray uniform distribution method for shaded surface.As the spacecraft surface was wrapped with multilayer insulation material,the temperature field of multilayer insulation material was calculated with nodal network method and finite volume method.The temperature of other parts without wrap was calculated with finite element method.The temperature of unconnected regions available with radiation heat transfer relations was analyzed,and the calculation formulae were deduced.Numerical experiment shows that the simulation program is correct and effective.

Study on the Influence of Piloti on Mean Radiant Temperature in Residential Blocks by 3-D Unsteady State Heat Balance Radiation Calculation

Piloti is commonly used in tropical and subtropical climate zones to get high wind velocity and create shadowed areas in order to optimize the living environment of residential blocks,but there are few studies to reveal the influence of piloti on the radiant environment of residential blocks systematically. Taking the city of Guangzhou as an example,using 3-D Unsteady State Heat Balance Radiation Calculation Method,this paper shows that the mean radiant temperature( MRT) under piloti area increases with the increase of piloti ratio,and especially when piloti ratio is equal to 100%,the MRT increase trend becomes sharp. The MRT of exposed area decreases with the increase of piloti ratio,especially when piloti ratio reaches 100%,the decrease trend of MRT becomes sharp,which offers the reference for the study on piloti design in subtropical climate zones and further research on living environment by CFD simulation in residential blocks.

A calculation method of the sensible heat flux by sodar

During the second course of USA - PRC joint air sea interaction experiment in 1986, the temperature structure parameters CT2 were measured by sodar over the Western Pacific Ocean. Based on similarity theory, a method is discussed to calculate the sensible heat flux over the ocean in unstable stratification. Becausehumidity is great over the ocean, so we have to consider the influence of water vapor structure parameter Ce2and the correlation coefficient betweene and T on the calculation of sensible heat flux using CT2 profiles measured by sodar. A new formula is suggested in terms of parameterization. The sensible heat flux calculated by sodar measurements is compared with that by bulk transfer method, and the results agree well.

A Calorimetric Study Assisted with First Principle Calculations of Specific Heat for Si-Ge Alloys within a Broad Temperature Range

Calorimetric measurements are performed to determine the specific heat of Si-xat.% Ge(where x = 0, 10, 30,50, 70, 90 and 100) alloys within a broad temperature range from 123 to 823 K. The measured specific heat increases dramatically at low temperatures, and the composition dependence of specific heat is evaluated from the experimental results. Meanwhile, the specific heat at constant volume, the thermal expansion, and the bulk modulus of Si and Ge are investigated by the first principle calculations combined with the quasiharmonic approximation. The negative thermal expansion is observed for both Si and Ge. Furthermore, the isobaric specific heat of Si and Ge is calculated correspondingly from OK to their melting points, which is verified by the measured results and accounts for the temperature dependence in a still boarder range.

Numerical Simulation on Subcooled Boiling Heat Transfer Characteristics of Water-Cooled W/Cu Divertors

In order to realize safe and stable operation of a water-cooled W/Cu divertor under high heating condition,the exact knowledge of its subcooled boiling heat transfer characteristics under different design parameters is crucial.In this paper,subcooled boiling heat transfer in a water-cooled W/Cu divertor was numerically investigated based on computational fluid dynamic（CFD）.The boiling heat transfer was simulated based on the Euler homogeneous phase model,and local differences of liquid physical properties were considered under one-sided high heating conditions.The calculated wall temperature was in good agreement with experimental results,with the maximum error of 5%only.On this basis,the void fraction distribution,flow field and heat transfer coefficient（HTC）distribution were obtained.The effects of heat flux,inlet velocity and inlet temperature on temperature distribution and pressure drop of a water-cooled W/Cu divertor were also investigated.These results provide a valuable reference for the thermal-hydraulic design of a water-cooled W/Cu divertor.

Calculations of heat of solvation by a simple electrostatic approach to molecular interactions

An extremely simple formula to estimate the heat of formation of complexes between an ion and a polar molecule or between highly polar systems is presented.The formula is entirely electrostatic and the expression used is verified by means of perturbation theory.This formula is test- ed for several ion-molecule and molecule-molecule pairs.It is also applied to estimate the heat of hydration of simple salts.

Planck’s Oscillators at Low Temperatures and Haken’s Perturbation Approach to the Quantum Oscillators Reconsidered

In the first step the extremal values of the vibrational specific heat and entropy represented by the Planck oscillators at the low temperatures could be calculated. The positions of the extrema are defined by the dimensionless ratios between the quanta of the vibrational energy and products of the actual temperature multiplied by the Boltzmann constant. It became evident that position of a local maximum obtained for the Planck’s average energy of a vibration mode and position of a local maximum of entropy are the same. In the next step the Haken’s time-dependent perturbation approach to the pair of quantum non-degenerate Schr?dinger eigenstates of energy is re-examined. An averaging process done on the time variable leads to a very simple formula for the coefficients entering the perturbation terms.

Research on Marine Boiler's Pressurized Combustion and Heat Transfer

The effect of pressure on combustion and heat transfer is analyzed. The research is based on the basic combustion and heat transfer theorem. A correction for the heat calculation method for pressurized furnace is made on the basis of the normal pressure case. The correction takes the effect of pressurizing into account. The results show that the correction is reasonable and the method is applicable to combustion and heat transfer of the marine supercharged boiler.