Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water ...Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water systems showed good agreement with those in the literatures.This kind of method was then applied to CH4/CO2+sodium dodecyl sulfate(SDS)aqueous solution,CH4/CO2+SDS aqueous solution+silica sand,and(CH4+C2H6+C3H8)gas mixture+SDS aqueous solution systems,where SDS was added to increase the hydrate formation rate without evident influence on the equilibrium conditions.The feasibility and reliability of the step-heating method,especially for porous media systems and gas mixtures systems were determined.The experimental data for CO2+silica sand data shows that the equilibrium pressure will change significantly when the particle size of silica sand is less than 96μm.The formation equilibrium pressure was also measured by the reformation of hydrate.展开更多
The density, equilibrium heat of fusion and equilibrium melting temperature of Nylon 1010 were determined by means of infrared spectrum, differential scanning calorimetry, wide angle X-ray diffraction and density meas...The density, equilibrium heat of fusion and equilibrium melting temperature of Nylon 1010 were determined by means of infrared spectrum, differential scanning calorimetry, wide angle X-ray diffraction and density measurement techniques. According to Starkweatber' s method crystalline density ρ_c and amorphous density ρ_a were estimated to be 1.098 and 1.003 g/cm^3 respectively by extrapolating the straight lines of the IR absorbanee against density to zero intensity. Owing to the less intense in absorbance and less sensitive to the change in crystallinity of the amorphors band the thus obtained ρ_c was too low in value. Thereby the value of the ratio ρ_c /ρ_a is far less than generally accepted mean value for most crystalline polymers. Accordingly, traditional X-ray diffraction method was used through determining thc crystalline dimension(a=4.9, b=5.4, c=27.8, α=49° β=77.0°, γ=63.5°), and a rather correct value of ρ_c or the crystal density 1.13 g/cm^3 was obtained. The equilibrium heat of fusion △H_m^0 was estimated to be 244.0 J/g piotting △H_m 's of specimens with different crystallinity against their corre sponding specific volumes_(sp), and extrapolating to completely crystalline condition (_(sp)~c= 1/ρ_c) As to the equilibrium melting temperature T_m^0, because of the easiness of recrystallization of melt crystallized Nylon 1010 specimen, the well-known Hoffman's T_m-T_c method failed in determining this value and an usually rarely used Kamide double extrapolation method was adopted. The so obtained value of T_m^0 487 seems to be fairly reasonable.展开更多
The nonlinear J-E characteristics under self-heating equilibrium for conductive composites based on high density polyethylene were studied. The results show that there are identical conduction mechanisms under self-he...The nonlinear J-E characteristics under self-heating equilibrium for conductive composites based on high density polyethylene were studied. The results show that there are identical conduction mechanisms under self-heating equilibrium for the composites with various initial resistivities determined by filler content or ambient temperature. The nonlinear conduction behavior was involved in the limited microstructure transformations of the conducting network induced by electrical field applied and the corresponding self-heating effect. A reversible thermal fuse (RTF) model was suggested to interpret the physical origin of the nonlinear J-E characteristics.展开更多
We study the steady-state entanglement and heat current of two coupled qubits, in which two qubits are connected with two independent heat baths(IHBs) or two common heat baths(CHBs). We construct the master equation i...We study the steady-state entanglement and heat current of two coupled qubits, in which two qubits are connected with two independent heat baths(IHBs) or two common heat baths(CHBs). We construct the master equation in the eigenstate representation of two coupled qubits to describe the dynamics of the total system and derive the solutions in the steadystate with stronger coupling regime between two qubits than qubit–baths. We do not make the rotating wave approximation(RWA) for the qubit–qubit interaction, and so we are able to investigate the behaviors of the system in both the strong coupling regime and the weak coupling regime, respectively. In an equilibrium bath, we find that the entanglement decreases with the bath temperature and energy detuning increasing under the strong coupling regime. In the weak coupling regime,the entanglement increases with coupling strength increasing and decreases with the bath temperature and energy detuning increasing. In a nonequilibrium bath, the entanglement without RWA is useful for entanglement at lower temperatures.We also study the heat currents of the two coupled qubits and their variations with the energy detuning, coupling strength and low temperature. In the strong(weak) coupling regime, the heat current increases(decreases) with coupling strength increasing when the temperature of one bath is lower(higher) than the other, and the energy detuning leads to a positive(negative) effect when the temperature is low(high). In the weak coupling regime, the variation trend of heat current is opposite to that of coupling strength for the IHB case and the CHB case.展开更多
Steel industry is high energy-consuming industry, and its waste?heat recovery is critically?important for energy utilization. In this study, pipeline bundle is used to enhance heat transfer in?waste?heat recovery devi...Steel industry is high energy-consuming industry, and its waste?heat recovery is critically?important for energy utilization. In this study, pipeline bundle is used to enhance heat transfer in?waste?heat recovery device,?and?associated gas-solid heat transfer and energy utilization performance with different pipeline arrangement, pipe diameter and shape of internal component are further analyzed. The temperatures of gas and particle in device with pipeline bundle periodically fluctuate in horizontal direction, and those in staggered system distribute more uniformly than those in paralleled system. Compared with paralleled device, exergy and waste heat utilization efficiency of staggered device have been improved, and they are both higher than?those without pipeline. As pipe diameter increases, exergy and waste heat utilization efficiency first increases and then decreases, and they reach the maxima with optimal pipe diameter.?As the width of internal component keeps constant, influence of its shape on heat transfer is very little.展开更多
With the development of society and the acceleration of urbanization, urban heat island phenomenon is becoming increasingly prominent. In this paper, enrichment capacity of plant light energy is supplemented based on ...With the development of society and the acceleration of urbanization, urban heat island phenomenon is becoming increasingly prominent. In this paper, enrichment capacity of plant light energy is supplemented based on OKe model according to law of energy conservation. By contrasting each component of energy balance equation between the cities and rural areas, the causes for urban heat island are explained.展开更多
A new calculating method of aerodynamic heating for unsteady hypersonic aircrafts with complex configuration is presented.This method,which considers the effects of high temperature chemical non-equilibrium and the he...A new calculating method of aerodynamic heating for unsteady hypersonic aircrafts with complex configuration is presented.This method,which considers the effects of high temperature chemical non-equilibrium and the heat transfer process in thermal protection structure,is based on the combination of the inviscid outerflow solution and the engineering method,where the Euler solver provides the flow parameters on boundary layer edge for engineering method in aerodynamic heating calculation.A high efficient interpolation technique,which can be applied to the fast computation of longtime aerodynamic heating for hypersonic aircraft,is developed for flying trajectory.In this paper,three hypersonic test cases are calculated,and the heat flux and temperature distribution of thermo-protection system are shown.The numerical results show the high efficiency of the developed method and the validation of thermal characteristics analysis on hypersonic aerodynamic heating.展开更多
The effect of heat treatment mode on the microstructure of Fe-Cr-B cast iron alloys was investigated inthis paper by comparing the difference of precipitation patterns of secondary particles after thermal cycling trea...The effect of heat treatment mode on the microstructure of Fe-Cr-B cast iron alloys was investigated inthis paper by comparing the difference of precipitation patterns of secondary particles after thermal cycling treatment(TCT) with those after normal heat treatment (NHT). No obvious differences were found in precipitation patterns ofsecondary particles between TCT and NHT when experimental temperature was below Ar1. However, whentemperature was over Ar1, there were significant differences, with secondary particles prominently segregated at thegrain boundaries under TCT, while the particles evenly distributed in the matrix under NHT. The reason for themicrostructure differences could be associated with the development of non-equilibrium segregation of boron duringTCT.展开更多
Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano...Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano or micro channels is always considered with adding nanoparticles into the flow, so as to enhance the heat transfer by convection between the fluid and the surface. However, for some applications with around 1 nm channels such as nano filtration or erosion of rocks, there should be no nanoparticles included. Hence, it is necessary to figure out the heat transfer mechanism in the single phase nanofluidics. Via non-equilibrium molecular dynamics simulations, we revealed the heat transfer inside nanofluidics and the one between fluid and walls by setting simulation into extremely harsh condition. It was found that the heat was conducted by molecular motion without temperature gradient in the area of low viscous heat, while it was transferred to the walls by increasing the temperature of fluids. If the condition back to normal, it was found that the viscous heat of nanofluidics could be easily removed by the fluid-wall temperature drop of less than 1 K.展开更多
基金Supported by the National Natural Science Foundation of China （20676145, U0633003）, the National Basic Research Program of China （2009CB219504） and the Program for New Century Excellent Talents in University of the State Ministry of Education.
文摘Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water systems showed good agreement with those in the literatures.This kind of method was then applied to CH4/CO2+sodium dodecyl sulfate(SDS)aqueous solution,CH4/CO2+SDS aqueous solution+silica sand,and(CH4+C2H6+C3H8)gas mixture+SDS aqueous solution systems,where SDS was added to increase the hydrate formation rate without evident influence on the equilibrium conditions.The feasibility and reliability of the step-heating method,especially for porous media systems and gas mixtures systems were determined.The experimental data for CO2+silica sand data shows that the equilibrium pressure will change significantly when the particle size of silica sand is less than 96μm.The formation equilibrium pressure was also measured by the reformation of hydrate.
文摘The density, equilibrium heat of fusion and equilibrium melting temperature of Nylon 1010 were determined by means of infrared spectrum, differential scanning calorimetry, wide angle X-ray diffraction and density measurement techniques. According to Starkweatber' s method crystalline density ρ_c and amorphous density ρ_a were estimated to be 1.098 and 1.003 g/cm^3 respectively by extrapolating the straight lines of the IR absorbanee against density to zero intensity. Owing to the less intense in absorbance and less sensitive to the change in crystallinity of the amorphors band the thus obtained ρ_c was too low in value. Thereby the value of the ratio ρ_c /ρ_a is far less than generally accepted mean value for most crystalline polymers. Accordingly, traditional X-ray diffraction method was used through determining thc crystalline dimension(a=4.9, b=5.4, c=27.8, α=49° β=77.0°, γ=63.5°), and a rather correct value of ρ_c or the crystal density 1.13 g/cm^3 was obtained. The equilibrium heat of fusion △H_m^0 was estimated to be 244.0 J/g piotting △H_m 's of specimens with different crystallinity against their corre sponding specific volumes_(sp), and extrapolating to completely crystalline condition (_(sp)~c= 1/ρ_c) As to the equilibrium melting temperature T_m^0, because of the easiness of recrystallization of melt crystallized Nylon 1010 specimen, the well-known Hoffman's T_m-T_c method failed in determining this value and an usually rarely used Kamide double extrapolation method was adopted. The so obtained value of T_m^0 487 seems to be fairly reasonable.
基金the National Advanced Material Committee of China (NAMCC)，国家自然科学基金
文摘The nonlinear J-E characteristics under self-heating equilibrium for conductive composites based on high density polyethylene were studied. The results show that there are identical conduction mechanisms under self-heating equilibrium for the composites with various initial resistivities determined by filler content or ambient temperature. The nonlinear conduction behavior was involved in the limited microstructure transformations of the conducting network induced by electrical field applied and the corresponding self-heating effect. A reversible thermal fuse (RTF) model was suggested to interpret the physical origin of the nonlinear J-E characteristics.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61675115 and 11704221)
文摘We study the steady-state entanglement and heat current of two coupled qubits, in which two qubits are connected with two independent heat baths(IHBs) or two common heat baths(CHBs). We construct the master equation in the eigenstate representation of two coupled qubits to describe the dynamics of the total system and derive the solutions in the steadystate with stronger coupling regime between two qubits than qubit–baths. We do not make the rotating wave approximation(RWA) for the qubit–qubit interaction, and so we are able to investigate the behaviors of the system in both the strong coupling regime and the weak coupling regime, respectively. In an equilibrium bath, we find that the entanglement decreases with the bath temperature and energy detuning increasing under the strong coupling regime. In the weak coupling regime,the entanglement increases with coupling strength increasing and decreases with the bath temperature and energy detuning increasing. In a nonequilibrium bath, the entanglement without RWA is useful for entanglement at lower temperatures.We also study the heat currents of the two coupled qubits and their variations with the energy detuning, coupling strength and low temperature. In the strong(weak) coupling regime, the heat current increases(decreases) with coupling strength increasing when the temperature of one bath is lower(higher) than the other, and the energy detuning leads to a positive(negative) effect when the temperature is low(high). In the weak coupling regime, the variation trend of heat current is opposite to that of coupling strength for the IHB case and the CHB case.
文摘Steel industry is high energy-consuming industry, and its waste?heat recovery is critically?important for energy utilization. In this study, pipeline bundle is used to enhance heat transfer in?waste?heat recovery device,?and?associated gas-solid heat transfer and energy utilization performance with different pipeline arrangement, pipe diameter and shape of internal component are further analyzed. The temperatures of gas and particle in device with pipeline bundle periodically fluctuate in horizontal direction, and those in staggered system distribute more uniformly than those in paralleled system. Compared with paralleled device, exergy and waste heat utilization efficiency of staggered device have been improved, and they are both higher than?those without pipeline. As pipe diameter increases, exergy and waste heat utilization efficiency first increases and then decreases, and they reach the maxima with optimal pipe diameter.?As the width of internal component keeps constant, influence of its shape on heat transfer is very little.
文摘With the development of society and the acceleration of urbanization, urban heat island phenomenon is becoming increasingly prominent. In this paper, enrichment capacity of plant light energy is supplemented based on OKe model according to law of energy conservation. By contrasting each component of energy balance equation between the cities and rural areas, the causes for urban heat island are explained.
文摘A new calculating method of aerodynamic heating for unsteady hypersonic aircrafts with complex configuration is presented.This method,which considers the effects of high temperature chemical non-equilibrium and the heat transfer process in thermal protection structure,is based on the combination of the inviscid outerflow solution and the engineering method,where the Euler solver provides the flow parameters on boundary layer edge for engineering method in aerodynamic heating calculation.A high efficient interpolation technique,which can be applied to the fast computation of longtime aerodynamic heating for hypersonic aircraft,is developed for flying trajectory.In this paper,three hypersonic test cases are calculated,and the heat flux and temperature distribution of thermo-protection system are shown.The numerical results show the high efficiency of the developed method and the validation of thermal characteristics analysis on hypersonic aerodynamic heating.
文摘The effect of heat treatment mode on the microstructure of Fe-Cr-B cast iron alloys was investigated inthis paper by comparing the difference of precipitation patterns of secondary particles after thermal cycling treatment(TCT) with those after normal heat treatment (NHT). No obvious differences were found in precipitation patterns ofsecondary particles between TCT and NHT when experimental temperature was below Ar1. However, whentemperature was over Ar1, there were significant differences, with secondary particles prominently segregated at thegrain boundaries under TCT, while the particles evenly distributed in the matrix under NHT. The reason for themicrostructure differences could be associated with the development of non-equilibrium segregation of boron duringTCT.
基金Supported by the National Basic Research Program of China(2015CB655301)the National Natural Science Foundation of China(21506091)+2 种基金the Jiangsu Natural Science Foundations(BK20150944)the Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund(the second phase)the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano or micro channels is always considered with adding nanoparticles into the flow, so as to enhance the heat transfer by convection between the fluid and the surface. However, for some applications with around 1 nm channels such as nano filtration or erosion of rocks, there should be no nanoparticles included. Hence, it is necessary to figure out the heat transfer mechanism in the single phase nanofluidics. Via non-equilibrium molecular dynamics simulations, we revealed the heat transfer inside nanofluidics and the one between fluid and walls by setting simulation into extremely harsh condition. It was found that the heat was conducted by molecular motion without temperature gradient in the area of low viscous heat, while it was transferred to the walls by increasing the temperature of fluids. If the condition back to normal, it was found that the viscous heat of nanofluidics could be easily removed by the fluid-wall temperature drop of less than 1 K.
