Performance of a 270 MW Gas Power Plant Using Exergy and Heat Rate

The performance of a 270 MW (9 × 30 MW) AES Corporation barge mounted gas turbine power plant in Nigeria is evaluated using the heat rate and entropy generation by the components of the plant to characterize the irreversibility in each component when operating at different loads between 90% and 25%. The power plants have the peculiarity that three of the plants were supplied by three (3) different Original Equipment Manufacturers (OEM);A, B and C. This study is sequel to the fact that the gas turbines were the first independent power plants in the country and after more than fifteen years of operation, it is reasonable to evaluate the performance of the major components. By analyzing the thermodynamic performance of these components, the study demonstrates the utility value of exergy efficiency as an important parameter in the evaluation of major components in a gas power plant. Exergy efficiency is shown to be an important parameter in ranking the power plant components, identifying and quantifying the possible areas of reduction in thermodynamic losses and improvement in efficiencies. A new relationship is derived to demonstrate the correlation between the exergy efficiency and the heat rate of a 30 MW gas power plant. The prediction of the derived relationship correlates well with the observed operational performance of the 30 MW power plants. The combustion chamber in each of the plants provides the maximum exergy destruction during operation. Its exergy efficiency is shown to exhibit good correlation with its energy efficiency and the plant rational exergy. The implication is that from an operational and component selection viewpoint in the specifications of a gas power plant, knowledge of the Heat Rate which is usually provided by the OEM is adequate to make a reasonable inference on the performance of some critical components of the plant.

Physics-informed neural network approach for heat generation rate estimation of lithium-ion battery under various driving conditions

Accurate insight into the heat generation rate(HGR) of lithium-ion batteries(LIBs) is one of key issues for battery management systems to formulate thermal safety warning strategies in advance.For this reason,this paper proposes a novel physics-informed neural network(PINN) approach for HGR estimation of LIBs under various driving conditions.Specifically,a single particle model with thermodynamics(SPMT) is first constructed for extracting the critical physical knowledge related with battery HGR.Subsequently,the surface concentrations of positive and negative electrodes in battery SPMT model are integrated into the bidirectional long short-term memory(BiLSTM) networks as physical information.And combined with other feature variables,a novel PINN approach to achieve HGR estimation of LIBs with higher accuracy is constituted.Additionally,some critical hyperparameters of BiLSTM used in PINN approach are determined through Bayesian optimization algorithm(BOA) and the results of BOA-based BiLSTM are compared with other traditional BiLSTM/LSTM networks.Eventually,combined with the HGR data generated from the validated virtual battery,it is proved that the proposed approach can well predict the battery HGR under the dynamic stress test(DST) and worldwide light vehicles test procedure(WLTP),the mean absolute error under DST is 0.542 kW/m^(3),and the root mean square error under WLTP is1.428 kW/m^(3)at 25℃.Lastly,the investigation results of this paper also show a new perspective in the application of the PINN approach in battery HGR estimation.

Effect of heating rate on the densification of NdFeB alloys sintered by an electric field

This study introduces a novel method of electric field sintering for preparing NdFeB magnets. NdFeB alloy compacts were all sintered by electric fields for 8 min at 1000~C with different preset heating rates. The characteristics of electric field sintering and the effects of heating rate on the sintering densification of NdFeB alloys were also studied. It is found that electric field sintering is a new non-pressure rapid sintering method for preparing NdFeB magnets with fine grains at a relatively lower sintering temperature and in a shorter sintering time. Using this method, the sintering temperature and process of the compacts can be controlled accurately. When the preset heating rate in- creasing from 5 to 2000~C/s the densification of NdFeB sintered compacts gradHally improves. As the preset heating rate is 2000C/s, Nd-rich phases are small, dispersed and uniformly distributed in the sintered compact, and the magnet has a better microstructure than that made by conventional vacuum sintering. Also, the maximum energy product of the sintered magnet reaches 95% of conventionally vacuum sintered magnets.

Effect of Heating Rates on the Formable Oxide Scale on a C-Steel Surface

Oxide scale formation on a C-steel surface has been investigated using linear heating rates ranging from 0.1℃/min to 10℃/min at high temperatures. The studies on the oxide scale formation at high temperature (650℃) at slower heating rate (0.1℃/min) shows that the kinetic regime is linear. X-ray diffraction measurements revealed that the scale constituents are significantly influenced by the heating rate. The adherence of the scale was improved by using slower heating rate (0.1℃/min-≤650℃), while above such degree the scale was susceptible to cracking and flaking out of the alloy surface. In fact, the development of oxide growth stresses can cause considerable scale cracking. As well, variation of the crystallite sizes under the aforementioned conditions might affect the scale stacking to the alloy surface. The secondary electron detector images of the oxide scale shows that the scale was imperfectly smooth and there were a number of voids and defects in the scale skin, especially at fast heating rate. This observation could be attributed to defects of the as-received alloy. In general, slower heating rate reduced the defects of the scale and improved its adherence.

Influence of Heating Rate on Double Reversible Transformation in CuZnAlMnNi Shape Memory Alloy

The influence of heating rate on double reversible transformation in CuZnAlMnNi shape memory alloy was investigated by differential scanning calorimetry. It was found that rapid heating inhibits X -->M transformation but is favorable to the reverse martensite transformation, giving rise to the approach of the two transformation peaks. With the decrease of heating rate, the two transformation peaks separate gradually.

Effect of temperature and heating rate on mechanical properties of magnesium alloy AZ31

Effects of temperature and heating rate on the mechanical properties of the tensile specimens of magnesium alloy AZ31 were experimentally investigated using a Gleeble-1500 thermo-mechanical material testing system.The metallurgraphs of the fracture section of the specimens were also experimentally observed and analyzed for exploring their failure mechanism under different temperatures and heating rates.The results show that the higher the temperature,the lower the ultimate strength of the specimens.And the higher the heating rate,the higher the ultimate strength of the specimens.The high temperatures and high heating rates will induce microvoids in the specimens which make the specimens failure under relatively low loads.

Effects of Heating Rate on the Process Parameters of Superplastic Forming for Zr_(55)Cu_(30)Al_(10)Ni_5

We investigated the effects of heating rate on the process parameters of superplastic forming for Zr55Cu30Al10Ni5 by differential scanning calorimetry. The continuous heating and isothermal annealing analyses suggested that the temperatures of glass transition and onset crystallization are heating rate-dependent in the supercooled liquid region. Then, the time-temperature-transformation diagram under different heating rates indicates that increasing the heating rate can lead to an increase of the incubation time at the same anneal temperature in the supercooled liquid region. Based on the Arrhenius relationship, we discovered that the incubation time increases by 1.08-1.11 times with double increase of the heating rate at the same anneal temperature, and then verified it by the data of literatures and the experimental results. The obtained curve of the max available incubation time reveals that the incubation time at a certain anneal temperature in the supercooled liquid region is not infinite, and will increase with increasing heating rate until this temperature shifts out of the supercooled liquid region because of exceeding critical heating rate. It is concluded that heating rate must be an important processing parameter of superplastic forming for Zr55Cu30Al10Ni5.

Spatial Distributions of Atmospheric Radiative Fluxes and Heating Rates over China during Summer

The latitude-altitude distributions of radiative fluxes and heating rates are investigated by utilizing CloudSat satellite data over China during summer. The Tibetan Plateau causes the downward shortwave fluxes of the lower atmosphere over central China to be smaller than the fluxes over southern and northern China by generating more clouds. The existence of a larger quantity of clouds over central China reflects a greater amount of solar radiation back into space. The vertical gradients of upward shortwave radiative fluxes in the atmosphere below 8 km are greater than those above 8 km. The latitudinal-altitude distributions of downward longwave radiative fluxes show a slantwise decreasing trend from low latitudes to high latitudes that gradually weaken in the downward direction. The upward longwave radiative fluxes also weaken in the upward direction but with larger gradients. The maximum heating rates by solar radiation and cooling rates by longwave infrared radiation are located over 28 40°N at 7 8 km mean sea level (MSL), and they are larger than the rates in the northern and southern regions. The heating and cooling rates match well both vertically and geographically.

EFFECT OF HEATING RATE ON THERMO-INDUCED AGGREGATION OF POLY(ETHYLENE OXIDE)-b-POLY(N-ISOPROPYLACRYLAMIDE) IN AQUEOUS SOLUTIONS

The effects of heating rate on the aggregate behavior of poly（ethylene oxide）-b-poly（N-isopropylacrylamide） in aqueous solutions were investigated in detail by laser light scattering and TEM. By employing two separate heating protocols, step-by-step heating at 〈 5 K/step and one-step jump, to heat the sample from 15℃ to the selected temperature, we found that the heating rate only showed significant effect on the aggregates above the cloud point. The aggregate formed by step-by-step heating exhibited a much larger size and a broader size distribution than those formed by one-step jump heating. Moreover, neither of the aggregates were ideal micellar structures as indicated by the size and the Rg/Rh values. On the contrary, at temperatures below the cloud point where the block copolymer formed core-shelled micelles, the heating rate showed negligible effect on the size and size distribution of the micelles. Since the system underwent a phase separation above the cloud point, the heating rate effect could be reasonably explained by the phase separation mechanisms： the nucleation-and-growth mechanism in the metastable region and the spinodal decomposition mechanism in the unstable region.

A FINITE-ELEMENT FORMULATION OF HEATING RATE AND SKIN FRICTION ON THE BASIS OF CONSERVAION LAWS

In the framework of the finite element method (FEM), a prediction method for the heating rate and the skin friction on a body surface is presented by using the energy and momentum conservation equations respectively. Meanwhile, a brief analysis is made of the role the weighted functions play in the present work.

Decline of nucleation in the heating process with a high heating rate

The effect of the heating rate on the nucleation of metallic glass in a rapid heating process starting from the glass transition temperature is investigated. The critical nucleus radius increases with the increase of the temperature of the undercooling liquid. If the increment rate of the critical nucleus radius, owing to the heating process, is higher than the growth rate of the nuclei, the nuclei generated at the low temperature will become the embryos at the high temperature. This means that the high heating rate can make no nucleation happen in the heating process. In consideration of the interfacial energy, the growth rate of the nuclei increases with the increase of their size and the growth rate of the critical nucleus is zero. Thus, the lower heating rate can also make the nuclei decline partially. Finally, this theory is used to analyze the nucleation process during laser remelting metallic glass.

Effects of the Annealing Heating Rate on Sputtered Aluminum Oxide Films

AlxOy films by DC reactive magnetron sputtering were annealed in air ambient at 500 ℃for 1 h with different heating rates of 5,15,and 25 ℃/min.Then heat treatments at 900 ℃ were carried out on these 500 ℃-annealed films to simulate the high-temperature application environment.Effects of the annealing heating rate on structure and properties of both 500 ℃-annealed and 900 ℃-heated films were investigated systematically.It was found that distinct γ-Al2O3 crystallization was observed in the 900 ℃-heated films only when the annealing heating rates are 15 and 25 ℃/min.The 500 ℃-annealed film possessed the most compact surface morphology in the case of 25 ℃/min.The highest microhardness of both 500 ℃-annealed and 900℃-heated films were obtained when the annealing heating rate was 15 ℃/min.

Effects of Heating Rate on Alumina Grain Growth

A rapid-heating method in the absence of electric/magnetic field was achieved by introducing a self-propagating-combustion （SHS） as heating source. The effect of heating rate on the alumina grain growth was explored based on this rapid-heating method. Comparing with the alumina prepared by two different heating ratios （greater than 1 000 ℃/min in SItS and about 50 ℃/min in common pressureless sintering furnace）, it was revealed that the rapid heating could promote the grain growth greatly without pressure during sintering. However, if a pressure was applied simultaneously, the grain growth would be almost completely restrained. Since these observations are quite different from the expectation, a new grain growth model was proposed.

RESEARCH ON RELATION BETWEEN MELTING POINT OF CEMENT CLINKER AND HEATING RATE

The relation between the melting point of Portland cement raw meal and its heating rate have been studied. The raw meal was burnt at different heating rate ranging from 10 similar to 900 degrees C/min Dy the following methods: (A) in electric resistance furnace; (B) in DTA-TG analyzer with infrared ray focused heating; (C) in high temperature microscope with electron stream heating. Based on thermal analysis theory and melt theory and the tests above, it is found that melting point T-m of cement raw meal decreases with the increased heating rate Phi during burning in the following relation: T-m=1280-0.107 empty set.

Effect of heating rate on the recrystallization microstructure and property of ultra-low-carbon steel

In the present work,the microstructure,texture,and mechanical properties of a cold-rolled Ti-IF steel,after annealing at different heating rates,have been investigated.The results reveal that the mean grain size is gradually refined from 19.2 to 16.3 μ m as the heating rate increases from 4 to 50 ℃/s,but refined only slightly at heating rates of over 50 ℃/s.The recrystallization microstructure has a strong texture,which is a result of the sharpening of the favorable { 111 }//ND （normal direction） texture components or γ-fiber.With increasing heating rates,the peak value off（g） of γ-fiber decreases from 17 to 9.The yield and tensile strengths increase gradually as the heating rate increases from 4 to 50 ℃/s,but remain almost unchanged at heating rates of more than 50 ℃/s.The total elongation and uniform elongation increase gradually as the heating rate increases from 4 to 100 ℃/s,but decreases slowly for heating rates higher than 100 ℃/s.As the heating rate increases from 4 to 100 ℃/s,the plastic strain ratio of the steel decreases from 2.8 to 2.2; however,it increases to 2.9 for heating rates above 100 ℃/s.The strain hardening exponent remains unchanged at 0.27 in all annealing cycles.

Effect of heating-rate on failure temperature of pre-loaded magnesium alloy

The response and failure of magnesium alloy AZ31 specimens subjected to different pre-loaded-stress levels and heating rates were investigated with a Gleeble-1500 thermo-mechanical material testing system.It is found that the increases of either pre-loaded stresses or heating-rates decrease the failure temperatures of the specimens.The metallographs of the tested specimens were also observed.It is shown that the high heating-rate may cause stronger local thermal inconsistency,which remarkably increases the microdefects and reduces the macroscopic mechanical properties of the material.

EFFECT OF HEATING RATE ON NONLINEARITY OF DOSE RESPONSE IN TL BY KINETICS MODEL

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Measurement of Heating Rates in a Microscopic Surface-Electrode Ion Trap

We report measurement of heating rates of 40 Ca＋ ions confined in our home-made microscopic surface-electrode trap by a Doppler recooling method. The ions are trapped with approximately 800 μm above the surface, and are subjected to heating due to various noises in the trap. There are 3-5 ions involved to measure the heating rates precisely and efficiently. We show the heating rates in variance with the number and the position of the ions as well as the radio-frequency power, which are helpful for understanding the trap imperfection.

Heat Production Rate Calculation of Thermal Manikin with a Compensation Method

Thermal manikin plays important roles in simulating thethermal state of human bodies to facilitate the evaluationof thermal comfort properties of various clothing assem-blies.Based on the heat balance principle and analysis ofrelated factors,the heat production rate of manikin isrecommended as an efficient evaluation index.Whereas,its inside heat production which occurs as a result of theexistence of temperature difference between its insidepart and outside surface,should not be ignored.Through a series of theoretical analysis and calculations,a compensative equation is deduced in this paper.

Effect of heating-rate on failure temperature of pre-loaded brass H62

The response and failure of brass H62 specimens subjected to different levels of pre-loaded stresses and heating rates were investigated using a Gleeble-1500 thermal-mechanical material testing system. The metallographs of the tested material were also observed and analyzed. It is found that the increase of either pre-loaded stress or heating-rate decreases the failure temperature. Metallographic analysis shows that high heating-rate may cause stronger local thermal inconsistency(LTI) and remarkably increase the microdefects in the material,which may markedly degrade the macroscopic mechanical properties of the material.