It’s necessary to forecast the shortest spontaneous combustion period for preventing and controlling the coal spontaneous combustion.During the experimental process,a calculating model of the SSCP is established on t...It’s necessary to forecast the shortest spontaneous combustion period for preventing and controlling the coal spontaneous combustion.During the experimental process,a calculating model of the SSCP is established on the basis of the oxidative heat release intensity and thermal capacity at different temperatures.According to the basic parameters of spontaneous combustion,heat of water evaporation and gas desorption,the SSCPs of different coals are further predicted.Finally,this study analyzed the relationships of the SSCP and the judging indexes of the self-ignite tendency.The result shows that the SSCP non-linearly increases with the decrease of dynamic oxygen adsorption and increase of activation energy.Compared with the practical fire situation of mine,this reliable method can meet the actual requirement of mine production.展开更多
Directly measuring the oxidative heat release intensity at low temperatures is difficult at present.We developed a new method based on heat conduction theory that directly measures heat release intensity of loose coal...Directly measuring the oxidative heat release intensity at low temperatures is difficult at present.We developed a new method based on heat conduction theory that directly measures heat release intensity of loose coal at low temperatures.Using this method, we calculated the oxidative heat release intensity of differently sized loose coals by comparing the temperature rise of the coal in nitrogen or an air environment.The results show that oxidation heat release intensity of Shenhua coal sized 0~15 mm is 0.001~0.03 W/m3 at 30~90 °C and increases with increasing temperature.The heat release intensity at a given temperature is larger for smaller sized coal.The temperature effect on heat release intensity is muted as the coal size increases.At lower temperature the change in heat release intensity as a function of size becomes smaller.These results show that the test system is usable for practical applications and is easy to operate and is capable of measuring mass samples.展开更多
Onsite mine fire generates large volumes of heat-affected coal in Jharia coalfields,India.Direct utilization of such heat-affected coal in thermal utilities is not feasible as such coal does not have the desirable vol...Onsite mine fire generates large volumes of heat-affected coal in Jharia coalfields,India.Direct utilization of such heat-affected coal in thermal utilities is not feasible as such coal does not have the desirable volatile matter required for combustion.In the present work,experimental studies have been carried out to investigate the possible utilization of such heat-affected coal in thermal utilities by blending with other coal.Heat-affected coal(31%ash and 5300 kcal/kg GCV)collected from Jharia coalfield were blended with thermal coal(28%ash and 5650 kcal/kg GCV)in different ratios of 90:10,80:20,70:30 and 60:40 to identify the desirable blend ratio for burning of blended coal in thermal utilities.Burning characteristics of all the coals were carried out using TGA.Various combustion parameters such as ignition temperature,peak temperature,burnout temperature,ignition index,burnout index,combustion performance index,rate and heat intensity index of the combustion process and activation energy were evaluated to analyse the combustion process.Experimental and theoretical analysis shows the blend ratio of 90:10 can be used in place of only thermal coal in utilities to reduce the fuel cost.展开更多
The volume hypothesis,a theory about the energy scale of comminution,was adopted to analyze the degradation behavior of lump coal under different heating time.The breakage energy of chars was determined by a compressi...The volume hypothesis,a theory about the energy scale of comminution,was adopted to analyze the degradation behavior of lump coal under different heating time.The breakage energy of chars was determined by a compression test,and the results show that the ultimate strength of chars decreased at the early stage during the heating process,resulting in a decrease of the char breakage energy.At the late stage during the heating process,the char breakage energy increased with the increase of heating time.The power consumption coefficients CKof different chars were determined by a drum experiment,and then the char degradation behavior under different power consumptions was predicted.In addition,agasification experiment was conducted to determine the gasification activation energy(with CO_2)of lump coal heated for different time.The results show that the gasification activation energy increased greatly at the early stage during the heating process,which showed opposite change to the breakage energy of chars.Furthermore,the internal temperature and heat changes of the bonded coal briquette were calculated by using an unsteady heat conduction equation.The large difference between the surface and the center temperatures of coal and the large amount of heat absorption at the early stage during the heating process may have a negative effect on the breakage energy of chars.展开更多
基金supported by China National Science Foundation of China (Nos.51074158 and 51304189)the Youth Science and Research Fund of China University of Mining and Technology of China (No.2009A006)
文摘It’s necessary to forecast the shortest spontaneous combustion period for preventing and controlling the coal spontaneous combustion.During the experimental process,a calculating model of the SSCP is established on the basis of the oxidative heat release intensity and thermal capacity at different temperatures.According to the basic parameters of spontaneous combustion,heat of water evaporation and gas desorption,the SSCPs of different coals are further predicted.Finally,this study analyzed the relationships of the SSCP and the judging indexes of the self-ignite tendency.The result shows that the SSCP non-linearly increases with the decrease of dynamic oxygen adsorption and increase of activation energy.Compared with the practical fire situation of mine,this reliable method can meet the actual requirement of mine production.
基金Projects 50474067 supported by the National Natural Science Foundation of China2007KF11 by the State Key Laboratory of Coal Resources and Safety Mining
文摘Directly measuring the oxidative heat release intensity at low temperatures is difficult at present.We developed a new method based on heat conduction theory that directly measures heat release intensity of loose coal at low temperatures.Using this method, we calculated the oxidative heat release intensity of differently sized loose coals by comparing the temperature rise of the coal in nitrogen or an air environment.The results show that oxidation heat release intensity of Shenhua coal sized 0~15 mm is 0.001~0.03 W/m3 at 30~90 °C and increases with increasing temperature.The heat release intensity at a given temperature is larger for smaller sized coal.The temperature effect on heat release intensity is muted as the coal size increases.At lower temperature the change in heat release intensity as a function of size becomes smaller.These results show that the test system is usable for practical applications and is easy to operate and is capable of measuring mass samples.
文摘Onsite mine fire generates large volumes of heat-affected coal in Jharia coalfields,India.Direct utilization of such heat-affected coal in thermal utilities is not feasible as such coal does not have the desirable volatile matter required for combustion.In the present work,experimental studies have been carried out to investigate the possible utilization of such heat-affected coal in thermal utilities by blending with other coal.Heat-affected coal(31%ash and 5300 kcal/kg GCV)collected from Jharia coalfield were blended with thermal coal(28%ash and 5650 kcal/kg GCV)in different ratios of 90:10,80:20,70:30 and 60:40 to identify the desirable blend ratio for burning of blended coal in thermal utilities.Burning characteristics of all the coals were carried out using TGA.Various combustion parameters such as ignition temperature,peak temperature,burnout temperature,ignition index,burnout index,combustion performance index,rate and heat intensity index of the combustion process and activation energy were evaluated to analyse the combustion process.Experimental and theoretical analysis shows the blend ratio of 90:10 can be used in place of only thermal coal in utilities to reduce the fuel cost.
基金supported by National Natural Science Foundation of China(51604208,51574189)Talent Technology Fund of Xi′an University of Architecture and Technology(RC1610)
文摘The volume hypothesis,a theory about the energy scale of comminution,was adopted to analyze the degradation behavior of lump coal under different heating time.The breakage energy of chars was determined by a compression test,and the results show that the ultimate strength of chars decreased at the early stage during the heating process,resulting in a decrease of the char breakage energy.At the late stage during the heating process,the char breakage energy increased with the increase of heating time.The power consumption coefficients CKof different chars were determined by a drum experiment,and then the char degradation behavior under different power consumptions was predicted.In addition,agasification experiment was conducted to determine the gasification activation energy(with CO_2)of lump coal heated for different time.The results show that the gasification activation energy increased greatly at the early stage during the heating process,which showed opposite change to the breakage energy of chars.Furthermore,the internal temperature and heat changes of the bonded coal briquette were calculated by using an unsteady heat conduction equation.The large difference between the surface and the center temperatures of coal and the large amount of heat absorption at the early stage during the heating process may have a negative effect on the breakage energy of chars.