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Effects of Red Mud on the Remediation of Pb, Zn and Cd in Heavy Metal Contaminated Paddy Soil 被引量:3
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作者 范美蓉 罗琳 +3 位作者 廖育林 汤海涛 魏建宏 吴家梅 《Agricultural Science & Technology》 CAS 2012年第2期388-392,共5页
[Objective] To study the remediation efficiency of red mud on Pb, Zn and Cd in the heavy metal contaminated paddy soil of mine area, to clarify its remediation mechanism and fertilizer efficiency on heavy metal contam... [Objective] To study the remediation efficiency of red mud on Pb, Zn and Cd in the heavy metal contaminated paddy soil of mine area, to clarify its remediation mechanism and fertilizer efficiency on heavy metal contaminated soil. [Method] The soil incubation experiment was conducted to study the effect of red mud on the pH values and electrical conductivity (EC), and the remediation efficiency of red mud on lead (Pb), zinc (Zn) and cadmium (Cd) in heavy metal contaminated soil. [Result] Red mud addition reduced the content of exchangeable Pb, Zn and Cd in the soil significantly. Compared with the control, when incubated for 30, 60 and 90 d with the red mud dosage of 4% (W/W), the exchangeable Pb content was decreased by 39.25%, 41.38% and 50.19%; exchangeable Zn content was decreased by 49.26%, 57.32% and 47.16%; and exchangeable Cd content was decreased by 19.53%, 24.06% and 25.70%, respectively. The application of red mud had significant impact on the share of Pb, Zn and Cd contents in five forms, and different amounts of red mud application all reduced the proportion of exchangeable Pb, Zn and Cd to the total Pb, Zn and Cd. In addition, the proportion of exchangeable Pb, Zn and Cd to total Pb, Zn and Cd decreased with the increasing amount of red mud addition. [Conclusion] The study provided references for reasonable application of red mud and reduction of heavy metal pollution in paddy soil. 展开更多
关键词 Red mud LEAD zinc and cadmium heavy metal contaminated soil Remediation efficiency
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Harmful evaluation of heavy metals from soil layer to the groundwater: Take the Jilin Hunchun Basin as an example 被引量:1
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作者 Xiao-Dong Guo Qiang Liu +3 位作者 Hui-Rong Zhang Xu-Fei Shi Chuan-Yu Qin Zhi-Qiang Zhang 《China Geology》 CAS CSCD 2024年第1期116-124,共9页
The continuous enrichment of heavy metals in soils has caused potential harm to groundwater.Quantitative methods to evaluate the harm of heavy metals in soil to groundwater are lacked in previous studies.Based on the ... The continuous enrichment of heavy metals in soils has caused potential harm to groundwater.Quantitative methods to evaluate the harm of heavy metals in soil to groundwater are lacked in previous studies.Based on the theory of groundwater circulation and solid-liquid equilibrium,a simple and easy-touse flux model of soil heavy metals migrating to groundwater is constructed.Based on groundwater environmental capacity,an innovative method for evaluating the harm of heavy metals in soil to groundwater is proposed,which has been applied in Hunchun Basin,Jilin Province,China.The results show that the fluxes of soil heavy metals into groundwater in the study area are Zn,Cu,As,Pb,Cd,Ni,and Hg in descending order.The content of heavy metals in groundwater(As,Hg,Cu,Pb,Zn,Ni,and Cd)in most areas has not risen to the threshold of environmental capacity within 10 years.The harm levels of soil heavy metals to groundwater in the most townships soils are at the moderate level or below.This evaluation method can quantify the flux of soil heavy metals into groundwater simply and quickly,determine the residual capacity of groundwater to heavy metals,evaluate the harm level of soil heavy metals to groundwater,provide support for relevant departments to carry out environmental protection of soil and groundwater,and provide a reference to carry out similar studies for related scholars. 展开更多
关键词 Soil heavy metals As+Hg+Cu+pb+Zn+Ni+Cd Environmental capacity GROUNDWATER Hazard degree Migration flux model Agricultural geological survey engineering Hunchun Basin Jilin Province
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Effect of combined pollution by heavy metals on soil enzymatic activities in areas polluted by tailings from Pb-Zn-Ag mine 被引量:35
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作者 CHENCheng-li LIAOMin HUANGChang-yong 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2005年第4期637-640,共4页
Some enzymatic activities were determined in the areas polluted by tailings from Tiantai Pb-Zn-Ag Mine in Zhejiang Province of China. The results indicated the soil enzymatic activities decreased significantly with in... Some enzymatic activities were determined in the areas polluted by tailings from Tiantai Pb-Zn-Ag Mine in Zhejiang Province of China. The results indicated the soil enzymatic activities decreased significantly with increase of concentrations of heavy metals or the distance away from mining tailing center, especially dehydrogenase and urease activities. Multivariate regression analysis between heavy metal contents and soil enzymatic activities indicated that single dehydrogenase activity was very significantly correlated to combined effect of soil heavy metals in mine area. Moreover, single urease, protease and acid phosphatase activities were significantly related to the combined effect of heavy metals. The results suggest it is feasible to use soil enzymatic activities to indicate the pollution situation by combined heavy metals in the soil of mine area. 展开更多
关键词 heavy metal pb-Zn-Ag mine tailing soil enzyme
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The Effect of Planting Oilseed Rape and Compost Application on Heavy Metal Forms in Soil and Cd and Pb Uptake in Rice 被引量:19
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作者 WU Fei-long LIN Dai-yan SU De-chun 《Agricultural Sciences in China》 CAS CSCD 2011年第2期267-274,共8页
Pot experiments were conducted under greenhouse condition to investigate whether Cd and Pb uptake by rice could be reduced when it was rotated with oilseed rape and compost application.The results showed that the rice... Pot experiments were conducted under greenhouse condition to investigate whether Cd and Pb uptake by rice could be reduced when it was rotated with oilseed rape and compost application.The results showed that the rice grown after oilseed rape had significantly lower Cd and Pb concentrations in both straw and grains.Cd and Pb concentrations in the grains of the rice rotated with oilseed rape decreased by approximately 46-80% and 17-86%,respectively,although the Cd and Pb removal by oilseed rape ranged only from 2.39-3.67 and 0.032-0.13% of the total content in soil.Compost amendment also decreased the bioavailability of Cd and Pb in the soil and reduced Cd and Pb uptake by oilseed rapes and rice.The concentrations of Cd and Pb significantly decreased in the exchangeable and carbonate fractions and Pb concentration decreased in the organic matter and sulfide fractions in the contaminated soil after planting oilseed rapes. 展开更多
关键词 heavy metal crop rotation COMPOST oilseed rape RICE
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Speciation and fractionation of heavy metals in soil experimentally contaminated with Pb, Cd, Cu and Zn together and effects on soil negative surface charge 被引量:10
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作者 ZHOU Dong mei, HAO Xiu zhen, TU Cong, CHEN Huai man, SI You bin (Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China. ) 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2002年第4期439-444,共6页
Speciation and fractionation of heavy metals in soil subsamples experimentally loaded with Pb, Cd, Cu and Zn in orthogonal design was investigated by sequential extraction, and operationally defined as water soluble ... Speciation and fractionation of heavy metals in soil subsamples experimentally loaded with Pb, Cd, Cu and Zn in orthogonal design was investigated by sequential extraction, and operationally defined as water soluble and exchangeable(SE), weakly specific adsorbed(WSA), Fe and Mn oxides bound(OX) and organic bound(ORG). The results showed that fractions of heavy metals in the soil subsamples depended on their speciation. About 90% of Cd and 75% of Zn existed in soil subsamples in the SE fraction. Lead and Cu existed in soil subsamples as SE, WSA and OX fractions simultaneously, although SE was still the major fraction. Organic bound heavy metals were not clearly apparent in all the soil subsamples. The concentration of some heavy metal fractions in soil subsamples showed the good correlation with ionic impulsion of soil, especially for the SE fraction. Continuous saturation of soil subsamples with 0.20 mol/L NH 4Cl, which is the first step for determination of the negative surface charge of soil by the ion retention method, resulted in desorption of certain heavy metals from the soil. It was found that the percentage desorption of heavy metals from soil subsamples depended greatly on pH, the composition and original heavy metal content of the soil subsamples. However, most of the heavy metals in the soil subsamples were still be retained after multiple saturation. Compared with the parent soil, the negative surface charge of soil subsamples loaded with heavy metals did not show difference significantly from that of the parent one by statistical analysis. Heavy metals existed in the soil subsamples mainly as exchangeable and precipitated simultaneously. 展开更多
关键词 SOIL heavy metals SPECIATION soil surface charge
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Spatial distribution of heavy metals(Cu, Pb, Zn, and Cd)in sediments of a coastal wetlands in eastern Fujian, China 被引量:8
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作者 Lili Zhao Weibin You +8 位作者 Haiqing Hu Wei Hong Xiaojuan LIAO Shihong Xiao Ren Wang Jinbiao Cai Xuncheng Fan Yong Tan Dongjin He 《Journal of Forestry Research》 SCIE CAS CSCD 2015年第3期703-710,共8页
We investigated the spatial distribution (horizontal and vertical concentrations) of copper (Cu), lead (Pb), zinc (Zn), and cadmium (Cd) in five wetland types (mudflat, aquaculture wetland, water area, farm... We investigated the spatial distribution (horizontal and vertical concentrations) of copper (Cu), lead (Pb), zinc (Zn), and cadmium (Cd) in five wetland types (mudflat, aquaculture wetland, water area, farmland wetland and mangrove) from three areas (Ningde, Fuding, and Xiapu), China. Cu concentrations in five wetland types descended in the order: farm wetland, mudflat, aquaculture, water area and mangrove. Pb concentrations decreased in the order: aquaculture, mangrove, farm wetland, mudflat, and water area. Zn content decreased in the order: farm wetland, water area, aquaculture, mudflat and mangrove, and Cd content decreased as follows: mangrove, aquacul- ture, water area, rnudflat, and farm wetland. Comparison of the concentrations of the same heavy metals in different areas showed that the highest Cu (63.75 mg kg-1) and Zn (152.32mgkg-1) concentrations occurred in Ningdecoastal wetlands; Pb (110.58 mg kg-1) and Cd (2.81 mg kg-1) contents were highest in Fuding wetlands, and the average contents of all heavy metals were very low in Xiapu wetlands. Examination of the vertical distribution showed that the Cu content was high in all mudflat layers; Pb and Cd concentrations were highest in aquaculture and mangrove wetlands, respectively, and Zn content was highest in farm wetlands. The spatial distribution of Cu and Zn contents for different areas decreased as follows: Ningde 〉 Fuding 〉 Xiapu, for Pb and Cd were most concentrated in Fuding coastal wetlands. Concentrations of Zn and Cu were highly correlated, while Zn and Cu were not significantly correlated with Pb. 展开更多
关键词 Coastal wetland heavy metal SPATIALDISTRIBUTION Eastem Fujian Ningde City
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Broadband 1.53 μm emission in Er^(3+)-doped Ga-Bi-Pb-Ge heavy metal oxide glasses 被引量:3
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作者 杨钢锋 李涛 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第6期924-927,共4页
We investigated the thermal stability and spectroscopic properties of the 1.53 μm emission from ^4I13/2→^4I15/2 transition of Er^3+ ions in Er^3+/Yb^3+-codoped Ga-Bi-Pb-Ge heavy metal oxide glass for use in broad... We investigated the thermal stability and spectroscopic properties of the 1.53 μm emission from ^4I13/2→^4I15/2 transition of Er^3+ ions in Er^3+/Yb^3+-codoped Ga-Bi-Pb-Ge heavy metal oxide glass for use in broadband fiber amplifiers. It was noted that the addition of GeO2 effectively enhanced the thermal stability of the heavy metal oxide glass studied. The emission peak located at approximately 1530 nm with a full width at haft-maximum of approximately 58 nm. The measured lifetime and the calculated emission cross-section of this transition were -3.2 ms and -10.3×10^-21 cm^2, respectively. As a result, Ga-Bi-Pb-Ge heavy metal oxide glasses were assumed to be potential host material for the 1.53 μm broadband optical fiber amplifiers. 展开更多
关键词 heavy metal oxide glass thermal stability spectroscopic properties rare earths
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Simulation on release of heavy metals Cd and Pb in sediments 被引量:5
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作者 Hong-jie YAN He-yang ZHANG +4 位作者 Ya-jun SHI Ping ZHOU Huan LI Dong-ling WU Liu LIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第1期277-287,共11页
The re-release process and the release rate of heavy metals,cadmium and plumbum,which are rich in sediments of a certain water area,were investigated using a combined experimental and numerical method.Results show tha... The re-release process and the release rate of heavy metals,cadmium and plumbum,which are rich in sediments of a certain water area,were investigated using a combined experimental and numerical method.Results show that the release law of Cd and Pb in sediments is divided into two stages:rapid release and dynamic equilibrium,which is in great agreement with the pseudo second-order kinetic equation with a correlation coefficient R2 above 0.99.As the flow velocity accelerates,the release rate of heavy metals increases.The analysis results indicate that the water quality in the area can exceed the surface water Class V standard less than 3 h,and all but one of the relative deviations between the simulation value and the field survey result are within±10%. 展开更多
关键词 SEDIMENT heavy metal pollution re-release rate numerical simulation
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Effects of Heavy Metal Ions (Cu^(2+), Pb^(2+) and Cd^(2+)) on DNA Damage of the Gills, Hemocytes and Hepatopancreas of Marine Crab, Charybdis japonica 被引量:4
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作者 PAN Luqing LIU Na ZHANG Hongxia WANG Jing MIAO Jingjing 《Journal of Ocean University of China》 SCIE CAS 2011年第2期177-184,共8页
There are rising concerns about the hazardous effects of heavy metals on the environment. In this study, comet assay and DNA alkaline unwinding assay were conducted on the tissues (gills, hepatopancreas, and hemocytes... There are rising concerns about the hazardous effects of heavy metals on the environment. In this study, comet assay and DNA alkaline unwinding assay were conducted on the tissues (gills, hepatopancreas, and hemocytes) of Charybdis japonica in order to illustrate genotoxicity of three heavy metal ions (Cu2+, Pb2+, and Cd2+) on the marine crabs C. japonica. The crabs were exposed to Cu2+ (10, 50, and 100 ?g.L?1), Pb2+ (50, 250, and 500 ?g L?1) and Cd2+ (5, 25, and 50 ?g L?1), and the tissues were sampled at days 0.5, 1, 3, 6, 9, and 15. DNA alkaline unwinding assay was used for testing the DNA single strand break in gills and hepatopancreas and comet assay was employed for testing the DNA damage in hemocytes. The results showed that the DNA damage (F-value) of gills in the crabs exposed to the three heavy metals was decreased gradually during the exposure periods and there was a dose-time response relationship in certain time, suggesting that the levels of DNA single strand break in all the experimental groups increased significantly compared to the controls. Changes of F-value in hepatopancreas of the crabs exposed to the three heavy metals were similar to those in gills except that the peak values were found in the 500 ?g L?1 Pb2+ treatment group at day 3 and the 50 ?g L?1 Cd2+ treatment group at day 9. The ranks of DNA damage in gills and hepatopancreas induced by the three heavy metal ions (50 ?g L?1, day 15) were Cd2+ >Pb2+ >Cu2+ and Pb2+ >Cu2+ >Cd2+. The levels of DNA damage in gills were higher than those in hepatopancreas in the same experimental group. It can be concluded that indices of DNA damage can be used as the potential biomarkers of heavy metal pollution in marine environment. 展开更多
关键词 CRABS heavy metal genotoxicity comet assay DNA alkaline unwinding assay
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Microplastic and Heavy Metals Distributions in Urban Rivers Sediments,China
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作者 SONG Dandan SHANG Yujun +4 位作者 WANG Xiuli ZHUANG Yuwei GUO Hui BI Shuping HU Jianjun 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第4期1015-1025,共11页
This study investigated the distribution of microplastics and heavy metals,along with the interaction between the two in the sediments of urban rivers in China.Results showed that the abundance of microplastics ranged... This study investigated the distribution of microplastics and heavy metals,along with the interaction between the two in the sediments of urban rivers in China.Results showed that the abundance of microplastics ranged from 2412±187.5 to 7638±1312items kg^(-1)dry sediment across different survey stations,with an average abundance at(4388±713)items kg^(-1)dry sediment.Upon further categorization,it was found that transparent fragments were the primary color and type of microplastics present.The potential ecological risk index(RI)of heavy metals in sediments suggested a low level of ecological risk within a majority of the urban rivers studied.Cd was identified as the main potential ecological risk factor in the sediments of the studied areas.There was a relatively good significant linear relationship between the RI of heavy metals and the abundance of microplastics,bolstering the linkage between these two environmental pollutants.However,the concentrations of heavy metals in microplastics were not dependent on their corresponding contents in sediments.In fact,the concentration of Cu,Cd,and As in microplastics were higher than those in the sediments.This finding confirmed that microplastics could serve as carriers of heavy metals and introduce potential risks to aquatic wildlife and human through the food chain. 展开更多
关键词 microplastic heavy metals risk assessment river sediments
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Heavy metal pollution of river water and eco-friendly remediation using potent microalgal species
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作者 Amudham Radha Amal Raj Prabhakaran Mylsamy +3 位作者 V.Sivasankar B.Sathish Kumar Kiyoshi Omine T.G.Sunitha 《Water Science and Engineering》 EI CAS CSCD 2024年第1期41-50,共10页
Pollution of rivers is mainly caused by anthropogenic activities such as discharge of effluent from industrial facilities,maintenance of sewage/effluent treatment plants,and dumping of solid waste on river banks.This ... Pollution of rivers is mainly caused by anthropogenic activities such as discharge of effluent from industrial facilities,maintenance of sewage/effluent treatment plants,and dumping of solid waste on river banks.This study dealt with the pollution issues of the Cooum River in the well-known city of Chennai in South India.Water samples from 27 locations were collected and analyzed for 12 elements,including Ba,B,and Al,as well as heavy metals such as Pb,Cr,Mn,Fe,Co,Ni,Cu,Zn,and Cd.The samples showed levels of these elements that exceeded World Health Organization recommendations.Pearson correlation analysis revealed the inter-dependency among elements,and the contribution of each element based on factor loadings showed its percentage contribution compared to others.Water samples from six significant locations were chosen for remediation with three algae:Chlorella vulgaris,Scenedesmus dimorphus,and Phormedium sp.The uptake of pollutants led to the continuous growth of algae during the incubation period of 15 d,effectively removing heavy metals from the river water.The increasing levels of algal counts and the chlorophyll a content confirmed the algal growth during the incubation period,followed by a declining stage after the incubation period.The scanning electron microscopic images of algae before and after the remediation showed no remarkable modification of morphological patterns.This study showed that the uptake of heavy metals using algae is an effective water pollution remediation measure,making the process practicable in the field on a large scale in the near future. 展开更多
关键词 heavy metal Cooum river Phycoremediation MICROALGAE Factor analysis
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Characterization of Nutrients,Heavy Metals,Petroleum and Their Impact on Phytoplankton in Laizhou Bay:Implications for Environmental Management and Monitoring
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作者 WANG Kai ZHAO Linlin +3 位作者 ZHU Yugui YANG Liqiang WANG Yunfeng HONG Xuguang 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期822-834,共13页
The Laizhou Bay(LB)represents a substantial ecological area that is vulnerable to human activities and confronts diverse environmental challenges.This study provides a comprehensive characterization of nutrients,petro... The Laizhou Bay(LB)represents a substantial ecological area that is vulnerable to human activities and confronts diverse environmental challenges.This study provides a comprehensive characterization of nutrients,petroleum,heavy metals,and phytoplankton community structure across seven distinct areas in LB.The results indicate relatively high concentrations of NO_(2)-N,SiO_(4)-Si,and NO_(3)-N in the Southwest Laizhou Bay(SWLB)and Huanghe River Estuary(HRE).In contrast,the East Laizhou bay(ELB)and the North of Huanghe River Estuary(NHRE)exhibit the highest concentrations of heavy metals(As,Cr and Hg).The areas with high phytoplankton density and community diversity are mainly located in the SWLB.After adjusting for basic environmental factors,phytoplankton density and Margalef richness index D are significantly associated with nutrients(NO_(3)-N,NO_(2)-N,NH_(4)-N,SiO_(4)-Si),and heavy metal(Cr)concentrations.We highlight that,in addition to Xiaoqinghe River,nutrients brought by the Mihe River in the SWLB and heavy metal(Cr)pollution in the ELB resulting from industrial and mining activities along the coast significantly influence phytoplankton growth and community structure.Therefore,it is recommended that more monitoring and management efforts be focused on these regions in the future. 展开更多
关键词 Huanghe River Estuary Laizhou Bay NUTRIENTS heavy metals PHYTOPLANKTON BIODIVERSITY
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Nanoscale Zero-Valent Iron(nZVI)for Heavy Metal Wastewater Treatment:A Perspective
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作者 Shaolin Li Lei Li Weixian Zhang 《Engineering》 SCIE EI CAS CSCD 2024年第5期16-20,共5页
Industries such as non-ferrous metal smelting discharge billions of gallons of highly toxic heavy metal wastewater(HMW)worldwide annually,posing a severe challenge to conventional wastewater treatment plants and harmi... Industries such as non-ferrous metal smelting discharge billions of gallons of highly toxic heavy metal wastewater(HMW)worldwide annually,posing a severe challenge to conventional wastewater treatment plants and harming the environment.HMW is traditionally treated via chemical precipitation using lime,caustic,or sulfide,but the effluents do not meet the increasingly stringent discharge standards.This issue has spurred an increase in research and the development of innovative treatment technologies,among which those using nanoparticles receive particular interest.Among such initiatives,treatment using nanoscale zero-valent iron(nZVI)is one of the best developed.While nZVI is already well known for its site-remediation use,this perspective highlights its application in HMW treatment with metal recovery.We demonstrate several advantages of nZVI in this wastewater application,including its multifunctionality in sequestrating a wide array of metal(loid)s(>30 species);its capability to capture and enrich metal(loid)s at low concentrations(with a removal capacity reaching 500 mg·g^(-1)nZVI);and its operational convenience due to its unique hydrodynamics.All these advantages are attributable to nZVI’s diminutive nanoparticle size and/or its unique iron chemistry.We also present the first engineering practice of this application,which has treated millions of cubic meters of HMW and recovered tons of valuable metals(e.g.,Cu and Au).It is concluded that nZVI is a potent reagent for treating HMW and that nZVI technology provides an eco-solution to this toxic waste. 展开更多
关键词 Nanoscale zero-valent iron WASTEWATER heavy metal Resource recovery
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Effective removal of chromium,copper,and nickel heavy metal ions from industrial electroplating wastewater by in situ oxidative adsorption using sodium hypochlorite as oxidant and sodium trititanate nanorod as adsorbent
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作者 Muhammad Tayyab Butt Hengbo Yin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第10期312-330,共19页
Sodium hypochlorite and synthesized sodium trititanate nanorods(Na_(2)Ti_(3)O_(7),186 nm×1270 nm)were used as the oxidant and adsorbents for in situ oxidative adsorption treatment of actual electroplating wastewa... Sodium hypochlorite and synthesized sodium trititanate nanorods(Na_(2)Ti_(3)O_(7),186 nm×1270 nm)were used as the oxidant and adsorbents for in situ oxidative adsorption treatment of actual electroplating wastewater containing Cr(Ⅵ)(2.6-5.2 mg·L^(-1)),Cu^(2+)(2.7-5.4 mg·L^(-1)),and Ni^(2+)(0.2705-0.541 mg·L^(-1))ions at pH of 8.8-9.1 and 20-60℃.The as-synthesized sodium trititanate nanorods were characterized by XRD,HRTEM,N2 adsorption/desorption,SEM,EDX,and zeta potential techniques.The concentrations of heavy metal ions in wastewater were analyzed by ICP technique.After in situ oxidative adsorption treatment under the concentrations of 25 g·L^(-1) for sodium hypochlorite and 125 mg·L^(-1) for sodium trititanate nanorods at 60℃ for 5 h,the heavy metal ion concentrations could be reduced from initial value of 2.6 to final value of 1.92 mg·L^(-1) for Cr(Ⅵ),3.6 to 0.17 mg·L^(-1) for Cu^(2+),and from 0.2705 to 0.097 mg·L^(-1) for Ni^(2+),respectively.Cr(Ⅵ),Cu^(2+) and Ni^(2+) ions could be effectively removed by the in situ oxidative adsorption method.The in situ oxidative adsorption processes of Cr(Ⅵ),Cu^(2+) and Ni^(2+) ions are satisfactorily simulated by the pseudo-second order adsorption kinetics and Langmuir adsorption isotherm,respectively.Adsorption thermodynamics analyses reveal that the oxidative adsorption processes of Cr(Ⅵ),Cu^(2+) and Ni^(2+) ions are spontaneous and endothermic.The oxidation degree of metalcontained complexes influences the values of thermodynamics functions. 展开更多
关键词 heavy metals Oxidative adsorption Electroplating wastewater Sodium trititanate nanorods Nanomaterials Oxidation
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Release characteristics and stabilization of heavy metals in antimony tailings in Yunnan Province,China
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作者 LUO Guangfei ZHANG Jin +2 位作者 HAN Zhiwei OUYANG Jidi WU Pan 《Journal of Mountain Science》 SCIE CSCD 2024年第10期3337-3352,共16页
The pollution caused by the mining and smelting of heavy metals is becoming an increasingly severe environmental problem.In this study,the environmental risks of mine tailings were explored using typical antimony tail... The pollution caused by the mining and smelting of heavy metals is becoming an increasingly severe environmental problem.In this study,the environmental risks of mine tailings were explored using typical antimony tailings(the depth of the sample taken from the ground to the deepest position of 120 cm)from the Zuoxiguo mine in Yunnan Province,Southwest China.The tailings were examined to explore the geological background,distribution characteristics,and release characteristics of heavy metals.Additionally,stabilizer treatments for heavy metals were investigated in consideration of waste treatment.The results showed that the contents of Sb and As(8.93×103 and 425 mg/kg,respectively)in the tailings were considerably higher than the local soil background values,suggesting that these metals pose a considerable threat to the surrounding environment.The geological background values of Cr,Cd,Pb,Cu,and Zn were relatively low.The results of static release showed that Sb,As,Cd,and Cr leached from the tailings more easily than Cu,Zn,and Pb under acidic conditions(pH=2.98).Geo-accumulation indices and potential ecological risk indices showed that Sb,As,Cd,and Pb were highly enriched in the tailings,whereas Cu,Cr,and Zn contents were relatively low.The single factor ecological risk index of the mining area showed that Sb and As are high ecological risk factors,whereas Cr,Cu,Zn,Cd,and Pb are not.The results of the orthogonal test results showed that by adding 15.0%(m/m)fly ash and 15.0%(m/m)zeolite powder to the quicklime and curing for 28 d,a significant stabilization effect was observed for Sb,As,and Pb.This study helps determine the priority control components for characteristic heavy metals in antimony tailings,and provides valuable insights regarding the formulation of appropriate mitigation strategies. 展开更多
关键词 heavy metals Antimony mine Tailing dumps Environmental pollution Release characteristics Stabilization efficiency
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Analysis and Assessment on the Heavy Metals in a Severely Degraded Subtropical Red Soil Region
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作者 Fang Wang Yun Zhou +5 位作者 Xiangping Fu Yuxiao Zhao Yiyao Wen Xintao Cui Shunbao Lu Yanjie Zhang 《American Journal of Plant Sciences》 CAS 2024年第2期110-121,共12页
5 different forests of Pinus massoniana, Schima superba, Liquidambar formosana, P. massoniana × S. superba, P. massoniana × L. formosana as the research object were set up to study the Cr, Cu and Zn content ... 5 different forests of Pinus massoniana, Schima superba, Liquidambar formosana, P. massoniana × S. superba, P. massoniana × L. formosana as the research object were set up to study the Cr, Cu and Zn content of degraded red soil region in subtropics. The soil heavy metal pollution degree was evaluated by national environmental quality standard (II class). The results showed that three soil metals of P. massoniana × S. superba were the highest, and the soil metals enrichment ability was strong. The order of single factor pollution index of metal elements was Cu (1.38) > Cr (0.81) > Zn (0.42), and moderately pollution, pollution warning and no pollution, respectively. There was no significant correlation between three soil heavy metals and soil total carbon (TC), total nitrogen (TN) and total phosphorus (TP). These results suggested that the accumulation of heavy metal elements was not derived from the parent material of soil. There was a significant positive correlation between the three metal elements which indicated that the sources of the three elements were similar. The structural equation model showed that the direct and indirect effects among the influencing factors ultimately affected the activity of heavy metals by cascade effects. 展开更多
关键词 Subtropical Forest Type Degraded Red Soil heavy metals Pollution Evaluation
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Use of oilseed crops biomass for heavy metal treatment in water
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作者 Carlos Pena-Guzman Angela Otalvaro-Alvarez Tatiana Jimenez-Ariza 《Oil Crop Science》 CSCD 2024年第3期177-186,共10页
The treatment of heavy metals in water is of high importance worldwide,and different treatment types have been developed.The use of plant material is becoming more and more important,and oilseed crops biomass have bee... The treatment of heavy metals in water is of high importance worldwide,and different treatment types have been developed.The use of plant material is becoming more and more important,and oilseed crops biomass have been investigated in terms of phytoremediation and biosorption processes.This article is a review of the literature reporting the applications in 10 different plants and evaluating the removal efficiencies for 12 metals,including the findings of 81 publications.Moringa olifera and Helianthus annuus are the most studied plants,whereas Cu(21.9%),Cd(18.5%),and Pb(19.9%)are the most studied metals.As a result,it was found that more than 90%of Pb,Cu,Cd,Fe,Zn,Ni,Cr,Sr and Mn showed removals in their experiments.At the same time,the variables most related to the efficiency of metal removal are pH,temperature,and contact time.This article includes a review of the biosorption isotherms used in the different studies. 展开更多
关键词 Oilseed crops PHYTOREMEDIATION BIOSORPTION heavy metals
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Leaching Behavior and Mechanism of Cement Solidified Heavy Metal Pb in Acid Medium 被引量:1
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作者 周明凯 王彩萍 +1 位作者 CHEN Yan CHEN Xiao 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2015年第4期781-786,共6页
The relationship between Pb leaching concentration and the solution's pH with time was analyzed when cement in its solidified form was leached in an acid medium. The effects of the particle size of the solidified for... The relationship between Pb leaching concentration and the solution's pH with time was analyzed when cement in its solidified form was leached in an acid medium. The effects of the particle size of the solidified form, the cement adding method, and the hydration degree on Pb solidification were also investigated. The experimental results indicate that cement is quickly dissolved and hydrated in the acid medium, forming a C-S-H gel or silicic acid sol with good adsorption. When cement-Pb solidified form is leached in an acetate solution, the hydrated product erodes with time, so the Pb concentration increases slightly in the beginning. Then, some of the Pb ions are absorbed by the newly generated silicic acid sol, C-S-H. Others produce Pb(OH)2 precipitation for secondary solidification, leading to a gradual decrease in the Pb concentration in a leaching time of more than two hours. Moreover, the particle size of the solidified form has important effects on the Pb dissolution. When the amount of added cement is low, with a pH of less than 9.5, the solidification affects the sequence of the original cement powder, the cement hydrated powder, and the cement- Pb solidified form. When the added amount of cement increases with a pH of more than 11, the effect of adding methods on solidification decreases, and the solidified form is a little better than others. 展开更多
关键词 CEMENT acid medium heavy metal leaching behavior
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Separation of halogens and recovery of heavy metals from secondary copper smelting dust
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作者 Zhi-lou LIU Zhi-kang CHEN +7 位作者 Fu-ze SUN Zhi-heng ZHANG Kang YAN Shui-ping ZHONG Hui LIU Rui-xiang WANG Jia-yuan LI Zhi-feng XU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第8期2686-2701,共16页
The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasib... The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasibility of the phase transformation to metal sulfates and to gaseous HF and HCl.Under the sulfating roasting conditions of the roasting temperature of 250℃ and the sulfuric acid excess coefficient of 1.8,over 74 wt.%of F and 98 wt.%of Cl were volatilized into flue gas.Approximately 98.6 wt.%of Zn and 96.5 wt.%of Cu in the roasting product were dissolved into the leaching solution after the water leaching process,while the leaching efficiencies of Pb and Sn were only 0.12%and 0.22%,respectively.The mechanism studies indicate the pivotal effect of roasting temperature on the sulphation reactions from various metal species to metal sulfates and the salting out reactions from various metal halides to gaseous hydrogen halides. 展开更多
关键词 secondary copper smelting dust sulfating roasting water leaching halogen volatilization heavy metal separation
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Assessment of heavy metals in sediment in a heavily polluted urban river in the Chaohu Basin, China 被引量:3
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作者 邵世光 薛联青 +4 位作者 刘成 商景阁 王兆德 何翔 范成新 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2016年第3期526-538,共13页
The Nanfei River (Anhui Province, China) is a severely polluted urban river that flows into Chaohu Lake. In the present study, sediments were collected from the river and analyzed for their heavy metal contents. Mul... The Nanfei River (Anhui Province, China) is a severely polluted urban river that flows into Chaohu Lake. In the present study, sediments were collected from the river and analyzed for their heavy metal contents. Multivariate statistics and the fuzzy comprehensive assessment method were used to determine the sources of pollution, the current pollution status, and spatial and temporal variations in heavy metal pollution in sediments. The concentrations of arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb), and zinc (Zn) in sediments ranged from 5.67-113, 0.08-40.2, 41.6-524, 15.5-460, 0.03-4.84, 13.5-180, 18.8-250, and 47.9-1 996 mg/kg, and the average concentrations of each metal were 1.7, 38.7, 1.8, 5.5, l 8.8, 1.3, 2.5, and 11.1 times greater than the background values, respectively. Multivariate statistical analysis demonstrated that Hg, Cu, Cr, Cd, and Ni may have originated from industrial activities, whereas As and Pb came from agricultural activities. The fuzzy comprehensive assessment method, based on the fuzzy mathematics theory, was used to obtain a detailed assessment of the sediment quality in the Nanfei River watershed. The results indicated that the pollution was moderate in the downstream tributaries of the Nianbu and Dianbu Rivers, but was severe in the main channel of the Nanfei River and in the upstream tributaries of the Sill and Banqiao Rivers. Therefore, sediments in the Nanfei River watershed are heavily polluted and urgent measures should be taken to remedy the status. 展开更多
关键词 fuzzy comprehensive assessment (FCA) heavy metal pollution changing process distribution characteristics Nanfei River SEDIMENT
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