The comprehensive improvement strategy of intra-county environment pollution in the city and countryside was searched.By the research method which combined the microscopic view,the macroscopic view with the dynamic pe...The comprehensive improvement strategy of intra-county environment pollution in the city and countryside was searched.By the research method which combined the microscopic view,the macroscopic view with the dynamic perspective,the seriousness of rural water quality,soil and atmospheric pollution in Xiangxiang,Xiangtan and the surrounding areas in Shaoshan irrigated area was revealed.The control measure which was 'four-dimensional pollution in the city and countryside'—— low-carbon-high-value agriculture and the technology innovation was proposed.The low-carbon-high-value technology innovation industrialization demonstration in three parts which included the pre-production,mid-production and post-production deep-processing of cultivation and breeding industry in the ecological cyclic agricultural garden in Shaoshan irrigated area was the driving force.We tried to propel the low-carbon ecological cultivation and breeding industry which included the paddy rice,grass,tree,medicinal herbs and pig,cow,chick,duck,fish.We wanted to relieve the structural unbalance of previous cultivation and breeding industry,'cheap grain hurting the farmers' and the short-leg problem of social-economic-ecological benefit.The results showed that the low-carbon-high-value agricultural system was a poly-generation technology system which promoted the multi-level and grading utilization,saved the energy,reduced the consumption and cleaned the production based on the ecology.展开更多
A suitable carburized microstructure with fine granular dispersed carbides in hypereutectoid zone,ultra fine martensite in matrix and recrystallized austenite to be refined to the grain size of 12~14 has been obtaine...A suitable carburized microstructure with fine granular dispersed carbides in hypereutectoid zone,ultra fine martensite in matrix and recrystallized austenite to be refined to the grain size of 12~14 has been obtained by a new process,which is a high carbon concentration carburizing with rare earth element at low temperature(860~880℃)in a discontinuous gas carburization furnace.There was not much difference for the microstructure in eutectic zone between this and conventional process.Forming mechanism of granular carbides has been also studied in this paper.展开更多
The effect of high pressure heat treatment on microstructure and compressive properties of low carbon steel were investigated by optical microscope,transmission electron microscope,hardness tester and compression test...The effect of high pressure heat treatment on microstructure and compressive properties of low carbon steel were investigated by optical microscope,transmission electron microscope,hardness tester and compression test methods.The results show that martensite appears in low carbon steel at 1-5GPa GPa and 950°C for 15 minutes treatment,high pressure heat treatment can improve the hardness and compressive properties of the steel,the yield strength of the steel increases with increasing pressure,and its compressive properties are better than that treated under normal pressure quenching.展开更多
The effect of fast cooling rate on the microstructure and mechanical properties of low-carbon high-strength steel annealed in the intercritical region was investigated using a Gleeble 1500 thermomechanical simulator a...The effect of fast cooling rate on the microstructure and mechanical properties of low-carbon high-strength steel annealed in the intercritical region was investigated using a Gleeble 1500 thermomechanical simulator and a continuous annealing thermomeehanical simulator. The results showed that the microstructure consisted of ferrite and bainite as the main phases with a small amount of retained austenite and martensite islands at cooling rate of 5 and 50 ℃/s, respectively. Fast cooling after continuous annealing affected all constituents of the microstructure. The mechanical properties were improved considerably. Ultimate tensile strength (U-TS) increased and total elongation (TEL) decreased with increasing cooling rate in all specimens. The specimen 1 at a cooling rate of 5 ℃/s exhibited the maximum TEL and UTSxTEL (20% and 27 200 MPa%, respectively) because of the competition between weakening by presence of the retained austenite plus the carbon indigence by carbide precipitation, and strengthening by martensitic islands and precipitation. The maximum UTS and YS (1 450 and 951 MPa, respectively) were obtained for specimen 2 at a cooling rate of 50 ℃/s. This is attributed to the effect of dispersion strengthening of finer martensite islands and the effect of precipitation strengthening of carbide precipitates.展开更多
For better processing performance of high carbon low alloy steel wire rod,an investigation about the influence of cementite lamellar spacing on wire 'easy drawing' performance is completed.It is pointed out th...For better processing performance of high carbon low alloy steel wire rod,an investigation about the influence of cementite lamellar spacing on wire 'easy drawing' performance is completed.It is pointed out that too thin cementite lamellar spacing(<80 um) reduces the strain hardening level of wire drawing, and reduce the torsion performance of drawn wire at same time.For the wire or wire rod from industrial production,compared with the micro-structure with troostite,the micro-structure with sorbite or sorbite mixed with pearlite is more suitable to the drawing process with high reduction ratio.展开更多
The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper....The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper. The achievements fully satisfeid the technical requirements of the large 700 MW stainless steel hydraulic turbine runner for the Three Gorges Hydropower Station, and become the major technical support for the design and manufacture of the largest 700 MW hydraulic turbine generator unit in the world developed through our own efforts. The characteristics of a new high yield to tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel with ultra low carbon and high cleanliness are also described. Over the next ten years, the large martensitic stainless steel castings and advanced manufacturing technologies will see a huge demand in clean energy industry such as nuclear power, hydraulic power at home and abroad. Therefore, the new high yield o tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel materials, the fast and flexible manufacturing technologies of large size castings, and new environment friendly sustainable process will face new challenges and opportunities.展开更多
The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic micr...The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic microscpe, chemical analysis etc. The result shows that the technology of carburizing in liquid cast-iron can expedite caburization distinctly and changes the carburizing layer structure. The carburizing rate is 60~80 times of that of the traditional technology, and there is about 43% decrease in the activation energy compared with gas-carburization. In outer structure layer, cementite is formed simultaneously both on the crystal boundary reticularly and inside the crystal grains stripedly. In inner carburizing layer, there is undissolved blocky ferrite in reticular cementite. Besides, rare earth element can expedite carburization process.展开更多
In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carb...In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carburized layer was also analyzed. The results show that the carburizing rate of low-carbon steel at high-temperature and short-term is so fast, and the microstructure of carburized layer possess higher carbon content, and cementite, pearlite and ferrite exist in carburized layer structure simultaneously. Besides, the kinetic equations of permeating layer forming have been presented, and the carburizing mechanism was preliminary discussed also.展开更多
Based on the low-carbon and high-value methodology of chemical ecology and chemical informatics,combining theory and methods,taking saving,environmental protection,low carbon,high production,high value and circulation...Based on the low-carbon and high-value methodology of chemical ecology and chemical informatics,combining theory and methods,taking saving,environmental protection,low carbon,high production,high value and circulation as values and aims,the relationship between human and land as a basis,ecosystem as a center,overall control as a goal and agricultural ecological engineering as a mean,environmental pollution detection,as one of bottlenecks for agricultural products and food security,should be solved firstly;through the field survey in dry years from 2009 to 2010 when drought and flood were frequent and the frequency of drought was higher than that of flood,plus the determination of surface water flow and water quantity in a small typical river basin,the correlation of local water,soil and gas in the county could be found,and the transfer of monitoring focus from water environment to atmospheric environment was possible and necessary.The study would promote the quantitative research on the correlation among water,soil and gas,and the results were in accordance with the conclusions of related studies.展开更多
Electrode materials have an important effect on the property of microbial fuel cell(MFC). Carbon foam is utilized as an anode and further modified by urea to improve its performance in marine benthic microbial fuel ce...Electrode materials have an important effect on the property of microbial fuel cell(MFC). Carbon foam is utilized as an anode and further modified by urea to improve its performance in marine benthic microbial fuel cell(BMFC) with higher voltage and output power. The electrochemical properties of plain carbon foam(PC) and urea-modified carbon foam(UC) are measured respectively. Results show that the UC obtains better wettability after its modification and higher anti-polarization ability than the PC. A novel phenomenon has been found that the electrical potential of the modified UC anode is nearly 100 m V lower than that of the PC, reaching-570 ±10 m V(vs. SCE), and that it also has a much higher electron transfer kinetic activity, reaching 9399.4 m W m-2, which is 566.2-fold higher than that from plain graphite anode(PG). The fuel cell containing the UC anode has the maximum power density(256.0 m W m-2) among the three different BMFCs. Urea would enhance the bacteria biofilm formation with a more diverse microbial community and maintain more electrons, leading to a lower anodic redox potential and higher power output. The paper primarily analyzes why the electrical potential of the modified anode becomes much lower than that of others after urea modification. These results can be utilized to construct a novel BMFC with higher output power and to design the conditioner of voltage booster with a higher conversion ratio. Finally, the carbon foam with a bigger pore size would be a potential anodic material in conventional MFC.展开更多
Polymer-based EOR methods in low-permeability reservoirs face injectivity issues and increased fracturing due to near wellbore plugging,as well as high-pressure gradients in these reservoirs.Polymer may cause pore blo...Polymer-based EOR methods in low-permeability reservoirs face injectivity issues and increased fracturing due to near wellbore plugging,as well as high-pressure gradients in these reservoirs.Polymer may cause pore blockage and undergo shear degradation and even oxidative degradation at high temperatures in the presence of very hard brine.Low-tension gas(LTG) flooding has the potential to be applied successfully for low-permeability carbonate reservoirs even in the presence of high formation brine salinity.In LTG flooding,the interfacial tension between oil and water is reduced to ultra-low values(10^-3 dyne/cm) by injecting an optimized surfactant formulation to maximize mobilization of residual oil post-waterflood.Gas(nitrogen,hydrocarbon gases or C02) is co-injected along with the surfactant slug to generate in situ foam which reduces the mobility ratio between the displaced(oil) and displacing phases,thus improving the displacement efficiency of the oil.In this work,the mechanism governing LTG flooding in low-permeability,high-salinity reservoirs was studied at a microscopic level using microemulsion properties and on a macroscopic scale by laboratory-scale coreflooding experiments.The main injection parameters studied were injected slug salinity and the interrelation between surfactant concentration and injected foam quality,and how they influence oil mobilization and displacement efficiency.Qualitative assessment of the results was performed by studying oil recovery,oil fractional flow,oil bank breakthrough and effluent salinity and pressure drop characteristics.展开更多
In this paper, a new carbon fiber based cathode — a low-outgassing-rate carbon fiber array cathode — is investigated experimentally, and the experimental results are compared with those of a polymer velvet cathode. ...In this paper, a new carbon fiber based cathode — a low-outgassing-rate carbon fiber array cathode — is investigated experimentally, and the experimental results are compared with those of a polymer velvet cathode. The carbon fiber array cathode is constructed by inserting bunches of carbon fibers into the cylindrical surface of the cathode. In experiment, the diode base pressure is maintained at 1×10^(-2) Pa–2×10^(-2) Pa, and the diode is driven by a compact pulsed power system which can provide a diode voltage of about 100 kV and pulse duration of about 30 ns at a repetition rate of tens of Hz.Real-time pressure data are measured by a magnetron gauge. Under the similar conditions, the experimental results show that the outgassing rate of the carbon fiber array cathode is an order smaller than that of the velvet cathode and that this carbon fiber array cathode has better shot-to-shot stability than the velvet cathode. Hence, this carbon fiber array cathode is demonstrated to be a promising cathode for the radial diode, which can be used in magnetically insulated transmission line oscillator(MILO) and relativistic magnetron(RM).展开更多
基金Supported by " Research on The Control Technology of Subtropical Agriculture Pollution System" Special Project of National Environment Protection Public Welfare Industry Science Research "Research on The Construction Strategy of Ecological Civilization" Development Plan Research Project of State Development and Reform Commission+1 种基金Xiangxiang " High-output and Efficient Cultivation of High Quality Rice and Processing Technology Industrialization Demonstration " in The Plan Test Site of National Science and Technology Enriching People and Developing County Special Project Action" Xiangxiang Middle and Long-term Development Plan of Modern Agriculture" of Subtropical Agriculture Ecology Institute in Chinese Academy of Science
文摘The comprehensive improvement strategy of intra-county environment pollution in the city and countryside was searched.By the research method which combined the microscopic view,the macroscopic view with the dynamic perspective,the seriousness of rural water quality,soil and atmospheric pollution in Xiangxiang,Xiangtan and the surrounding areas in Shaoshan irrigated area was revealed.The control measure which was 'four-dimensional pollution in the city and countryside'—— low-carbon-high-value agriculture and the technology innovation was proposed.The low-carbon-high-value technology innovation industrialization demonstration in three parts which included the pre-production,mid-production and post-production deep-processing of cultivation and breeding industry in the ecological cyclic agricultural garden in Shaoshan irrigated area was the driving force.We tried to propel the low-carbon ecological cultivation and breeding industry which included the paddy rice,grass,tree,medicinal herbs and pig,cow,chick,duck,fish.We wanted to relieve the structural unbalance of previous cultivation and breeding industry,'cheap grain hurting the farmers' and the short-leg problem of social-economic-ecological benefit.The results showed that the low-carbon-high-value agricultural system was a poly-generation technology system which promoted the multi-level and grading utilization,saved the energy,reduced the consumption and cleaned the production based on the ecology.
文摘A suitable carburized microstructure with fine granular dispersed carbides in hypereutectoid zone,ultra fine martensite in matrix and recrystallized austenite to be refined to the grain size of 12~14 has been obtained by a new process,which is a high carbon concentration carburizing with rare earth element at low temperature(860~880℃)in a discontinuous gas carburization furnace.There was not much difference for the microstructure in eutectic zone between this and conventional process.Forming mechanism of granular carbides has been also studied in this paper.
文摘The effect of high pressure heat treatment on microstructure and compressive properties of low carbon steel were investigated by optical microscope,transmission electron microscope,hardness tester and compression test methods.The results show that martensite appears in low carbon steel at 1-5GPa GPa and 950°C for 15 minutes treatment,high pressure heat treatment can improve the hardness and compressive properties of the steel,the yield strength of the steel increases with increasing pressure,and its compressive properties are better than that treated under normal pressure quenching.
基金Sponsored by National Natural Science Foundation of China(No.51004037)Shenyang City Application Basic Research Project(No.F13-316-1-15)
文摘The effect of fast cooling rate on the microstructure and mechanical properties of low-carbon high-strength steel annealed in the intercritical region was investigated using a Gleeble 1500 thermomechanical simulator and a continuous annealing thermomeehanical simulator. The results showed that the microstructure consisted of ferrite and bainite as the main phases with a small amount of retained austenite and martensite islands at cooling rate of 5 and 50 ℃/s, respectively. Fast cooling after continuous annealing affected all constituents of the microstructure. The mechanical properties were improved considerably. Ultimate tensile strength (U-TS) increased and total elongation (TEL) decreased with increasing cooling rate in all specimens. The specimen 1 at a cooling rate of 5 ℃/s exhibited the maximum TEL and UTSxTEL (20% and 27 200 MPa%, respectively) because of the competition between weakening by presence of the retained austenite plus the carbon indigence by carbide precipitation, and strengthening by martensitic islands and precipitation. The maximum UTS and YS (1 450 and 951 MPa, respectively) were obtained for specimen 2 at a cooling rate of 50 ℃/s. This is attributed to the effect of dispersion strengthening of finer martensite islands and the effect of precipitation strengthening of carbide precipitates.
文摘For better processing performance of high carbon low alloy steel wire rod,an investigation about the influence of cementite lamellar spacing on wire 'easy drawing' performance is completed.It is pointed out that too thin cementite lamellar spacing(<80 um) reduces the strain hardening level of wire drawing, and reduce the torsion performance of drawn wire at same time.For the wire or wire rod from industrial production,compared with the micro-structure with troostite,the micro-structure with sorbite or sorbite mixed with pearlite is more suitable to the drawing process with high reduction ratio.
文摘The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper. The achievements fully satisfeid the technical requirements of the large 700 MW stainless steel hydraulic turbine runner for the Three Gorges Hydropower Station, and become the major technical support for the design and manufacture of the largest 700 MW hydraulic turbine generator unit in the world developed through our own efforts. The characteristics of a new high yield to tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel with ultra low carbon and high cleanliness are also described. Over the next ten years, the large martensitic stainless steel castings and advanced manufacturing technologies will see a huge demand in clean energy industry such as nuclear power, hydraulic power at home and abroad. Therefore, the new high yield o tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel materials, the fast and flexible manufacturing technologies of large size castings, and new environment friendly sustainable process will face new challenges and opportunities.
文摘The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic microscpe, chemical analysis etc. The result shows that the technology of carburizing in liquid cast-iron can expedite caburization distinctly and changes the carburizing layer structure. The carburizing rate is 60~80 times of that of the traditional technology, and there is about 43% decrease in the activation energy compared with gas-carburization. In outer structure layer, cementite is formed simultaneously both on the crystal boundary reticularly and inside the crystal grains stripedly. In inner carburizing layer, there is undissolved blocky ferrite in reticular cementite. Besides, rare earth element can expedite carburization process.
文摘In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carburized layer was also analyzed. The results show that the carburizing rate of low-carbon steel at high-temperature and short-term is so fast, and the microstructure of carburized layer possess higher carbon content, and cementite, pearlite and ferrite exist in carburized layer structure simultaneously. Besides, the kinetic equations of permeating layer forming have been presented, and the carburizing mechanism was preliminary discussed also.
基金Supported by Specific Research Project for National Environmental Public Welfare Industry " Study on the Control Technology of Agricultural Pollution System in the Subtropical Zone"Postdoctoral Science Foundation of Central South University
文摘Based on the low-carbon and high-value methodology of chemical ecology and chemical informatics,combining theory and methods,taking saving,environmental protection,low carbon,high production,high value and circulation as values and aims,the relationship between human and land as a basis,ecosystem as a center,overall control as a goal and agricultural ecological engineering as a mean,environmental pollution detection,as one of bottlenecks for agricultural products and food security,should be solved firstly;through the field survey in dry years from 2009 to 2010 when drought and flood were frequent and the frequency of drought was higher than that of flood,plus the determination of surface water flow and water quantity in a small typical river basin,the correlation of local water,soil and gas in the county could be found,and the transfer of monitoring focus from water environment to atmospheric environment was possible and necessary.The study would promote the quantitative research on the correlation among water,soil and gas,and the results were in accordance with the conclusions of related studies.
基金supported by the Key Project of Natural Science Fund of Shandong Province,China(ZR2011 BZ008)the Special Fund of Marine Renewable Energy from State Ocean Bureau,China(GHME2011GD 04)
文摘Electrode materials have an important effect on the property of microbial fuel cell(MFC). Carbon foam is utilized as an anode and further modified by urea to improve its performance in marine benthic microbial fuel cell(BMFC) with higher voltage and output power. The electrochemical properties of plain carbon foam(PC) and urea-modified carbon foam(UC) are measured respectively. Results show that the UC obtains better wettability after its modification and higher anti-polarization ability than the PC. A novel phenomenon has been found that the electrical potential of the modified UC anode is nearly 100 m V lower than that of the PC, reaching-570 ±10 m V(vs. SCE), and that it also has a much higher electron transfer kinetic activity, reaching 9399.4 m W m-2, which is 566.2-fold higher than that from plain graphite anode(PG). The fuel cell containing the UC anode has the maximum power density(256.0 m W m-2) among the three different BMFCs. Urea would enhance the bacteria biofilm formation with a more diverse microbial community and maintain more electrons, leading to a lower anodic redox potential and higher power output. The paper primarily analyzes why the electrical potential of the modified anode becomes much lower than that of others after urea modification. These results can be utilized to construct a novel BMFC with higher output power and to design the conditioner of voltage booster with a higher conversion ratio. Finally, the carbon foam with a bigger pore size would be a potential anodic material in conventional MFC.
基金supported by Petroleum Development Oman and Shell Global Solutions International。
文摘Polymer-based EOR methods in low-permeability reservoirs face injectivity issues and increased fracturing due to near wellbore plugging,as well as high-pressure gradients in these reservoirs.Polymer may cause pore blockage and undergo shear degradation and even oxidative degradation at high temperatures in the presence of very hard brine.Low-tension gas(LTG) flooding has the potential to be applied successfully for low-permeability carbonate reservoirs even in the presence of high formation brine salinity.In LTG flooding,the interfacial tension between oil and water is reduced to ultra-low values(10^-3 dyne/cm) by injecting an optimized surfactant formulation to maximize mobilization of residual oil post-waterflood.Gas(nitrogen,hydrocarbon gases or C02) is co-injected along with the surfactant slug to generate in situ foam which reduces the mobility ratio between the displaced(oil) and displacing phases,thus improving the displacement efficiency of the oil.In this work,the mechanism governing LTG flooding in low-permeability,high-salinity reservoirs was studied at a microscopic level using microemulsion properties and on a macroscopic scale by laboratory-scale coreflooding experiments.The main injection parameters studied were injected slug salinity and the interrelation between surfactant concentration and injected foam quality,and how they influence oil mobilization and displacement efficiency.Qualitative assessment of the results was performed by studying oil recovery,oil fractional flow,oil bank breakthrough and effluent salinity and pressure drop characteristics.
基金Project supported by the National Natural Science Foundation of China(Grant No.61671457)
文摘In this paper, a new carbon fiber based cathode — a low-outgassing-rate carbon fiber array cathode — is investigated experimentally, and the experimental results are compared with those of a polymer velvet cathode. The carbon fiber array cathode is constructed by inserting bunches of carbon fibers into the cylindrical surface of the cathode. In experiment, the diode base pressure is maintained at 1×10^(-2) Pa–2×10^(-2) Pa, and the diode is driven by a compact pulsed power system which can provide a diode voltage of about 100 kV and pulse duration of about 30 ns at a repetition rate of tens of Hz.Real-time pressure data are measured by a magnetron gauge. Under the similar conditions, the experimental results show that the outgassing rate of the carbon fiber array cathode is an order smaller than that of the velvet cathode and that this carbon fiber array cathode has better shot-to-shot stability than the velvet cathode. Hence, this carbon fiber array cathode is demonstrated to be a promising cathode for the radial diode, which can be used in magnetically insulated transmission line oscillator(MILO) and relativistic magnetron(RM).