Electronic textiles hold the merits of high conformability with the human body and natural surrounding,possessing large market demand and wide application foreground in smart wearable and portable devices.However,thei...Electronic textiles hold the merits of high conformability with the human body and natural surrounding,possessing large market demand and wide application foreground in smart wearable and portable devices.However,their further application is largely hindered by the shortage of flexible and stable power sources with multifunctional designability.Herein,a free-standing ZnHCF@CF electrode(ZnHCF grown on carbon nanotube fiber)with good mechanical deformability and high electrochemical performance for aqueous fiber-shaped calcium ion battery(FCIB)is reported.Benefiting from the unique Ca^(2+)/H^(+)co-insertion mechanism,the ZnHCF@CF cathode can exhibit great ion storage capability within a broadened voltage window.By pairing with a polyaniline(PANI)@CF anode,a ZnHCF@CF//PANI@CF FCIB is successfully fabricated,which exhibits a desirable volumetric energy density of 43.2mWh cm^(-3)and maintains superior electrochemical properties under different deformations.Moreover,the high-energy FCIB can be harmoniously integrated with a fiber-shaped strain sensor(FSS)to achieve real-time physiological monitoring on knees during long-running,exhibiting great promise for the practical application of electronic textiles.展开更多
Geometries, energies, and vibrational frequencies for two C4N12O4 isomers with pagodane- and isopagodane-like structures have been calculated at the B3LYP/6-31G＊ level.Isomers 1 and 2 are of D2h and D2d symmetry, res...Geometries, energies, and vibrational frequencies for two C4N12O4 isomers with pagodane- and isopagodane-like structures have been calculated at the B3LYP/6-31G＊ level.Isomers 1 and 2 are of D2h and D2d symmetry, respectively. Heats of formation for the two C4N12O4 isomers have been estimated in this paper, indicating they would be reasonable candidates for high energy density materials.展开更多
特高压直流GIL运行可靠性取决于内绝缘设计的可靠性。此外,导电元件直流电流密度的取值、弹簧触头的定位设计、GIL各元件中的绝缘件与金具连接处的楔形气隙的处理以及母线中支撑件的结构设计细节,都会对产品运行可靠性产生重大影响,不...特高压直流GIL运行可靠性取决于内绝缘设计的可靠性。此外,导电元件直流电流密度的取值、弹簧触头的定位设计、GIL各元件中的绝缘件与金具连接处的楔形气隙的处理以及母线中支撑件的结构设计细节,都会对产品运行可靠性产生重大影响,不能忽视。对于运行环境十分严酷的UHV DC GIL为保证内绝缘工作可靠性和减少气体维护工作量,文中还提出了高气密性结构设计。为适应-50℃低温运行要求,产品选用了液化温度很低的N_(2)/SF_(6)混合气体,对两种气体的配比,压力特性和绝缘特性进行了讨论与计算。还有产品的局放、气体密度及微水含量的监视系统的可靠性设计,都会对产品运行可靠性产生直接影响。文中对上述问题的研究成果作了介绍,可供高压直流产品设计使用。对其中未解的新技术如基于冷镜露点测试原理、微机电技术制作的智能气体湿度和密度监测装置、高压直流复合绝缘套管伞面局放起始场强提出了研究方案。文中提出的诸多GIL运行可靠性设计要点,对于其他超/特高压直流气体绝缘电器可参考选用。展开更多
基金partially supported by the Natural Science Foundation of Liaoning Province(2023-MS-115)the Large Instrument and Equipment Open Foundation of Dalian University of Technology+1 种基金the National Natural Science Foundation of China(22308261)funding from the Fundamental Research Funds for the Central Universities,conducted at Tongji University。
文摘Electronic textiles hold the merits of high conformability with the human body and natural surrounding,possessing large market demand and wide application foreground in smart wearable and portable devices.However,their further application is largely hindered by the shortage of flexible and stable power sources with multifunctional designability.Herein,a free-standing ZnHCF@CF electrode(ZnHCF grown on carbon nanotube fiber)with good mechanical deformability and high electrochemical performance for aqueous fiber-shaped calcium ion battery(FCIB)is reported.Benefiting from the unique Ca^(2+)/H^(+)co-insertion mechanism,the ZnHCF@CF cathode can exhibit great ion storage capability within a broadened voltage window.By pairing with a polyaniline(PANI)@CF anode,a ZnHCF@CF//PANI@CF FCIB is successfully fabricated,which exhibits a desirable volumetric energy density of 43.2mWh cm^(-3)and maintains superior electrochemical properties under different deformations.Moreover,the high-energy FCIB can be harmoniously integrated with a fiber-shaped strain sensor(FSS)to achieve real-time physiological monitoring on knees during long-running,exhibiting great promise for the practical application of electronic textiles.
基金This work was supported by the Natural Science Foundation of Shandong Province (Y2002G11)
文摘Geometries, energies, and vibrational frequencies for two C4N12O4 isomers with pagodane- and isopagodane-like structures have been calculated at the B3LYP/6-31G＊ level.Isomers 1 and 2 are of D2h and D2d symmetry, respectively. Heats of formation for the two C4N12O4 isomers have been estimated in this paper, indicating they would be reasonable candidates for high energy density materials.
文摘特高压直流GIL运行可靠性取决于内绝缘设计的可靠性。此外,导电元件直流电流密度的取值、弹簧触头的定位设计、GIL各元件中的绝缘件与金具连接处的楔形气隙的处理以及母线中支撑件的结构设计细节,都会对产品运行可靠性产生重大影响,不能忽视。对于运行环境十分严酷的UHV DC GIL为保证内绝缘工作可靠性和减少气体维护工作量,文中还提出了高气密性结构设计。为适应-50℃低温运行要求,产品选用了液化温度很低的N_(2)/SF_(6)混合气体,对两种气体的配比,压力特性和绝缘特性进行了讨论与计算。还有产品的局放、气体密度及微水含量的监视系统的可靠性设计,都会对产品运行可靠性产生直接影响。文中对上述问题的研究成果作了介绍,可供高压直流产品设计使用。对其中未解的新技术如基于冷镜露点测试原理、微机电技术制作的智能气体湿度和密度监测装置、高压直流复合绝缘套管伞面局放起始场强提出了研究方案。文中提出的诸多GIL运行可靠性设计要点,对于其他超/特高压直流气体绝缘电器可参考选用。
