The sulfide-based solid-state electrolytes(SEs)reactivity toward moisture and Li-metal are huge barriers that impede their large-scale manufactu ring and applications in all-solid-state lithium batteries(ASSLBs).Herei...The sulfide-based solid-state electrolytes(SEs)reactivity toward moisture and Li-metal are huge barriers that impede their large-scale manufactu ring and applications in all-solid-state lithium batteries(ASSLBs).Herein,we proposed an Al and O dual-doped strategy for Li_(3)PS_(4)SE to regulate the chemical/electrochemical stability of anionic PS_(4)^(3-)tetrahedra to mitigate structural hydrolysis and parasitic reactions at the SE/Li interface.The optimized Li_(3.08)A_(10.04)P_(0.96)S_(3.92)O_(0.08)SE presents the highestσLi+of 3.27 mS cm^(-1),which is~6.8 times higher than the pristine Li_(3)PS_(4)and excellently inhibits the structural hydrolysis for~25 min@25%humidity at RT.DFT calculations confirmed that the enhanced chemical stability was revealed to the intrinsically stable entities,e.g.,POS33-units.Moreover,Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)SE cycled stably in Li//Li symmetric cell over 1000 h@0.1 mA cm^(-2)/0.1 mA h cm^(-2),could be revealed to Li-Al alloy and Li_(2)Oat SE/Li interface impeding the growth of Li-dendrites during cycling.Resultantly,LNO@LCO/Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)/Li-In cell delivered initial discharge capacities of 129.8 mA h g^(-1)and 83.74%capacity retention over 300 cycles@0.2 C at RT.Moreover,the Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)SE presented>90%capacity retention over 200 and 300 cycles when the cell was tested with LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA)cathode material vs.5 and 10 mg cm^(-2)@RT.展开更多
The microstructure of ripening processed Cu-15%Cr alloys and deformed samples were examined under a 12T high magnetic field.The high magnetic field has accelerated the Ostwald Ripening process of Cr phase,the Cr-rich ...The microstructure of ripening processed Cu-15%Cr alloys and deformed samples were examined under a 12T high magnetic field.The high magnetic field has accelerated the Ostwald Ripening process of Cr phase,the Cr-rich particles in 12T HMF case are coarser compared with 0T case.The 12T high magnetic field increased the peak strength of Cu(111)crystal plane and Cr(110)crystal plane,and appeared to has an orientation effect.Compared with the 0T case, the 12T high magnetic field case decreased the tensile strength and hardness.展开更多
The membranes of sulfonated poly（etheretherketone） of 48.3% sulfonation degree doped with Y2O3 were prepared, and then treated with parallel high magnetic field of 6 and 12 T at 120 oC for 4 h, respectively. The sma...The membranes of sulfonated poly（etheretherketone） of 48.3% sulfonation degree doped with Y2O3 were prepared, and then treated with parallel high magnetic field of 6 and 12 T at 120 oC for 4 h, respectively. The small-angle X-ray scattering revealed that the struc- ture of the composite membranes would be changed by high magnetic field treatment. The cross-section morphology of the composite membranes by a scanning electron microscope showed that the Y2O3 could be dispersed evenly in the composite membranes which were relatively smooth and compact but formed small conglomeration with increasing Y2O3 content and treating high magnetic field. The water uptake of membranes would be reduced with Y2O3 content increasing, but not be modified by the treatment of high magnetic field. The proton conductivity of membranes would be increased with temperature rising from 20 to 60 oC, and improved under high magnetic field, which could all exceed 10–2 S/cm at 75% relative humidity, but decrease with doping content of Y2O3 from 2 wt.% to 8 wt.%. The methanol permeability of the composite membranes would be decreased with Y2O3 content increasing and slightly reduced after high magnetic field treatment.展开更多
该文介绍了中国自行研制的第一套移动式直接冷却高温超导磁储能系统(moveable conduction-cooled high temperature superconducting magnetic energy storage system,M-SMES)的工作原理、组件结构、性能实验、动模实验和现场试验。该...该文介绍了中国自行研制的第一套移动式直接冷却高温超导磁储能系统(moveable conduction-cooled high temperature superconducting magnetic energy storage system,M-SMES)的工作原理、组件结构、性能实验、动模实验和现场试验。该系统额定值为380 V/35 kJ/7 kW,包括高温超导磁体及杜瓦、制冷单元、变流器、监控单元、箱体等主要组件及其它辅助部件,可吊装至集装箱车上移动到所需的位置,通过简单接线即可投入使用。针对该系统分别进行了电力系统动态模拟实验和现场试验。各项试验结果表明:该M-SMES具有四象限功率快速调节能力,具有良好的移动性和抗震性,现场运行性能稳定,能够抑制电力系统功率振荡,稳定系统电压,在电力系统中具有良好的应用前景。展开更多
基金supported by the National Natural Science Foundation of China(Nos.21203008,21975025,12274025)the Hainan Province Science and Technology Special Fund(Nos.ZDYF2021SHFZ232,ZDYF2023GXJS022)the Hainan Province Postdoctoral Science Foundation(No.300333)。
文摘The sulfide-based solid-state electrolytes(SEs)reactivity toward moisture and Li-metal are huge barriers that impede their large-scale manufactu ring and applications in all-solid-state lithium batteries(ASSLBs).Herein,we proposed an Al and O dual-doped strategy for Li_(3)PS_(4)SE to regulate the chemical/electrochemical stability of anionic PS_(4)^(3-)tetrahedra to mitigate structural hydrolysis and parasitic reactions at the SE/Li interface.The optimized Li_(3.08)A_(10.04)P_(0.96)S_(3.92)O_(0.08)SE presents the highestσLi+of 3.27 mS cm^(-1),which is~6.8 times higher than the pristine Li_(3)PS_(4)and excellently inhibits the structural hydrolysis for~25 min@25%humidity at RT.DFT calculations confirmed that the enhanced chemical stability was revealed to the intrinsically stable entities,e.g.,POS33-units.Moreover,Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)SE cycled stably in Li//Li symmetric cell over 1000 h@0.1 mA cm^(-2)/0.1 mA h cm^(-2),could be revealed to Li-Al alloy and Li_(2)Oat SE/Li interface impeding the growth of Li-dendrites during cycling.Resultantly,LNO@LCO/Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)/Li-In cell delivered initial discharge capacities of 129.8 mA h g^(-1)and 83.74%capacity retention over 300 cycles@0.2 C at RT.Moreover,the Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)SE presented>90%capacity retention over 200 and 300 cycles when the cell was tested with LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA)cathode material vs.5 and 10 mg cm^(-2)@RT.
基金Item Sponsored by National Natural Science Foundation of China(No.50901019)China Postdoctoral Science Foundation(No.20100471458)+4 种基金Fundamental Research Funds for the Central Universities(No.N100409009)Wuhan National High Magnetic Field Center(No.WHMFCKF2011007)National Natural Science Foundation of China(No.51004038)National High-tech R&D Program of China(No.2007AA03Z519)the 111 Project of China(No.B07015)
文摘The microstructure of ripening processed Cu-15%Cr alloys and deformed samples were examined under a 12T high magnetic field.The high magnetic field has accelerated the Ostwald Ripening process of Cr phase,the Cr-rich particles in 12T HMF case are coarser compared with 0T case.The 12T high magnetic field increased the peak strength of Cu(111)crystal plane and Cr(110)crystal plane,and appeared to has an orientation effect.Compared with the 0T case, the 12T high magnetic field case decreased the tensile strength and hardness.
基金Project supported by the National Natural Science Foundation of China (50975167)Shanghai Leading Academic Discipline Project (S30107)Wenling Science and Technology Bureau ([2009]29-01-31) for continuing support on this research
文摘The membranes of sulfonated poly（etheretherketone） of 48.3% sulfonation degree doped with Y2O3 were prepared, and then treated with parallel high magnetic field of 6 and 12 T at 120 oC for 4 h, respectively. The small-angle X-ray scattering revealed that the struc- ture of the composite membranes would be changed by high magnetic field treatment. The cross-section morphology of the composite membranes by a scanning electron microscope showed that the Y2O3 could be dispersed evenly in the composite membranes which were relatively smooth and compact but formed small conglomeration with increasing Y2O3 content and treating high magnetic field. The water uptake of membranes would be reduced with Y2O3 content increasing, but not be modified by the treatment of high magnetic field. The proton conductivity of membranes would be increased with temperature rising from 20 to 60 oC, and improved under high magnetic field, which could all exceed 10–2 S/cm at 75% relative humidity, but decrease with doping content of Y2O3 from 2 wt.% to 8 wt.%. The methanol permeability of the composite membranes would be decreased with Y2O3 content increasing and slightly reduced after high magnetic field treatment.
文摘该文介绍了中国自行研制的第一套移动式直接冷却高温超导磁储能系统(moveable conduction-cooled high temperature superconducting magnetic energy storage system,M-SMES)的工作原理、组件结构、性能实验、动模实验和现场试验。该系统额定值为380 V/35 kJ/7 kW,包括高温超导磁体及杜瓦、制冷单元、变流器、监控单元、箱体等主要组件及其它辅助部件,可吊装至集装箱车上移动到所需的位置,通过简单接线即可投入使用。针对该系统分别进行了电力系统动态模拟实验和现场试验。各项试验结果表明:该M-SMES具有四象限功率快速调节能力,具有良好的移动性和抗震性,现场运行性能稳定,能够抑制电力系统功率振荡,稳定系统电压,在电力系统中具有良好的应用前景。
