INFLUENCE OF AIRCRAFT DEICER ON FREEZE-THAW DURABILITY OF HIGH PERFORMANCE CONCRETE

The influence of glycol,the main composition of the most frequently used aircraft dicer,on the freeze-thaw durability of high performance concrete（HPC）is investigated.Freeze-thaw durability of HPC is tested by accelerated freeze-thaw test.Four kinds of the solution,i.e.,tap water,3.5% NaCl solution,glycol solutions,and a LBR-A type commercial aircraft deicer are employed.Results show that freeze-thaw durability of HPC exposed to glycol solutions is closely related to the solution concentrations.The failure of HPC exposed to 3.5% glycol solution is similar to that of those exposed to 3.5% NaCl solution,i.e.,serious surface scaling.While the damage of HPC exposed to 12.5%—25% glycol solutions is postponed.Compared with glycol solution,the commercial aircraft deicer has much more negative effects on HPC freeze-thaw durability compared with 3.5% NaCl solution.In the presence of commercial aircraft deicer for HPC subjected to freeze-thaw cycles,the deterioration is mainly due to scaling and spalling.

Carbonation Resistance of Sulphoaluminate Cement-based High Performance Concrete

The influences of water/cement ratio and admixtures on carbonation resistance of sulphoaluminate cement-based high performance concrete （HPC） were investigated. The experimental results show that with the decreasing water/cement ratio, the carbonation depth of sulphoaluminate cement-based HPC is decreased remarkably, and the carbonation resistance capability is also improved with the adding admixtures. The morphologies and structure characteristics of sulphoaluminate cement hydration products before and after carbonation were analyzed using SEM and XRD. The analysis results reveal that the main hydration product of sulphoaluminate cement, that is ettringite （AFt）, decomposes after carbonation.

Preparation of High Performance Non-dispersible Concrete

A new-type underwater non-dispersible concrete admixture NDA was prepared,its function mechanism was analyzed,and C40 high performance non-dispersible underwater concrete was manufactured by applying NDA.The results indicate that NDA has a suitable workability,low strength loss,and excellent anti-dispersion;the fresh non-dispersible underwater concrete with NDA has high anti-dispersion,excellent workability such as self-compacting and not bleeding;hardened non-dispersible underwater concrete with NDA has a high strength,high durability such as high anti-abrasion,impermeability and anticorrosion.

STUDY ON OPTIMIZATION OF HIGH PERFORMANCE CONCRETE ADMIXTURES

Influences of admixtures on the workability and strength of high performance concrete （HPC） are in- vestigated. The types of investigated admixtures include naphthalene series high range water reducing agent, polycarboxlic series high range water reduce agent and sodium sulfate hardening accelerating agent. Two kinds of curing condition, namely steam curing condition and standard curing condition, are adopted. The result shows that HPC, added with polycarboxlic series of high performance water reducer, has high workability and strength, while sodium sulfate accelerating agent causes poor workability and low strength. Thus for vapor-cured HPC and its formulations, naphthalene series high range water reducing agent with less sodium sulfate should be given pri- ority. Therefore, the differences of curing conditions should be considered when selecting HPC admixtures.

Anti-chloride permeability and anti-chloride corrodibility of a green high performance concrete admixture in concrete

The effects of green high performance concrete (GHPC) admixture on the anti-chloride permeability and anti- chloride corrodibility of concrete are studied by a series of experiments designed on the basis of the diffusion principle and electro-chemical principle. The GHPC admixture consists of fly ash, gangue, slag, red mud, etc., of which the mass fraction of industrial residues is over 96 %. The anti-permeabilities and anti-corrodibilities of the tested GHPC and normal concrete (NC) are evaluated by the Diffusion Coefficients of chloride which was obtained by measuring the concentration of chloride in the tested systems by the voltage difference method. It is found that the adoption of GHPC admixture greatly improves the anti-chloride permeability and anti-chloride corrodibility by modifying the inner structure and contracting the porosity of concrete to the reduce considerably the diffusion rate of chloride. The admixture is desirable regarding its engineering performances as well as economical and environmental interests.

INFLUENCE OF MINERAL ADMIXTURES ON MECHANICAL PROPERTIES OF HIGH-PERFORMANCE CONCRETE

The improvements of the mechanical properties, including bulk density of fresh mixtures, elastic modulus, and compressive strengths of four high-performance concrete mixtures, made with the addition of fly ash, refined ground blast - furnace microslag (microslag) and silica fume are studied. The concrete mixtures were determined based on the dispersion testing results. The study indicates that the elastic modulus at 28 and 91 days, and compressive strengths of the concretes are improved a lot when fly ash and microslag by 25 percent by weight of cement are added into the mixtures individually. The improvement is especially evident when silica fume by 5 percent and fly ash by 25 percent by weight of cement are added together into the mixture, while the fresh concrete mixture keeps a good workability. Through the analysis of chemically combined water ratios of the four mixtures at various hydration ages, it is found that the addition of all these mineral mixtures are beneficial to the hydration process, especially, at later stages, which might be one of the reasons for the improvement of mechanical properties. (Author abstract) 4 Refs.

Development of Optimal Structural System for Hybrid Cable-Stayed Bridges Using Ultra High Performance Concrete

This study developed an optimal structural system for the hybrid cable-stayed bridge expected to have a durable lifetime of 200 years and of which major structural members are made of ultra high performance concrete (UHPC) with 200 MPa-class compressive strength. This innovative cable-stayed bridge system makes it possible to reduce each of the construction and maintenance costs by 20% compared to the conventional concrete cable-stayed bridge by improving significantly the weight and durability of the bridge. Therefore, detail design is carried out considering a real 800 m cable-stayed bridge and the optimal structure of the hybrid cable-stayed bridge is proposed and verified.

Creep experimental test and analysis of high-performance concrete in bridge

Factors that have effect on concrete creep include mixture composition,curing conditions,ambient exposure conditions,and element geometry.Considering concrete mixtures influence and in order to improve the prediction of prestress loss in important structures,an experimental test under laboratory conditions was carried out to investigate compression creep of two high performance concrete mixtures used for prestressed members in one bridge.Based on the experimental results,a power exponent function of creep degree for structural numerical analysis was used to model the creep degree of two HPCs,and two series of parameters of this function for two HPCs were calculated with evolution program optimum method.The experimental data was compared with CEB-FIP 90 and ACI 209(92) models,and the two code models both overestimated creep degrees of the two HPCs.So it is recommended that the power exponent function should be used in this bridge structure analysis.

Seismic Performance of High-Strength Short Concrete Column with High-Strength Stirrups Constraints

The seismic performance of four short concrete columns was investigated under low cycle and repeated loads, including the failure characteristics, hysteretic behavior, rigidity degeneracy and steel-bar stress. The influences of reinforcement strength, stirrup ratio and shear span ratio were also compared. Test results reveal that the restriction effect of stirrups can improve the peak stress, so the bearing capacity of specimen can be improved; for the high-strength short concrete column with high-strength stirrups, it was more reasonable to use ultimate displacement angle to reflect the ductility of the specimen, and the yield strength of high-strength stirrups should be devalued when calculating the stirrup characteristic value; the seismic performance of short column would be improved with the increase of volume–stirrup ratio and shear span ratio; the high-strength stirrups and high-strength longitudinal reinforcements did not yield when the load acting on the specimen reached the peak value, which brought adequate safety stock to these short columns. © 2017, Tianjin University and Springer-Verlag Berlin Heidelberg.

SULFATE RESISTANCE MECHANISM OF HIGH- PERFORMANCE CONCRETE CONTAINING NCI

It is found that the incorporation of Nitrite Corrosion Inhibitor (NCI) greatly weakens the resistance of mixtures to sulfate attack. To study the mechanism of this phenomenon, in this paper, the influence of NCI addition on the cement paste and microstructure change of high performance concrete specimens is studied by means of quantitative XRD, SEM tests. The results demonstrate that the incorporation of NCI accelerates the formation of calcium hydroxide and ettringite crystals, and weakens the pore refinement effect caused by the secondary hydration reaction of fly ash and microsilica. At the age up to one year, the relative crystal quantity in mixture containing NCI is always higher than that in control mixture. The reasons for the degradation in sulfate resistance of mixtures may be attributed to the increase and stability of the calcium hydroxide and ettringite crystals formed and the weakening of secondary hydration reaction. Based on the results, conclusion can be drawn that NCI should be used cautiously in practical engineering where high resistance to sulfate attack is required. (Author abstract) 7 Refs.

Design of Eco-friendly Ultra-high Performance Concrete with Supplementary Cementitious Materials and Coarse Aggregate

Aiming to investigate the mix design of eco-friendly UHPC with supplementary cementitious materials and coarser aggregates, we comprehensively studied the workability, microstructure, porosity, compressive strength, flexural strength, and Young’s modulus of UHPC. Relationship between compressive strength and Young’s modulus was obtained eventually. It is found that the compressive strength, flexural strength, and Young’s modulus of UHPC increase by 19.01%, 10.81%, and 5.99%, respectively, when 40 wt% cement is replaced with supplementary cementitious materials. The relationship between compressive strength and Young’s modulus of UHPC is an exponential form.

Influence of shrinkage-reducing admixture on drying shrinkage and mechanical properties of high-performance concrete

High-performance concrete （HPC） has specific performance advantages over conventional concrete in strength and durability. HPC mixtures are usually produced with water/binder mass ratios （mW/mB） in the range of 0.2-0.4, so volume changes of concrete as a result of drying, chemical reactions, and temperature change cannot be avoided. For these reasons, shrinkage and cracking are frequent phenomena. It is necessary to add some types of admixture for reduction of shrinkage and cracking of HPC. This study used a shrinkage-reducing admixture （SRA） for that purpose. Concrete was prepared with two different mW/mB （0.22 and 0.40） and four different mass fractions of SRA to binder （w（SRA） = 0%, 1%, 2%, and 4%）. The mineral admixtures used for concrete mixes were： 25% fly ash （FA） and 25% slag by mass of binder for the mixture with mW/mB = 0.40, and 15% silica fume （SF） and 25% FA for the mixture with mW/mB = 0.22. Tests were conducted on 24 prismatic specimens, and shrinkage strains were measured through 120 days of drying. Compressive strength, splitting strength, and static modulus of elasticity were also determined. The results show that the SRA effectively reduces some mechanical properties of HPC. The reductions in compressive strength, splitting tensile strength, and elastic modulus of the concrete were 7%-24%, 9%-19%, and 5%-12%, respectively, after 90 days, compared to concrete mixtures without SRA. SRA can also help reduce drying shrinkage of concrete. The shrinkage strains of HPC with SRA were only as high as 41% of the average free shrinkage of concrete without SRA after 120 days of drying.

Spalling and Mechanical Properties of Fiber Reinforced High-performance Concrete Subjected to Fire

Spalling and mechanical properties of FRHPC subjected to fire were tested on notched beams. The results confirm that the internal vapor pressure is the leading reason for spalling of high-performance concrete （HPC）. At the same time, the temperature-increasing velocity and constrained conditions of concrete element also play significant roles in spalling. Steel fibers cannot reduce the risk of spalling, although they have obvious beneficial effects on the mechanical properties of concrete before and after exposure to fire. Polypropylene （PP） fibers are very useful in preventing HPC from spalling, however, they have negative effects on the strengths. By using hybrid fibers （steel fibers＋PP fibers）, both good anti-spalling performance and improved mechanical properties come true, which may provide necessary safe guarantee for the rescue work and structure repair after fire disaster.

Assessment of early-age cracking of high-performance concrete in restrained ring specimens

High-performance concrete （HPC） is stronger and more durable than conventional concrete. However, shrinkage and shrinkage cracking are common phenomena in HPC, especially early-age cracking. This study assessed early-age cracking of HPC for two mixtures using restrained ring tests. The two mixtures were produced with water/binder mass ratio （mw/mB） of 0.22 and 0.40, respectively. The results show that, with greater steel thickness, the higher degree of restraint resulted in a higher interface pressure and earlier cracking. With steel thickness of 6 mm, 19 mm, and 30 mm, the age of cracking were, respectively, 12 days, 8 days, and 5.4 days with the mw/mB = 0.22 mixture; and 22.5 days, 12.6 days, and 7.1 days with the mw/mB= 0.40 mixture. Cases of the same steel thickness show that the ring specimens with a thicker concrete wall crack later. With the mw/mB = 0.22 mixture, concrete walls with thicknesses of 37.5 mm, 75 mm, and 112.5 mm cracked at 3.4 days, 8.0 days, and 9.8 days, respectively; with the mw/mB = 0.40 mixture, the ages of cracking were 7.1 days, 12.6 days, and 16.0 days, respectively.

FAILURE MODE AND CONSTITUTIVE MODEL OF PLAIN HIGH-STRENGTH HIGH-PERFORMANCE CONCRETE UNDER BIAXIAL COMPRESSION AFTER EXPOSURE TO HIGH TEMPERATURES

An orthotropic constitutive relationship with temperature parameters for plain highstrength high-performance concrete （HSHPC） under biaxial compression is developed. It is based on the experiments performed for characterizing the strength and deformation behavior at two strength levels of HSHPC at 7 different stress ratios including a=σs ： σ3=0.00：-1,-0.20：-1,-0.30 ： -1,-0.40：-1,-0.50：-1,-0.75：-1,-1.00：-1, after the exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600℃, and using a large static-dynamic true triaxial machine. The biaxial tests were performed on 100 mm×100 mm×100 mm cubic specimens, and friction-reducing pads were used consisting of three layers of plastic membrane with glycerine in-between for the compressive loading plane. Based on the experimental results, failure modes of HSHPC specimens were described. The principal static compressive strengths, strains at the peak stress and stress-strain curves were measured; and the influence of the temperature and stress ratios on them was also analyzed. The experimental results showed that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease dramatically with the increase of temperature. The ratio of the biaxial to its uniaxial compressive strength depends on the stress ratios and brittleness-stiffness of HSHPC after exposure to different temperature levels. Comparison of the stress-strain results obtained from the theoretical model and the experimental data indicates good agreement.

Dynamic Mechanical Behaviour of Ultra-high Performance Fiber Reinforced Concretes

Ultra-high performance fiber reinforced concretes （UHPFRC） were prepared by replacing 60% of cement with ultra-fine industrial waste powder. The dynamic mechanical behaviour of UHPFRC with different fiber volume fraction was researched on repeated compressive impact in four kinds of impact modes through split Hopkinson pressure bar （SHPB）. The experimental results show that the peak stress and elastic modulus decrease and the strain rate and peak strain increase gradually with the increasing of impact times. The initial material damage increases and the peak stress of the specimen decreases from the second impact with the increasing of the initial incident wave. Standard strength on repeated impact is defined to compare the ability of resistance against repeated impact among different materials. The rate of reduction of standard strength is decreased by fiber reinforcement under repeated impact. The material damage is reduced and the ability of repeated impact resistance of UHPFRC is improved with the increasing of fiber volume fraction.

Multi-powder dam concrete with high performance and low adiabatic temperature rise

Based on the fluidity, strength, heat of hydration and loop crack resistance experiment of multi-powder paste, the components and proportion of multi-powder were optimized and the concrete properties were studied. The multi-powder consists of limestone powder, slag, fly ash and moderate heat Portland cement (PMH cement). The results show that the compressive strength of the multi-powder paste and mortar is close to those of PMH cement, fly ash paste and mortar currently used in dam concrete, yet the flexural strength is relatively higher. The multi-powder paste is featured by larger fluidity, lower heat of hydration and delayed cracking time. In comparison, less unit water consumption and cement is used in multi-powder concrete, and under premise of equal mechanical performance, deformation, thermal performance and durability, the adiabatic temperature rise at 28 d is reduced by 2 ℃. In this way, the crack resistance is improved and it is feasible both technically and economically to produce HPC for dam concrete.

Strength Regularity and Failure Criterion of High-Strength High-Performance Concrete under Multiaxial Compression

Multiaxial compression tests were performed on 100 mm×100 mm×100 mm high-strength high-performance concrete （HSI-IPC） cubes and normal strength concrete （NSC） cubes. The failure modes of specimens were presented, the static compressive strengths in principal directions were measured, the influence of the stress ratios was analyzed. The experimental results show that the ultimate strengths for HSHPC and NSC under multiaxial compression are greater than the uniaxial compressive strengths at all stress ratios, and the multiaxial strength is dependent on the brittleness and stiffness of concrete, the stress state and the stress ratios. In addition, the Kupfer-Gersfle and Ottosen＇s failure criteria for plain HSHPC and NSC under multiaxial compressive loading were modified.

Seismic Performance of Steel Reinforced Ultra High-strength Concrete Columns

The seismic performance of steel reinforced ultra-high-strength concrete columns(SRSHC) with various shear-span ratios(λ) were studied through a series of experiments.The concrete compressive cube strength value of experimental specimens ranged from 92.9 MPa to 108.1 MPa.The main experimental variables affecting seismic performance of specimens were axial load ratio and stirrup reinforcement ratio.The columns(λ=2.75) subjected to low cyclic reversed lateral loads failed mainly in the flexural-shear mode failure and columns(λ≤2.0) subjected to low cyclic reversed lateral loads failed mainly in the shear mode failure.Shear force-displacement hysteretic curves and skeleton curves were drawn.Coefficient of the specimen displacement ductility was calculated.Experimental results indicate that ductility decreases with axial pressure ratio increasing,and increases with stirrup reinforcement ratio increasing.Limit values of axial pressure ratio and minimum stirrup reinforcement ratio of columns are proposed to satisfy definite ductility requirement.The suggested values provide a reference for engineering application and for the amendment of the current Chinese design code of steel reinforced concrete composite structures.

Flexural Bond Behavior of Rebar in Ultra-High Performance Concrete Beams Considering Lap-Splice Length and Cover Depth

This study intends to find out the correlation between the cover depth and the bond characteristics of UHPC through pull-out tests of UHPC specimens with different cover depths and bond tests of rebar using flexural members. In this experimental study, specimens are fabricated with the lap-splice length as test variable in relation with the calculation of the lap-splice length for 180- MPa UHPC. Moreover, specimens are also fabricated with the cover depth as test variable to evaluate the effect of the cover depth on the UHPC flexural members. The load-displacement curves are analyzed for each of these test variables to compute the lap-splice length proposed in the K-UHPC structural design guideline and to evaluate the influence of the cover depth on the flexural members. As a result, the stability of the structural behavior can be significantly enhanced by increasing slightly the cover depth specification of the current UHPC Structure Design Guideline from the maximum value between 1.5 times of rebar diameter and 20 mm to the maximum value between 1.5 times of rebar diameter and 25 mm.