High Nb containing TiAl alloy was fabricated in argon atmosphere by reactive hot pressing process. Reaction mechanism was investigated by means of microstructural analyses and thermodynamic calculations. The results s...High Nb containing TiAl alloy was fabricated in argon atmosphere by reactive hot pressing process. Reaction mechanism was investigated by means of microstructural analyses and thermodynamic calculations. The results show that it is feasible to prepare high Nb containing TiAl alloy with fine lamellar colonies by reactive hot pressing process. The reaction between Ti and Al powders is dominant in Ti-Al-Nb system. Nb powders dissolve into the Ti-Al matrix by diffusion. Pore nests are formed in situ after Nb powders diffusion. The hot pressing atmosphere is optimized by thermodynamic calculations. Vacuum or argon protective atmosphere should be adopted.展开更多
Porous TiAl intermetallic compound, as a novel substitute for current inorganic porous material, offsets the shortages of both ceramics and metals. The environmental corrosion resistance of porous TiAl intermetallic c...Porous TiAl intermetallic compound, as a novel substitute for current inorganic porous material, offsets the shortages of both ceramics and metals. The environmental corrosion resistance of porous TiAl intermetallic compound was investigated. The kinetic equation for the cyclic oxidation of porous TiAl alloy at 600 ℃ is determined to be △m2=1.08×10-5t. After total oxidation of 140 h, porous TiAl intermetallic compound shows more stability of pore structure and the mass gain of TiAl alloy is 0.042 g/m2, which is only 10.6% that of porous 316L stainless steel. The kinetic equation for the cyclic corrosion behavior of porous TiAl alloy in hydrochloric acid with pH=2 at 90 ℃ is determined to be △m2=5.41×10-5t-2.08×10-4. After 50 h exposure, the mass loss of TiAl alloy is 0.049 g/m2, which is only 14.8% and 5.57% that of porous Ti and stainless steel, respectively. The kinetic equation in hydrochloric acid with pH=3 is determined to be △m2=2.63×10-6t-3.72×10-6.展开更多
基金Project(704008) supported by the Key Grant Project of Chinese Ministry of Education Project(NCET-04-01017) supported by the Program for New Century Excellent Talents in University, China
文摘High Nb containing TiAl alloy was fabricated in argon atmosphere by reactive hot pressing process. Reaction mechanism was investigated by means of microstructural analyses and thermodynamic calculations. The results show that it is feasible to prepare high Nb containing TiAl alloy with fine lamellar colonies by reactive hot pressing process. The reaction between Ti and Al powders is dominant in Ti-Al-Nb system. Nb powders dissolve into the Ti-Al matrix by diffusion. Pore nests are formed in situ after Nb powders diffusion. The hot pressing atmosphere is optimized by thermodynamic calculations. Vacuum or argon protective atmosphere should be adopted.
基金Projects(20636020, 20476106 and 50825102) supported by the National Natural Science Foundation of ChinaProject(2003CB615707) supported by the National Basic Research Program of China+1 种基金Project(2006AA03Z511) supported by the Hi-tech Research and Development Program of ChinaProject(50721003) supported by the Creative Research Group of National Natural Science Foundation of China
文摘Porous TiAl intermetallic compound, as a novel substitute for current inorganic porous material, offsets the shortages of both ceramics and metals. The environmental corrosion resistance of porous TiAl intermetallic compound was investigated. The kinetic equation for the cyclic oxidation of porous TiAl alloy at 600 ℃ is determined to be △m2=1.08×10-5t. After total oxidation of 140 h, porous TiAl intermetallic compound shows more stability of pore structure and the mass gain of TiAl alloy is 0.042 g/m2, which is only 10.6% that of porous 316L stainless steel. The kinetic equation for the cyclic corrosion behavior of porous TiAl alloy in hydrochloric acid with pH=2 at 90 ℃ is determined to be △m2=5.41×10-5t-2.08×10-4. After 50 h exposure, the mass loss of TiAl alloy is 0.049 g/m2, which is only 14.8% and 5.57% that of porous Ti and stainless steel, respectively. The kinetic equation in hydrochloric acid with pH=3 is determined to be △m2=2.63×10-6t-3.72×10-6.
