B-C Bond in Diamond Single Crystal Synthesized with h-BN Additive at High Pressure and High Temperature

The synthesis of diamond single crystal in the Fe64Ni36-C system with h-BN additive is investigated at pressure 6.5 GPa and temperature range of 1300-1400℃. The color of the obtained diamond crystals translates from yellow to dark green with increasing the h-BN addition. Fourier-transform infrared （FTIR） results indicate that sp2 hybridization B-N-B and B-N structures generate when the additive content reaches a certain value in the system. The two peaks are located at 745 and 1425cm-1, respectively. Fhrthermore, the FTIR characteristic peak resulting from nitrogen pairs is noticed and it tends to vanish when the h-BN addition reaches 1.1 wt%. Furthermore, Raman peak of the synthesized diamond shifts down to a lower wavenumber with increasing the h-BN ~ddition content in the synthesis system.

Study on Tribology Performance of Different Lubricant Additives under Atmospheric Pressure and High Vacuum Conditions

By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS), the tribological mechanisms of these additives were studied. In air, O_2 can react with metal to form metal oxide that can protect the surfaces of rubbing pair during the tribological tests. According to the theory of the competitive adsorption, the function of some active elements is weakened. In a vacuum environment, the additives contributed more to the lubrication performance. The sulfur-containing additives could react with Fe to produce Fe Sx and "M—C" bonds("M" represents metal). They both had contributions to the lubrication. As for the phosphorus-containing additives, they only generated the phosphates during the tests. When the sulfur and phosphorus-containing additives were applied, the generated phosphates and Fe Sx had the primary contribution to the lubrication performance during the tests.

Comparison of microstructure and property of high chromium bearing steel with and without nitrogen addition

Microstructure and property of bearing steel with and without nitrogen addition were investigated by microstructural observation and hardness measurement after different heat treatment processing. Based on the microstructural observation of both 9Cr18 steel and X90N steel, it was found that nitrogen addition could effectively reduce the amount and size of coarse carbides and also refine the original austenite grain size. Due to addition of nitrogen, more austenite phase was found in X90N steel than in 9Cr18 steel. The retained austenite of X90N steel after quenching at 1050℃ could be reduced from about 60% to about 7 9% by cold treatment at -73℃ and subsequent tempering, and thus finally increased the hardness up to 60 HRC after low temperature tempering and to 63 HRC after high temperature tempering. Furthermore, both the wear and corrosion resistance of X90N steel were found much more superior than those of 9Cr18 steel, which was attributed to the addition of nitrogen. It was proposed at last that nitrogen alloying into the high chromium bearing steel was a promising way not only to refine the size of both carbides and austenite, but also to achieve high hardness, high wear property and improved corrosion resistance of the stainless bearing steel.

高新技术企业认定政策的创新增量效应及作用机制

以湖北2015—2017年新三板年报披露的463家公司数据,从信号传递与股权集中度的调节角度,运用“倾向得分匹配”方法,评估了高新技术企业认定政策的创新增量效应及其作用机制。实证发现:①高新技术企业认定政策能有效激励产出增量,策略性创新激励效应大于实质性创新激励效应;②信号传递的调节作用存在异质性。金融支撑体系对认定政策的投入增量和产出增量效应具有负向调节作用,股权流通性对认定政策的产出增量效应具有正向调节作用;③股权集中度对认定政策的产出增量效应具有负向调节作用。研究结果从投入与产出增量视角丰富了创新激励影响因素研究的文献,并为高新技术企业认证的政策完善提供了实证指导。

Biomedical titanium alloys and their additive manufacturing

Titanium and its alloys have been widely used for biomedical applications due to their better biomechanical and biochemical compatibility than other metallic materials such as stainless steels and Co-based alloys.A brief review on the development of the b-type titanium alloys with high strength and low elastic modulus is given and the use of additive manufacturing technologies to produce porous titanium alloy parts,using Ti-6Al-4V as a reference,and its potential in fabricating biomedica replacements are discussed in this paper.