Using high-precision zircon U-Pb ID-TIMS geochronology,tuffs from the Chang 9 shale and the Chang 7 shale were dated.The tuff in the Chang 9 shale is 241.47±0.17 Ma,which falls between the top tuff age of 241.06&...Using high-precision zircon U-Pb ID-TIMS geochronology,tuffs from the Chang 9 shale and the Chang 7 shale were dated.The tuff in the Chang 9 shale is 241.47±0.17 Ma,which falls between the top tuff age of 241.06±0.12 Ma and the bottom tuff age of 241.558±0.093 Ma in the Chang 7 shale.These reveal that the Chang 9 and Chang 7 shales are contemporaneous,belonging to the Ladinian stage of the Middle Triassic.This insight expands the region of the main source rock of Chang 7 to the northeast and will inform the search for the deep Chang 9 shale petroleum system,increasing the scope for exploring the Chang 7 shale system in northern Shaanxi.The research results clarify the relationship between the two sets of shale in the Yanchang Formation and redefine the distribution range of the Chang 7 shale in the Ordos Basin.At the same time,it shows that there is a cross-layer problem in the stratigraphic division of the Yanchang Formation in different regions,the high-precision U-Pb dating technology providing a reference for the fine stratigraphic correlation of other continental basins in the world.展开更多
The eutectic CoFeNi2V0.5Nb0.75 high entropy alloys （HEAs） were heated at 500, 600, 700, 800 and 1000 ℃, respectively for 6 h and subsequently quenched in the water to investigate their thermal stability and phase t...The eutectic CoFeNi2V0.5Nb0.75 high entropy alloys （HEAs） were heated at 500, 600, 700, 800 and 1000 ℃, respectively for 6 h and subsequently quenched in the water to investigate their thermal stability and phase transformation at high temperature. The microstructure and mechanical properties of the samples were investigated by scanning electron microscopy, X-ray diffraction, compressive and hardness tests. It was found that the as-cast CoFeNi2V0.5Nb0.75 HEAs showed a eutectic microstructure with alternating fcc solid solution phase and Fe2Nb-type Laves phase. The NbNi4-type intermetallic phase appeared when the heat-treated temperature was higher than 600 ℃. With increasing quenching temperature, the volume fraction of the NbNi4-type intermetallic phase increased while that of the eutectic regions decreased. The sample quenched at 800 ℃ showed the most excellent comprehensive mechanical properties; its fracture strength, yield strength and plastic strain were as high as 2586.76 MPa, 2075.18 MPa and 16.73%, respectively. Moreover, the eutectic CoFeNi2V0.5Nb0.75 HEAs exhibited apparent age hardening, especially quenched at 700 ℃, the hardness reached up to the maximum value of HV 727.52.展开更多
基金supported by the Research Program of the Research Institute of Petroleum Exploration and Development of the Changqing Oilfield(Grant No.J2019168)。
文摘Using high-precision zircon U-Pb ID-TIMS geochronology,tuffs from the Chang 9 shale and the Chang 7 shale were dated.The tuff in the Chang 9 shale is 241.47±0.17 Ma,which falls between the top tuff age of 241.06±0.12 Ma and the bottom tuff age of 241.558±0.093 Ma in the Chang 7 shale.These reveal that the Chang 9 and Chang 7 shales are contemporaneous,belonging to the Ladinian stage of the Middle Triassic.This insight expands the region of the main source rock of Chang 7 to the northeast and will inform the search for the deep Chang 9 shale petroleum system,increasing the scope for exploring the Chang 7 shale system in northern Shaanxi.The research results clarify the relationship between the two sets of shale in the Yanchang Formation and redefine the distribution range of the Chang 7 shale in the Ordos Basin.At the same time,it shows that there is a cross-layer problem in the stratigraphic division of the Yanchang Formation in different regions,the high-precision U-Pb dating technology providing a reference for the fine stratigraphic correlation of other continental basins in the world.
基金supported by the National Natural Science Foundation of China (Nos. 51104029, 51134013, 51471044, 51104029 and 51375070)the Fundamental Research Funds for the Central Universitiesthe Natural Science Foundation of Liaoning Province (No. 2014028013)
文摘The eutectic CoFeNi2V0.5Nb0.75 high entropy alloys （HEAs） were heated at 500, 600, 700, 800 and 1000 ℃, respectively for 6 h and subsequently quenched in the water to investigate their thermal stability and phase transformation at high temperature. The microstructure and mechanical properties of the samples were investigated by scanning electron microscopy, X-ray diffraction, compressive and hardness tests. It was found that the as-cast CoFeNi2V0.5Nb0.75 HEAs showed a eutectic microstructure with alternating fcc solid solution phase and Fe2Nb-type Laves phase. The NbNi4-type intermetallic phase appeared when the heat-treated temperature was higher than 600 ℃. With increasing quenching temperature, the volume fraction of the NbNi4-type intermetallic phase increased while that of the eutectic regions decreased. The sample quenched at 800 ℃ showed the most excellent comprehensive mechanical properties; its fracture strength, yield strength and plastic strain were as high as 2586.76 MPa, 2075.18 MPa and 16.73%, respectively. Moreover, the eutectic CoFeNi2V0.5Nb0.75 HEAs exhibited apparent age hardening, especially quenched at 700 ℃, the hardness reached up to the maximum value of HV 727.52.
