Liquid crystal（LC） compound with isothiocyanate and naphthyl group is an attractive high birefringence LC material,and can be used in optical devices. In this paper, the electro-optical properties of a series of thi...Liquid crystal（LC） compound with isothiocyanate and naphthyl group is an attractive high birefringence LC material,and can be used in optical devices. In this paper, the electro-optical properties of a series of this type of LC compounds were investigated. The melting points and enthalpy values of these LC compounds were higher than those of corresponding compounds with the phenyl group. These compounds exhibited high birefringence with a maximum value of 0.66. Fluorine substitution in the molecular almost does not affect the birefringence value. When these LC compounds with the naphthyl group were dissolved in a commercial LC mixture, the electro-optical properties depending on temperature were investigated. In the low-temperature region, LC mixtures with the naphthyl-group LC compounds exhibited higher viscosity than pure commercial LCs. In the high-temperature region, viscosity values very closely approached each other. When response performance was investigated, figure-of-merit（FoM） values were measured. The Fo M values of LC mixtures containing LC compounds with naphthyl group were lower than those of reference benzene LCs in the low-temperature region. However, in the high-temperature region, the results were reversed. These isothiocyanate LC compounds with naphthyl group can be applied in special fast-response LC device, particularly the ones used under high-temperature conditions.展开更多
A novel high-birefringence photonic crystal fiber （HB-PCF） with two zero-dispersion wavelengths （ZDWs） is designed, and an extraordinarily high modal birefringence of 1.56×10-2 is obtained at pump wavelength ...A novel high-birefringence photonic crystal fiber （HB-PCF） with two zero-dispersion wavelengths （ZDWs） is designed, and an extraordinarily high modal birefringence of 1.56×10-2 is obtained at pump wavelength λp=1850nm. With the designed HB-PCF, the effect of the pump parameters on the modulation instability （MI） in the anomalous dispersion region close to the second ZDWs of the HB-PCF is comprehensively studied in this work. A broadband and tunable optical amplification is achieved by controlling the pump power and the pump wavelength based on the combined operation of Raman effect and cross phase modulation. By optimizing the pump parameters, the amplification bandwidth along the fiber slow axis reaches 152 nm for the pump power Pp=280W and the pump wavelength λp=1675nm, while the gain bandwidth along the fiber fast axis is 165 nm for the pump power Pp=600W and the pump wavelength λp=1818nm.展开更多
We report on the generation of a high energy and long pulse for pumping optical parametric chirped-pulse amplification （OPCPA） by a high-birefringence photonic crystal fibre （HB-PCF） and a laser-diode-pumped regen...We report on the generation of a high energy and long pulse for pumping optical parametric chirped-pulse amplification （OPCPA） by a high-birefringence photonic crystal fibre （HB-PCF） and a laser-diode-pumped regenerative chirped pulse amplifier. Using the femtosecond pump pulse centred at 815 nm, a 1064 nm soliton pulse is produced in the HB-PCF. After injecting it into an Nd：YAG regenerative amplifier with the glass etalons, a narrow-band amplified pulse with an energy of -4 mJ and a duration of 235 ps is achieved at a repetition rate of 10 Hz, which is suitable for being used as a pump source in the 800 nm OPCPA system.展开更多
In this paper, a novel photonic crystal fiber （PCF） with high birefringence and nonlinearity is designed. The charac- teristics of birefringence, dispersion and nonlinearity are studied by using the full-vector fini...In this paper, a novel photonic crystal fiber （PCF） with high birefringence and nonlinearity is designed. The charac- teristics of birefringence, dispersion and nonlinearity are studied by using the full-vector finite element method （FVFEM）. The numerical results show that the phase birefringence and nonlinear coefficient of PCF can be up to 4.51× 10-3 and 32.8972 w-l.km-1 at 1.55 μm, respectively. The proposed PCF could be found to have important applications in the polarization-dependent nonlinear optics such as the pulse compress and reshaping in the C waveband.展开更多
By adjusting the polarisation state of the pump at 805 nm parallel to slow （x） and fast （y） axes of the highly birefringent photonic crystal fibre with zero dispersion wavelengths 790 nm and 750 nm, this paper dem...By adjusting the polarisation state of the pump at 805 nm parallel to slow （x） and fast （y） axes of the highly birefringent photonic crystal fibre with zero dispersion wavelengths 790 nm and 750 nm, this paper demonstrates the efficient polarisation-sensitive four wave mixing involved in pump, anti-Stokes and Stokes signals and soliton self- frequency shift effects induced by the phase-matching between red-shifted solitons and blue-shifted dispersive waves. If the reduction of coupling efficiency to the circular pump laser mode or other circular fibres due to asymmetry of the core is neglected, more than 98% of the total input power is kept in a single linear polarisation. Controlled dispersion characteristic of the doublet of fundamental guided-modes results in achieving light field strongly confined in principal axes of photonic crystal fibre, and enhancing the corresponding nonlinear-optical process through the remarkable nonlinear birefringence.展开更多
Three epoxy-based azo polymers （PEP-AZ-C1, PEP-AZ-CN and PEP-AZ-NT） with high chromophore density were synthesized by using post-polymerization azo-coupling reactions between epoxy-based precursor polymer （PEP-AN）...Three epoxy-based azo polymers （PEP-AZ-C1, PEP-AZ-CN and PEP-AZ-NT） with high chromophore density were synthesized by using post-polymerization azo-coupling reactions between epoxy-based precursor polymer （PEP-AN） and diazonium salts of 4-chloroaniline, 4-aminobenzonitrile and 4-nitroaniline, respectively. The structures and properties of the azo polymers were characterized by using 1H-NMR, FT-IR, UV-Vis and thermal analyses. The photoinduced birefringence of the azo polymers was studied by irradiating spin-coated films of the polymers with laser beam at three different wavelengths （488, 532, and 589 nm）. The results indicate that the photoinduced birefringence of the azo polymers is related with the electron-withdrawing group on azo chromophores and the excitation wavelength. The excitation wavelength that can cause the efficient responses is determined by the absorption band positions of the a~：o chromophores, which are mainly affected by the electron-withdrawing group on the chromophores. Therefore, the,. azo polymers containing chromophores with different electron-withdrawing groups show different respon,;ive behavior to the irradiation light at different wavelengths. When irradiated with 488 nm light, PEP-AZ-Cl shows the shortest time to reach the saturated birefringence but with the lowest saturation birefringence level compared with the other two azo polymers. When irradiated with 532 nm light, PEP-AZ-CN shows the shortest time to reach the saturated birefringence. When irradiated with 532 and 589 nm light, PEP-AZ-NT shows the highest saturation birefringence level.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61378075,61377032,11604327,and 61475152)the Science Foundation of State Key Laboratory of Applied Optics,China
文摘Liquid crystal（LC） compound with isothiocyanate and naphthyl group is an attractive high birefringence LC material,and can be used in optical devices. In this paper, the electro-optical properties of a series of this type of LC compounds were investigated. The melting points and enthalpy values of these LC compounds were higher than those of corresponding compounds with the phenyl group. These compounds exhibited high birefringence with a maximum value of 0.66. Fluorine substitution in the molecular almost does not affect the birefringence value. When these LC compounds with the naphthyl group were dissolved in a commercial LC mixture, the electro-optical properties depending on temperature were investigated. In the low-temperature region, LC mixtures with the naphthyl-group LC compounds exhibited higher viscosity than pure commercial LCs. In the high-temperature region, viscosity values very closely approached each other. When response performance was investigated, figure-of-merit（FoM） values were measured. The Fo M values of LC mixtures containing LC compounds with naphthyl group were lower than those of reference benzene LCs in the low-temperature region. However, in the high-temperature region, the results were reversed. These isothiocyanate LC compounds with naphthyl group can be applied in special fast-response LC device, particularly the ones used under high-temperature conditions.
基金the National Natural Science Foundation of China(Grant No.11226148)the Scientific Research Foundation of Zhejiang Province,China(Grant No.LY12F05006)the Education Department Foundation of Zhejiang Province,China(Grant No.Y201121906)
文摘A novel high-birefringence photonic crystal fiber （HB-PCF） with two zero-dispersion wavelengths （ZDWs） is designed, and an extraordinarily high modal birefringence of 1.56×10-2 is obtained at pump wavelength λp=1850nm. With the designed HB-PCF, the effect of the pump parameters on the modulation instability （MI） in the anomalous dispersion region close to the second ZDWs of the HB-PCF is comprehensively studied in this work. A broadband and tunable optical amplification is achieved by controlling the pump power and the pump wavelength based on the combined operation of Raman effect and cross phase modulation. By optimizing the pump parameters, the amplification bandwidth along the fiber slow axis reaches 152 nm for the pump power Pp=280W and the pump wavelength λp=1675nm, while the gain bandwidth along the fiber fast axis is 165 nm for the pump power Pp=600W and the pump wavelength λp=1818nm.
基金Project supported by the National Basic Research Program of China (Grant No. 2006CB806001)the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KGCX-YW-417-2)the Fund of the State Key Laboratory of High Field Laser Physics and Shanghai Commission of Science and Technology,China (Grant No. 07JC14055)
文摘We report on the generation of a high energy and long pulse for pumping optical parametric chirped-pulse amplification （OPCPA） by a high-birefringence photonic crystal fibre （HB-PCF） and a laser-diode-pumped regenerative chirped pulse amplifier. Using the femtosecond pump pulse centred at 815 nm, a 1064 nm soliton pulse is produced in the HB-PCF. After injecting it into an Nd：YAG regenerative amplifier with the glass etalons, a narrow-band amplified pulse with an energy of -4 mJ and a duration of 235 ps is achieved at a repetition rate of 10 Hz, which is suitable for being used as a pump source in the 800 nm OPCPA system.
基金Project partly supported by the State Major Basic Research Development Program of China(Grant No.2010CB327604)the National Natural Science Foundation of China(Grant No.61377100)
文摘In this paper, a novel photonic crystal fiber （PCF） with high birefringence and nonlinearity is designed. The charac- teristics of birefringence, dispersion and nonlinearity are studied by using the full-vector finite element method （FVFEM）. The numerical results show that the phase birefringence and nonlinear coefficient of PCF can be up to 4.51× 10-3 and 32.8972 w-l.km-1 at 1.55 μm, respectively. The proposed PCF could be found to have important applications in the polarization-dependent nonlinear optics such as the pulse compress and reshaping in the C waveband.
基金partly supported by the National Basic Research Program (Grant Nos. 2010CB327605 and 2010CB328300)Nationa lHigh-Technology Research and Development Program of China (Grant Nos. 2007AA03Z447 and 2009AA01Z220)+2 种基金the National Natural Science Foundation of China (Grant No. 60807022)the Key Grant of Ministry of Education of China (Grant No. 109015)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20070013001)
文摘By adjusting the polarisation state of the pump at 805 nm parallel to slow （x） and fast （y） axes of the highly birefringent photonic crystal fibre with zero dispersion wavelengths 790 nm and 750 nm, this paper demonstrates the efficient polarisation-sensitive four wave mixing involved in pump, anti-Stokes and Stokes signals and soliton self- frequency shift effects induced by the phase-matching between red-shifted solitons and blue-shifted dispersive waves. If the reduction of coupling efficiency to the circular pump laser mode or other circular fibres due to asymmetry of the core is neglected, more than 98% of the total input power is kept in a single linear polarisation. Controlled dispersion characteristic of the doublet of fundamental guided-modes results in achieving light field strongly confined in principal axes of photonic crystal fibre, and enhancing the corresponding nonlinear-optical process through the remarkable nonlinear birefringence.
文摘Three epoxy-based azo polymers （PEP-AZ-C1, PEP-AZ-CN and PEP-AZ-NT） with high chromophore density were synthesized by using post-polymerization azo-coupling reactions between epoxy-based precursor polymer （PEP-AN） and diazonium salts of 4-chloroaniline, 4-aminobenzonitrile and 4-nitroaniline, respectively. The structures and properties of the azo polymers were characterized by using 1H-NMR, FT-IR, UV-Vis and thermal analyses. The photoinduced birefringence of the azo polymers was studied by irradiating spin-coated films of the polymers with laser beam at three different wavelengths （488, 532, and 589 nm）. The results indicate that the photoinduced birefringence of the azo polymers is related with the electron-withdrawing group on azo chromophores and the excitation wavelength. The excitation wavelength that can cause the efficient responses is determined by the absorption band positions of the a~：o chromophores, which are mainly affected by the electron-withdrawing group on the chromophores. Therefore, the,. azo polymers containing chromophores with different electron-withdrawing groups show different respon,;ive behavior to the irradiation light at different wavelengths. When irradiated with 488 nm light, PEP-AZ-Cl shows the shortest time to reach the saturated birefringence but with the lowest saturation birefringence level compared with the other two azo polymers. When irradiated with 532 nm light, PEP-AZ-CN shows the shortest time to reach the saturated birefringence. When irradiated with 532 and 589 nm light, PEP-AZ-NT shows the highest saturation birefringence level.
