Enhanced reversible hydrogen storage properties of wrinkled graphene microflowers confined LiBH_(4) system with high volumetric hydrogen storage capacity

LiBH_(4)with high hydrogen storage density,is regarded as one of the most promising hydrogen storage materials.Nevertheless,it suffers from high dehydrogenation temperature and poor reversibility for practical use.Nanoconfinement is effective in achieving low dehydrogenation temperature and favorable reversibility.Besides,graphene can serve as supporting materials for LiBH_(4)catalysts and also destabilize LiBH_(4)via interfacial reaction.However,graphene has never been used alone as a frame material for nanoconfining LiBH_(4).In this study,graphene microflowers with large pore volumes were prepared and used as nanoconfinement framework material for LiBH_(4),and the nanoconfinement effect of graphene was revealed.After loading 70 wt%of LiBH_(4) and mechanically compressed at 350 MPa,8.0 wt% of H2 can be released within 100 min at 320C,corresponding to the highest volumetric hydrogen storage density of 94.9 g H2 L^(-1)ever reported.Thanks to the nanoconfinement of graphene,the rate-limiting step of dehydrogenation of nanoconfined LiBH_(4) was changed and its apparent activation energy of the dehydrogenation(107.3 kJ mol^(-1))was 42%lower than that of pure LiBH_(4).Moreover,the formation of the intermediate Li_(2)B_(12)H_(12) was effectively inhibited,and the stable nanoconfined structure enhanced the reversibility of LiBH_(4).This work widens the understanding of graphene's nanoconfinement effect and provides new insights for developing high-density hydrogen storage materials.

Regulating intramolecular hydrogen bonds of p-phenylenediimidazole-based small-molecule compounds towards the enhanced lithium storage capacity

The use of redox-active organic electrode materials in energy storage is restricted due to their inferior solvent resistance,abysmal conductivity,and the resultant low practical capacity.To address these issues,a class of bipolar p-phenylenediimidazole-based small-molecule compounds are designed and fabricated.Theπ-conjugated backbone of these small molecules allows for electron delocalization on a big conjugation plane,endowing them with good conductivity and reaction reversibility.Furthermore,when the para-positions of phenylene are occupied by hydroxyl groups,as-formed intramolecular hydrogen bonds(N-H...O)between phenolic hydroxyl groups and the–NH groups of imidazole rings further enhance the structural planarity,resulting in higherπ-conjugation degree and better conductivity,and thus higher utilization of active sites and electrode capacity,proved by both experimental results and theoretical calculations.The optimized composite electrode DBNQ@rGO-45 shows a high specific capacity(∼308 mA h g^(−1)at 100 mA g^(−1))and a long cycling stability(112.9 mA h g^(−1)after 6000 cycles at 2000 mA g^(−1)).The significantly better electrochemical properties for hydroxyl group-containing compounds than those without hydroxyl groups attributed to intramolecular hydrogen bond-induced conjugation enhancement will inspire the structure design of organic electrodes for better energy storage.

Development of High Areal Capacity Electrolytic MnO_(2)-Zn Battery via an Iodine Mediator

The commercialization of electrolytic MnO_(2)-Zn batteries is highly applauded owing to the advantages of cost-effectiveness,high safety,high energy density,and durable working performance.However,due to the low reversibility of the cathode MnO_(2)/Mn^(2+)chemistry at high areal capacities and the severe Zn anode corrosion,the practical application of MnO_(2)-Zn batteries is hampered by inadequate lifespan.Leveraging the full advantage of an iodine redox mediator,here we design a highly rechargeable electrolytic MnO_(2)-Zn battery with a high areal capacity.The MnO_(2)-Zn battery coupled with an iodine mediator in a mild electrolyte shows a high discharge voltage of 1.85 V and a robust areal capacity of 10 mAh cm^(-2)under a substantial discharge current density of 160 mA cm^(-2).The MnO_(2)/I_(2)-Zn battery with an areal capacity of 10 mAh cm^(-2)exhibits prolonged stability of over 950 cycles under a high-capacity retention of~94%.The scaled-up MnO_(2)/I_(2)-Zn battery reveals a stable cycle life under a cell capacity of~600 mAh.Moreover,our constructed MnO_(2)/I_(2)-Zn battery demonstrates a practical energy density of~37 Wh kg^(-1)and a competitive energy cost of<18 US$kWh^(-1)by taking into account the cathode,anode,and electrolyte.The MnO_(2)/I_(2)-Zn battery,with its remarkable reversibility and reasonable energy density,enlightens a new arena of large-scale energy storage devices.

Enlarging Zn deposition space via regulating Sn-induced effective interface for high areal capacity zinc-based flow battery

Zinc-based flow batteries(ZFBs)have aroused great favor in large-scale energy storage due to the high security and low cost.However,the low areal capacity arising from the limited space for Zn plating hinders the further development.Herein,a novel carbon felt-Sn-carbon felt sandwich host(CSCH)is designed and constructed.Benefiting from the strong chemical absorption and the dehydration effect on Zn(H_(2)O)_(6)^(2+),the Sn activation layer in the CSCH demonstrates the lowest comprehensive resistance for Zn deposition.Thus,Zn is induced to nucleate preferentially on the Sn activation layer,and grows towards the membrane,regulating the spatial distribution of Zn electrochemical deposits,which remarkably improves the areal capacity and cyclic stability of Zn anode.Consequently,the zinc-bromine flow batteries equipped with CSCH electrodes can achieve the ultra-high areal capacity of 120 mA h cm^(-2)at 80 mA cm^(-2),and run stably for 140 h with average energy efficiency of 80.3%in the extreme condition(80 mA cm^(-2),80 mA h cm^(-2)).This innovative work will inspire future advanced designs for high areal capacity electrodes in ZFBs.

Residual Capacity of Friction⁃Type High⁃Strength Bolted T⁃stub Connection with Nut Corrosion Damage

Corrosion is a primary cause of the slippage of friction⁃type high⁃strength bolted(FHSB)T⁃stub connections.This paper attempts to quantify the residual capacity of FHSB T⁃stub connections with corroded nuts.Firstly,corrosion simulation tests were conducted on 48 manually cut nuts to find out the relationship between the damage degree of nut section and the residual clamping force(RCF)of bolt.Then,static load tests were carried out on 24 FHSB T⁃stub connections with nuts of different degrees of damage to obtain the failure modes.By finite⁃element(FE)models,a comparative analysis was performed on the initial friction load(IFL)and ultimate strength(US)of each connection with corroded nuts.Finally,the parameters of 96 FE models for FHSB T⁃stub connections were analyzed and used to derive the calculation formulas for the degree of damage for each nut and the IFL and US of each connection.The results show that the RCF decay of a bolt is a quadratic function of the equivalent radius loss ratio and the shear failure after nut corrosion;the IFL of each connection had a clear linear correlation with the RCF of the corresponding bolts,and the correlation depends on the applied load and static friction on connecting plate interface induced by the clamping force;the static friction had little impact on the US of the connection;the proposed IFL and US formulas can effectively derive the residual anti⁃slip capacity of FHSB T⁃stub connections from the degree of damage of the corroded nut section.The research results provide a scientific basis for the replacement and maintenance of corroded bolts of FHSB T⁃stub connections.

Fast hydrogenation kinetics of acridine as a candidate of liquid organic hydrogen carrier family with high capacity

Hydrogen has been deemed as one of the most efficient energy carriers for a broad variety of industrial applications[1,2].Large-scale,low-cost hydrogen production,safe storage and delivery represent a tremendous technological challenge and have become a subject of intense research and development activities in the past few decades[3–5].

A Silicon Monoxide Lithium-Ion Battery Anode with Ultrahigh Areal Capacity

Silicon monoxide(SiO)is an attractive anode material for next-generation lithium-ion batteries for its ultra-high theoretical capacity of 2680 mAh g−1.The studies to date have been limited to electrodes with a rela-tively low mass loading(<3.5 mg cm^(−2)),which has seriously restricted the areal capacity and its potential in practical devices.Maximizing areal capacity with such high-capacity materials is critical for capitalizing their potential in practi-cal technologies.Herein,we report a monolithic three-dimensional(3D)large-sheet holey gra-phene framework/SiO(LHGF/SiO)composite for high-mass-loading electrode.By specifically using large-sheet holey graphene building blocks,we construct LHGF with super-elasticity and exceptional mechanical robustness,which is essential for accommodating the large volume change of SiO and ensuring the structure integrity even at ultrahigh mass loading.Additionally,the 3D porous graphene network structure in LHGF ensures excellent electron and ion transport.By systematically tailoring microstructure design,we show the LHGF/SiO anode with a mass loading of 44 mg cm^(−2)delivers a high areal capacity of 35.4 mAh cm^(−2)at a current of 8.8 mA cm^(−2)and retains a capacity of 10.6 mAh cm^(−2)at 17.6 mA cm^(−2),greatly exceeding those of the state-of-the-art commercial or research devices.Furthermore,we show an LHGF/SiO anode with an ultra-high mass loading of 94 mg cm^(−2)delivers an unprecedented areal capacity up to 140.8 mAh cm^(−2).The achievement of such high areal capacities marks a critical step toward realizing the full potential of high-capacity alloy-type electrode materials in practical lithium-ion batteries.

Graphene as a High-capacity Anode Material for Lithium Ion Batteries

Graphene was produced via a soft chemistry synthetic route for lithium ion battery applications. The sample was characterized by X-ray diffraction, nitrogen adsorption-desorption, field emission scanning electron microscopy and transmission electron microscopy, respectively. The electrochemical performances of graphene as anode material were measured by cyclic voltammetry and galvanostatic charge/ discharge cycling. The experimental results showed that the graphene possessed a thin wrinkled paper-like morphology and large specific surface area （342 m2 · g ^-1）. The first reversible specific capacity of the graphene was as high as 905 mA· h · g ^-1 at a current density of 100 mA · g ^-1. Even at a high current density of 1000 or 2000 mA · g ^-1, the graphene maintained good cycling stability, indicating that it is a promising anode material for high-performance lithium ion batteries.

Highly Thermally Conductive Polymer/Graphene Composites with Rapid Room‑Temperature Self‑Healing Capacity

Composites that can rapidly self-healing their structure and function at room temperature have broad application prospects.However,in view of the complexity of composite structure and composition,its self-heal is facing challenges.In this article,supramolecular effect is proposed to repair the multistage structure,mechanical and thermal properties of composite materials.A stiff and tough supramolecular frameworks of 2-[[(butylamino)carbonyl]oxy]ethyl ester(PBA)–polydimethylsiloxane(PDMS)were established using a chain extender with double amide bonds in a side chain to extend prepolymers through copolymerization.Then,by introducing the copolymer into a folded graphene film(FGf),a highly thermally conductive composite of PBA–PDMS/FGf with self-healing capacity was fabricated.The ratio of crosslinking and hydrogen bonding was optimized to ensure that PBA–PDMS could completely self-heal at room temperature in 10 min.Additionally,PBA–PDMS/FGf exhibits a high tensile strength of 2.23±0.15 MPa at break and high thermal conductivity of 13±0.2 W m^(−1)K^(−1);of which the self-healing efficiencies were 100%and 98.65%at room temperature for tensile strength and thermal conductivity,respectively.The excellent self-healing performance comes from the efficient supramolecular interaction between polymer molecules,as well as polymer molecule and graphene.This kind of thermal conductive self-healing composite has important application prospects in the heat dissipation field of next generation electronic devices in the future.

High-capacity Bi_(2)O_(3) anode for 2.4 V neutral aqueous sodium-ion battery-supercapacitor hybrid device through phase conversion mechanism

Aqueous battery-supercapacitor hybrid devices(BSHs)are of great importance to enrich electrochemical energy storage systems with both high energy and power densities.However,further improvement of BSHs in aqueous electrolytes is greatly hampered by operating voltage and capacity limits.Different from the conventional intercalation/de-intercalation mechanism,Bi_(2)O_(3) implements charge storage by a reversible phase conversion mechanism.Herein,taking Bi_(2)O_(3) electrode with wide potential window(from-1.2 to 1 V vs.saturated calomel electrode)and high capacity as battery-type anode,we propose that the overall performance of aqueous BSHs can be greatly upgraded under neutral condition.By paring with stable layer-structuredδ-MnO_(2) cathode,a sodium-ion Bi_(2)O_(3)//MnO_(2) BSH with an ultrahigh voltage of 2.4 V in neutral sodium sulfate electrolyte is developed for the first time.This hybrid device exhibits high capacity(~215 C g^(-1) at 1 mA cm^(-2)),relatively long lifespan(~77.2%capacity retention after 1500 cycles),remarkable energy density(71.7 Wh kg^(-1)@400.5 W kg^(-1))and power density(3204.3 W kg^(-1)@18.8 Wh kg^(-1)).Electrochemical measurements combining a set of spectroscopic techniques reveal the reversible phase conversion between bismuth oxide and metallic bismuth(Bi_(2)O_(3)?Bi0)through Bi^(2+) transition phase in neutral sodium sulfate solution,which can deliver multielectron transfer up to 6,leading to the high-energy BSHs.Our work sheds light on the feasibility of using Bi_(2)O_(3) electrode under neutral condition to address the issue of narrow voltage and low capacity for aqueous BSHs.

Preparation and Electrochemical Performances of Nickel Metal Hydride Batteries with High Specific Volume Capacity

Cylindrical nickel metal hydride （Ni-MH） battery with high specific volume capacity was prepared by using the oxyhydroxide Ni（OH）2 and AB5 type hydrogen storage alloy and adjusting the designing parameters of positive and negative electrodes. The oxyhydroxide Ni（OH）2 was synthesized by oxidizing spherical β-Ni（OH）2 with chemical method. The X-ray diffraction （XRD） patterns and the Fourier transform infrared （PT-IR） spectra indicated that 7-NiOOH was formed on the oxyhydroxide Ni（OH）2 powders, and some H2O molecules were inserted into their crystal lattice spacing. The battery capacity could not be improved when the oxyhydroxide Ni（OH）2 sample was directly used as the positive active materials. However, based on the conductance and residual capacity of the oxyhydroxide Ni（OH）2 powders, AA size Ni-MH battery with 2560 mA.h capacity and 407 W·h·L^-1 specific volume energy at 0.2C was obtained by using the commercial spherical β-Ni（OH）2 and AB5-type hydrogen-storage alloy powders as the active materials when 10% mass amount of the oxyhydroxide Ni（OH）2 with 2.50 valence was added to the positive active materials and subsequently the battery designing parameters were adjusted as well. The as-prepared battery showed 70% initial capacity after 80 cycles at 0.5C. The possibility for adjusting the capacity ratio of positive and negative electrodes from 1 ： 1.35 to 1 ： 1.22 was demonstrated preliminarily. It is considered the as-prepared battery can meet the requirement of some special portable electrical instruments.

High Capacity Mobile Ad Hoc Network Using THz Frequency Enhancement

We propose a new design of the high channel capacity in Mobile Ad Hoc Network that uses the dense wave-length division multiplexing wavelength enhancement, in which the increasing in channel capacity and sig-nal security can be provided. The increasing in number of channel can be obtained by the increasing in wavelength density, while the security is introduced by the specific wavelength filter, which is operated by the Ad Hoc node operator and link with other nodes in coverage by dedicated one-to-one in direct or relay node. The optical communication wavelength enhancement is reviewed. The advantage is that the proposed system can be implemented and used incorporating with the existed communication link in both infrastruc-ture-based and Ad Hoc networks wireless network, where the privacy can be provided, which is discussed in details.

Pyridinic nitrogen enriched porous carbon derived from bimetal organic frameworks for high capacity zinc ion hybrid capacitors with remarkable rate capability

Aqueous zinc ion hybrid capacitors(ZIHCs)hold great potential for large-scale energy storage applications owing to their high safety and low cost,but suffer from low capacity and energy density.Herein,pyridinic nitrogen enriched porous carbon(nPC)was successfully synthesized via the growth,subsequent annealing and acid etching of bimetal organic frameworks for high capacity and safe ZIHCs with exceptional rate capability.Benefiting from the mesopores for easy ion diffusion,high electrical conductivity enabled by in-situ grown carbon nanotubes matrix and residual metal Co nanoparticles for fast electron transfer,sufficient micropores and high N content(8.9 at%)with dominated pyridinic N(54%)for enhanced zinc ion storage,the resulting nPC cathodes for ZIHCs achieved high capacities of 302 and137 m Ah g^(-1) at 1 and 18 A g^(-1),outperforming most reported carbon based cathodes.Theoretical results further disclosed that pyridinic N possessed larger binding energy of-4.99 eV to chemically coordinate with Zn2+than other N species.Moreover,quasi-solid-state ZIHCs with gelatin based gel electrolytes exhibited high energy density of 157.6 Wh kg^(-1) at 0.69 kW kg^(-1),high safety and mechanical flexibility to withstand mechanical deformation and drilling.This strategy of developing pyridinic nitrogen enriched porous carbon will pave a new avenue to construct safe ZIHCs with high energy densities.

Comparison of Gas Distribution Properties of Conventional and High Capacity Structured Packings

This paper presents the results of an experimental study carried out using large scale equipment to observe the effect of geometry on gas distribution properties of a high capacity corrugated sheet structured packing （Montz-pak B 1-250M） and to compare it with that of its conventional counterpart （Montz-pak B1-250）. Although the high capacity packing exhibits a significantly lower overall pressure drop, the gas distribution performance is similar to that of the conventional packing, and in both cases consistently good one.

Extreme high reversible capacity with over 8.0 wt% and excellent hydrogen storage properties of MgH2 combined with LiBH4 and Li3AlH6

Magnesium hydride has attracted great attention because of its high theoretical capacity and outstanding reversibility, nevertheless, its practical applications have been restricted by the disadvantages of the sluggish kinetics and high thermodynamic stability. In this work, an unexpected high reversible hydrogen capacity over 8.0 wt% has been achieved from MgH2 metal hydride composited with small amounts of LiBH4 and Li3AlH6 complex hydrides, which begins to release hydrogen at 276 ℃ and then completely dehydrogenates at 360 ℃. The dehydrogenated MgH2+LiBH4/Li3AlH6 composite can fully reabsorb hydrogen below 300 ℃ with an excellent cycling stability. The composite exhibits a significant reduction of dehydrogenation activation energy from 279.7 kJ/mol(primitive MgH2) to 139.3 kJ/mol(MgH2+LiBH4/Li3AlH6),as well as a remarkable reduction of dehydrogenation enthalpy change from 75.1 k J/mol H2(primitive MgH2) to 62.8 kJ/mol H2(MgH2+LiBH4/Li3AlH6). The additives of LiBH4 and Li3AlH6 not only enhance the cycling hydrogen capacity, but also simultaneously improve the reversible de/rehydrogenation kinetics, as well as the dehydrogenation thermodynamics. This notable improvement on the hydrogen absorption/desorption behaviors of the MgH2+LiBH4/Li3AlH6 composite could be attributed to the dehydrogenated products including Li3Mg7, Mg17Al12 and MgAlB4, which play a key role on reducing the dehydrogenation activation energy and increasing diffusion rate of hydrogen. Meanwhile, the LiBH4 and Li3AlH6 effectively destabilize MgH2 with a remarkable reduction on dehydrogenation enthalpy change in terms of thermodynamics. In particular, the Li3Mg7, Mg17Al12 and MgAlB4 phases can reversibly transform into MgH2, Li3AlH6 and LiBH4 after rehydrogenation, which contribute to maintain a high cycling capacity.This constructing strategy can further promote the development of high reversible capacity Mg-based materials with suitable de/rehydrogenation properties.

Effect of yttrium on microstructure and mold filling capacity of a near-α high temperature titanium alloy

The addition of rare earth yttrium(Y) can improve the performances of high temperature titanium alloys,such as the tensile ductility,thermal stability and creep property,etc.However,few studies on the effect of Y on the castability of titanium alloys have been carried out,which is significant to fabrication of thin-walled complex titanium castings by investment casting.In this study,the microstructure and mold filling capacity of a Ti-1100 alloy with different Y additions(0,0.1wt.%,0.3wt.%,0.5wt.% and 1.0wt.%) were investigated systematically through investment casting experiments,and the casting experiments were carried out in a centrifugal titanium casting machine.The microstructures of the alloy were observed via the optical microscopy,scanning electron microscopy and transmission electron microscopy.The mold filling capacity was tested by using of a grid pattern and was evaluated by the number of segments completely filled by the cast alloy.The results indicate that the grain size is decreased and the mold filling capacity is improved significantly with increasing the addition of Y from 0 to 1.0wt.%.The average primary grain size of Ti-1100 alloy is reduced from 250 μm to 50 μm and the mold filling capacity is increased from 61.5% to 100%.Considering the potential harmful effect on tensile properties of titanium alloys due to high concentrations of Y,it is suggested that Y addition should be about 0.3wt.%.

A High Capacity and Working Voltage Potassium-Based Dual Ion Batteries

Potassium-based dual ion batteries(KDIBs)have attracted significant attention owing to high working voltage,high safety,low processing cost,and environmental friendliness.Nevertheless,one great challenge for practical KDIBs is to develop suitable anode materials with high specific capacity.Herein,we report an architecture of hierarchically porous antimony nanoparticles/carbon nanofibers(HPSb CNFs)as flexible,free-standing anode for high-performance KDIBs.The HPSb CNFs with hierarchically porous structure,and high-content nitrogen doping,not only offer sufficient free space to tolerate the repetitive volume expansion of Sb nanoparticles during long-term cycling,but also greatly facilitate the transport of electrons and ions within electrode,ensuring high material utilization ratio.Thus,the KDIBs,constituted by HPSb CNFs-700(calcined at 700°C)anode and graphite cathode,exhibited a high reversible capacity of 440 m Ah g^(-1)with high discharge medium voltage of 4.5 V at a specific current of 200 m A g^(-1)(the highest capacity for all KDIBs normalized by the mass of the anode),and excellent cyclic life.Outstanding electrochemical reversibility of the KDIBs was further demonstrated by ex situ XRD,ex situ Raman spectrum,and HRTEM.These results suggest the as-designed HPSb CNFs-700 with highcapacity and long-term cycling stability is a promising anode material for high-performance KDIBs.

“All‐In‐One” integrated ultrathin SnS2@3D multichannel carbon matrix power high‐areal–capacity lithium battery anode

Construction of a thickness‐independent electrode with high active material mass loading is crucial for the development of high energy rechargeable lithium battery.Herein,we fabricate an all‐in‐one integrated SnS2@3D multichannel carbon matrix(SnS2@3DMCM)electrode with in‐situ growth of ultrathin SnS2 nanosheets inside the inner walls of three dimensional(3D)multichannels.The interconnected conductive carbon matrix derived from natural wood acts as an integrated porous current collector to avail the electrons transport and accommodate massive SnS2 nanosheets,while plenty of 3D aligned multichannels facilitate fast ions transport with electrode thickness‐independent even under high mass loading.As expected,the integrated SnS2@3DMCM electrode exhibits remarkable electrochemical lithium storage performance,such as exceptional high‐areal‐capacity of 6.4 mAh cm−2,high rate capability of 3 mAh cm−2 under current of 6.8 mAcm−2(10 C),and stable cycling performance of 6.8 mAcm−2 with a high mass loading of 7mg cm−2.The 3D integrated porous electrode constructing conveniently with the natural source paves new avenues towards future high‐performance lithium batteries.

Maximum heat transfer capacity of high temperature heat pipe with triangular grooved wick

A mathematical model was developed to predict the maximum heat transfer capacity of high temperature heat pipe with triangular grooved wick. The effects of the inclination angle and geometry structure were considered in the proposed model.Maximum heat transfer capacity was also investigated experimentally. The model was validated by comparing with the experimental results. The maximum heat transfer capacity increases with the vapor core radius increasing. Compared with the inclination angle of0°, the maximum heat transfer capacity increases at the larger inclination angle, and the change with temperature is larger. The performance of heat pipe with triangular grooved wick is greatly influenced by gravity, so it is not recommended to be applied to the dish solar heat pipe receiver.

A high Li-ion diffusion kinetics in multidimensional and compact-structured electrodes via vacuum filtration casting

Manufacturing process,diffusion co-efficient and areal capacity are the three main criteria for regulating thick electrodes for lithium-ion batteries(LIBs).However,simultaneously regulating these criteria for LIBs is desirable but remains a significant challenge.In this work,niobium pentoxide(Nb_(2)O_(5))anode and lithium iron phosphate(LiFePO_(4))cathode materials were chosen as the model materials and demonstrate that these three parameters can be simultaneously modulated by incorporation of micro-carbon fibers(MCF)and carbon nanotubes(CNT)with both Nb_(2)O_(5) and LFP via vacuum filtration approach.Both as-prepared MNC-20 anode and MLC-20 cathode achieves high reversible areal capacity of≈5.4 m A h cm^(-2)@0.1 C and outstanding Li-ion diffusion coefficients of≈10~(-8)cm~2 s~(-1)in the half-cell configuration.The assembled MNC-20‖MLC-20 full cell LIB delivers maximum energy and power densities of244.04 W h kg^(-1)and 108.86 W kg^(-1),respectively.The excellent electrochemical properties of the asprepared thick electrodes can be attributed to the highly conductive,mechanical compactness and multidimensional mutual effects of the MCF,CNT and active materials that facilitates rapid Li-ion diffusion kinetics.Furthermore,electrochemical impedance spectroscopy(EIS),symmetric cells analysis,and insitu Raman techniques clearly validates the enhanced Li-ion diffusion kinetics in the present architecture.