Sixteen indole derivatives have been computed at B3LYP/6-31 IG^＊＊ level using density functional theory （DFF）. Based on linear solvation energy theory, the structural parameters were employed to present correlatio...Sixteen indole derivatives have been computed at B3LYP/6-31 IG^＊＊ level using density functional theory （DFF）. Based on linear solvation energy theory, the structural parameters were employed to present correlation between the parameters of chromatograph capacity factor （CCF） and molecular structural parameters. As a result, the correlation equation of the reversed phased high performance liquid chromatograph capacity factor to the intercept lgk＇w and slope S of CCF were obtained, from which the correlation coefficients of lgk＇w to the structural parameters are r^2 = 0.9596 and q^2 = 0.9262. While the correlation coefficients of the parameter S r^2 q^2 with structures are = 0.9750 and = 0.9252. Moreover, the effect of water as solvent on the present two models was also considered using SCRF method, and the result shows that the predicting capacity of correlation equation of lgkw＇ increases, while that of the model for S decreases slightly. Both two correlation equations achieved in this work are more advantageous than those using theoretical descriptors from molecular connectivity indices.展开更多
为了合理评估高比例新能源并网的多馈入高压直流输电(multi-infeed HVDC,MIDC)系统电压支撑能力,该文首先分析MIDC系统结构特点,随后基于多馈入短路比(multi-infeed short circuit ratio,MISCR)指标,并结合新能源短路电流幅值和相位随...为了合理评估高比例新能源并网的多馈入高压直流输电(multi-infeed HVDC,MIDC)系统电压支撑能力,该文首先分析MIDC系统结构特点,随后基于多馈入短路比(multi-infeed short circuit ratio,MISCR)指标,并结合新能源短路电流幅值和相位随机端电压变化的特性(以下简称“幅相特性”),提出多馈入暂态短路比(multi-infeed transient short circuit ratio,MITSCR)指标;其次,根据国家标准的要求分析以双馈风机(doubly-fed induction generator,DFIG)为代表的新能源在不同控制模式下的幅相特性,并通过MITSCR指标分析DFIG接入对MIDC系统节点电压支撑能力影响;最后,利用PSACD/EMTDC软件进行时域仿真分析,结果表明,MITSCR指标能有效表征节点的电压支撑能力,验证了该指标的有效性与优越性。展开更多
The new generation particle accelerator requires a highly stable radio frequency（RF） system. The stability of the RF system is realized by the Low Level RF（LLRF） subsystem which controls the amplitude and phase of...The new generation particle accelerator requires a highly stable radio frequency（RF） system. The stability of the RF system is realized by the Low Level RF（LLRF） subsystem which controls the amplitude and phase of the RF signal. The detection of the RF signal＇s amplitude and phase is fundamental to LLRF controls. High-speed ADC（Analog to Digital Converter） ,DAC（Digital to Analog Converter） and FPGA（Field Programmable Gate Array） play very important roles in digital LLRF control systems. This paper describes the implementation of real-time amplitude and phase detection based of the FPGA with an analysis of the main factors that affect the detection accuracy such as jitter,algorithm＇s defects and non-linearity of devices,which is helpful for future work on high precision detection and control.展开更多
相控阵列天线的各收发通道幅相误差会对其性能产生较大影响。在分析相控阵列天线幅相误差的产生原因的基础上,提出了一种幅相误差外、内校准结合方法,其中外校准方法基于(Multiple Signal Classification,MUSIC)算法引入模拟退火算法对...相控阵列天线的各收发通道幅相误差会对其性能产生较大影响。在分析相控阵列天线幅相误差的产生原因的基础上,提出了一种幅相误差外、内校准结合方法,其中外校准方法基于(Multiple Signal Classification,MUSIC)算法引入模拟退火算法对互耦矩阵和阵元位置扰动进行联合估计,可补偿加工制造安装公差及天线阵元间的互耦导致的幅相误差,内校准方法可补偿天线工作环境变化、器件老化等因素导致的幅相误差。计算机仿真结果表明了方法的有效性。展开更多
动态原子力显微镜(atomic force microscope,AFM)是通过检测悬臂谐振状态的变化来对物体表面形貌进行测量的。通过对谐振状态的三种因素即振幅、相位、频率的检测,动态AFM可以分为三种工作模式,即振幅反馈、相位反馈与频率反馈模式,这...动态原子力显微镜(atomic force microscope,AFM)是通过检测悬臂谐振状态的变化来对物体表面形貌进行测量的。通过对谐振状态的三种因素即振幅、相位、频率的检测,动态AFM可以分为三种工作模式,即振幅反馈、相位反馈与频率反馈模式,这三种反馈模式有着不同的扫描特点。基于硅悬臂具有高阶谐振的特性,动态原子力显微镜可以在悬臂工作于高阶谐振状态时对物体进行扫描。综合上述工作模式研制了一套多模态动态AFM,可以在三种反馈模式、不同阶谐振状态下对物体进行扫描测量。利用该系统在不同反馈模式、不同阶谐振状态下进行了扫描测试,结果显示,系统在各模式下具有亚纳米分辨力,其中在相位反馈模式,悬臂二阶谐振时可达到最优灵敏度与分辨力,分别为17.5V/μm和0.29nm,在最优灵敏度与分辨力状态下对光栅试样进行了三维扫描,得到光栅的三维形貌图。展开更多
基金This work was supported by the National Basic Research Program of China (2003CB415002) and the China Postdoctoral Science Foundation (No. 2003033486) and the Natural Science Research Fund of University in Jiangsu (04KJB150149)
文摘Sixteen indole derivatives have been computed at B3LYP/6-31 IG^＊＊ level using density functional theory （DFF）. Based on linear solvation energy theory, the structural parameters were employed to present correlation between the parameters of chromatograph capacity factor （CCF） and molecular structural parameters. As a result, the correlation equation of the reversed phased high performance liquid chromatograph capacity factor to the intercept lgk＇w and slope S of CCF were obtained, from which the correlation coefficients of lgk＇w to the structural parameters are r^2 = 0.9596 and q^2 = 0.9262. While the correlation coefficients of the parameter S r^2 q^2 with structures are = 0.9750 and = 0.9252. Moreover, the effect of water as solvent on the present two models was also considered using SCRF method, and the result shows that the predicting capacity of correlation equation of lgkw＇ increases, while that of the model for S decreases slightly. Both two correlation equations achieved in this work are more advantageous than those using theoretical descriptors from molecular connectivity indices.
基金Supported by Knowledge Innovation Program of Chinese Academy of Sciences and National Natural Science Foundation of China (10675142)
文摘The new generation particle accelerator requires a highly stable radio frequency（RF） system. The stability of the RF system is realized by the Low Level RF（LLRF） subsystem which controls the amplitude and phase of the RF signal. The detection of the RF signal＇s amplitude and phase is fundamental to LLRF controls. High-speed ADC（Analog to Digital Converter） ,DAC（Digital to Analog Converter） and FPGA（Field Programmable Gate Array） play very important roles in digital LLRF control systems. This paper describes the implementation of real-time amplitude and phase detection based of the FPGA with an analysis of the main factors that affect the detection accuracy such as jitter,algorithm＇s defects and non-linearity of devices,which is helpful for future work on high precision detection and control.
文摘相控阵列天线的各收发通道幅相误差会对其性能产生较大影响。在分析相控阵列天线幅相误差的产生原因的基础上,提出了一种幅相误差外、内校准结合方法,其中外校准方法基于(Multiple Signal Classification,MUSIC)算法引入模拟退火算法对互耦矩阵和阵元位置扰动进行联合估计,可补偿加工制造安装公差及天线阵元间的互耦导致的幅相误差,内校准方法可补偿天线工作环境变化、器件老化等因素导致的幅相误差。计算机仿真结果表明了方法的有效性。
文摘动态原子力显微镜(atomic force microscope,AFM)是通过检测悬臂谐振状态的变化来对物体表面形貌进行测量的。通过对谐振状态的三种因素即振幅、相位、频率的检测,动态AFM可以分为三种工作模式,即振幅反馈、相位反馈与频率反馈模式,这三种反馈模式有着不同的扫描特点。基于硅悬臂具有高阶谐振的特性,动态原子力显微镜可以在悬臂工作于高阶谐振状态时对物体进行扫描。综合上述工作模式研制了一套多模态动态AFM,可以在三种反馈模式、不同阶谐振状态下对物体进行扫描测量。利用该系统在不同反馈模式、不同阶谐振状态下进行了扫描测试,结果显示,系统在各模式下具有亚纳米分辨力,其中在相位反馈模式,悬臂二阶谐振时可达到最优灵敏度与分辨力,分别为17.5V/μm和0.29nm,在最优灵敏度与分辨力状态下对光栅试样进行了三维扫描,得到光栅的三维形貌图。
