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Fluid-chemical modeling of the near-cathode sheath formation process in a high current broken in DC air circuit breaker
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作者 彭世东 李静 +3 位作者 段薇 曹云东 刘树鑫 黄浩 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期523-538,共16页
When the contacts of a medium-voltage DC air circuit breaker(DCCB) are separated, the energy distribution of the arc is determined by the formation process of the near-electrode sheath. Therefore, the voltage drop thr... When the contacts of a medium-voltage DC air circuit breaker(DCCB) are separated, the energy distribution of the arc is determined by the formation process of the near-electrode sheath. Therefore, the voltage drop through the near-electrode sheath is an important means to build up the arc voltage, which directly determines the current-limiting performance of the DCCB. A numerical model to describe the near-electrode sheath formation process can provide insight into the physical mechanism of the arc formation, and thus provide a method for arc energy regulation. In this work, we establish a two-dimensional axisymmetric time-varying model of a medium-voltage DCCB arc when interrupted by high current based on a fluid-chemical model involving 16 kinds of species and 46 collision reactions. The transient distributions of electron number density, positive and negative ion number density, net space charge density, axial electric field, axial potential between electrodes, and near-cathode sheath are obtained from the numerical model. The computational results show that the electron density in the arc column increases, then decreases, and then stabilizes during the near-cathode sheath formation process, and the arc column's diameter gradually becomes wider. The 11.14 V–12.33 V drops along the17 μm space charge layer away from the cathode(65.5 k V/m–72.5 k V/m) when the current varies from 20 k A–80 k A.The homogeneous external magnetic field has little effect on the distribution of particles in the near-cathode sheath core,but the electron number density at the near-cathode sheath periphery can increase as the magnetic field increases and the homogeneous external magnetic field will lead to arc diffusion. The validity of the numerical model can be proven by comparison with the experiment. 展开更多
关键词 near-cathode sheath atmospheric pressure air arc fluid-chemical model high current DC air circuit breaker(DCCB)
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A theoretical analysis of the electromigration-induced void morphological evolution under high current density 被引量:7
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作者 Yuexing Wang Yao Yao 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2017年第5期868-878,共11页
In this work, analysis of electromigration-induced void morphological evolution in solder interconnects is performed based on mass diffusion theory. The analysis is conducted for three typical experimentally observed ... In this work, analysis of electromigration-induced void morphological evolution in solder interconnects is performed based on mass diffusion theory. The analysis is conducted for three typical experimentally observed void shapes: circular, ellipse, and cardioid. Void morphological evolution is governed by the competition between the electric field and surface capillary force. In the developed model, both the electric field and capillary force on the void's surface are solved analytically. Based on the mass conversation principle, the normal velocity on the void surface during diffusion is obtained. The void morphological evolution behavior is investigated, and a physical model is developed to predict void collapse to a crack or to split into sub-voids under electric current. It is noted that when the electric current is being applied from the horizontal direction, a circular void may either move stably along the electric current direction or collapse to a finger shape, depending on the relative magnitude of the electric current and surface capillary force. However, the elliptical-shaped void will elongate along the electric current direction and finally collapse to the finger shape. On the other hand, the cardioid-shaped void could bifurcate into two sub-voids when the electric current reaches a critical value. The theoretical predictions agree well with the experimental observations. 展开更多
关键词 ELECTROMIGRATION Analytical solution Void evolution high current density Mass diffusion
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Research of growth mechanism of ceramic coatings fabricated by micro-arc oxidation on magnesium alloys at high current mode 被引量:12
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作者 Wei-wei Chen Ze-xin Wang +1 位作者 Lei Sun Sheng Lu 《Journal of Magnesium and Alloys》 SCIE EI CAS 2015年第3期253-257,共5页
Micro-arc oxidation(MAO)coatings of ZK60 magnesium alloys were formed in a self-developed dual electrolyte composed of sodium silicate and phosphate at the high constant current of 1.8 A(15 A/dm^(2)).The MAO process a... Micro-arc oxidation(MAO)coatings of ZK60 magnesium alloys were formed in a self-developed dual electrolyte composed of sodium silicate and phosphate at the high constant current of 1.8 A(15 A/dm^(2)).The MAO process and growth mechanism were investigated by scanning electron microscopy(SEM)coupled with an energy dispersive spectrometer(EDS),confocal laser scanning microscopy and X-ray diffraction(XRD).The results indicate that the growth process of MAO coating mainly goes through“forming→puncturing→rapid growth of micro-arc oxidation→large arc discharge→self-repairing”.The coating grows inward and outward at the same time in the initial stage,but outward growth of the coating is dominant later.Mg,Mg_(2)SiO_(4) and MgO are the main phases of ceramic coating. 展开更多
关键词 ZK60 magnesium alloys Micro-arc oxidation high current Growth mechanism
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The Development of a Megawatt-Level High Current Ion Source 被引量:6
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作者 胡纯栋 谢亚红 NBI team 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第1期75-77,共3页
Neutral beam injection is one of the main plasma heating methods in nuclear fusion devices. In order to support the scientific study of the Experimental Advanced Superconducting Tokamak (EAST), a megawatt-level high... Neutral beam injection is one of the main plasma heating methods in nuclear fusion devices. In order to support the scientific study of the Experimental Advanced Superconducting Tokamak (EAST), a megawatt-level high current ion source is designed and manufactured in the ASIPP, and the progress and preliminary test results will be presented in this paper. 展开更多
关键词 NBI ion source MEGAWATT high current
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N‑Doped Graphene‑Decorated NiCo Alloy Coupled with Mesoporous NiCoMoO Nano‑sheet Heterojunction for Enhanced Water Electrolysis Activity at High Current Density 被引量:8
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作者 Guangfu Qian Jinli Chen +2 位作者 Tianqi Yu Lin Luo Shibin Yin 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第5期77-89,共13页
Developing highly effective and stable non-noble metalbased bifunctional catalyst working at high current density is an urgent issue for water electrolysis(WE).Herein,we prepare the N-doped graphene-decorated NiCo all... Developing highly effective and stable non-noble metalbased bifunctional catalyst working at high current density is an urgent issue for water electrolysis(WE).Herein,we prepare the N-doped graphene-decorated NiCo alloy coupled with mesoporous NiCoMoO nano-sheet grown on 3D nickel foam(NiCo@C-NiCoMoO/NF)for water splitting.NiCo@C-NiCoMoO/NF exhibits outstanding activity with low overpotentials for hydrogen and oxygen evolution reaction(HER:39/266 mV;OER:260/390 mV)at±10 and±1000 mA cm^(−2).More importantly,in 6.0 M KOH solution at 60℃ for WE,it only requires 1.90 V to reach 1000 mA cm−2 and shows excellent stability for 43 h,exhibiting the potential for actual application.The good performance can be assigned to N-doped graphene-decorated NiCo alloy and mesoporous NiCoMoO nano-sheet,which not only increase the intrinsic activity and expose abundant catalytic activity sites,but also enhance its chemical and mechanical stability.This work thus could provide a promising material for industrial hydrogen production. 展开更多
关键词 N-doped graphene-decorated NiCo alloy Catalyst Mesoporous nano-sheet Water electrolysis high current density
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Compounded Surface Modification of ZK60 Mg Alloy by High Current Pulsed Electron Beam+Micro-plasma Oxidation 被引量:3
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作者 高波 郝仪 +3 位作者 涂赣峰 石为喜 于福晓 李世伟 《Plasma Science and Technology》 SCIE EI CAS CSCD 2010年第1期67-70,共4页
In this study, compounded surface modification technology-high current pulsed electron beam (HCPEB) + micro-plasma oxidation (MPO) was applied to treat ZK60 Mg alloys. The characteristics of the microstructure of... In this study, compounded surface modification technology-high current pulsed electron beam (HCPEB) + micro-plasma oxidation (MPO) was applied to treat ZK60 Mg alloys. The characteristics of the microstructure of ZK60 Mg alloy after single MPO and HCPEB+MPO compounded treatment were investigated by SEM. The results showed that the density of the ceramic layer of HCPEB+MPO-treated ZK60 Mg alloy was improved and defects were reduced compared to that under MPO treatment alone. Surface modified layer of ZK60 Mg alloys treated by HCPEB+MPO was divided into three zones, namely the top loose ceramic zone, middle compact zone and inside HCPEB-induced melted zone. Corrosion resistance of ZK60 Mg alloy before and after the compounded surface modification was measured in a solution of 3.5% NaCl by potentiodynamic polarization curves. It was found that the corrosion current density of ZK60 Mg alloys could be reduced by about three orders of magnitude, from 311μA/cm^2 of the original sample to 0.2μA/cm^2 of the HCPEB+MPO-treated sample. This indicates the great application potential of the HCPEB+MPO compounded surface modification technology in improving the corrosion resistance of ZK60 Mg alloys in the future. 展开更多
关键词 ZK60 Mg alloy high current pulsed electron beam micro-plasma oxidation compounded surface modification corrosion resistance
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Regulation of hydrogen evolution performance of titanium oxide-carbon composites at high current density with a Ti-O hybrid orbital 被引量:1
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作者 Meichen Liu Zhiping Lei +9 位作者 Qingping Ke Peixin Cui Jiancheng Wang Jingchong Yan Zhanku Li Hengfu Shui Shibiao Ren Zhicai Wang Ying Kong Shigang Kang 《Carbon Energy》 SCIE CAS 2022年第3期480-490,共11页
Rational design and controllable synthesis of practical electrodes with high sta bility and activity at high current density for a hydrogen evolution reaction(HER)are critical for renewable and sustainable energy conv... Rational design and controllable synthesis of practical electrodes with high sta bility and activity at high current density for a hydrogen evolution reaction(HER)are critical for renewable and sustainable energy conversion.However,high-performance TiO_(2)-based electrocatalysts for HER are quite limited,and the cat alytic active centers still remain elusive.Herein,a simple strategy is demonstrated for the synthesis of TiO_(2)-carbon composite(TiO_(2)/C)with high HER performance and stability.The remarkable HER performance of TiO_(2)/C can be ascribed to the doping of carbon atoms,which leads to stronger hybridization of Ti 3d and O 2p orbitals,thus substantially improving the electrocatalytic efficiency.This study elucidates that the hydrogen evolution activity of oxide electrocatalysts can be largely improved by regulating their electronic structures by doping carbon atoms and also provides an effective strategy for designing heterostructured electro catalysts with high catalytic activity and stability at high current density for HER. 展开更多
关键词 C doping HER high current density Ti-O hybridization TiO_(2)/C
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Characterizing modified surface layer of 316L stainless steel treated by high current pulsed electron beam
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作者 GROSDIDIER Thierry 《Rare Metals》 SCIE EI CAS CSCD 2007年第S1期61-66,共6页
High current pulsed electron beam(HCPEB) is now developing as a useful tool for surface modification of materials.When concentrated electron flux transferring its energy into the surface layer of target material withi... High current pulsed electron beam(HCPEB) is now developing as a useful tool for surface modification of materials.When concentrated electron flux transferring its energy into the surface layer of target material within a short pulse time,coupled thermal and stress processes would lead to the formation of metastalbe microstructure with improved properties.In the present work,HCPEB treatment of 316L stainless steel(SS) was carried out and the microstructural changes in modified surface layer were characterized with optical microscopy,X-ray diffractometry and electron backscatter diffractometry(EBSD) techniques.The corrosion resistance of modified surface was measured in a 5wt.% salt solution.The evolution regularity of surface craters and grain refinement effect,as well as the preferred orientation of(111) crystal plane occurring in the HCPEB treatment under different working parameters were discussed along with their influence on corrosion resistance. 展开更多
关键词 high current pulsed electron beam surface modification 316L stainless steel MICROSTRUCTURE CORROSION
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Microstructure and properties of Nb/Ta multilayer films irradiated by a high current pulse electron beam
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作者 马欣新 郭光伟 +2 位作者 唐光泽 孙明仁 王黎钦 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第5期407-411,共5页
Nb/Ta multilayer films deposited on Ti6A14V substrate with Nb and Ta monolayer thicknesses of 30 nm, 120 nm, and 240 nm were irradiated by a high current pulse electron beam (HCPEB) to prepare Nb-Ta alloyed layers. ... Nb/Ta multilayer films deposited on Ti6A14V substrate with Nb and Ta monolayer thicknesses of 30 nm, 120 nm, and 240 nm were irradiated by a high current pulse electron beam (HCPEB) to prepare Nb-Ta alloyed layers. The mi- crostructure and the composition of the outmost surface of melted alloyed layers were investigated using a transmission electron microscope (TEM) equipped with an X-ray energy dispersive spectrometer (EDS) attachment. The Ta content of the alloyed surface layer prepared from the monolayer of thickness 30 nm, 120 nm, and 240 nm was- 27.7 at.%, 6.37 at.%, and 0 at.%, respectively. It was found that the Ta content in the alloyed layer plays a dominant role in the microstructure of the films. The hardness and the wear rate of the alloyed layers decrease with the increasing content of Ta in the surface laver. 展开更多
关键词 Nb-Ta alloyed layer multilayer film high current pulse electron beam wear resistance
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A novel 4H-SiC lateral bipolar junction transistor structure with high voltage and high current gain
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作者 邓永辉 谢刚 +1 位作者 汪涛 盛况 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第9期559-563,共5页
In this paper, a novel structure of a 4H-SiC lateral bipolar junction transistor (LBJT) with a base tield plate and double RESURF in the drift region is presented. Collector-base junction depletion extension in the ... In this paper, a novel structure of a 4H-SiC lateral bipolar junction transistor (LBJT) with a base tield plate and double RESURF in the drift region is presented. Collector-base junction depletion extension in the base region is restricted by the base field plate. Thin base as well as low base doping of the LBJT therefore can be achieved under the condition of avalanche breakdown. Simulation results show that thin base of 0.32 μm and base doping of 3 × 1017 cm 3 are obtained, and corresponding current gain is as high as 247 with avalanche breakdown voltage of 3309 V when the drift region length is 30 μm. Besides, an investigation of a 4H-SiC vertical BJT (VBJT) with comparable breakdown voltage (3357 V) shows that the minimum base width of 0.25 ~tm and base doping as high as 8 × 10^17 cm^-3 contribute to a maximum current gain of only 128. 展开更多
关键词 4H-SIC lateral bipolar junction transistor (BJT) high current gain high breakdown voltage
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High-Performance In0.23Ga0.77As Channel MOSFETs with High Current Ratio Ion/Ioff Grown on Semi-insulating GaAs Substrates by MOCVD
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作者 孔祥挺 周旭亮 +4 位作者 李士颜 乔丽君 刘洪刚 王圩 潘教青 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第3期121-123,共3页
We demonstrate high-performance In0.23 Ga0.77 As channel metal-oxide-semiconductor field-effect transistors ( MOS- FETs) with high on-current to off-current (Ion/Ioff) ratio grown on semi-insulating GaAs wafers by... We demonstrate high-performance In0.23 Ga0.77 As channel metal-oxide-semiconductor field-effect transistors ( MOS- FETs) with high on-current to off-current (Ion/Ioff) ratio grown on semi-insulating GaAs wafers by metal-organic chemical vapor deposition (MOCVD). The 2μm channel-length devices exhibit a peak extrinsic transeonductance of 150 mS/mm and a drain current up to 500 mA/mm. The maximum effective mobility is 1680 cm2/Vs extracted by the split C-V method. Furthermore, the Ion/Ioff ratio is significantly improved from approximately 4.5 × 10^3 up to approximately 4.32 × 10^4 by controlling the etch thickness of In0.49Ga0.51P, The high drain current and high Ion/Ioff ratio of the In0.23Ga0.77As channel MOSFETs are achieved due to the high effective mobility and the low gate leakage current density. 展开更多
关键词 As Channel MOSFETs with high current Ratio I MOSFET Ga Grown on Semi-insulating GaAs Substrates by MOCVD off
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Ultra Fast Shutter Driven by Pulsed High Current
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作者 曾江涛 孙凤举 +3 位作者 邱爱慈 尹佳辉 郭建明 陈玉兰 《Plasma Science and Technology》 SCIE EI CAS CSCD 2005年第2期2781-2784,共4页
Radiation simulation utilizing plasma radiation sources (PRS) generates a large number of undesirable debris, which may damage the expensive diagnosing detectors. An ultra fast shutter (UFS) driven by pulsed high curr... Radiation simulation utilizing plasma radiation sources (PRS) generates a large number of undesirable debris, which may damage the expensive diagnosing detectors. An ultra fast shutter (UFS) driven by pulsed high current can erect a physical barrier to the slowly moving debris after allowing the passage of X-ray photons. The UFS consists of a pair of thin metal foils twisting the parallel axes in a Nylon cassette, compressed with an outer magnetic field, generated from a fast capacitor bank, discharging into a single turn loop. A typical capacitor bank is of 7.5μF charging voltages varying from 30 kV to 45 kV, with corresponding currents of approximately 90 kA to140 kA and discharging current periods of approximately 13.1μs. A shutter closing time as fast as 38 microseconds has been obtained with an aluminium foil thickness of 100 micrometers and a cross-sectional area of 15 mm by 20 mm. The design, construction and the expressions of the valve-closing time of the UFS are presented along with the measured results of valve-closing velocities. 展开更多
关键词 plasma radiation source (PRS) ultra fast shutter pulsed high current
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High performance electrocoagulation process in treating palm oil mill effluent using high current intensity application 被引量:2
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作者 Mohd Nasrullah A.W.Zularisam +3 位作者 Santhana Krishnan Mimi Sakinah Lakhveer Singh Yap Wing Fen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第1期208-217,共10页
Electrocoagulation process using high current intensity to treat palm oil mill effluent(POME) was investigated in this study.Various operating parameters such as electrolysis time, inter-electrode distance and initial... Electrocoagulation process using high current intensity to treat palm oil mill effluent(POME) was investigated in this study.Various operating parameters such as electrolysis time, inter-electrode distance and initial pH were carried out to determine the efficient process condition on the removal of chemical oxygen demand(COD),biological oxygen demand(BOD) and suspended solids(SS).The highest treatment was achieved at 50 min with the removal efficiencies for COD, BOD and SS obtained as 85%, 83%, and 84%, respectively.More than 50 min treatment showed the fluctuated trends of removal efficiencies which can be considered insignificant.The application of higher current resulted in higher removals of organics while the gas bubbles also assisted in removing the pollutant particles by floatation.In an inter-electrode distance study, the removal efficiency decreased when inter-electrode distance was either higher or lower than 10 mm due to the increase of solution resistance and the decrease of anode active surface area.In initial pH study, it was found that high removal efficiencies were achieved in slightly acidic POME sample rather than in neutral or basic condition.An electrocoagulation process by using the optimum operating parameters was able to remove COD, BOD and SS up to 95%, 94% and 96% respectively.The experimental results confirm that application of high current intensity in electrocoagulation provided high treatment efficiency at a reduced reaction time. 展开更多
关键词 ELECTROCHEMISTRY Environment ELECTROCOAGULATION PALM oil MILL EFFLUENT high current INTENSITY
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Improvement of Wear Resistance of Magnesium Alloy AZ91HP by High Current Pulsed Electron Beam Treatment 被引量:2
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作者 GAOBo HAOSheng-zhi +3 位作者 ZOUJian-xin JIANGLi-min ZHOUJI-yang DONGChuang 《材料热处理学报》 EI CAS CSCD 北大核心 2004年第05B期1029-1031,共3页
Surface modification of magnesium alloy AZ91HP (9wt%Al, 0.5wt%Zn, 0.5wt%Mn, Mg remaining percentage) by high current pulsed electron beam (HCPEB) treatment was studied in this paper. The secondary phase MgnAln is near... Surface modification of magnesium alloy AZ91HP (9wt%Al, 0.5wt%Zn, 0.5wt%Mn, Mg remaining percentage) by high current pulsed electron beam (HCPEB) treatment was studied in this paper. The secondary phase MgnAln is nearly completely dissolved and as a result, a super-saturated solid solution forms on the re-melted surface. The microhardness is increased both in and far beyond the heat-affected zone (HAZ), reaching about 250um. Measurements on sliding wear have shown that the wear resistance of the treated samples was improved by a factor of about 2.4 as compared to the as-received sample. It is also found that the sliding wear resistance can be further improved by surface alloying with TiN. 展开更多
关键词 镁合金 HCPEB 磨损性能 AZ91HP 表面改性 高电流脉冲电子束
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Improvement of wear resistance of AZ31 and AZ91HP by high current pulsed electron beam treatment 被引量:1
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作者 高波 郝胜智 +1 位作者 董闯 涂赣峰 《中国有色金属学会会刊:英文版》 EI CSCD 2005年第5期978-984,共7页
The surface modification of magnesium alloys (AZ31 and AZ91HP) was studied by a high current pulsed electron beam(HCPEB). The results show that the cross-sectional microhardness of treated samples increases not only i... The surface modification of magnesium alloys (AZ31 and AZ91HP) was studied by a high current pulsed electron beam(HCPEB). The results show that the cross-sectional microhardness of treated samples increases not only in the heat affected zone(HAZ), but also beyond HAZ, reaching over 250μm. This is due to the action of quasi-static thermal stress and the shock thermal stress wave with materials, which result in its fast deformation on the surface layer and so increases microhardness. For the AZ91HP alloy, a nearly complete dissolution of the intermetallic phase Mg_ 17Al_ 12 is observed, and a super-saturated solid solution forms on the re-melted surface, which is due to the solute trapping effect during the fast solidification process. Measurements on sliding wear show that wear resistance is improved by approximately 5.6 and 2.4 times for the AZ31 and AZ91HP respectively, as compared with as-received samples. 展开更多
关键词 铝合金 磨损阻力 脉冲处理 电子波 强度 密度 金属相
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Phase Evolution Study and Optimization of the Heat Treatment Process for High Current Capacity Bi-2223 Tapes 被引量:1
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作者 白利锋 张胜楠 +3 位作者 LI Chengshan HAO Qingbin LIU Guoqing ZHANG Pingxiang 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2017年第4期862-865,共4页
Powder in tube process(PIT) was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment(HT1), intermediate rolling(IR), and second heat treat... Powder in tube process(PIT) was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment(HT1), intermediate rolling(IR), and second heat treatment(HT2) was performed. The phase evolution mechanism and microstructure changes during these heat treatment processes were systematically discussed. The influences of HT1 parameters on the phase evolution process of Bi-2223 tapes were discussed. With the optimized HT1 process, a proper Bi-2223 content of about 90% was achieved. HT2 process was also optimized by adding a post annealing process. An obvious increase of current capacity was obtained due to the enhancement of intergrain connections. Single filament Bi-2223 tapes with the critical current of Ic-90 A were fabricated with the optimized sintering process. 展开更多
关键词 high temperature superconductor Bi-2223 phase evolution spray drying critical current density
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Development of a high current short pulse electron gun
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作者 宗阳 张子民 +7 位作者 袁平 申晓康 赵全堂 王燕茹 李中平 曹树春 刘铭 景漪 《Nuclear Science and Techniques》 SCIE CAS CSCD 2014年第3期43-46,共4页
Dielectric wall accelerator(DWA), towards high gradient acceleration field(30 MeV/m–100 MeV/m), is under development at Institute of Modern Physics. A prototype was designed and constructed to prove the principle. Th... Dielectric wall accelerator(DWA), towards high gradient acceleration field(30 MeV/m–100 MeV/m), is under development at Institute of Modern Physics. A prototype was designed and constructed to prove the principle. This needs a short pulse high current electron source to match the acceleration field generated by the Blumlein-type pulse forming lines(PFLs). In this paper, we report the design and test of a new type short pulse high current electron gun based on principle of vacuum arc discharge. Electron beams of 100 mA with pulse width of 10 ns were obtained. 展开更多
关键词 电子枪 短脉冲 高电流 近代物理研究所 脉冲形成线 加速度场 放电原理 真空电弧
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Numerical simulation of thermal-mechanical process of Al-Si-Pb alloy treated by high current pulsed electron beam
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作者 吕晓霞 李荣广 安健 《中国有色金属学会会刊:英文版》 CSCD 2006年第A03期1433-1436,共4页
The modified microstructure of Al-Si-Pb alloys irradiated by high current electron beam (HCPEB) reveals three distinct regions: a molten zone, an overlapped zone of heat-affected and quasistatic thermal stress-affecte... The modified microstructure of Al-Si-Pb alloys irradiated by high current electron beam (HCPEB) reveals three distinct regions: a molten zone, an overlapped zone of heat-affected and quasistatic thermal stress-affected zone, and a transition zone followed by the substrate. The hardness and wear properties of the alloys were significantly improved. To better understand these changes in microstructure and properties, the physical model for the simulation of temperature and quasistatic stress fields was established. Based on experimental investigation and physical models, the temperature field and stress field were simulated for Al-Si-Pb alloy. The starting melting position, largest crater depth, melting layer thickness, and quasistatic stress distribution were obtained. These results reveal the mechanism of crater formation on the surface and improvement of hardness and wear resistance. 展开更多
关键词 热量行为 机械性能 合金 电子束 有色金属
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Mitigating the Reconstruction of Metal Sulfides for Ultrastable Oxygen Evolution at High Current Density
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作者 Shuai Niu Tang Tang +6 位作者 Yuanju Qu Yuyun Chen Hao Luo Hui Pan Wen-Jie Jiang Jianan Zhang Jin-Song Hu 《CCS Chemistry》 CSCD 2024年第1期137-148,共12页
Metal sulfides are emerging highly active electrocatalysts for the oxygen evolution reaction(OER),but still suffer from the instability caused by their inevitable reconstruction,especially at industrial-level current ... Metal sulfides are emerging highly active electrocatalysts for the oxygen evolution reaction(OER),but still suffer from the instability caused by their inevitable reconstruction,especially at industrial-level current density.Here,it is discovered that Fe-incorporated Ni3S2 nanowires can deliver extraordinary durability with an ultralow potential degradation rate of 0.006 mV/h in alkaline electrolytes made with fresh water and seawater at a benchmark of 500 mA cm^(-2) while meeting the industrial activity requirement for overpotential less than 300 mV(290 mV).Systematic experiments and theoretical simulations suggest that after forming the S-doped NiFeOOH shell to boost intrinsic activity,Fe incorporation effectivelymitigates the reconstruction of the Ni_(3)S_(2) nanowire core by restraining Ni oxidation and S dissolution,justifying the performance.This work highlights the significance of circumventing reconstruction and provides a strategy to explore practical chalcogenides-based OER electrocatalysts. 展开更多
关键词 oxygen evolution reaction sulfur-doped NiFeOOH NiFe sulfides nanowire ultrastable high current density
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High current limits in chemical vapor deposited graphene spintronic devices
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作者 Daria Belotcerkovtceva J.Panda +3 位作者 M.Ramu Tapati Sarkar Ulrich Noumbe M.Venkata Kamalakar 《Nano Research》 SCIE EI CSCD 2023年第4期4233-4239,共7页
Understanding the stability and current-carrying capacity of graphene spintronic devices is key to their applications in graphene channel-based spin current sensors,spin-torque oscillators,and potential spin-integrate... Understanding the stability and current-carrying capacity of graphene spintronic devices is key to their applications in graphene channel-based spin current sensors,spin-torque oscillators,and potential spin-integrated circuits.However,despite the demonstrated high current densities in exfoliated graphene,the current-carrying capacity of large-scale chemical vapor deposited(CVD)graphene is not established.Particularly,the grainy nature of chemical vapor deposited graphene and the presence of a tunnel barrier in CVD graphene spin devices pose questions about the stability of high current electrical spin injection.In this work,we observe that despite structural imperfections,CVD graphene sustains remarkably highest currents of 5.2×10^(8)A/cm^(2),up to two orders higher than previously reported values in multilayer CVD graphene,with the capacity primarily dependent upon the sheet resistance of graphene.Furthermore,we notice a reversible regime,up to which CVD graphene can be operated without degradation with operating currents as high as 108 A/cm^(2),significantly high and durable over long time of operation with spin valve signals observed up to such high current densities.At the same time,the tunnel barrier resistance can be modified by the application of high currents.Our results demonstrate the robustness of large-scale CVD graphene and bring fresh insights for engineering and harnessing pure spin currents for innovative device applications. 展开更多
关键词 chemical vapor deposited(CVD)graphene high current density graphene spintronics spin integrated circuits graphene spin valve
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