Ultrafast dynamics of femtosecond laser-induced high spatial frequency periodic structures on silicon surfaces

Femtosecond laser-induced periodic surface structures(LIPSS)have been extensively studied over the past few decades.In particular,the period and groove width of high-spatial-frequency LIPSS(HSFL)is much smaller than the diffraction limit,making it a useful method for efficient nanomanufacturing.However,compared with the low-spatial-frequency LIPSS(LSFL),the structure size of the HSFL is smaller,and it is more easily submerged.Therefore,the formation mechanism of HSFL is complex and has always been a research hotspot in this field.In this study,regular LSFL with a period of 760 nm was fabricated in advance on a silicon surface with two-beam interference using an 800 nm,50 fs femtosecond laser.The ultrafast dynamics of HSFL formation on the silicon surface of prefabricated LSFL under single femtosecond laser pulse irradiation were observed and analyzed for the first time using collinear pump-probe imaging method.In general,the evolution of the surface structure undergoes five sequential stages:the LSFL begins to split,becomes uniform HSFL,degenerates into an irregular LSFL,undergoes secondary splitting into a weakly uniform HSFL,and evolves into an irregular LSFL or is submerged.The results indicate that the local enhancement of the submerged nanocavity,or the nanoplasma,in the prefabricated LSFL ridge led to the splitting of the LSFL,and the thermodynamic effect drove the homogenization of the splitting LSFL,which evolved into HSFL.

Tunable wideband absorber based on resistively loaded lossy high-impedance surface

A lossy high-impedance surface comprised of two layers of resistive frequency selective surfaces is employed to design a tunable electromagnetic absorber. The tunability is realized through changing the composite unit cell by moving the top layer mechanically. To explain the absorbing mechanism, an equivalent circuit model with an interacting coefficient is proposed. Then, simulations and measurements are carried out and agree well with each other. Results show that the complex structure with a thickness less than λ0/4 is able to achieve a wideband absorption in a frequency range from5.90 GHz to 19.73 GHz. Moreover, it is tunable in the operation frequency band.

High surface area biocarbon monoliths for methane storage

New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable energy source for heating and electricity generation due to its high combustion value.Currently,natural gas accounts for a large portion of electricity generation and chemical feedstock in manufacturing plastics and other commercially important organic chemicals.In the near future,natural gas will be widely used as a fuel for vehicles.Therefore,a practical storage device for its storage and transportation is very beneficial to the deployment of natural gas as an energy source for new technologies.In this tutorial review,biomaterials-based carbon monoliths(CMs),one kind of carbonaceous material,was reviewed as an adsorbent for natural gas(methane)adsorption and storage.

High impedance fault detection in distribution network based on S-transform and average singular entropy

When a high impedance fault(HIF)occurs in a distribution network,the detection efficiency of traditional protection devices is strongly limited by the weak fault information.In this study,a method based on S-transform(ST)and average singular entropy(ASE)is proposed to identify HIFs.First,a wavelet packet transform(WPT)was applied to extract the feature frequency band.Thereafter,the ST was investigated in each half cycle.Afterwards,the obtained time-frequency matrix was denoised by singular value decomposition(SVD),followed by the calculation of the ASE index.Finally,an appropriate threshold was selected to detect the HIFs.The advantages of this method are the ability of fine band division,adaptive time-frequency transformation,and quantitative expression of signal complexity.The performance of the proposed method was verified by simulated and field data,and further analysis revealed that it could still achieve good results under different conditions.

Dynamic surface control-backstepping based impedance control for 5-DOF flexible joint robots

A new impedance controller based on the dynamic surface control-backstepping technique to actualize the anticipant dynamic relationship between the motion of end-effector and the external torques was presented.Comparing with the traditional backstepping method that has "explosion of terms" problem,the new proposed control system is a combination of the dynamic surface control technique and the backstepping.The dynamic surface control(DSC) technique can resolve the "explosion of terms" problem that is caused by differential coefficient calculation in the model,and the problem can bring a complexity that will cause the backstepping method hardly to be applied to the practical application,especially to the multi-joint robot.Finally,the validity of the method was proved in the laboratory environment that was set up on the 5-DOF(degree of freedom) flexible joint robot.Tracking errors of DSC-backstepping impedance control that were 2.0 and 1.5 mm are better than those of backstepping impedance control which were 3.5 and 2.5 mm in directions X,Y in free space,respectively.And the anticipant Cartesian impedance behavior and compliant behavior were achieved successfully as depicted theoretically.

ANALYSIS OF DYNAMIC INSTABILITY OF INTERFACIAL SLIP WAVES BASED ON THE SURFACE IMPEDANCE TENSOR

A new method relying on the Stroh formulism and the theory of the surface impedance tensor was developed to investigate the dynamic instability of interfacial slip waves.The concept of the surface impedance tensor was extended to the case where the wave speed is of a complex value,and the boundary conditions at the frictionally contacting interface were expressed by the surface impedance tensor.Then the boundary value problem was transformed to searching for zeroes of a complex polynomial in the unit circle.As an example,the steady frictional sliding of an elastic half-space in contact with a rigid flat surface was considered in details.A quartic complex characteristic equation was derived and its solution behavior in the unit circle was discussed.An explicit expression for the instability condition of the interfacial slip waves was presented.

Efficient Computation of Scattering from Targets with Negative Impedance Surface

Current surface integral equations used for computing scattering from targets with negative impedance boundary condition（IBC）are not efficient.A modified surface dual integral equation（M-SDIE）for targets with negative IBC is presented.A pure imaginary number is used to balance the formulations.It is proved that the M-SDIE is accurate and efficient with three numerical examples.The first numerical example shows that the M-SDIE is accurate compared with Mie.The second example shows that the presented SIE is efficient.In the third example,a missile head is selected to present the computing power of the M-SDIE.All the examples show that the M-SDIE is an efficient algorithm for negative IBC.

Surface Dissociation Properties of Short Chain Carboxyl Mercaptan Self-Assembled Monolayers by Impedance Titration

Impedance titration was used to determine the surface dissociation characteristics of short-chain carboxyl mercaptan self-assembled monolayers （SAMs）. Based on the change of the cyclic voltammetric peak current and the charge-transfer resistance, which was related to pH value of the solution, the surface pKa of mercaptoacetic acid（MA）, 3-mercaptopropionic acid（MPA） and ω-mercaptohexanic acid（MHA） self-assembled membranes, with ionic strength being 0.1 mol/L, were determined to be 5.20, 4.80, 7.40, respectively. In addition, factors such as time needed for assembling, structure of monolayers and ionic strength, which effected the surface pKa, were studied as well. Such surface pKa shifts were sufficiently explained by interactions between interfacial molecules and hydrophobicity.

Determination of Surface pKa of Pure Mercaptoacetic Acid and 2-Mercaptobenzothiazole Mixed Monolayers by Impedance Titration

Interfacial proton transfer reactions of pure mercaptoacetic acid (MA) and 2-mercaptobenzothiazole (Mbz) mixed self-assembled monolayers (SAMs) have been studied using a.c. impedance titration method. The charge-transfer resistance (Rct,) is measured with the monolayer composition and the ionic strength of pH solution. The surface pKa can be obtained by the plots of Rct and pH, the reasons of shifts of surface pKa are also explained.

Impact of Surface Sensible Heating over the Tibetan Plateau on the Western Pacific Subtropical High: A Land–Air–Sea Interaction Perspective

The impact of surface sensible heating over the Tibetan Plateau （SHTP） on the western Pacific subtropical high （WPSH） with and without air-sea interaction was investigated in this study. Data analysis indicated that SHTP acts as a relatively independent factor in modulating the WPSH anomaly compared with ENSO events. Stronger spring SHTP is usually fol- lowed by an enhanced and westward extension of the WPSH in summer, and vice versa. Numerical experiments using both an AGCM and a CGCM confirmed that SHTP influences the large-scale circulation anomaly over the Pacific, which features a barotropic anticyclonic response over the northwestern Pacific and a cyclonic response to the south. Owing to different background circulation in spring and summer, such a response facilitates a subdued WPSH in spring but an en- hanced WPSH in summer. Moreover, the CGCM results showed that the equatorial low-level westerly at the south edge of the cyclonic anomaly brings about a warm SST anomaly （SSTA） in the equatorial central Pacific via surface warm advection. Subsequently, an atmospheric Rossby wave is stimulated to the northwest of the warm SSTA, which in turn enhances the at- mospheric dipole anomalies over the western Pacific. Therefore, the air-sea feedbacks involved tend to reinforce the effect of SHTP on the WPSH anomaly, and the role of SHTP on general circulation needs to be considered in a land-air-sea interaction framework.

Optimization of High-Protein Glutinous Rice Flour Production Using Response Surface Method

A response surface method was employed to study the effect of α-amylase concentration, hydrolysis temperature and time on the production of high protein glutinous rice flour(HPGRF). The suspension of glutinous rice flour(15%) that contained 6.52% protein was gelatinized and subsequently hydrolyzed by thermostable α-amylase. The hydrolysis yielded 0.144–0.222 g/g HPGRF with 29.4%–45.4% protein content. Hydrolysis time exerted a significant effect, while enzyme concentration and hydrolysis temperature showed insignificant effect on the protein content and production yield of HPGRF. The result of response surface method showed that the optimum condition for the production of HPGRF that contained at least 36% protein was treating gelatinized 15% glutinous rice flour suspension with 0.90 Kilo Novo α-amylase Unit(KNU)/g α-amylase at 80 oC for 99 min. By carrying out the predicted hydrolysis condition, HPGRF with 35.9% protein and 61.8% carbohydrates was resulted. The process yielded 0.172 g/g HPGRF. HPGRF contained higher amount of essential amino acids compared to glutinous rice flour. HPGRF had higher solubility and lower swelling power, and also showed no pasting peak compared with glutinous rice flour.

Wave height measurement in the Taiwan Strait with a portable high frequency surface wave radar

As an important equipment for sea state remote sensing, high frequency surface wave radar （HFSWR） has received more and more attention. The conventional method for wave height inversion is based on the ratio of the integration of the second-order spectral continuum to that of the first-order region, where the strong external noise and the incorrect delineation of the first- and second-order Doppler spectral regions due to spectral aliasing are two major sources of errors in the wave height. To account for these factors, two more indices are introduced to the wave height estimation, i.e., the ratio of the maximum power of the second-or- der continuum to that of the Bragg spectral region （RSCB） and the ratio of the power of the second harmonic peak to that of the Bragg peak （RSHB）. Both indices also have a strong correlation with the underlying wave height. On the basis of all these indices an empirical model is proposed to estimate the wave height. This method has been used in a three-months long experiment of the ocean state measuring and analyzing ra- dar, type S （OSMAR-S）, which is a portable HFSWR with compact cross-loop/monopole receive antennas developed by Wuhan University since 2006. During the experiment in the Taiwan Strait, the significant wave height varied from 0 to 5 m. The significant wave heights estimated by the OSMAR-S correlate well with the data provided by the Oceanweather Inc. for comparison, with a correlation coefficient of 0.74 and a root mean square error （RMSE） of 0.77 m. The proposed method has made an effective improvement to the wave height estimation and thus a further step toward operational use of the OSMAR-S in the wave height extraction.

Investigation of Surface Damage in Forming of High Strength and Galvanized Steel Sheets

Powdering/exfoliating of coatings and scratching galvanized steels and high strength steels （HSS）, are the main forms of surface damage in the forming of which result in increased die maintenance cost and scrap rate. In this study, a special rectangular box was developed to investigate the behavior and characteristics of surface damage in sheet metal forming （SMF） processes. U-channel forming tests were conducted to study the effect of tool hardness on surface damage in the forming of high strength steels and galvanized steels （hot-dip galvanized and galvannealed steels）. Experimental results indicate that sheet deformation mode influences the severity of surface damage in SMF and surface damage occurs easily at the regions where sheet specimen deforms under the action of compressive stress. Die corner is the position where surface damage initiates. For HSS sheet, surface damage is of major interest due to high forming pressure. The HSS and hot-dip galvanized steels show improved ability of damage-resistance with increased hardness of the forming tool. However, for galvannealed steel it is not the forming tool with the highest hardness value that performs best.

Hierarchical microstructures with high spatial frequency laser induced periodic surface structures possessing different orientations created by femtosecond laser ablation of silicon in liquids

High spatial frequency laser induced periodic surface structures(HSFLs)on silicon substrates are often developed on flat surfaces at low fluences near ablation threshold of 0.1 J/cm2,seldom on microstructures or microgrooves at relatively higher fluences above 1 J/cm^2.This work aims to enrich the variety of HSFLs-containing hierarchical microstructures,by femtosecond laser(pulse duration:457 fs,wavelength:1045 nm,and repetition rate:100 kHz)in liquids(water and acetone)at laser fluence of 1.7 J/cm^2.The period of Si-HSFLs in the range of 110–200 nm is independent of the scanning speeds(0.1,0.5,1 and 2 mm/s),line intervals(5,15 and 20μm)of scanning lines and scanning directions(perpendicular or parallel to light polarization direction).It is interestingly found that besides normal HSFLs whose orientations are perpendicular to the direction of light polarization,both clockwise or anticlockwise randomly tilted HSFLs with a maximal deviation angle of 50°as compared to those of normal HSFLSs are found on the microstructures with height gradients.Raman spectra and SEM characterization jointly clarify that surface melting and nanocapillary waves play important roles in the formation of Si-HSFLs.The fact that no HSFLs are produced by laser ablation in air indicates that moderate melting facilitated with ultrafast liquid cooling is beneficial for the formation of HSFLs by LALs.On the basis of our findings and previous reports,a synergistic formation mechanism for HSFLs at high fluence was proposed and discussed,including thermal melting with the concomitance of ultrafast cooling in liquids,transformation of the molten layers into ripples and nanotips by surface plasmon polaritons(SPP)and second-harmonic generation(SHG),and modulation of Si-HSFLs direction by both nanocapillary waves and the localized electric field coming from the excited large Si particles.

Preparation and Characterization of Porous Yttrium Oxide Powders with High Specific Surface Area

The porous cubic yttrium oxides with high specific surface area were prepared yttrium nitrate and its complex formed with methyl salicylate. The specific surface area by the explosive decomposition of and properties of powders synthesized at various temperatures were characterized using BET, X-ray diffraction （XRD）, infrared spectra （IR）, and scanning electron microscopy （SEM）. The results indicate that the highest specific surface area is found to be 65.37 m^2·g^-1 at the calcination temperature of 600 ℃, and then decreases to 20.33 m2· g^- 1 with the calcination temperature rising from 600 to 900 ℃. The powders show strong surface activity for adsorping water and carbon dioxide in air, which also decreases with the rising calcination temperature. The drop both on the surface area and surface activity of samples at higher temperatures may be due to pore-narrowing（sintering） effects.

Surface tidal currents in the open sea area to the east of the Zhoushan Islands measured with high frequency surface wave radar

Based on the quasi-harmonic analysis of 11 d vector ocean currents obtained from two high frequency sur- face wave radars located at Zhujiajian Island and Shengshan Island, the spatial distribution characteristics of surface tidal currents in the open sea area to the east of the Zhoushan Islands of Zhejiang Province, China are studied. The following conclusions are drawn from the analysis： the tidal current pattern in the open sea area to the east of Zhoushan Islands is primarily regular semidiurnal, which is significantly affected by the shallow water constituents. The directions of the major axes of tidal current ellipses of M2 lie approx- imately in the NW-SE direction. With the increasing of distance away from the coast, the directions of the tidal current ellipses gradually shift toward the E-W direction. The tidal currents are mainly reversing cur- rents. The spatial distribution of probable maximum current velocities decreases gradually from northeast to southwest which is basically in accordance with the spatial distribution of measured maximum current velocities. The residual currents near the coast are larger than those far away from the coast. The directions of the residual currents are basically north by east, and the angle to the due north increases gradually with the increasing distance away from the coast. The topography shows a certain impact on the spatial distri- bution of shallow water constituents, the rotation of tidal currents, the probable maximum currents and the residual currents.

Compounded Surface Modification of ZK60 Mg Alloy by High Current Pulsed Electron Beam+Micro-plasma Oxidation

In this study, compounded surface modification technology-high current pulsed electron beam （HCPEB） ＋ micro-plasma oxidation （MPO） was applied to treat ZK60 Mg alloys. The characteristics of the microstructure of ZK60 Mg alloy after single MPO and HCPEB＋MPO compounded treatment were investigated by SEM. The results showed that the density of the ceramic layer of HCPEB＋MPO-treated ZK60 Mg alloy was improved and defects were reduced compared to that under MPO treatment alone. Surface modified layer of ZK60 Mg alloys treated by HCPEB＋MPO was divided into three zones, namely the top loose ceramic zone, middle compact zone and inside HCPEB-induced melted zone. Corrosion resistance of ZK60 Mg alloy before and after the compounded surface modification was measured in a solution of 3.5% NaCl by potentiodynamic polarization curves. It was found that the corrosion current density of ZK60 Mg alloys could be reduced by about three orders of magnitude, from 311μA/cm^2 of the original sample to 0.2μA/cm^2 of the HCPEB＋MPO-treated sample. This indicates the great application potential of the HCPEB＋MPO compounded surface modification technology in improving the corrosion resistance of ZK60 Mg alloys in the future.

Novel Salt-Assisted Combustion Synthesis of High Surface Area Ceria Nanopowders by An Ethylene Glycol-Nitrate Combustion Process

A novel salt-assisted combustion process with ethylene glycol as a fuel and nitrate as an oxidant to synthesize high surface area celia nanopowders was reported. The effects of various tunable conditions, such as fuel-to-oxidant ratio, type of salts, and amount of added salts, on the characteristics of the as-prepared powders were investigated by X-ray diffraction, transmission electron microscopy and BET surface area measurement. A mechanism scheme was proposed to illustrate the possible formation processes of well-dispersed ceria nanoparticles in the salt-assisted combustion synthesis. It was verified that the simple introduction of leachable inert inorganic salts as an excellent agglomeration inhibitor into the redox mixture precursor leads to the formation of well-dispersed ceria particles with particle size in the range of 4 ～6 nm and a drastic increase in the surface area. The presence of KCl results in an over ten-fold increment in specific surface area from 14.10 m^2·g^-1 for the produced ceria powders via the conventional combustion synthesis process to 156.74 m^2·g^-1 for the product by the salt-assisted combustion synthesis process at the same molar ratio of ethylene glycol-nitrate.

Preparation of Zirconia-Ceria Powders with High Specific Surface Area

Zirconia-ceria mixed oxide powders were prepared by high temperature aging method.The effects of the temperature and the time of aging, cerium content and calcination on powder performance were studied.The result shows that high temperature aging is an efficient way of preparation of ZrO2-CeO2 mixed oxide powders with high specific surface area and good thermal stability, and that addition of a small amount of cerium to hydrous zirconia can promote the preparation of high specific surface area powders.

Effect of Quenching Parameters on Mechanical Property of Ultra High Strength Steel BR1500HS Based on Response Surface Methodology

Hot stamping of high strength steels is defined as a process in which blank is heated to the temperature of the austenite stabilization region for a definite time and then formed and quenched simultaneously in a mold with cooling channels. During this process,the processing parameters of austenite temperature and soaking time have strong effects on the mechanical properties such as quenching hardness,tensile strength and elongation. Hence,it is necessary to investigate the relationship between the mechanical properties and the two processing parameters. In this paper,the orthogonal experiment with two factors and five levels was applied, and the experimental data based on the orthogonal experiment was acquired. Based on the data,regression models were set up and the results of the analysis of variance( ANOVA) showed that it is reliable to predict the quenching hardness,tensile strength and elongation by the regression models. Besides,the optimal results of each single object were obtained based on response surface methodology( RSM),and global optimums was gained by employing ideal point method in which the quenching hardness,and tensile strength and elongation were considered simultaneously.