Colorless‐to‐black switching has attracted widespread attention for smart windows and multifunctional displays because they are more useful to control solar energy.However,it still remains a challenge owing to the t...Colorless‐to‐black switching has attracted widespread attention for smart windows and multifunctional displays because they are more useful to control solar energy.However,it still remains a challenge owing to the tremendous difficulties in the design of completely reverse absorptions in transmissive and colored states.Herein,we report on an electrochemical device that can switch between colorless and black by using the electrochemical process of hybrid organic–inorganic perovskite MAPbBr_(3),which shows a high integrated contrast ratio of up to 73%from 400 to 800 nm.The perovskite solution can be used as the active layer to assemble the device,showing superior transmittance over the entire visible region in neutral states.By applying an appropriate voltage,the device undergoes reversible switching between colorless and black,which is attributed to the formation of lead and Br_(2)in the redox reaction induced by the electron transfer process in MAPbBr_(3).In addition,the contrast ratio can be modulated over the entire visible region by changing the concentration and the applied voltage.These results contribute toward gaining an insightful understanding of the electrochemical process of perovskites and greatly promoting the development of switchable devices.展开更多
为了对特高压(UHV)串补装置高电位平台上的一次设备绝缘和二次系统电磁兼容(EMC)进行优化设计,需要对隔离开关操作或旁路间隙击穿引起的瞬态地电位升(PPR)和电磁骚扰进行测量。为此,提出了高电位、强电磁环境下的瞬态地电位升和电磁骚...为了对特高压(UHV)串补装置高电位平台上的一次设备绝缘和二次系统电磁兼容(EMC)进行优化设计,需要对隔离开关操作或旁路间隙击穿引起的瞬态地电位升(PPR)和电磁骚扰进行测量。为此,提出了高电位、强电磁环境下的瞬态地电位升和电磁骚扰测量方法。采用电磁屏蔽、直流供电、光纤通信等技术措施,研制了主要由高电位平台上的测量仪器、地面上的监控系统和通信系统组成的瞬态测量系统,该系统包含3个屏蔽区域。进行了特高压串补装置真型试验平台的隔离开关操作试验,获得了瞬态测量信号的幅域、时域和频域等特征。对瞬态测量系统的功能性测试表明:其屏蔽效能>40 d B,电磁兼容抗扰度满足国标规定的3级及以上且试验评价结果均为A级,工频耐压和冲击耐压分别为4、10 kV,主要性能指标满足特高压串补装置瞬态地电位升和电磁骚扰的测量要求。展开更多
基金Natural Science Foundation of Hebei Province(China),Grant/Award Numbers:B2020203013,B2021203016Science and Technology Project of Hebei Education Department(China),Grant/Award Number:QN2020137+3 种基金Cultivation Project for Basic Research Innovation of Yanshan University(China),Grant/Award Number:2021LGZD015Subsidy for Hebei Key Laboratory of Applied Chemistry after Operation Performance(China),Grant/Award Number:22567616HNatural Science Foundation of Heilongjiang Province(China),Grant/Award Number:LH2022B025Fundamental Research Funds for the Provincial Universities of Heilongjiang Province(China),Grant/Award Number:KYYWF10236190104。
文摘Colorless‐to‐black switching has attracted widespread attention for smart windows and multifunctional displays because they are more useful to control solar energy.However,it still remains a challenge owing to the tremendous difficulties in the design of completely reverse absorptions in transmissive and colored states.Herein,we report on an electrochemical device that can switch between colorless and black by using the electrochemical process of hybrid organic–inorganic perovskite MAPbBr_(3),which shows a high integrated contrast ratio of up to 73%from 400 to 800 nm.The perovskite solution can be used as the active layer to assemble the device,showing superior transmittance over the entire visible region in neutral states.By applying an appropriate voltage,the device undergoes reversible switching between colorless and black,which is attributed to the formation of lead and Br_(2)in the redox reaction induced by the electron transfer process in MAPbBr_(3).In addition,the contrast ratio can be modulated over the entire visible region by changing the concentration and the applied voltage.These results contribute toward gaining an insightful understanding of the electrochemical process of perovskites and greatly promoting the development of switchable devices.
文摘为了对特高压(UHV)串补装置高电位平台上的一次设备绝缘和二次系统电磁兼容(EMC)进行优化设计,需要对隔离开关操作或旁路间隙击穿引起的瞬态地电位升(PPR)和电磁骚扰进行测量。为此,提出了高电位、强电磁环境下的瞬态地电位升和电磁骚扰测量方法。采用电磁屏蔽、直流供电、光纤通信等技术措施,研制了主要由高电位平台上的测量仪器、地面上的监控系统和通信系统组成的瞬态测量系统,该系统包含3个屏蔽区域。进行了特高压串补装置真型试验平台的隔离开关操作试验,获得了瞬态测量信号的幅域、时域和频域等特征。对瞬态测量系统的功能性测试表明:其屏蔽效能>40 d B,电磁兼容抗扰度满足国标规定的3级及以上且试验评价结果均为A级,工频耐压和冲击耐压分别为4、10 kV,主要性能指标满足特高压串补装置瞬态地电位升和电磁骚扰的测量要求。
