Continuous rolling techniques were used in this study to produce steel with a medium level of carbon but a high level of sulfur. Controlled rolling techniques were used to control the shape of sulfide. The effect of s...Continuous rolling techniques were used in this study to produce steel with a medium level of carbon but a high level of sulfur. Controlled rolling techniques were used to control the shape of sulfide. The effect of sulfide on the microstructure of steel was also investigated in this study. The size and distribution of sulfide are determined through the use of an image analyzer and the statistics of the products ＆ service solution （SPSS） software. A comparison between the microstructures of normalized and quenched steel reveals that sulfide can pin the boundaries of the austenite grain boundary and refine the microstructure of the austenite grain. It also reveals that the size relationship between sulfide and austenite grain satisfies the Zener equation.展开更多
Segregation and inclusion precipitation are the common behaviours of steel solidification, which are resulted from the redistribution and diffusion of the solute elements at the solid-liquid interface. The effect of t...Segregation and inclusion precipitation are the common behaviours of steel solidification, which are resulted from the redistribution and diffusion of the solute elements at the solid-liquid interface. The effect of the phase transition of high-sulfur free-cutting steel is quantified in the present work for the solute partition coefficient(ki), inclusion precipitation, and microsegregation by establishing a coupling model of microsegregation and inclusion precipitation, wherein the quantified dependencies of ki in terms of temperature, phase and carbon(C) content were applied. Results showed that the solidification temperature range and phase transition of high-sulfur steel that under different solidification paths and C contents were quite different, leading to differences in ki and eventually in microsegregation. kC,kP, and kS were mainly affected by phase composition and kSi was primarily by temperature, while kMn depended on both phase composition and temperature during solidification. Increasing the C content within the interval 0.07-0.48 wt%, the ‘proportion of the δ phase maintained temperature region during solidification’(Pδ), kave Pand kave S(kiave, the average value of the ki across the whole stages of solidification)decreased monotonically, whereas kave Cincreased linearly. The peritectic reaction impacted on the phase composition and ki, leading to the change in microsegregation. Such effect of the peritectic reaction was more significant at the last stage of solidification. When the Pδ was between 75% and 100%(corresponding to 0.07-0.16 wt% C), the solidification path resulted in a greater effect on the microsegregation of solutes C, P, and S because of the peritectic reaction. The microsegregation of solutes Mn and S were comprehensively influenced by kMn, kS and Mn S precipitation as well. The studies would help reveal the solute redistribution at the solid-liquid interface, and improve the segregation of high-sulfur steel by controlling the solidification and precipitation in practice.展开更多
西宁特钢Y15易切削钢(%:0.10～0.15C、1.00～1.20Mn、0.30S)由25 t EAF-LF-657 kg铸锭流程生产。试验结果表明,通过控制电弧炉氧化终点[C]0.06%～0.10%和脱氧工艺将[O]控制在(150～250)×10^(-6),控制钢中Mn/S=2.77、O/S=0.059时,...西宁特钢Y15易切削钢(%:0.10～0.15C、1.00～1.20Mn、0.30S)由25 t EAF-LF-657 kg铸锭流程生产。试验结果表明,通过控制电弧炉氧化终点[C]0.06%～0.10%和脱氧工艺将[O]控制在(150～250)×10^(-6),控制钢中Mn/S=2.77、O/S=0.059时,钢中夹杂物大多数为(Mn,Fe)S和硫化物包裹氧化物,少数为MnS,使钢具有良好的切削性能。展开更多
基金funded by the National Science and Technology Research Project 2007BAE51B03
文摘Continuous rolling techniques were used in this study to produce steel with a medium level of carbon but a high level of sulfur. Controlled rolling techniques were used to control the shape of sulfide. The effect of sulfide on the microstructure of steel was also investigated in this study. The size and distribution of sulfide are determined through the use of an image analyzer and the statistics of the products ＆ service solution （SPSS） software. A comparison between the microstructures of normalized and quenched steel reveals that sulfide can pin the boundaries of the austenite grain boundary and refine the microstructure of the austenite grain. It also reveals that the size relationship between sulfide and austenite grain satisfies the Zener equation.
基金financially supported by the National Natural Science Foundation of China (Nos. 51504048, 51611130062, 51874059 and 51874060)the Natural Science Foundation of Chongqing (No. cstc2018jcyjAX0647)the Fundamental Research Funds for the Central Universities of China (No. cqu2018CDHB1B05)
文摘Segregation and inclusion precipitation are the common behaviours of steel solidification, which are resulted from the redistribution and diffusion of the solute elements at the solid-liquid interface. The effect of the phase transition of high-sulfur free-cutting steel is quantified in the present work for the solute partition coefficient(ki), inclusion precipitation, and microsegregation by establishing a coupling model of microsegregation and inclusion precipitation, wherein the quantified dependencies of ki in terms of temperature, phase and carbon(C) content were applied. Results showed that the solidification temperature range and phase transition of high-sulfur steel that under different solidification paths and C contents were quite different, leading to differences in ki and eventually in microsegregation. kC,kP, and kS were mainly affected by phase composition and kSi was primarily by temperature, while kMn depended on both phase composition and temperature during solidification. Increasing the C content within the interval 0.07-0.48 wt%, the ‘proportion of the δ phase maintained temperature region during solidification’(Pδ), kave Pand kave S(kiave, the average value of the ki across the whole stages of solidification)decreased monotonically, whereas kave Cincreased linearly. The peritectic reaction impacted on the phase composition and ki, leading to the change in microsegregation. Such effect of the peritectic reaction was more significant at the last stage of solidification. When the Pδ was between 75% and 100%(corresponding to 0.07-0.16 wt% C), the solidification path resulted in a greater effect on the microsegregation of solutes C, P, and S because of the peritectic reaction. The microsegregation of solutes Mn and S were comprehensively influenced by kMn, kS and Mn S precipitation as well. The studies would help reveal the solute redistribution at the solid-liquid interface, and improve the segregation of high-sulfur steel by controlling the solidification and precipitation in practice.
文摘西宁特钢Y15易切削钢(%:0.10～0.15C、1.00～1.20Mn、0.30S)由25 t EAF-LF-657 kg铸锭流程生产。试验结果表明,通过控制电弧炉氧化终点[C]0.06%～0.10%和脱氧工艺将[O]控制在(150～250)×10^(-6),控制钢中Mn/S=2.77、O/S=0.059时,钢中夹杂物大多数为(Mn,Fe)S和硫化物包裹氧化物,少数为MnS,使钢具有良好的切削性能。
