Effects of Al and Co doping on the structural stability and high temperature cycling performance of LiNi_(0.5)Mn_(1.5)O_(4) spinel cathode materials

The poor structural stability and capacity retention of the high-voltage spinel-type LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)limits their further application.Herein,Al and Co were doped in LNMO materials for a more stable structure and capacity.The LNMO,LiNi_(0.45)Al_(0.05)Mn_(1.5)O_(4)(LNAMO)and LiNi_(0.45)Co_(0.05)Mn_(1.5)O_(4)(LNCMO)were synthesized by calcination at 900℃ for 8 h,which was called as solid-phase method and applied universally in industry.XRD,FT-IR and CV test results showed the synthesized samples have cation disordering Fd-3m space group structures.Moreover,the incorporation of Al and Co increased the cation disordering of LNMO,thereby increasing the transfer rate of Li+.The SEM results showed that the doped samples performed more regular and ortho-octahedral.The EDS elemental analysis confirmed the uniform distribution of each metal element in the samples.Moreover,the doped samples showed better electrochemical properties than undoped LNMO.The LNAMO and LNCMO samples were discharged with specific capacities of 116.3 mA·h·g^(-1)and 122.8 mA·h·g^(-1)at 1 C charge/discharge rate with good capacity retention of 95.8% and 94.8% after 200 cycles at room temperature,respectively.The capacity fading phenomenon of the doped samples at 50℃ and 1 C rate was significantly improved.Further,cations doping also enhanced the rate performance,especially for the LNCMO,the discharge specific capacity of 117.9 mA·h·g^(-1)can be obtained at a rate of 5 C.

Discussion on New Evaluation Technology of Non-Metallic Composite Continuous Pipe for Oil and Gas Field

In view of the serious lack and lag of the test and evaluation technology of non-metallic composite continuous pipe, and focusing on the characteristics of the application of non-metallic composite continuous pipe in oil field, this paper discusses a series of new full-scale test and evaluation technologies for accurately evaluating the product quality and practical application performance of non-metallic composite continuous pipe, which effectively solves the major technical problem that the new products of non-metallic pipe cannot be accurately evaluated. Based on the characteristics of the application of non-metallic composite continuous pipe in oil field, a series of new full-scale test evaluation technologies which can accurately evaluate the product quality and practical application performance of non-metallic pipe are designed through a large number of tests. The test and evaluation technology can accurately evaluate the key performance of high and low pressure cycle, high and low temperature cycle, gas permeability resistance, minimum bending radius etc. It provides a scientific evaluation basis for the standardized application of non-metallic continuous pipe and a reliable quality control method for the selection of products in oil field.