Development and performance evaluation of high temperature resistant strong adsorption rigid blocking agent

As drilling wells continue to move into deep ultra-deep layers,the requirements for temperature resistance of drilling fluid treatments are getting higher and higher.Among them,blocking agent,as one of the key treatment agents,has also become a hot spot of research.In this study,a high temperature resistant strong adsorption rigid blocking agent(QW-1)was prepared using KH570 modified silica,acrylamide(AM)and allyltrimethylammonium chloride(TMAAC).QW-1 has good thermal stability,average particle size of 1.46μm,water contact angle of 10.5.,has a strong hydrophilicity,can be well dispersed in water.The experimental results showed that when 2 wt%QW-1 was added to recipe A(4 wt%bentonite slurry+0.5 wt%DSP-1(filtration loss depressant)),the API filtration loss decreased from 7.8to 6.4 m L.After aging at 240.C,the API loss of filtration was reduced from 21 to 14 m L,which has certain performance of high temperature loss of filtration.At the same time,it is effective in sealing 80-100mesh and 100-120 mesh sand beds as well as 3 and 5μm ceramic sand discs.Under the same conditions,the blocking performance was superior to silica(5μm)and calcium carbonate(2.6μm).In addition,the mechanism of action of QW-1 was further investigated.The results show that QW-1 with amide and quaternary ammonium groups on the molecular chain can be adsorbed onto the surface of clay particles through hydrogen bonding and electrostatic interaction to form a dense blocking layer,thus preventing further intrusion of drilling fluid into the formation.

Highly reinforce the interface stability using 2-Phenyl-1H-imidazole-1-sulfonate electrolyte additive to enhance the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries

This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries.After 450 cycles at room temperature(25℃),the discharge capacity retentions of batteries with blank and PHIS-containing electrolyte are 56.03%and 94.92%respectively.After 230 cycles at high temperatures(45℃),their values are 75.30%and 88.38%respectively.The enhanced electrochemical performance of the batteries with PHIS-containing electrolyte is supported by the spectroscopic characterization and theoretical calculations.It is demonstrated that this PHIS electrolyte additive can facilitate the construction of the electrode interface films,remove the H2O/HF in the electrolyte,and improve the electrochemical performance of the batteries.This work not only develops a sulfonate-based electrolyte but also can stimulate new ideas of functional additives to improve the battery performance.

Effects of flaky rare earth oxide additives on the high temperature performance of nickel electrodes

Effects of flaky rare earth oxide additives including Er2O3,Tm2O3,and Yb2O3,Lu2O3 on high temperature and high rate discharge performance of nickel electrodes were investigated.The discharge efficiency at 0.2C reached 96% at 60 oC for electrodes with 1 at.% flaky rare earth oxides.The high rate discharge performance for electrodes with flaky rare earth oxides were improved significantly,for example,discharge efficiency at 5C improved from 50% to 70%.The results showed that the end charging potential of the ...

Shrinkage Behavior of High Performance Concrete at Different Elevated Temperatures under Different Sealing Conditions

The shrinkage behavior of high performance cement concrete made from Portland cement, ultra fine granulated blast furnace slag and pulverized fly ash with addition of superplasticizer at different temperatures from ambient temperature to 120 ℃ under different seuliug conditions was investigated by means of length change measurement on cylindrical concrete specimens along with curing age. Results show that drying shrinkage deformations of titled concrete specimens increased rapidly as the curing temperature rose. The development of dryiing shrinkage deformatian can be efficiently controlled with the aid of aluminum tape sealing as compared with the unsealed specimens, especially when the curing temperature is below 60℃ , although it will increase dramatically when the curing temperature is elevated to above 90%＂ . Polymer coating on concrete specimens showed a similar effect on the control of drying shrinkage as the sealing operation with aluminum tape.

High Temperature Performances of Spherical Nickel Hydroxide with Additive Y_2O_3

The effect Of Y2O3 as additive to the positive electrode on the high-temperature performances of the Ni-MH batteries was studied. The specific capacities of the positive electrode in Ni-MH battery at higher temperatures are much lower than usual. In order to improve high-temperature performances, charge/discharge curves of the Ni(OH)(2) electrodes with different amounts Of Y2O3 it different temperatures were studied. It is found that the specific capacities of the spherical Ni (OH)(2) with Y2O3 as additive are much higher than those of the regular at higher temperatures. The specific capacity of Ni (OH)(2) containing 1% Y2O3 at 0.2C C/D rate is 35% higher than that of the regular. The specific capacity of Ni (OH)(2) containing 0.2% Y2O3 at 1C C/D rate is 15% higher than that of the regular. Mechanism Of Y2O3 improving high temperature performances of Ni(OH)(2) electrode was also discussed in detail.

Experimental Performance of Moderate and High Temperature Heat Pump Charged with Refrigerant Mixture BY-3

Theoretical and experimental analysis of a new refrigerant mixture BY-3 was conducted based on a single-stage vapor compression refrigeration system. The water-water heat pump system used BY-3 to produce hot water when the low temperature was 20 ℃. The following results were obtained: the highest temperature at the condenser outlet reached about 85 ℃; when the difference between the water temperatures at the condenser outlet and the evaporator inlet was less than 40 ℃, the coefficient of performance (COP) was larger than 4; when the difference reached 55 ℃, the COP still kept 3; the discharge temperature of BY-3 was lower than 100 ℃, and the refrigerant vapor pressure kept lower than 1.8 MPa. When the water temperature at the condenser outlet reached over 85 ℃, nearly a 5 ℃ superheating temperature was maintained.

Comprehensive Analysis of High Temperature Performance of SBS-modified Asphalt Mixture

Evaluation of high temperature performance of SBS-modified asphalt mixture was presented.Both wheel loaded method and creep method were adopted for two different mixtures and two kinds of specimens with different height,and corresponding indicators were measured.Meanwhile,the correlation between these indicators was thoroughly analyzed and two kinds of mixtures were compared.The experimental results show that there is a good linear relationship between LWT indicators and CT indicators for M-13,while a relatively poor relationship for M-25,especially that between dynamic stiffness and static stiffness and that between dynamic stability and static creep stiffness.Besides,logarithmic relationship between DS and RD has a higher determination coefficient than that for linear relationship.Thus,multi-index evaluation should be taken for synthetically assessing high temperature performance of asphalt mixture.

High-temperature electrochemical performance and phase composition of Ti_(0.7) Zr_(0.5) V_(0.2) Mn_(1.8-x)Ni_x hydrogen storage electrode alloys

The rapid development of electric vehicles demands the development of high performance nickel metal hydride battery that is able to endure high temperature. The discharge properties of Ti 0.7 Zr 0.5 V 0.2 Mn 1.8- x Ni x ( x =0.4, 0.8, 1.1, 1.4, 1.7)hydrogen storage alloys was investigated and its phase composition was analyzed using X ray diffraction. The results show that the cycling life was improved as the content of nickel increases. When x =0.4, 0.8, 1.1 and 1.4, the main phase is MgZn 2 type C14 Laves phase and the second one is cubic TiNi phase. When x =1.7, the Laves phase structure disappears. EDAS analysis shows that the increase of nickel content is effective in suppressing the dissolution of vanadium component in alloys. [

Influence of the Steel-making Dust on High Temperature and Fatigue Performance of Asphalt Mortars

To research the possibility of steel-making dust as a kind of mineral filler in asphalt mixture, two steel-making dusts and one ordinary mineral filler were adopted. The specific density, specific surface area, fineness modulus and mineralogy component of the dusts were tested. Scanning electron microscopy(SEM) was carried out to research the microstructure of the dusts; dynamic shear rheological(DSR) test and time sweep test were used to research the high temperature and fatigue performance of asphalt mortars containing steel-making dust. The experimental results indicate that, compared with ordinary mineral filler, steel-making dusts have more active ingredients, difference surface characteristics and micro-structure. Furthermore, the high temperature and fatigue performance of steel-making dusts corresponding asphalt mortars are superior to those of reference group. Therefore, the steel-making dust would be an alternative to the ordinary mineral filler to improve the performance of asphalt mortars and reduce the harm of the dusts to the environment at the same time.

FAILURE MODE AND CONSTITUTIVE MODEL OF PLAIN HIGH-STRENGTH HIGH-PERFORMANCE CONCRETE UNDER BIAXIAL COMPRESSION AFTER EXPOSURE TO HIGH TEMPERATURES

An orthotropic constitutive relationship with temperature parameters for plain highstrength high-performance concrete （HSHPC） under biaxial compression is developed. It is based on the experiments performed for characterizing the strength and deformation behavior at two strength levels of HSHPC at 7 different stress ratios including a=σs ： σ3=0.00：-1,-0.20：-1,-0.30 ： -1,-0.40：-1,-0.50：-1,-0.75：-1,-1.00：-1, after the exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600℃, and using a large static-dynamic true triaxial machine. The biaxial tests were performed on 100 mm×100 mm×100 mm cubic specimens, and friction-reducing pads were used consisting of three layers of plastic membrane with glycerine in-between for the compressive loading plane. Based on the experimental results, failure modes of HSHPC specimens were described. The principal static compressive strengths, strains at the peak stress and stress-strain curves were measured; and the influence of the temperature and stress ratios on them was also analyzed. The experimental results showed that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease dramatically with the increase of temperature. The ratio of the biaxial to its uniaxial compressive strength depends on the stress ratios and brittleness-stiffness of HSHPC after exposure to different temperature levels. Comparison of the stress-strain results obtained from the theoretical model and the experimental data indicates good agreement.

Design of the material performance test apparatus for high temperature gas-cooled reactor

Most materials can be easily corroded or ineffective in carbonaceous atmospheres at high temperatures in the reactor core of the high temperature gas-cooled reactor(HTGR).To solve the problem,a material performance test apparatus was built to provide reliable materials and technical support for relevant experiments of the HTGR.The apparatus uses a center high-purity graphite heater and surrounding thermal insulating layers made of carbon fiber felt to form a strong carbon reducing atmosphere inside the apparatus.Specially designed tungsten rhenium thermocouples which can endure high temperatures in carbonaceous atmospheres are used to control the temperature field.A typical experimental process was analyzed in the paper,which lasted 76 hours including seven stages.Experimental results showed the test apparatus could completely simulate the carbon reduction atmosphere and high temperature environment the same as that confronted in the real reactor and the performance of screened materials had been successfully tested and verified.Test temperature in the apparatus could be elevated up to 1600oC,which covered the whole temperature range of the normal operation and accident condition of HTGR and could fully meet the test requirements of materials used in the reactor.

Synthesis and high-temperature performance of Ti substituted α-Ni(OH)_2

Ti substituted α-Ni（OH）2（c=2.121nm, a =0.307nm） with perfect high-temperature performance was prepared by the co-precipitation method. The effects of Ti addition on the structure and the electrochemical properties were investigated. The results indicate that the substitution of Ti for Ni leads to the conversion of β-Ni（OH）2 to α-Ni（OH）2 and the increase of the inter layer distance along c-axis from 0.464nm to 0.707nm. Infrared study reveals that more anions（SO2-4 and CO2-3 ions） and H2O exist in the Ti substituted α-Ni（OH）2. The discharge capacity of the Ti substituted α-Ni（OH）2 is 210mA·h/g at 20℃ and reaches up to 270mA·h/g at 80℃ owing to the inhibition of the oxygen evolution at high temperature.

Optimization of technical measures for improving high-temperature performance of asphalt-rubber mixture

Asphalt-rubber pavements often become dam-aged in high-temperature regions and appear rutted or wavy, and experience slippage. To improve the high-temperature performance of the asphalt-rubber mixture, technical measurements, such as, the optimal adjustment of gradation, technique of composite modification, and control of compaction were investigated. An optimal adjustment of aggregate gradation based on stone matrix asphalt improves the high-temperature stability of the asphaltrubber mixture significantly. Through composite modifi- cation, the effect of asphalt-rubber modification was enhanced, and the dynamic stability and relative defor- mation indices of the asphalt-rubber mixture were improved significantly. Furthermore, compaction parame- ters had a significant influence on the high-temperature stability of the asphalt-rubber mixture. The rolling times for compacting the asphalt-rubber mixture should be controlled to within 18-20 round-trips at a molding temperature at 180℃; if the rolling time is a 12 round-trip, the compaction temperature of the asphalt-rubber mixture should be controlled between 180 and 190℃.

Effect of Lu_2O_3 on Charge/discharge Performances of Spherical Nickel Hydroxide at High Temperature

Nickel-metal hydride （Ni/MH） batteries are one of promising batteries for electric vehicle applications, but at high temperature the charge efficiency of nickel electrode is very low. In order to improve the high-temperature-efficiency of nickel electrode, spherical nickel hydroxide mixed with various ratios of Lu2O3 was used as active material of pasted nickel electrodes. The results of charge/discharge experiments, cyclic voltammetric measurements and XRD characterizations have shown that after addition of Lu2O3, the oxygen evolution overpotcntial is elevated much, the charge efficiency of nickel electrode at high temperature is greatly improved and the content of β-NiOOH phase increases in charged electrodes. In addition, the mixed ratio of Lu2O3 has different effects on high temperature performances of nickel electrode at different charge/discharge currents, 3.5 % is the optimum mixed ratio, and the action of Lu2O3 on high temperature electrochemical behaviors is more apparent when nickel electrodes are charged at small current than large current.

Multi-powder dam concrete with high performance and low adiabatic temperature rise

Based on the fluidity, strength, heat of hydration and loop crack resistance experiment of multi-powder paste, the components and proportion of multi-powder were optimized and the concrete properties were studied. The multi-powder consists of limestone powder, slag, fly ash and moderate heat Portland cement (PMH cement). The results show that the compressive strength of the multi-powder paste and mortar is close to those of PMH cement, fly ash paste and mortar currently used in dam concrete, yet the flexural strength is relatively higher. The multi-powder paste is featured by larger fluidity, lower heat of hydration and delayed cracking time. In comparison, less unit water consumption and cement is used in multi-powder concrete, and under premise of equal mechanical performance, deformation, thermal performance and durability, the adiabatic temperature rise at 28 d is reduced by 2 ℃. In this way, the crack resistance is improved and it is feasible both technically and economically to produce HPC for dam concrete.

Evaluation on High-temperature Adhesion Performance of Hot-applied Sealant for Asphalt Pavement

In order to investigate the high-temperature performances of the asphalt pavement hot-applied sealant, as well as to reduce failures of the sealant pullout, the softening point test and the flow test（two existing methods for evaluating high-temperature performances） were conducted. It was found that both tests could not accurately reflect the adhesion performances of the sealant at high temperatures. For this purpose, the adhesion test for PSAT（pressure sensitive adhesive tape） has been taken as a reference to develop a device that is suitable for evaluating the adhesion performances, by modifying relevant test parameters according to the road conditions at high temperatures. Thirteen common sealants were tested in the modified adhesion test, softening point test and f low test. The experimental results show that no significant correlation（p〉0.05） exists between the adhesion value, softening point, adhesion value and flow value; while a significant correlation（p〈0.05） exists between the softening point and flow value. The modified adhesion test is efficient in distinguishing the hightemperature adhesion performances of different sealants, and can be used as a standard method for evaluating such performances.

Robust Performance of AlGaN-Channel Metal-Insulator-Semiconductor High-Electron-Mobility Transistors at High Temperatures

Superior characteristics of Al Ga N-channel metal-insulator-semiconductor（MIS） high electron mobility transistors（HEMTs） at high temperatures are demonstrated in detail. The temperature coefficient of the maximum saturation drain current for the Al GaN-channel MIS HEMT can be reduced by 50% compared with the Ga N-channel HEMT. Moreover, benefiting from the better suppression of gate current and reduced leakage current in the buffer layer, the Al Ga N-channel MIS HEMT demonstrates an average breakdown electric field of 1.83 MV/cm at25℃ and 1.06 MV/cm at 300℃, which is almost 2 times and 3 times respectively larger than that of the reference Ga N-channel HEMT. Pulsed mode analyses suggest that the proposed device suffers from smaller current collapse when the temperature reaches as high as 300℃.

Low-temperature performance and high-rate discharge capability of AB_5-type non-stoichiometric hydrogen storage alloy

Low-temperature performance and high-rate discharge capability of AB5-type non-stoichiometric hydrogen storage are studied. X-ray diffraction(XRD),pressure-composition-temperature(PCT) curves and electrochemical impedance spectroscopy(EIS) are applied to characterize the electrochemical properties of ABx(x=4.8,4.9,5.0,5.1,5.2) alloys. The results show that the non-stoichiometric alloys exhibit better electrochemical properties compared with that of the AB5 alloy.

Thermal Performance Test of the Hot Gas Duct of10MW High Temperature Reactor Test Modulegh

he thermal performance test of the horizontal coaxial double tube hot gas duct (HGD) with an internal thermal insulation for the 10MW High Temperature Reactor Test Module (HTR10) was conducted on a Helium Test Loop(HETL). The present paper deals with the technical feature of the HETL, the test section and the thermal performance test of the HGD. The HGD test section with a triple tube structure includes an inner heater, a HGD model and a coldhot gas mixer. A counterflow of cold and hot helium gas under the pressure of about 3.0 MPa and the minimum temperature of 100℃ in the annular passage and the maximum of 950℃ in the central tube of the HGD model was formed. The HGD model was undergone 20 times of pressure cycle test under the pressure ranging from 0.1 to 3.4 MPa, 18 times of the temperature cycle test under the temperature ranging from 100 to 950℃ and high temperature (700 to 950℃) helium flow test for a period of more than 350 hours. The effective thermal conductivity (λeff) of the internal insulation of the HGD was investigated experimentally. The relationship of the effective thermal conductivity with the average tmperature of the internal insulation layer is λeff(W/m/℃)=0.3512+0.0003T(℃). The test results indicate that the HGD model has good abilities to resist heat flux from the central tube to the annular passage, temperature variations, and pressure variations.

Study on low temperature performance of Gussasphalt on steel decks with hard bitumen

Using a Hamburg wheel-track test device, the resistance to rutting of Gussasphalt is tested and compared. Gussasphalt with hard bitumen has good resistance to rutting. The related resistance abilities to cracking at low temperature of Gussasphalt are tested and compared through flexural experiments and the composite structure fatigue test with temperature dropping. Gussasphalt with high performance polymer modified bitumen has a longer fatigue life and a lower breaking temperature; they can be used in the future surfaces for steel bridge decks in Germany.