An innovative idea was proposed to prepare the overbased nano-sized calcium carbonate-calcium petroleum sulfonate in-situ the HIGEE reactor. The test sample prepared by this technology could meet the requirement of th...An innovative idea was proposed to prepare the overbased nano-sized calcium carbonate-calcium petroleum sulfonate in-situ the HIGEE reactor. The test sample prepared by this technology could meet the requirement of the industry standard SH0042-91 for the first-grade product on a par with similar overseas product. The test results obtained upon observation under microscope after freezing etching of specimen revealed that the crystal size of colloidal calcium sulfonate was in the range of 10-30 nm with an average size of 20 nm. The size of the detergent additive was uniform with good transmittance and fluidity. The HIGEE technology possesses five specific features as shown below: Firstly, the carbonation reaction is completed in one step with the reaction time reduced by more than 50% as compared to traditional batch reactor process along with enhanced reaction efficiency, good operability of the process and stabilized product quality. Secondly, ammonia emitted from the reaction is used as the co- promoter without the need for adding ammonia and water as promoters to simplify the promoter system along with effective and strong coupling of reactions. Thirdly, the utilization rate of Ca(OH)2 and CO2 is increased by 15% and 30%, respectively, with product yield increased by 15%, and calcium residue decreased by 65%. Fourthly, the HIGEE technology is environmental benign because of gasoline is used in this technology instead of toxic toluene and xylene. Fifthly, the dimension of HIGEE reactor is reduced by above two-thirds. The success in development of this new technology will offer new ideas and technology platform for the synthesis of metal detergent additive to lubricating oils in China.展开更多
孤岛油田东区属于高温高钙普通稠油油藏,地层温度71℃,配注水钙镁离子230 mg/L,地面原油粘度1 500 m Pa·s^3 000 m Pa·s,目前已进入特高含水开发阶段。本文针对孤岛油田东区II类油藏温度高,钙镁离子含量高,原油粘度高的特点,...孤岛油田东区属于高温高钙普通稠油油藏,地层温度71℃,配注水钙镁离子230 mg/L,地面原油粘度1 500 m Pa·s^3 000 m Pa·s,目前已进入特高含水开发阶段。本文针对孤岛油田东区II类油藏温度高,钙镁离子含量高,原油粘度高的特点,通过增加石油磺酸盐(SLPS)相对分子质量、调整SLPS及非离子活性剂gd-1复配比例提高体系界面活性和抗钙能力,设计出了适合用于目的区块的高效二元驱配方,其抗钙镁能力大于500 mg/L,界面张力4.4×10-3m N/m,室内提高采收率17.4%。配方于2010年应用于孤岛东区北Ng3-4单元,矿场取得了很好的降水增油效果,已经累计增油87.7万t,提高采收率5.98%。孤岛东区二元复合驱矿场试验的成功为今后高温高钙稠油油藏大幅度提高采收率研究提供了指导。展开更多
文摘An innovative idea was proposed to prepare the overbased nano-sized calcium carbonate-calcium petroleum sulfonate in-situ the HIGEE reactor. The test sample prepared by this technology could meet the requirement of the industry standard SH0042-91 for the first-grade product on a par with similar overseas product. The test results obtained upon observation under microscope after freezing etching of specimen revealed that the crystal size of colloidal calcium sulfonate was in the range of 10-30 nm with an average size of 20 nm. The size of the detergent additive was uniform with good transmittance and fluidity. The HIGEE technology possesses five specific features as shown below: Firstly, the carbonation reaction is completed in one step with the reaction time reduced by more than 50% as compared to traditional batch reactor process along with enhanced reaction efficiency, good operability of the process and stabilized product quality. Secondly, ammonia emitted from the reaction is used as the co- promoter without the need for adding ammonia and water as promoters to simplify the promoter system along with effective and strong coupling of reactions. Thirdly, the utilization rate of Ca(OH)2 and CO2 is increased by 15% and 30%, respectively, with product yield increased by 15%, and calcium residue decreased by 65%. Fourthly, the HIGEE technology is environmental benign because of gasoline is used in this technology instead of toxic toluene and xylene. Fifthly, the dimension of HIGEE reactor is reduced by above two-thirds. The success in development of this new technology will offer new ideas and technology platform for the synthesis of metal detergent additive to lubricating oils in China.
文摘孤岛油田东区属于高温高钙普通稠油油藏,地层温度71℃,配注水钙镁离子230 mg/L,地面原油粘度1 500 m Pa·s^3 000 m Pa·s,目前已进入特高含水开发阶段。本文针对孤岛油田东区II类油藏温度高,钙镁离子含量高,原油粘度高的特点,通过增加石油磺酸盐(SLPS)相对分子质量、调整SLPS及非离子活性剂gd-1复配比例提高体系界面活性和抗钙能力,设计出了适合用于目的区块的高效二元驱配方,其抗钙镁能力大于500 mg/L,界面张力4.4×10-3m N/m,室内提高采收率17.4%。配方于2010年应用于孤岛东区北Ng3-4单元,矿场取得了很好的降水增油效果,已经累计增油87.7万t,提高采收率5.98%。孤岛东区二元复合驱矿场试验的成功为今后高温高钙稠油油藏大幅度提高采收率研究提供了指导。
