High-Energy Lithium-Ion Batteries:Recent Progress and a Promising Future in Applications

It is of great significance to develop clean and new energy sources with high-efficient energy storage technologies,due to the excessive use of fossil energy that has caused severe environmental damage.There is great interest in exploring advanced rechargeable lithium batteries with desirable energy and power capabilities for applications in portable electronics,smart grids,and electric vehicles.In practice,high-capacity and low-cost electrode materials play an important role in sustaining the progresses in lithium-ion batteries.This review aims at giving an account of recent advances on the emerging high-capacity electrode materials and summarizing key barriers and corresponding strategies for the practical viability of these electrode materials.Effective approaches to enhance energy density of lithium-ion batteries are to increase the capacity of electrode materials and the output operation voltage.On account of major bottlenecks of the power lithium-ion battery,authors come up with the concept of integrated battery systems,which will be a promising future for high-energy lithium-ion batteries to improve energy density and alleviate anxiety of electric vehicles.

Cross-satellite calibration of high-energy electron fluxes measured by FengYun-4A based on Arase observations

We use the High-energy Electron Experiments(HEP)instrument onboard Arase(ERG)to conduct an energy-dependent cross-satellite calibration of electron fluxes measured by the High Energy Particle Detector(HEPD)onboard FengYun-4A(FY-4A)spanning from April 1,2017,to September 30,2019.By tracing the two-dimensional magnetic positions(L,magnetic local time[MLT])of FY-4A at each time,we compare the datasets of the conjugate electron fluxes over the range of 245–894 keV in 6 energy channels for the satellite pair within different sets of L×MLT.The variations in the electron fluxes observed by FY-4A generally agree with the Arase measurements,and the percentages of the ratios of electron flux conjunctions within a factor of 2 are larger than 50%.Compared with Arase,FY-4A systematically overestimates electron fluxes at all 6 energy channels,with the corresponding calibration factors ranging from 0.67 to 0.81.After the cross-satellite calibration,the electron flux conjunctions between FY-4A and Arase show better agreement,with much smaller normalized root mean square errors.Our results provide a valuable reference for the application of FY-4A high-energy electron datasets to in-depth investigations of the Earth’s radiation belt electron dynamics.

Microstructure and electrical properties of Y_2O_3-doped ZnO-based varistor ceramics prepared by high-energy ball milling

Y2O3-doped ZnO-based varistor ceramics were prepared using high-energy ball milling （HEBM） and low-temperature sin- tering technique, with voltage-gradient of 1934-2197 V/mm, non-linear coefficients of 20.8-21.8, leakage currents of 0.59-1.04 μA, and densities of 5.46-5.57 g/cm3. With increasing Y2O3 content, the voltage-gradient increases because of the decrease of ZnO grain size; the non-linear coefficient and the leakage current improve but the density decreases because of more porosity; the donor con- centration and density of interface states decrease, whereas the barrier height and width increase because of the acceptor effect of Y2O3 in varistor ceramics.

Study on "fracturing-sealing" integration technology based on high-energy gas fracturing in single seam with high gas and low air permeability

To improve the gas extraction efficiency of single seam with high gas and low air permeability,we developed the"fracturing-sealing"integration technology,and carried out the engineering experiment in the3305 Tunliu mine.In the experiment,coal seams can achieve the aim of antireflection effect through the following process:First,project main cracks with the high energy pulse jet.Second,break the coal body by delaying the propellant blasting.Next,destroy the dense structure of the hard coal body,and form loose slit rings around the holes.Finally,seal the boreholes with the"strong-weak-strong"pressurized sealing technology.The results are as follows:The average concentration of gas extraction increases from8.3%to 39.5%.The average discharge of gas extraction increases from 0.02 to 0.10 m^3/min.The tunneling speeds up from 49.5 to 130 m/month.And the permeability of coal seams improves nearly tenfold.Under the same conditions,the technology is much more efficient in depressurization and antireflection than common methods.In other words,it will provide a more effective way for the gas extraction of single seam with high gas and low air permeability.

Microstructure and Electrical Properties of Er_2O_3-Doped ZnO-Based Varistor Ceramics Prepared by High-Energy Ball Milling

The microstructure, electrical properties and density of ZnO-based varistor ceramics with different Er2O3 content prepared by high-energy ball milling （HEBM） and sintered at 800℃ were investigated. With increasing Er2O3 content, the ZnO grain size decreases due to the Er-rich phases inhibiting grain growth ; and nonlinear coefficient （ α ） decreases because of the decrease of barrier height （φB） The breakdown voltage （Eb） and density increase, whereas leakage current （IL） decreases with increasing Er2O3 content. The barrier height （φB）, donor concentration （Nd）, density of interface states （Ns） decrease and barrier width （ω） increases with increasing Er2O3 content due to acceptor effect of Er2O3 in varistor ceramics.

Towards High-Energy and Anti-Self-Discharge Zn-Ion Hybrid Supercapacitors with New Understanding of the Electrochemistry

Aqueous Zn-ion hybrid supercapacitors(ZHSs)are increasingly being studied as a novel electrochemical energy storage system with prominent electrochemical performance,high safety and low cost.Herein,high-energy and anti-self-discharge ZHSs are realized based on the fibrous carbon cathodes with hierarchically porous surface and O/N heteroatom functional groups.Hierarchically porous surface of the fabricated free-standing fibrous carbon cathodes not only provides abundant active sites for divalent ion storage,but also optimizes ion transport kinetics.Consequently,the cathodes show a high gravimetric capacity of 156 mAh g^(−1),superior rate capability(79 mAh g^(−1)with a very short charge/discharge time of 14 s)and exceptional cycling stability.Meanwhile,hierarchical pore structure and suitable surface functional groups of the cathodes endow ZHSs with a high energy density of 127 Wh kg−1,a high power density of 15.3 kW kg^(−1)and good anti-self-discharge performance.Mechanism investigation reveals that ZHS electrochemistry involves cation adsorption/desorption and Zn_(4)SO_(4)(OH)_(6)·5H_(2)O formation/dissolution at low voltage and anion adsorption/desorption at high voltage on carbon cathodes.The roles of these reactions in energy storage of ZHSs are elucidated.This work not only paves a way for high-performance cathode materials of ZHSs,but also provides a deeper understanding of ZHS electrochemistry.

Surface segregation of InGaAs films by the evolution of reflection high-energy electron diffraction patterns

Surface segregation is studied via the evolution of reflection high-energy electron diffraction （RHEED） patterns under different values of As4 BEP for InGaAs films. When the As4 BEP is set to be zero, the RHEED pattern keeps a 4x3/（nx3） structure with increasing temperature, and surface segregation takes place until 470 ℃ The RHEED pattern develops into a metal-rich （4x2） structure as temperature increases to 495℃. The reason for this is that surface segregation makes the In inside the InGaAs film climb to its surface. With the temperature increasing up to 515℃, the RHEED pattern turns into a GaAs（2x4） structure due to In desorption. While the As4 BEP comes up to a specific value （1.33 x 10-4 Pa-1.33 x 10-3 Pa）, the surface temperature can delay the segregation and desorption. We find that As4 BEP has a big influence on surface desorption, while surface segregation is more strongly dependent on temperature than surface desorption.

Porous Co_(2)VO_(4) Nanodisk as a High-Energy and Fast-Charging Anode for Lithium-Ion Batteries

High-energy–density lithium-ion batteries(LIBs)that can be safely fast-charged are desirable for electric vehicles.However,sub-optimal lithiation potential and low capacity of commonly used LIBs anode cause safety issues and low energy density.Here we hypothesize that a cobalt vanadate oxide,Co_(2)VO_(4),can be attractive anode material for fast-charging LIBs due to its high capacity(~1000 mAh g^(−1))and safe lithiation potential(~0.65 V vs.Li^(+)/Li).The Li+diffusion coefficient of Co2VO4 is evaluated by theoretical calculation to be as high as 3.15×10^(-10) cm^(2) s^(−1),proving Co_(2)VO_(4) a promising anode in fast-charging LIBs.A hexagonal porous Co2VO4 nanodisk(PCVO ND)structure is designed accordingly,featuring a high specific surface area of 74.57 m^(2) g^(−1) and numerous pores with a pore size of 14 nm.This unique structure succeeds in enhancing Li^(+) and electron transfer,leading to superior fast-charging performance than current commercial anodes.As a result,the PCVO ND shows a high initial reversible capacity of 911.0 mAh g^(−1) at 0.4 C,excellent fast-charging capacity(344.3 mAh g^(−1) at 10 C for 1000 cycles),outstanding long-term cycling stability(only 0.024% capacity loss per cycle at 10 C for 1000 cycles),confirming the commercial feasibility of PCVO ND in fast-charging LIBs.

Optimization of Process Parameters for in High-Energy Ball Milling of CNTs/Al2024 Composites Through Response Surface Methodology

The mathematical models are developed to evaluate the ultimate tensile strength( UTS) and hardness of CNTs / Al2024 composites fabricated by high-energy ball milling. The effects of the preparation variables which are milling time,rotational speed,mass fraction of CNTs and ball to powder ratio on UST and hardness of CNTs / Al2024 composites are investigated. Based on the central composite design( CCD),a quadratic model is developed to correlate the fabrication variables to the UST and hardness. From the analysis of variance( ANOVA),the most influential factor on each experimental design response is identified. The optimum conditions for preparing CNTs / Al2024 composites are found as follows: 1. 53 h milling time,900 r / min rotational speed,mass fraction of CNTs 2. 87% and Ball to powder ratio 25 ∶ 1. The predicted maximum UST and hardness are 273.30 MPa and 261.36 HV,respectively. And the experimental values are 283.25 MPa and256.8 HV,respectively. It is indicated that the predicted UST and hardness after process optimization are found to agree satisfactory with the experimental values.

Azimuthal distributions of final-state particles and fragments and transverse structure of emission source in high-energy nucleus-nucleus collisions

The azimuthal distributions of final-state particles and fragments produced in high-energy nucleus-nucleus collisions are described by a modified multisource ideal gas model which contains the expansions and movements of the emission sources. The transverse structures of the sources are given in the transverse plane by momentum components Px and Py, and described by parameters in the model. The results of the azimuthal distributions, calculated by the Monte Carlo method, are in good agreement with the experimental data in nucleus-nucleus collisions at high energies.

Characterization of MCrAlY/nano-Al_(2)O_(3) nanocomposite powder produced by high-energy mechanical milling as feedstock for high-velocity oxygen fuel spraying deposition

Al_(2)O_(3) nanoparticles and MCrAlY/nano-Al_(2)O_(3) nanocomposite powder(M=Ni,Co,or NiCo)were produced using high-energy ball milling.The MCrAlY/nano-Al_(2)O_(3) coating was deposited by selecting an optimum nanocomposite powder as feedstock for high-velocity oxy-gen fuel thermal spraying.The morphological and microstructural examinations of the Al_(2)O_(3) nanoparticles and the commercial MCrAlY and MCrAlY/nano-Al_(2)O_(3) nanocomposite powders were investigated using X-ray diffraction analysis,field-emission scanning electron microscopy coupled with electron dispersed spectroscopy,and transmission electron microscopy.The structural investigations and Williamson-Hall res-ults demonstrated that the ball-milled Al_(2)O_(3) powder after 48 h has the smallest crystallite size and the highest amount of lattice strain among the as-received and ball-milled Al_(2)O_(3) owing to its optimal nanocrystalline structure.In the case of developing MCrAlY/nano-Al_(2)O_(3) nanocompos-ite powder,the particle size of the nanocomposite powders decreased with increasing mechanical-milling duration of the powder mixture.

A Strategy for Magnifying Vibration in High-Energy Orbits of a Bistable Oscillator at Low Excitation Levels

This work focuses on how to maintain a high-energy orbit motion of a bistable oscillator when subjected to a low level excitation. An elastic magnifier （EM） positioned between the base and the bistable oscillator is used to magnify the base vibration displacement to significantly enhance the output characteristics of the bistable oscillator. The dimensionless electromechanical equations of the bistable oscillator with an EM are derived, and the effects of the mass and stiffness ratios between the EM and the bistable oscillator on the output displacement are studied. It is shown that the jump phenomenon occurs at a lower excitation level with increasing the mass and stiffness ratios. With the comparison of the displacement trajectories and the phase portraits obtained from experiments, it is vMidated that the bistable oscillator with an EM can effectively oscillate in a high-energy orbit and can generate a superior output vibration at a low excitation level as compared with the bistable oscillator without an EM.

Phase transition model of water flow irradiated by high-energy laser in a chamber

In the absorption chamber of a high-energy laser energy meter, water is directly used as an absorbing medium and the interaction of the high-power laser and the water flow can produce a variety of physical phenomena such as phase transitions. The unit difference method is adopted to deduce the phase transition model for water flow irradiated by a high-energy laser. In addition, the model is simulated and verified through experiments. Among them, the experimental verification uses the photographic method, shooting the distribution and the form of the air mass of water flow in different operating conditions, which are compared with the simulation results. The research shows that it is achievable to reduce the intensity of the phase transition by increasing the water flow, reducing the power intensity of the beam, shortening the distance the beam covers, reducing the initial water temperature or adopting a shorter wavelength laser. The study＇s results will provide the reference for the design of a water-direct-absorption-type high-energy laser energy meter as well as an analysis of the interaction processes of other similar high-power lasers and water flow.

Differences in MBUs induced by high-energy and medium-energy heavy ions in 28 nm FPGAs

Multiple-bit upsets(MBUs)have become a threat to modern advanced field-programmable gate arrays(FPGAs)applications in radiation environments.Hence,many investigations have been conducted using mediumenergy heavy ions to study the effects of MBU radiation.However,high-energy heavy ions(HEHIs)greatly affect the size and percentage of MBUs because their ionizationtrack structures differ from those of medium-energy heavy ions.In this study,the different impacts of high-energy and medium-energy heavy ions on MBUs in 28 nm FPGAs as well as their mechanisms are thoroughly investigated.With the Geant4 calculation,more serious energy effects of HEHIs on MBU scales were successfully demonstrated.In addition,we identified worse MBU responses resulting from lowered voltages.The MBU orientation effect was observed in the radiation of different dimensions.The broadened ionization tracks for tilted tests in different dimensions could result in different MBU sizes.The results also revealed that the ionization tracks of tilted HEHIs have more severe impacts on the MBU scales than mediumenergy heavy ions with much higher linear energy transfer.Therefore,comprehensive radiation with HEHIs is indispensable for effective hardened designs to apply highdensity 28 nm FPGAs in deep space exploration.

High-Energy Atmospheric Physics: Ball Lightning

This article proposes an explanation for High-Energy Atmospheric phenomena through the frames of Hypersphere World-Universe Model (WUM). In WUM, Terrestrial Gamma-Ray Flashes (TGFs) are, in fact, Gamma-Ray Bursts (GRBs). The spectra of TGFs at very high energies are explained by Dark Matter particles annihilation in Geocorona. Lightning initiation problem is solved by GRBs that slam into thunderclouds and carve a conductive path through a thunderstorm. We introduce Multiworld consisting of Macro-World, Large-World, Small-World, and Micro-World, characterized by suggested Gravitational, Extremely-Weak, Super-Weak, and Weak interaction respectively. We propose a new model of Ball Lightning formation based on the Dark Matter Core surrounded by electron-positron plasma in the Small-World.

A 5.12-GHz LC-based phase-locked loop for silicon pixel readouts of high-energy physics

There is an urgent need for high-quality and high-frequency clock generators for high-energy physics experiments.The transmission data rate exceeds 10 Gbps for a single channel in future readout electronics of silicon pixel detectors.Others,such as time measurement detectors,require a high time resolution based on the time-to-digital readout architecture.A phase-locked loop(PLL)is an essential and broadly used circuit in these applications.This study presents an application-specific integrated circuit of a low-jitter,low-power LC-tank that is PLL fabricated using 55-nm CMOS technology.It includes a 3rd-order frequency synthesis loop with a programmable bandwidth,a divide-by-2 pre-scaler,standard low-voltage differential signaling interfaces,and a current mode logic(CML)driver for clock transmissions.All the d-flip-flop dividers and phase-frequency detectors are protected from single-event upsets using the triple modular redundancy technique.The proposed VCO uses low-pass filters to suppress the noise from bias circuits.The tested LC-PLL covers a frequency locking range between 4.74 GHz and 5.92 GHz with two sub-bands.The jitter measurements of the frequency-halved clock(2.56 GHz)are less than 460 fs and 0.8 ps for the random and deterministic jitters,respectively,and a total of 7.5 ps peak-to-peak with a bit error rate of 10^(-12).The random and total jitter values for frequencies of 426 MHz and 20 MHz are less than 1.8 ps and 65 ps,respectively.The LC-PLL consumed 27 mW for the core and 73.8 mW in total.The measured results nearly coincided with the simulations and validated the analyses and tests.

Modelling of the High-Energy Ball Milling Process

In this paper, the milling parameters of high energy ball mill (Fritsch Pulverisette 7) like vial geometry, number and size of balls and speed of the mill were modelled and discussed. Simulations through discrete element method (DEM) provide correlation between the milling parameters. A mathematical model is used to improve and develop this process. The results show that the loss of powder mass can remarkably improve the performance of milling. The balls made of stainless-steel have a positive effect on the milling efficiency. The simulation shows that the high ball milling velocities can contribute to faster particle size reduction.

DEGRADATION DUE TO ENERGY PULSE IN HIGH-ENERGY ZnO VARISTORS

The degradation phenomena due to the energy pulse in the high-energy ZnO varistors used for deexitation and overvoltage protection of hydroelectric generator are investigated. The energy pulse, obtained by releasing the energy stored in an inductor, can be equivalent to the combination of the DC field components and the energy component. The variations of the characterized voltages, nonlinear coefficients and pre-breakdown V-A characteristics, increase with the number of the applied energy pulse. The asymmetrical variations of the electric properties of the high-energy ZnO varistors after the energy pulse arise from the deformation of the double Schottky barriers due to the ion migration occuring in the depletion layer and in the grain boundary.

Generation of high-energy dual-wavelength domain wall pulse with low repetition rate in an HNLF-based fiber ring laser

The generation of high-energy dual-wavelength domain wall pulse with a low repetition rate is demonstrated in a highly nonlinear fiber （HNLF）-based fiber ring laser. By introducing the intracavity birefringence-induced spectral filtering effect, the dual-wavelength lasing operation can be achieved. In order to enhance the cross coupling effect between the two lasing beams for domain wall pulse formation, a 215-m HNLF is incorporated into the laser cavity. Experimentally, it is found that the dual-wavelength domain wall pulse with a repetition rate of 77.67 kHz could be efficiently obtained through simply rotating the polarization controller （PC）. At a maximum pump power of 322 mW, the 655-nJ single pulse energy in cavity is obtained. The proposed configuration provides a simpler and more efficient way to generate high energy pulse with a low repetition rate.