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Hybrid 2D/3D Graphitic Carbon Nitride-Based High-Temperature Position-Sensitive Detector
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作者 Xuexia Chen Dongwen Yang +6 位作者 Xun Yang Qing Lou Zhiyu Liu Yancheng Chen Chaofan Lv Lin Dong Chongxin Shan 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第1期275-283,共9页
Ultraviolet position-sensitive detectors(PSDs)are expected to undergo harsh environments,such as high temperatures,for a wide variety of applications in military,civilian,and aerospace.However,no report on relevant PS... Ultraviolet position-sensitive detectors(PSDs)are expected to undergo harsh environments,such as high temperatures,for a wide variety of applications in military,civilian,and aerospace.However,no report on relevant PSDs operating at high temperatures can be found up to now.Herein,we design a new 2D/3D graphitic carbon nitride(g-C_(3)N_(4))/gallium nitride(GaN)hybrid heterojunction to construct the ultraviolet high-temperature-resistant PSD.The g-C_(3)N_(4)/GaN PSD exhibits a high position sensitivity of 355 mV mm^(-1),a rise/fall response time of 1.7/2.3 ms,and a nonlinearity of 0.5%at room temperature.The ultralow formation energy of-0.917 eV atom^(-1)has been obtained via the thermodynamic phase stability calculations,which endows g-C_(3)N_(4)with robust stability against heat.By merits of the strong built-in electric field of the 2D/3D hybrid heterojunction and robust thermo-stability of g-C_(3)N_(4),the g-C_(3)N_(4)/GaN PSD delivers an excellent position sensitivity and angle detection nonlinearity of 315 mV mm^(-1)and 1.4%,respectively,with high repeatability at a high temperature up to 700 K,outperforming most of the other counterparts and even commercial silicon-based devices.This work unveils the high-temperature PSD,and pioneers a new path to constructing g-C_(3)N_(4)-based harsh-environment-tolerant optoelectronic devices. 展开更多
关键词 graphitic carbon nitride high-temperature stability lateral photovoltaic effect position-sensitive detectors two-dimensional materials
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Harness High-Temperature Thermal Energy via Elastic Thermoelectric Aerogels 被引量:1
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作者 Hongxiong Li Zhaofu Ding +5 位作者 Quan Zhou Jun Chen Zhuoxin Liu Chunyu Du Lirong Liang Guangming Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第8期196-210,共15页
Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature moni... Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature monitoring/warning in industrial and wearable applications remains a great challenge.Herein,a highly elastic,flame-retardant and high-temperature-resistant TE aerogel,made of poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate)/single-walled carbon nanotube(PEDOT:PSS/SWCNT)composites,has been fabricated,displaying attractive compression-induced power factor enhancement.The as-fabricated sensors with the aerogel can achieve accurately pressure stimuli detection and wide temperature range monitoring.Subsequently,a flexible TE generator is assembled,consisting of 25 aerogels connected in series,capable of delivering a maximum output power of 400μW when subjected to a temperature difference of 300 K.This demonstrates its outstanding high-temperature heat harvesting capability and promising application prospects for real-time temperature monitoring on industrial high-temperature pipelines.Moreover,the designed self-powered wearable sensing glove can realize precise wide-range temperature detection,high-temperature warning and accurate recognition of human hand gestures.The aerogel-based intelligent wearable sensing system developed for firefighters demonstrates the desired self-powered and highly sensitive high-temperature fire warning capability.Benefitting from these desirable properties,the elastic and high-temperature-resistant aerogels present various promising applications including self-powered high-temperature monitoring,industrial overheat warning,waste heat energy recycling and even wearable healthcare. 展开更多
关键词 THERMOELECTRICS AEROGEL SELF-POWERED high-temperature monitoring high-temperature warning
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Enhanced High-Temperature Energy Storage Performance of All-Organic Composite Dielectric via Constructing Fiber-Re in forced Structure 被引量:1
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作者 Mengjia Feng Yu Feng +5 位作者 Changhai Zhang Tiandong Zhang Xu Tong Qiang Gao Qingguo Chen Qingguo Chi 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期299-307,共9页
Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control systems.Selecting a polymer with a hi... Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control systems.Selecting a polymer with a higher glass transition temperature(T_(g))as the matrix is one of the effective ways to increase the upper limit of the polymer operating temperature.However,current high-T_(g)polymers have limitations,and it is difficult to meet the demand for high-temperature energy storage dielectrics with only one polymer.For example,polyetherimide has high-energy storage efficiency,but low breakdown strength at high temperatures.Polyimide has high corona resistance,but low high-temperature energy storage efficiency.In this work,combining the advantages of two polymer,a novel high-T_(g)polymer fiber-reinforced microstructure is designed.Polyimide is designed as extremely fine fibers distributed in the composite dielectric,which will facilitate the reduction of high-temperature conductivity loss for polyimide.At the same time,due to the high-temperature resistance and corona resistance of polyimide,the high-temperature breakdown strength of the composite dielectric is enhanced.After the polyimide content with the best high-temperature energy storage characteristics is determined,molecular semiconductors(ITIC)are blended into the polyimide fibers to further improve the high-temperature efficiency.Ultimately,excellent high-temperature energy storage properties are obtained.The 0.25 vol%ITIC-polyimide/polyetherimide composite exhibits high-energy density and high discharge efficiency at 150℃(2.9 J cm^(-3),90%)and 180℃(2.16 J cm^(-3),90%).This work provides a scalable design idea for high-performance all-organic high-temperature energy storage dielectrics. 展开更多
关键词 all-organic energy storage density high-temperature high-temperature breakdown strength
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TiN/Fe_(2)N/C composite with stable and broadband high-temperature microwave absorption
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作者 Yahong Zhang Yi Zhang +5 位作者 Huimin Liu Dan Li Yibo Wang Chunchao Xu Yuping Tian Hongjie Meng 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第11期2508-2517,共10页
Facing the complex variable high-temperature environment,electromagnetic wave(EMW)absorbing materials maintaining high stability and satisfying absorbing properties is essential.This study focused on the synthesis and... Facing the complex variable high-temperature environment,electromagnetic wave(EMW)absorbing materials maintaining high stability and satisfying absorbing properties is essential.This study focused on the synthesis and EMW absorbing performance evaluation of TiN/Fe_(2)N/C composite materials,which were prepared using electrostatic spinning followed by a high-temperature nitridation process.The TiN/Fe_(2)N/C fibers constructed a well-developed conductive network that generates considerable conduction loss.The heterogeneous interfaces between different components generated a significant level of interfacial polarization.Thanks to the synergistic effect of stable dielectric loss and optimized impedance matching,the TiN/Fe_(2)N/C composite materials demonstrated excellent and stable absorption performance across a wide temperature range(293-453 K).Moreover,TiN/Fe_(2)N/C-15 achieved a minimum reflection loss(RL)of−48.01 dB and an effective absorption bandwidth(EAB)of 3.64 GHz at 2.1 mm and 373 K.This work provides new insights into the development of high-efficiency and stabile EMW absorbing materials under complex variable high-temperature conditions. 展开更多
关键词 high-temperature impedance matching stable permittivity dielectric loss
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Synergistic effect of Zr and Mo on precipitation and high-temperature properties of Al-Si-Cu-Mg alloys
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作者 Chao Gao Bing-rong Zhang +2 位作者 Yin-ming Li Zhi-ming Wang Xiang-bin Meng 《China Foundry》 SCIE EI CAS CSCD 2024年第1期71-81,共11页
This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,... This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg alloy.The synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were studied.Results show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the alloy.They can improve the strength of the alloy by hindering dislocation movement and crack propagation.In addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain refinement.The addition of Mo greatly improves the heat resistance of the alloy.The extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy. 展开更多
关键词 Al-Si-Cu-Mg alloy high-temperature properties Zr-Mo-rich intermetallics nano-strengthening phases
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HZSM-5 zeolites undergoing the high-temperature process for boosting the bimolecular reaction in n-heptane catalytic cracking
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作者 Chenggong Song Zhenzhou Ma +6 位作者 Xu Hou Hao Zhou Huimin Qiao Changchang Tian Li Yin Baitang Jin Enxian Yuan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期136-144,共9页
High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,... High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,N2physisorption,27Al magic angle spinning nuclear magnetic resonance(MAS NMR),and temperature-programmed desorption of ammonia results indicated that the hightemperature treatment at 650℃ hardly affected the inherent crystal and texture of HZSM-5zeolites but facilitated the conversion of framework Al to extra-framework Al,reducing the acid site and enhancing the acid strength.Moreover,the high-temperature treatment improved the performance of HZSM-5 zeolites in n-heptane catalytic cracking,promoting the conversion and light olefins yield while inhibiting coke formation.Based on the kinetic and mechanism analysis,the improvement of HZSM-5 performance caused by high-temperature treatment has been attributed to the formation of extra-framework Al,which enhanced the acid strength,facilitated the bimolecular reaction,and promoted the entropy change to overcome a higher energy barrier in n-heptane catalytic cracking. 展开更多
关键词 HZSM-5 N-HEPTANE Catalytic cracking high-temperature treatment Extra-framework Al
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A review of in-situ high-temperature characterizations for understanding the processes in metallurgical engineering
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作者 Yifan Zhao Zhiyuan Li +2 位作者 Shijie Li Weili Song Shuqiang Jiao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第11期2327-2344,共18页
For the rational manipulation of the production quality of high-temperature metallurgical engineering,there are many challenges in understanding the processes involved because of the black box chemical/electrochemical... For the rational manipulation of the production quality of high-temperature metallurgical engineering,there are many challenges in understanding the processes involved because of the black box chemical/electrochemical reactors.To overcome this issue,various in-situ characterization methods have been recently developed to analyze the interactions between the composition,microstructure,and solid-liquid interface of high-temperature electrochemical electrodes and molten salts.In this review,recent progress of in-situ hightemperature characterization techniques is discussed to summarize the advances in understanding the processes in metallurgical engineering.In-situ high-temperature technologies and analytical methods mainly include synchrotron X-ray diffraction(s-XRD),laser scanning confocal microscopy,and X-ray computed microtomography(X-rayμ-CT),which are important platforms for analyzing the structure and morphology of the electrodes to reveal the complexity and variability of their interfaces.In addition,laser-induced breakdown spectroscopy,high-temperature Raman spectroscopy,and ultraviolet-visible absorption spectroscopy provide microscale characterizations of the composition and structure of molten salts.More importantly,the combination of X-rayμ-CT and s-XRD techniques enables the investigation of the chemical reaction mechanisms at the two-phase interface.Therefore,these in-situ methods are essential for analyzing the chemical/electrochemical kinetics of high-temperature reaction processes and establishing the theoretical principles for the efficient and stable operation of chemical/electrochemical metallurgical processes. 展开更多
关键词 in-situ characterization methods high-temperature electrochemistry ELECTRODES molten salts interfacial reaction
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Carbonation of Pure Minerals in Portland Cement:Evolution in Products as a Function of Water-to-solid Ratio
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作者 XIONG Kun SHANG Xiaopeng +1 位作者 LI Hongyan WANG Dan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1214-1222,共9页
Minerals in Portland cement including tricalcium silicate(C_(3)S),β-dicalcium silicate(β-C_(2)S),tricalcium aluminate(C_(3)A),and tetracalcium ferroaluminate(C_(4)AF),show a significantly different activity and prod... Minerals in Portland cement including tricalcium silicate(C_(3)S),β-dicalcium silicate(β-C_(2)S),tricalcium aluminate(C_(3)A),and tetracalcium ferroaluminate(C_(4)AF),show a significantly different activity and product evolution for CO_(2)curing at various water-to-solid ratios.These pure minerals were synthesized and subject to CO_(2)curing in this study to make an in-depth understanding for the carbonation properties of cement-based materials.Results showed that the optimum water-to-solid ratios of C_(3)S,β-C_(2)S,C_(3)A and C_(4)AF were 0.25,0.15,0.30 and 0.40 for carbonation,corresponding to 2 h carbonation degree of 38.5%,38.5%,24.2%,and 21.9%,respectively.The produced calcite duringβ-C_(2)S carbonation decreased as the water-to-solid ratio increased,with an increase in content of metastable CaCO_(3)of vaterite and aragonite.The thermodynamic stability of CaCO_(3)produced during carbonation was C_(3)A>C_(4)AF>β-C_(2)S>C_(3)S.The carbonation degree of Portland cement was predicted based on the results of pure minerals and the composition of cement,and the error of predicted production of CaCO_(3)was only 1.1%,which provides a potential method to predict carbonation properties of systems with a complex mineral composition. 展开更多
关键词 accelerated carbonation portland cement calcium carbonate water-to-solid ratio
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Natural Lignin:A Sustainable and Cost-Effective Electrode Material for High-Temperature Na-Ion Battery
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作者 Yuqi She Xiwei Li +4 位作者 Yanqin Zheng Dong Chen Xianhong Rui Xuliang Lin Yanlin Qin 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期1-8,共8页
Rechargeable sodium-ion batteries usually suffer from accelerated electrode destruction at high temperatures and high synthesis costs of electrode materials.Therefore,it is highly desirable to explore novel organic el... Rechargeable sodium-ion batteries usually suffer from accelerated electrode destruction at high temperatures and high synthesis costs of electrode materials.Therefore,it is highly desirable to explore novel organic electrodes considering their cost-effectiveness and large adaptability to volume changes.Herein,natural biomass,pristine lignin,is employed as the sodium-ion battery anodes,and their sodium storage performance is investigated at room temperature and 60℃.The lignin anodes exhibit excellent high-temperature sodium-ion battery performance.This mainly results from the generation of abundant reactive sites(C=O)due to the high temperature-induced homogeneous cleavage of the C_(β)-O bond in the lignin macromolecule.This work can inspire researchers to explore other natural organic materials for large-scale applications and high-value utilization in advanced energy storage devices. 展开更多
关键词 high-temperature performance LIGNIN Na storage mechanism organic anode sodium-ion battery
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Carbonation of Dicalcium Silicate Enhanced by Ammonia Bicarbonate and Its Mechanism
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作者 周浩 刘鹏 +1 位作者 WANG Fazhou HU Chuanlin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期69-74,共6页
The strength development law of γ-type dicalcium silicate (γ-C_(2)S) under different carbonation processes was investigated,and the carbonation mechanism of γ-C_(2)S under the action of NH_(4)HCO_(3) was clarified ... The strength development law of γ-type dicalcium silicate (γ-C_(2)S) under different carbonation processes was investigated,and the carbonation mechanism of γ-C_(2)S under the action of NH_(4)HCO_(3) was clarified by using a wide range of test methods,including XRD and SEM.A method of saturated NH_(4)HCO_(3) solution as a curing agent was identified to improve the carbonation efficiency and enhance the carbonation degree of γ-C_(2)S,and then a high-strength carbonated specimen was obtained.Microhardness analysis and SEM morphology analysis were conducted on the carbonised specimens obtained under atmospheric pressure carbonisation conditions using the curing agent.It was found that γ-C_(2)S could perform carbonisation well under atmospheric pressure,which promoted the carbonisation efficiency and decreased the carbonisation cost simultaneously.Therefore,a new carbonisation process solution was proposed for the rapid carbonisation of γ-C_(2)S. 展开更多
关键词 type dicalcium silicate carbonization process curing agent atmospheric carbonization
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High-efficiency Carbonation Modification Methods of Recycled Coarse Aggregates
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作者 张美香 YANG Xiaolin +3 位作者 丁亚红 SUN Bo ZHANG Xianggang LÜXiuwen 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期386-398,共13页
To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put fo... To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put forward.The carbonation effect of modified recycled coarse aggregate with three different carbonation methods was evaluated,and water absorption,apparent density and crush index of modified recycled coarse aggregate were measured.Combined with XRD,SEM,and MIP microscopic analysis,the high-efficiency carbonation strengthening mechanism of modified recycled coarse aggregate was revealed.The experimental results show that,compared with the non-carbonated recycled coarse aggregate,the physical and microscopic properties of carbonated recycled coarse aggregate are improved.The method of carbonation with nano-SiO_(2) pre-soaking can realize the high-efficiency carbonation of recycled coarse aggregate,for modified recycled coarse aggregate with the method,water absorption is reduced by 23.03%,porosity is reduced by 44.06%,and the average pore diameter is 21.82 nm.The high-efficiency carbonation strengthening mechanism show that the pre-socked nano-SiO_(2) is bound to the hydration product Ca(OH)_(2) of the old mortar with nano-scale C-S-H,which can improve the CO_(2) absorption rate,accelerate the carbonation reaction,generate more stable CaCO_(3) and nano-scale silica gel,and bond to the dense three-dimensional network structure to realize the bidirectional enhancement of nano-materials and pressurized carbonation.It is concluded that the method of carbonation with nano-SiO_(2) pre-soaking is a novel high-efficiency carbonation modification of recycled coarse aggregate. 展开更多
关键词 recycled coarse aggregate pressurized carbonation high-efficiency carbonation NANO-SIO2 strengthening mechanism
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A Novel Fracturing Fluid with High-Temperature Resistance for Ultra-Deep Reservoirs
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作者 Lian Liu Liang Li +2 位作者 Kebo Jiao Junwei Fang Yun Luo 《Fluid Dynamics & Materials Processing》 EI 2024年第5期975-987,共13页
Ultra-deep reservoirs play an important role at present in fossil energy exploitation.Due to the related high temperature,high pressure,and high formation fracture pressure,however,methods for oil well stimulation do ... Ultra-deep reservoirs play an important role at present in fossil energy exploitation.Due to the related high temperature,high pressure,and high formation fracture pressure,however,methods for oil well stimulation do not produce satisfactory results when conventional fracturing fluids with a low pumping rate are used.In response to the above problem,a fracturing fluid with a density of 1.2~1.4 g/cm^(3)was developed by using Potassium formatted,hydroxypropyl guanidine gum and zirconium crosslinking agents.The fracturing fluid was tested and its ability to maintain a viscosity of 100 mPa.s over more than 60 min was verified under a shear rate of 1701/s and at a temperature of 175℃.This fluid has good sand-carrying performances,a low viscosity after breaking the rubber,and the residue content is less than 200 mg/L.Compared with ordinary reconstruction fluid,it can increase the density by 30%~40%and reduce the wellhead pressure of 8000 m level reconstruction wells.Moreover,the new fracturing fluid can significantly mitigate safety risks. 展开更多
关键词 Ultra-deep reservoir high-temperature resistance weighted fracturing fluid guanidine gum potassium formatted
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Novel Method for Evaluating the Aging of Aviation Turbine Engine Oils via High-Temperature Bearing Deposit Tests
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作者 Hao Lichun Yang He +3 位作者 Song Haiqing Zhou Yunfan He Jingjian Liang Yuxiang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第1期67-77,共11页
Aviation turbine engine oils require excellent thermal-oxidative stability because of their high-temperature environments.High-temperature bearing deposit testing is a mandatory method for measuring the thermal-oxidat... Aviation turbine engine oils require excellent thermal-oxidative stability because of their high-temperature environments.High-temperature bearing deposit testing is a mandatory method for measuring the thermal-oxidative performance of aviation lubricant oils,and the relevant apparatus was improved in the present study.Two different commercial aviation turbine engine oils were tested,one with standard performance(known as the SL oil)and the other with high thermal stability,and their thermal-oxidative stability characteristics were evaluated.After 100 h of high-temperature bearing testing,the SL oil was analyzed by using various analytical techniques to investigate its thermal-oxidative process in the bearing test,with its thermal-oxidative degradation mechanism also being discussed.The results indicate that the developed high-temperature bearing apparatus easily meets the test requirements of method 3410.1 in standard FED-STD-791D.The viscosity and total acid number(TAN)of the SL oil increased with the bearing test time,and various deposits were produced in the bearing test,with the micro-particles of the carbon deposits being sphere-like,rod-like,and sheet-like in appearance.The antioxidant additives in the oil were consumed very rapidly in the first 30 h of the bearing test,with N-phenyl-1-naphthylamine being consumed faster than dioctyldiphenylamine.Overall,the oil thermal-oxidative process involves very complex physical and chemical mechanisms. 展开更多
关键词 aviation turbine engine oil high-temperature bearing deposit test thermal-oxidative degradation antioxidant additives
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Mapping and resource evaluation of deep high-temperature geothermal resources in the Jiyang Depression,China
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作者 Shaozheng Wang Yaoqi Zhou +5 位作者 Xin Zhang Yangzhou Wang Yonghong Yang Yuehan Shang Yang Chen Xiaoxin Shi 《Energy Geoscience》 EI 2024年第4期142-155,共14页
In China,geothermal resource utilization has mainly focused on resources at shallow and medium depths.Yet,the exploration of deep,high-temperature geothermal resources holds significant importance for achieving the“d... In China,geothermal resource utilization has mainly focused on resources at shallow and medium depths.Yet,the exploration of deep,high-temperature geothermal resources holds significant importance for achieving the“dual carbon”goals and the transition of energy structure.The Jiyang Depression in the Bohai Bay Basin has vast potential for deep,high-temperature geothermal resources.By analyzing data from 2187 wells with temperature logs and 270 locations for temperature measurement in deep strata,we mapped the geothermal field of shallow to medium-deep layers in the Jiyang Depression using ArcGIS and predicted the temperatures of deep layers with a burial depth of 4000 m.Through stochastic modeling and numerical simulation,a reservoir attribute parameter database for favorable deep,high-temperature geothermal areas was developed,systematically characterizing the spatial distribution of geothermal resources within a play fairway of 139.5 km2 and estimating the exploitable deep geothermal resource potential by using the heat storage method and Monte Carlo data analysis.The study reveals that the Fan 54 well block in the Boxing-Jijia region is of prime significance to develop deep,high-temperature geothermal resources in the Jiyang Depression.Strata from the Cenozoic to the Upper Paleozoic are identified as effective cap layers for these deep geothermal resources.The Lower Paleozoic capable of effectively storing thermal energy and possessing an exploitable resource volume up to 127 million tons of standard coal,is identified as a target system for the development of deep high-temperature geothermal resources,providing significant insights for the efficient development of geothermal resources in the Jiyang Depression. 展开更多
关键词 Deep high-temperature geothermal resource Geological modeling Resource assessment Lower Paleozoic Jiyang Depression
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High-performance and robust high-temperature polymer electrolyte membranes with moderate microphase separation by implementation of terphenyl-based polymers
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作者 Jinyuan Li Congrong Yang +3 位作者 Haojiang Lin Jicai Huang Suli Wang Gongquan Sun 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期572-578,共7页
Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel cells.To overcome these barriers,poly(te... Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel cells.To overcome these barriers,poly(terphenyl piperidinium)s constructed from the m-and p-isomers of terphenyl were synthesized to regulate the microstructure of the membrane.Highly rigid p-terphenyl units prompt the formation of moderate PA aggregates,where the ion-pair interaction between piperidinium and biphosphate is reinforced,leading to a reduction in the plasticizing effect.As a result,there are trade-offs between the proton conductivity,mechanical strength,and PA retention of the membranes with varied m/p-isomer ratios.The designed PA-doped PTP-20m membrane exhibits superior ionic conductivity,good mechanical strength,and excellent PA retention over a wide range of temperature(80–160°C)as well as satisfactory resistance to harsh accelerated aging tests.As a result,the membrane presents a desirable combination of performance(1.462 W cm^(-2) under the H_(2)/O_(2)condition,which is 1.5 times higher than that of PBI-based membrane)and durability(300 h at 160°C and 0.2 A cm^(-2))in the fuel cell.The results of this study provide new insights that will guide molecular design from the perspective of microstructure to improve the performance and robustness of HT-PEMs. 展开更多
关键词 Fuel cell high-temperature polymer electrolyte membranes Microphase separation Poly(terphenyl piperidinium)s Phosphoric acid
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Integrated multi-scale approach combining global homogenization and local refinement for multi-field analysis of high-temperature superconducting composite magnets
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作者 Hanxiao GUO Peifeng GAO Xingzhe WANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第5期747-762,共16页
Second-generation high-temperature superconducting(HTS)conductors,specifically rare earth-barium-copper-oxide(REBCO)coated conductor(CC)tapes,are promising candidates for high-energy and high-field superconducting app... Second-generation high-temperature superconducting(HTS)conductors,specifically rare earth-barium-copper-oxide(REBCO)coated conductor(CC)tapes,are promising candidates for high-energy and high-field superconducting applications.With respect to epoxy-impregnated REBCO composite magnets that comprise multilayer components,the thermomechanical characteristics of each component differ considerably under extremely low temperatures and strong electromagnetic fields.Traditional numerical models include homogenized orthotropic models,which simplify overall field calculation but miss detailed multi-physics aspects,and full refinement(FR)ones that are thorough but computationally demanding.Herein,we propose an extended multi-scale approach for analyzing the multi-field characteristics of an epoxy-impregnated composite magnet assembled by HTS pancake coils.This approach combines a global homogenization(GH)scheme based on the homogenized electromagnetic T-A model,a method for solving Maxwell's equations for superconducting materials based on the current vector potential T and the magnetic field vector potential A,and a homogenized orthotropic thermoelastic model to assess the electromagnetic and thermoelastic properties at the macroscopic scale.We then identify“dangerous regions”at the macroscopic scale and obtain finer details using a local refinement(LR)scheme to capture the responses of each component material in the HTS composite tapes at the mesoscopic scale.The results of the present GH-LR multi-scale approach agree well with those of the FR scheme and the experimental data in the literature,indicating that the present approach is accurate and efficient.The proposed GH-LR multi-scale approach can serve as a valuable tool for evaluating the risk of failure in large-scale HTS composite magnets. 展开更多
关键词 epoxy-impregnated high-temperature superconducting(HTS)magnet multi-scale method global homogenization(GH) local refinement(LR) multi-field analysis
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Design and evaluation of UHPP steel bridge deck pavement for high-temperature and rainy regions
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作者 Qian Zhendong Zhang Shaojin +1 位作者 Min Yitong Zhao Xinyuan 《Journal of Southeast University(English Edition)》 EI CAS 2024年第3期257-265,共9页
To enhance the serviceability of steel bridge deck pavement(SBDP)in high-temperature and rainy regions,a concept of rigid bottom and flexible top was summarized using engineering practices,which led to the proposal of... To enhance the serviceability of steel bridge deck pavement(SBDP)in high-temperature and rainy regions,a concept of rigid bottom and flexible top was summarized using engineering practices,which led to the proposal of a three-layer ultra-high-performance pavement(UHPP).The high-temperature rutting resistance and wet-weather skid resistance of UHPP were evaluated through composite structure tests.The internal temperature distribution within the pavement under typical high-temperature conditions was analyzed using a temperature field model.Additionally,a temperature-stress coupling model was employed to investigate the key load positions and stress response characteristics of the UHPP.The results indicate that compared with the traditional guss asphalt+stone mastic asphalt structure,the dynamic stability of the UHPP composite structure can be improved by up to 20.4%.Even under cyclic loading,UHPP still exhibits superior surface skid resistance compared to two traditional SBDPs.The thickness composition of UHPP significantly impacts its rutting resistance and skid resistance.UHPP exhibits relatively low tensile stress but higher shear stress levels,with the highest shear stress occurring between the UHPP and the steel plate.This suggests that the potential risk of damage for UHPP primarily lies within the interlayer of the pavement.Based on engineering examples,introducing interlayer gravel and optimizing the amount of bonding layer are advised to ensure that UHPP possesses sufficient interlayer shear resistance. 展开更多
关键词 steel bridge deck pavement(SBDP) high-temperature environment rainy weather rigid bottom and flexible top temperature field composite structure
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Repair of Second-Generation Recycled Fine Aggregate of Waste Concrete from Freeze-Thaw Environment by Carbonation Treatment
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作者 Jie Huang Rongbin Jiang +1 位作者 Xiaobo Sun Yingyong Shuai 《Journal of Renewable Materials》 EI CAS 2024年第1期187-201,共15页
The reuse of waste recycled concrete from harsh environments has become a research hotspot in the field of construction.This study investigated the repair effect of carbonation treatment on second-generation recycled ... The reuse of waste recycled concrete from harsh environments has become a research hotspot in the field of construction.This study investigated the repair effect of carbonation treatment on second-generation recycled fine aggregate(SRFA)obtained from recycled fine aggregate concrete(RFAC)subjected to freeze-thaw(FT)cycles.Before and after carbonation,the properties of SRFA were evaluated.Carbonated second-generation recycled fine aggregate(CSRFA)at five substitution rates(0%,25%,50%,75%,100%)to replace SRFA was used to prepare carbonated second-generation recycled fine aggregate concrete(CSRFAC).The water absorption,porosity and mechanical properties of CSRFAC were tested,and its frost-resisting durability was evaluated.The results showed after carbonation treatment,the physical properties of SRFA was improved and met the requirements of II aggregate.The micro-hardness of the interfacial transition zone and attached mortar in CSRFA was 50.5%and 31.2%higher than that in SRFA,respectively.With the increase of CSRFA replacement rate,the water absorption and porosity of CSRFAC gradually decreased,and the mechanical properties and frost resistance of CSRFAC were gradually improved.Carbonation treatment effectively repairs the damage of SRFA caused by FT cycles and improves its application potential. 展开更多
关键词 carbonation treatment REPAIR freeze-thaw cycles second-generation recycled fine aggregate
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Investigation of Carbonation of Concrete Based on Crushed Sand and Admixtures
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作者 Jacques Herve Koung à Bediang Emmanuel Elat Assoua Moukete +1 位作者 Paul Djomou Djonga Michel Mbessa 《Journal of Minerals and Materials Characterization and Engineering》 2024年第5期247-264,共18页
Carbonation is a natural aging process that occurs in all types of concrete. One of its primary implications is the acceleration of steel corrosion caused by the phenomena of depassivation. The goal of this research i... Carbonation is a natural aging process that occurs in all types of concrete. One of its primary implications is the acceleration of steel corrosion caused by the phenomena of depassivation. The goal of this research is to investigate the carbonation of quarry sand-based concrete. The concrete is made of 100% crushed sand 0/6.3, gravel 8/15, and 15/25 from the Arab Contractor quarry in Nomayos, Cameroon, with CEM II B-P 42.5 R from CIMENCAM (Cimenteries du Cameroun). The study employed two admixtures: one with a dual superplasticizing and reducing action (Sikamen) and another with a water-repellent effect (Sika liquid). Carbonation was performed on concrete samples at the following dates: 0, 7, 14, 28, 56, 90, 180 days, one year, and six months. Carbonated concrete (CC) and non-carbonated concrete (NCC) samples are compared in terms of their physical attributes and mineralogical characteristics. The results of this investigation reveal that after more than a year and six months of carbonation, porosity decreases and permeability increases. Despite the high fineness modulus of quarry sand, the compressive strength of quarry sand-based concrete is satisfactory. Carbonation depth is relatively high on some dates, exceeding the minimal cover value for concrete reinforcement. Sikament additive increases concrete compactness and durability while decreasing permeability. Sika water repellant mixes with the lime in cement to generate complimentary crystallizations that block the mortar’s capillaries, making it watertight. 展开更多
关键词 carbonation CONCRETE Crushed Sand Sikamant WATER-REPELLENT
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Study on Durability of Recycled Aggregate Concrete in High-Temperature and Complex Environments
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作者 Xiaoqing Hu Yao Tong +1 位作者 Xuan Min Rongchong Xu 《Journal of World Architecture》 2024年第5期66-71,共6页
Recycled aggregate concrete refers to a new type of concrete material made by processing waste concrete materials through grading,crushing,and cleaning,and then mixing them with cement,water,and other materials in a c... Recycled aggregate concrete refers to a new type of concrete material made by processing waste concrete materials through grading,crushing,and cleaning,and then mixing them with cement,water,and other materials in a certain gradation or proportion.This type of concrete is highly suitable for modern construction waste disposal and reuse and has been widely used in various construction projects.It can also be used as an environmentally friendly permeable brick material to promote the development of modern green buildings.However,practical applications have found that compared to ordinary concrete,the durability of this type of concrete is more susceptible to high-temperature and complex environments.Based on this,this paper conducts theoretical research on its durability in high-temperature and complex environments,including the current research status,existing problems,and application prospects of recycled aggregate concrete’s durability in such environments.It is hoped that this analysis can provide some reference for studying the influence of high-temperature and complex environments on recycled aggregate concrete and its subsequent application strategies. 展开更多
关键词 Recycled aggregate concrete Construction engineering high-temperature and complex environment DURABILITY
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