Research on material design and high-temperature friction and wear properties of new graphitic steel

To solve the problem of the severe mismatch between the product and roll materials in the preliminary rolling line,a new graphitic steel material was designed,its microstructure and high-temperature friction and wear properties were investigated.Moreover,the feasibility of replacing semi-steel with this new material in the V1 stand roll was studied herein.The results show that the graphitic steel matrix is strengthened by silicon and nickel elements.The presence of spherical graphite also provides self-lubrication and heat conduction and prevents the propagation of cracks.Carbides in the appropriate amount and size strengthen the matrix,reduce the cracking effect of the matrix,and are not easily broken,thereby reducing high-temperature abrasive wear.Under the same hightemperature friction and wear conditions,compared with semi-steel,the wear-scar surface of graphitic steel exhibits less wear-scar depth and wear volume,a smaller friction coefficient,reduced oxide layer thickness,and fewer instances of peeling and microcracks.Therefore,the newly designed graphitic steel has higher wear resistance and hot-crack resistance than semi-steel,which makes it feasible for use in replacing semi-steel as a new V1 frame roll material in the blooming mill.

Research on microstructure and high-temperature friction and wear properties of a cobalt-based alloy for hot extrusion die

The hot extrusion die is a key tool for determining the surface quality and dimensional accuracy of extruded products.Because its service process is subject to high temperature,high pressure,and wear,it must be resistant to these conditions.In this paper,the high-temperature friction and wear properties of a cobalt(Co)-based alloy were investigated and compared with those of a titanium carbide(TiC)cemented material.The results show that the high-temperature wear performance of the Co-based alloy is better than that of the TiC cemented material,and that Co-based materials have the potential for replacing TiC cemented materials as hot-extrusion-die materials.Due to the high density and good combination of the matrix and carbide,the carbides do not easily peel off from the matrix during the wear process.Due to the higher impact toughness of the Co-based alloys,microcracks that can cause worn-surface peeling are not easily generated.As a result,the high-temperature wear performance of Co-based alloys is found to be better than that of TiC cemented materials.

Microstructural Dependence of Friction and Wear Behavior in Biological Shells

As an essential renewable mineral resource,mollusk shells can be used as handicrafts,building materials,adsor-bents,etc.However,there are few reports on the wear resistance of their structures.The Vicker’s hardness and friction,and wear resistance of different microstructures in mollusk shells were comparatively studied in the pre-sent work.The hardness of prismatic structures is lower than that of cross-lamellar and nacreous structures.How-ever,the experimental results of sliding tests indicate that the prismatic structure exhibits the best anti-wear ability compared with foliated,crossed-lamellar,and nacreous structures.The anti-wear and hardness do not present a positive correlation,as the wear resistance properties of different microstructures in mollusk shells are governed jointly by organic matrix,structural arrangement,and basic building block actions.The present researchfindings are expected to provide fundamental insight into the design of renewable bionic materials with high wear resistance.

Friction and wear behavior and mechanism of low carbon microalloyed steel containing Nb

Dry sliding friction and wear test of Nb containing low carbon microalloyed steel was carried out at room temperature,and the effect of Nb on the wear behavior of the steel,as welll as the mechanism was studied.Scanning electron microscopy(SEM) and energy dispersive spectrometry(EDS) were employed to analyze the morphology and composition of the worn surface,and the structure evolution of the plastic deformation layer.The carbide content and type in the steel were analyzed by the electrolytic extraction device and X-ray diffraction(XRD).The experimental results demonstrate that the addition of 0.2% Nb can refine the grain and generate Nb C to improve the wear resistance of the steel.By enhancing the load and speed of wear experiment,the wear mechanism of the test steel with 0.2% Nb changes from slight oxidation wear to severe adhesion wear and oxidation wear.Compared with the load,the increase in the rotation speed exerts a greater influence on the wear of the test steel.

Effect of La_2O_3 on microstructure and high-temperature wear property of hot-press sintering FeAl intermetallic compound

FeAl intermetallic compound with different contents of rare earth oxide La2O3 addition was prepared by hot pressing the mechanically alloyed powders.Effect of La2O3 on microstructure and high-temperature wear property of the sintered FeAl samples was investigated in this paper.The results showed that 1 wt.% La2O3 addition could refine the microstructure and increase the density of the FeAl intermetallic compound,and correspondingly improved the high-temperature wear resistance.SEM and EDS analyses of the wo...

Exploring the Friction and Wear Properties of Silver Coatings on 718 Alloy

Fasteners of 718 alloys are used to set up connection between each support and other components for ITER system, metal-based Ag solid lubricant coating is widely used as an anti-seizure lubricant coating due to its strong low-temperature shear resistance. But the poor adhesion to the steel surfaces has been a critical restriction for applying the silver coatings to the practical machine elements. In this work, an 8-μm silver self-lubricating coating was deposited on the surface of 718 alloy by the method of magnetron sputtering. The coating was uniform, dense and consistent. The wear mechanism was investigated by analyzing the friction and wear properties of the coating. Stress is one of the important impacts on the friction coefficient, the results showed that it first increased and then decreased with the increase of pressure at room temperature and under vacuum. Temperature exerted an effect on the silver self-lubricating coating. A study was conducted under vacuum on the friction and wear performance of the coating at 300 K, 225 K, 155 K, and 77 K, respectively. The results showed that the wear mechanism and wear state varied under various low-temperature conditions, with the severity of wear reaching the maximum only at 225 K. Through the same silver coating process, the washer of superbolt was improved by silver coating treatment.

High temperature frictional wear behaviors of nano-particle reinforced NiCoCrAlY cladded coatings

The NiCoCrAlY coatings strengthened by three nano-particles with the same addition were prepared on a Ni-base super alloy using laser cladding technique. The dry frictional wear behaviors of the coatings at 500 ℃ in static air were investigated. The comparison was made with the coating without nano-particles. The results show that the wear mechanism of the NiCoCrAlY coatings with nano-particles, like the coating without nano-particles, is the delamination wear due to the strong plastic deformation and oxidative wear. However, the frictional coefficient of the coatings increases and presents the decrease trend with the increase of sliding distance after adding nano-particles. Moreover, the wear rate of the coatings with nano-particles is only 34.0%-64.5% of the coating without nano-particles. Among the three nano-particles, the improvement of nano-SiC on the high temperature wear resistance of the coating is the most significant.

Fretting wear and friction oxidation behavior of 0Cr20Ni32AlTi alloy at high temperature

The fretting wear behavior of 0Cr20Ni32AlTi alloy was investigated with crossed cylinder contact under 80 N at 300 and 400 °C.Wear scar and debris were analyzed systematically by scanning electron microscopy and X-ray photoelectron spectroscopy.The results show that the friction logs are mixed fretting regime and gross slip regime with the magnitudes of displacement of 10 and 20 μm,respectively.Severe wear and friction oxidation occur on the material surface.A large number of granular debris produced in the fretting process can be easily congregated and adhered at the contact zone after repeated crushes.The resultant of friction oxidation is mainly composed of Fe3O4,Fe2O3,Cr2O3 and NiO.Temperature and friction are the major factors affecting the oxidation reaction rate.The fretting friction effect can enhance the oxidation reaction activity of surface atoms of 0Cr20Ni32AlTi alloy and reduce the oxidation activation energy.As result,the oxidation reaction rate is accelerated.

Friction and wear properties of in-situ synthesized Al_2O_3 reinforced aluminum composites

Al-5%Si-AI2O3 composites were prepared by powder metallurgy and in-situ reactive synthesis technology. Friction and wear properties of Al-5%Si-Al2O3 composites were studied using an M-2000 wear tester. The effects of load, sliding speed and long time continuous friction on friction and wear properties of Al-5%Si-Al2O3 composites were investigated, respectively. Wear surface and wear mechanism of Al-5%Si-Al2O3 composites were studied by Quanta 200 FE-SEM. Results showed that with load increasing, wear loss and coefficient of friction increased. With sliding speed going up, the surface temperature of sample made the rate of the producing of oxidation layer increase, while wear loss and coefficient of friction decreased. With the sliding distance increasing, coefficient of friction increased because the adhesive wear mechanism occurred in the initial stage, then formation and destruction of the oxide layer on the surface of the sample tended to a dynamic equilibrium, the surface state of the sample was relatively stable and so did the coefficient of friction. The experiment shows that the main wear mechanism of Al-5%Si-Al2O3 composites includes abrasive wear, adhesive wear and oxidation wear.

Preparation, friction and wear properties of hydrophobic lanthanum borate nanorods in rapeseed oil

Oleic acid (denoted as OA) surface-caped lanthanum borate nanorods, abbreviated as OA/LaBO3·H2O, were prepared via hydrothermal method. The microstructures of the as-prepared OA/LaBO3·H2O nanorods were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. The friction and wear properties of OA/LaBO3·H2O nanorods in rapeseed oil were evaluated with a four-ball tribo-tester. The results show that the as-prepared OA/LaBO3·H2O nanorods are hydrophobic and display nanorods morphology with uniform diameter of about 50 nm and length of up to 500 nm. In the meantime, OA/LaBO3·H2O nanorods can obviously improve the anti-wear and friction-reducing capacities of rapeseed oil, and the optimal anti-wear and friction-reducing properties of rapeseed oil were obtained at an OA/LaBO3·H2O content of 1% (mass fraction).

Friction and wear behaviors of Nb-Ti-Si-Cr based ultrahigh temperature alloy and its Zr-Y jointly modified silicide coatings

Zr-Y jointly modified silicide coatings were prepared on an Nb-Ti-Si-Cr based ultrahigh temperature alloy by pack cementation process. The wear behaviors of both the base alloy and coatings were comparatively studied at room temperature and 800 ℃ using SiC balls as the counterpart. The Zr-Y jointly modified silicide coating is mainly composed of a thick （Nb,X）Si2 outer layer and a thin （Ti,Nb）5Si4 inner layer. The coatings possess much higher microhardness than the base alloy. The wear rates of both the base alloy and coatings increase with increasing the sliding loads. However, the coatings have much lower wear rates than the base alloy under the same sliding conditions. The coatings have superior anti-friction property, and can provide effective protection for the base alloy at both room temperature and 800 ℃ in air.

STUDY OF THE PERFORMANCE ON THE WEAR AND FRICTION OF THE C/Cu COMPOSITE MATERIAL

The friction and wear properties of the C/Cu composite material were investigated. The experiments were conducted on a block on ring type friction machine. It has been found that the friction coefficient and the wear rate of the composite material increase slowly as the pressure is increased in a mild wear state. Scanning electron microscopy and electron probe X ray micro analyzer observations indicate that the low values of μ and W L are due to the formation of a film that impedes adhesion and confers some degree of self lubrication.

Dry Friction and Wear Characteristics of Impregnated Graphite in a Corrosive Environment

Tribological properties of impregnated graphite are greatly influenced by preparation technology and working conditions and it’s highly susceptible to corrosion environmental impacts,but the experimental research about it are few.In this paper,three kinds of impregnated graphite samples are prepared with different degree of graphitization,the tribological properties of these samples in the dry friction environment and in a corrosive environment are analyzed and contrasted.The tribo-test results show that the friction coefficient of samples is reduced and the amount of wear of samples increase when the graphitization degree of samples increases in dry friction condition.While in a corrosive environment（samples are soaked N2O4）,the friction coefficient and amount of wear are changed little if the graphitization degree of samples are low.If the degree of graphitization increase,the friction coefficient and amount of wear of samples increase too,the amount of wear is 2 to 3 times as the samples tested in the non-corrosive environment under pv value of 30MPa？m/s.The impregnated graphite,which friction coefficient is stable and graphitization degree is in mid level,such#2,is more appropriate to have a work in the corrosion conditions.In this paper,preparation and tribological properties especially in corrosive environment of the impregnated graphite is studied,the research conclusion can provide an experimental and theoretical basis for the selection and process improvement of graphite materials,and also provide some important design parameters for contact seal works in a corrosive environment.

Enhancement of wear and ballistic resistance of armour grade AA7075 aluminium alloy using friction stir processing

Industrial applications of aluminium and its alloys are restricted because of their poor tribological properties. Thermal spraying, laser surfacing, electron beam welding are the most widely used techniques to alter the surface morphology of base metal. Preliminary studies reveal that the coating and layering of aluminium alloys with ceramic particles enhance the ballistic resistance. Furthermore, among aluminium alloys,7075 aluminium alloy exhibits high strength which can be compared to that of steels and has profound applications in the designing of lightweight fortification structures and integrated protection systems. Having limitations such as poor bond integrity, formation of detrimental phases and interfacial reaction between reinforcement and substrate using fusion route to deposit hard particles paves the way to adopt friction stir processing for fabricating surface composites using different sizes of boron carbide particles as reinforcement on armour grade 7075 aluminium alloy as matrix in the present investigation. Wear and ballistic tests were carried out to assess the performance of friction stir processed AA7075 alloy. Significant improvement in wear resistance of friction stir processed surface composites is attributed to the change in wear mechanism from abrasion to adhesion. It has also been observed that the surface metal matrix composites have shown better ballistic resistance compared to the substrate AA7075 alloy. Addition of solid lubricant Mo S2 has reduced the depth of penetration of the projectile to half that of base metal AA7075 alloy. For the first time, the friction stir processing technique was successfully used to improve the wear and ballistic resistances of armour grade high strength AA7075 alloy.

Friction and Wear Characteristics of Mg-Al Alloy Containing Rare Earths

The influence of rare earth on the friction and wear characteristics of magnesium alloy AZ91 and AM60 were studied. The results show that the wear resistance properties of rare earth magnesium alloys are better than those of matrix alloy under the testing conditions. The anti wear behaviour of AZ91 alloy is much better than that of AM60 alloy. In dry sliding process,magnesium alloys undergo a transition from mild wear to severe wear. The addition of rare earths refine the structure of alloys, improve the comprehensive behaviors of magnesium alloys, increase the stability of oxidation films on worn surfaces, enhance the loading ability of rare earth magnesium alloys, and delay the transition from mild wear to severe wear effectively.

Friction and Wear Study on Friction Pairs with a Biomimetic Non-smooth Surface of 316L Relative to CF/PEEK under a Seawater Lubricated Condition

Current studies of a seawater axial piston pump mainly solve the problems of corrosion and wear in a slipper pair by selecting materials with corrosion resistance, self-lubrication, and wear resistance. In addition, an appropriate biomimetic non-smooth surface design for the slipper pair can further improve the tribological behavior. In this paper, 316 L stainless steel and CF/PEEK were selected to process the upper and bottom specimens, and the biomimetic non-smooth surface was introduced into the interface between the friction pair. The friction and wear tests were performed on a MMD-5 A tester at a rotation speed of 1000 r/min and load of 200 N under seawater lubricated condition. The results indicate that the main friction form of the smooth surface friction pair corresponds to abrasive wear and adhesive wear and that it exhibits a friction coe cient of 0.05–0.07, a specimen temperature of 56 ℃, a high wear rate, and surface roughness. Pits on the non-smooth surface friction pairs produced hydrodynamic lubrication and reduced abrasive wear, and thus the plowing e ect is their main friction form. The non-smooth surface friction pairs exhibit a friction coe cient of 0.03–0.04, a specimen temperature of 48 ℃, a low wear rate, and surface roughness. The study has important theoretical significance for enriching the lubrication, friction, and wear theory of a seawater axial piston pump, and economic significance and military significance for promoting the marine development and the national defense military.

Friction and Wear Performance of Boron Doped, Undoped Microcrystalline and Fine Grained Composite Diamond Films

Chemical vapor deposition （CVD） diamond films have attracted more attentions due to their excellent mechanical properties. Whereas as-fabricated traditional diamond films in the previous studies don＇t have enough adhesion or surface smoothness, which seriously impact their friction and wear performance, and thus limit their applications under extremely harsh conditions. A boron doped, undoped microcrystalline and fine grained composite diamond （BD-UM-FGCD） film is fabricated by a three-step method adopting hot filament CVD （HFCVD） method in the present study, presenting outstanding comprehensive performance, including the good adhesion between the substrate and the underlying boron doped diamond （BDD） layer, the extremely high hardness of the middle undoped microcrystalline diamond （UMCD） layer, as well as the low surface roughness and favorable polished convenience of the surface fine grained diamond （FGD） layer. The friction and wear behavior of this composite film sliding against low-carbon steel and silicon nitride balls are studied on a ball-on-plate rotational friction tester. Besides, its wear rate is further evaluated under a severer condition using an inner-hole polishing apparatus, with low-carbon steel wire as the counterpart. The test results show that the BD-UM-FGCD film performs very small friction coefficient and great friction behavior owing to its high surface smoothness, and meanwhile it also has excellent wear resistance because of the relatively high hardness of the surface FGD film and the extremely high hardness of the middle UMCD film. Moreover, under the industrial conditions for producing low-carbon steel wires, this composite film can sufficiently prolong the working lifetime of the drawing dies and improve their application effects. This research develops a novel composite diamond films owning great comprehensive properties, which have great potentials as protecting coatings on working surfaces of the wear-resistant and anti-frictional components.

Friction and Wear Properties of TiAl and Ti_2AlN/TiAl Composites at High Temperature

The high-temperature friction and wear properties of TiAl alloys and Ti2AlN/TiAl composites （TTC） in contact with nickel-based superalloy were studied. The results showed that, at 800 and 1 000 ℃, the coefficient of the friction （COF） decreased with the increase of sliding velocity and the wear loss of the TTC decreased with the increase of volume fraction of Ti2AlN. The wear mechanisms of the pairs are adhesive wear and the wear debris mainly comes from the contacting nickel-based superalloy. The intergranular fracture and the cracking of the phase boundary in the lamellar structure are the wear mode of TiAl alloy. The wear mode of TTC is phase boundary fracture and adhesive spalling. The abrasive resistance of TTC is slightly higher than that of TiAl alloy.

The Friction and Wear Properties of the Spherical Plain Bearings with Self-lubricating Composite Liner in Oscillatory Movement

A test method based on the condition simulation and a friction and wear test machine featuring in oscillatory movement were set up for self-lubricating spherical plain bearings (SPB). In the machine the condition parameters such as load, angle and frequency of oscillation and number of test cycles can be properly controlled. The data relating to the tribological properties of the bearing, in terms of friction coefficient, linear wear amount, temperature near friction surface and applied load, can be monitored and recorded simultaneously during test process by a computerized measuring system of the machine. Efforts were made to improve the measurement technology of the friction coefficient in oscillating motion. In result, a well-designed bearing torque mechanism was developed, which could reveal the relation between the friction coefficient and the displacement of oscillating angle in any defined cycle while the curve of friction coefficient vs number of testing cycles was continuously plotted. The tribological properties and service life of four kinds of the bearings, i.e, the sampleⅠ-Ⅳ with different self-lubricating composite liners, including three kinds of polytetrafluoroethylene (PTFE) fiber weave/epoxy resin composite liners and a PTFE plastic/copper grid composite liner, were evaluated by testing, and the wear mechanisms of the liner materials were analyzed.

Friction and Wear Behaviors of Nanostructured Metals

Nanostructured （ns） materials, i.e., polycrystalline materials with grain sizes in the nanometer regime （typically below 100 nm）, have drawn considerable attention in the past decades due to their unique properties such as high strength and hardness. Wear resistance of ns materials, one of the most important properties for engineering materials, has been extensively investigated in the past decades. Obvious differences have been identified in friction and wear behaviors Between the ns materials and their corresponding coarse-grained （cg） counterparts, consistently correlating with their unique structure characteristics and mechanical properties. On the other hand, the superior tribological properties of ns materials illustrate their potential applications under contact loads. The present overview will summarize the important progresses achieved on friction and wear behaviors of ns metallic materials, including ultrafine-grained （ufg） materials in recent years. Tribological properties and effects on friction and wear behaviors of ns materials will be discussed under different wear conditions including abrasive wear, sliding wear, and fretting wear. Their correlations with mechanical properties will be analyzed. Perspectives on development of this field will be highlighted as well.