Geothermal energy exploitation from depleted high-temperature gas reservoirs by recycling CO_(2): The superiority and existing problems

CO_(2) can be used as an alternative injectant to exploit geothermal energy from depleted high-temperature gas reservoirs due to its high mobility and unique thermal properties.However,there has been a lack of systematic analysis on the heat mining mechanism and performance of CO_(2),as well as the problems that may occur during geothermal energy exploitation at specific gas reservoir conditions.In this paper,a base numerical simulation model of a typical depleted high-temperature gas reservoir was established to simulate the geothermal energy exploitation processes via recycling CO_(2) and water,with a view to investigate whether and/or at which conditions CO_(2) is more suitable than water for geothermal energy exploitation.The problems that may occur during the CO_(2)-based geothermal energy exploitation were also analyzed along with proposed feasible solutions.The results indicate that,for a depleted low-permeability gas reservoir with dimensions of 1000 m×500 m×50 m and temperature of 150℃ using a single injection-production well group for 40 years of operation,the heat mining rate of CO_(2) can be up to 3.8 MW at a circulation flow rate of 18 kg s^(-1)due to its high mobility along with the flow path in the gas reservoir,while the heat mining rate of water is only about 2 MW due to limitations on the injectivity and mobility.The reservoir physical property and injection-production scheme have some effects on the heat mining rate,but CO_(2)always has better performance than water at most reservoir and operation conditions,even under a high water saturation.The main problems for CO_(2) circulation are wellbore corrosion and salt precipitation that can occur when the reservoir has high water saturation and high salinity,in which serious salt precipitation can reduce formation permeability and result in a decline of CO_(2) heat mining rate (e.g.up to 24%reduction).It is proposed to apply a low-salinity water slug before CO_(2)injection to reduce the damage caused by salt precipitation.For high-permeability gas reservoirs with high water saturation and high salinity,the superiority of CO_(2) as a heat transmission fluid becomes obscure and water injection is recommended.

Research on thermal insulation materials properties under HTHP conditions for deep oil and gas reservoir rock ITP-Coring

Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability,resulting in distorted resource assessments.The development of in situ temperaturepreserved coring(ITP-Coring)technology for deep reservoir rock is urgent,and thermal insulation materials are key.Therefore,hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials)were proposed as thermal insulation materials.The materials properties under coupled hightemperature and high-pressure(HTHP)conditions were tested.The results indicated that high pressures led to HGM destruction and that the materials water absorption significantly increased;additionally,increasing temperature accelerated the process.High temperatures directly caused the thermal conductivity of the materials to increase;additionally,the thermal conduction and convection of water caused by high pressures led to an exponential increase in the thermal conductivity.High temperatures weakened the matrix,and high pressures destroyed the HGM,which resulted in a decrease in the tensile mechanical properties of the materials.The materials entered the high elastic state at 150℃,and the mechanical properties were weakened more obviously,while the pressure led to a significant effect when the water absorption was above 10%.Meanwhile,the tensile strength/strain were 13.62 MPa/1.3%and 6.09 MPa/0.86%at 100℃ and 100 MPa,respectively,which meet the application requirements of the self-designed coring device.Finally,K46-f40 and K46-f50 HGM/EP materials were proven to be suitable for ITP-Coring under coupled conditions below 100℃ and 100 MPa.To further improve the materials properties,the interface layer and EP matrix should be optimized.The results can provide references for the optimization and engineering application of materials and thus technical support for deep oil and gas resource development.

Thermodynamic and experimental study of high-temperature roasting of blast furnace gas ash for recovery of metallic zinc and iron

A high-temperature reduction roasting method was used to achieve metallic iron and zinc recovery from blast furnace gas ash(BFA).The reduction processes for Zn-containing and Fe-containing oxides were analyzed in detail by using ther-modynamic equilibrium calculation and the principle of minimum free energy.The results showed that the main reaction in the system is the reduction of ZnFe_(2)_(4)and iron oxides.Over the full temperature range,iron oxides were more easily reduced than zinc oxides.Regardless of the amount of CO contained in the system,the reduction of ZnO to Zn was difficult to proceed below the boiling point(906℃)of Zn.When the reduction temperature is below 906℃,the reduction process of zinc ferrate was ZnFe_(2)_(4)→ZnO;when the reduction temperature is above 906℃,its reduction process becomed ZnFe_(2)_(4)→ZnO→Zn(g).The metallization and dezincification rates of the BFA gradually increased with increasing reaction temperature.As the C/O ratio increased,the metallization and dezincification rates first increased and then decreased.The effect of reduction time on BFA reduction was similar to that of reaction temperature.

Study on the Effects of Helium-Argon Gas Mixture on the Laser Welding Performance of High Temperature Alloys

In order to solve the problem of porosity in laser deep penetration welding of GH3625 high-temperature alloy plates,five different ratios of high-purity helium gas and high-purity argon gas mixed gases were compared in welding experiments after various process parameter improvements and adjustments failed to achieve Class I welds.The experimental results show that using high-purity helium gas or a mixture of 50%high-purity helium gas and 50%high-purity argon gas can both achieve Class I welds.This indicates that using high-purity helium gas or an appropriate mixed gas instead of pure argon is one of the effective ways to solve the problem of porosity in laser deep penetration welding of high-temperature alloys.The mixture of 50%high-purity argon gas and 50%high-purity helium gas can reduce the consumption of high-purity helium gas,lower production costs,and is more suitable.

Elimination of cracks in stainless steel casings via 3D printed sand molds with an internal topology structure

The important supporting component in a gas turbine is the casing,which has the characteristics of large size,complex structure,and thin wall.In the context of existing 3DP sand casting processes,casting crack defects are prone to occur.This leads to an increase in the scrap rate of casings,causing significant resource wastage.Additionally,the presence of cracks poses a significant safety hazard after the casings are put into service.The generation of different types of crack defects in stainless steel casings is closely related to casting stress and the high-temperature concession of the sand mold.Therefore,the types and causes of cracks in stainless steel casing products,based on their structural characteristics,were systematically analyzed.Various sand molds with different internal topology designs were printed using the 3DP technology to investigate the impact of sand mold structures on high-temperature concession.The optimal sand mold structure was used to cast casings,and the crack suppression effect was verified by analyzing its eddy current testing results.The experimental results indicate that the skeleton structure has an excellent effect on suppressing cracks in the casing.This research holds important theoretical and engineering significance in improving the quality of casing castings and reducing production costs.

Purification of Produced Water from a Sour Oilfield in South Kuwait. 1. Oil-Water Separation and Industrial Salt Production

Produced water from an oil extraction site in South Kuwait was sampled after primary oil – water separation had been carried out. The produced water was filtered through a mixture of activated charcoal and esterified cellulosic material gained from spent coffee grounds as a tertiary adsorption treatment. The earth-alkaline metal ions and heavy metals were separated from the de-oiled produced water by addition of either sodium or potassium hydroxide in the presence of carbon dioxide or by direct addition of solid sodium carbonate. The resulting filtrate gave salt of industrial purity upon selective crystallization on evaporation.

Purification of Produced Water from a Sour Oilfield in South Kuwait. 2. Oil-Water Separation and Crystallization of Calcium Carbonate

Oil-water separation for produced water (PW) originating from an oil extraction site in South Kuwait was carried out using bleached, esterified cellulosic material from used coffee grounds. Thereafter, earth-alkaline metal ions, specifically calcium ions, of the de-oiled PW were removed by precipitation with sodium carbonate to give access to pure sodium chloride as industrial salt from the remaining PW. While the purity of the precipitated calcium carbonate (CaCO3) depends on the precipitation conditions, CaCO3 of up to 95.48% purity can be obtained, which makes it a salable product. The precipitation of CaCO3 decreases the amount of calcium ions in PW from 11,300 ppm to 84 ppm.

Evaluation of gas-liquid separation performance of natural gas filters

Fibrous filters are often used to remove contaminants including both dusts and liquid droplets from natural gas. This paper aims to evaluate the gas-liquid separation performance of three types of cartridge filters used in the West-East natural gas transmission project. The comparison of the original pressure drop of clean filters and the evolution of pressure drop as liquid droplets deposited in the filter media are described. The original pressure drops of these filters were similar but the pressure drops at a steady state were different. Fractional efficiency was used to study the separation performance of cartridge filters. Droplets at the outlet of the filters had small diameters, no more than 3 μm, but were very numerous. The effect of filtration velocity on gas-liquid separation performance was analyzed. Higher filtration velocity indicated better gas-liquid separation performance. Finally the quality factor related to pressure drop and filtration efficiency was applied to evaluate the gas-liquid separation performance.

Recent progresses in dry gas polymeric filters

Filtration and membrane separation are popular methods in gas separation since they are cost and energy efficient. Despite to air filters, there are comparatively few studies on dry gas filters, particularly at industrial scale. In fact, major unsolved challenges such as high efficiency, low pressure drop, long-term stability, high-thermal and chemical stability and advanced physiochemical properties, are still remained. The aim of this review is to scrutinize the advanced scientific and technological practices (such as selection of appropriate polymeric materials and additives, nanotechnology, modification techniques and preparation methods) towards design and fabrication of an efficient filter media for solid particles removal from the natural gas flow. Recent progresses in solid particle separation mechanisms, modeling and simulation techniques and the effect of membrane fabrication methods on its performance, strategies for modification of filter media, current challenges and future perspective are discussed.

NEW MODEL OF GAS FLOW PROBLEM IN MULTI-LAYERED GAS RESERVOIR AND APPLICATION

In this paper, the new model of the real gas filtration problem has been presented multi-layered gas reservoir, when a gas well output and wellbore storage may be variable, and have obtained the exact solutions of pressure distribution for each reservoir bed under three kinds of typical out-boundary conditions. As a special case, according to the new model have also obtained the qxact solutions of presssure distribution in homogeneous reservoir and is given important application in gas reservoir development.

Processing and Properties of Flexible Hot Gas Sealing Materials for Ceramic Membrane

Ceramic membranes are effective to reduce PM2.5 emission when used for hot flue gas filtration.The properties of the sealing material play a decisive role infiltration efficiency.However,there are few studies on sealing materials for hot flue gas filtration above 700 ℃.This investigation was performed to develop flexible sealing materials which can be used for a long time at high temperatures.In order to obtain sufficient mechanical strength and continuous flexibility,three kinds of binders were selected as coating binders.The sealing materials based on high silica fiber fabric and aluminum silicate fiber fabric were successfully prepared.The effect of aging on mechanical properties and microstructural characteristics of the composites subjected to coating had been investigated by XRD,SEM and EDS.The results show that waterborne polyurethane (WPU) is a suitable coating binder for the sealing materials,which can be used for a long time at 1 000 ℃ and 700 ℃,respectively,without significant decrease in strength.However,the other two binders,aluminum dihydrogen phosphate and aluminum chromium phosphate will weaken the flexibility,resulting in frangibility and reducing sealing performance.The developed composites possess required thermo-stability and desired mechanical strength as flexible sealing materials,indicating their strong application possibility in hot flue gas filtration.

2015 -07 -62 Research on the anti-haze technol. ogy of gas turbine inlet system

This paper briefly introduced the structure and compo- sition of gas turbine inlet air filtration system, and analyzed the reason why inlet air titration system cannot adapt to bad weather. Meanwhile, some optimized transformation plans are proposed in this paper, such as arranging the coarse filter G3 in the anti- freeze warehouse and adding medium efficiency filter M5 etc. Furthermore, the net benefit in the first year after the optimized transformation is calculated. These optimized transformation plans could effectively decrease the rising velocity of air inlet system＇s total pressure differences, reduce the workload and costs of maintenancing air inlet system, extent the lifespan of fine cartridge, enhance the adaptability against bad weather of unit, improve the security and stability of unit operation and in- crease the economic benefit of unit, which is worth of populari- zation and application in the optimized transformation of similar gas turbine inlet system.

Black Powder in Sales Gas Pipelines: Sources and Technical Recommendations

One of the most severe problems affecting the efficient operations of gas pipelines is corrosion caused by black powder. According to the literature, the primary source for the existence of black powder is condensed water. In this case study, the temperature (40°C) of the sales gas is much higher than its dew point (9.24°C). The water is therefore in vapor phase. It is then proposed to remove water vapor from the gas at the entrance of the plant using an adsorption process. The recommended technology is the Layered Bed Temperature-Swing Adsorption (LBTSA) with micro-channels with molecular sieve zeolite 4A and activated alumina as adsorbents. In the case of presence of aerosols that could condense water, it is suggested to utilize a RED (Rare Earth Drum) magnetic separator in order to remove black powder from the gaseous feed.

Application of ultrasonic fatigue technology in very-high-cycle fatigue testing of aviation gas turbine engine blade materials:A review

The need for very-high-cycle fatigue(VHCF)testing up to 1010cycles of aviation gas turbine engine blade materials under combined mechanical loads and complex environments has encouraged the development of VHCF testing instrumentation and technology.This article begins with a comprehensive review of the existing available techniques that enable VHCF testing.Recent advances in ultrasonic fatigue testing(UFT)techniques are highlighted,containing their new capabilities and methods for single load,multiaxial load,variable amplitude fatigue,and combined cycle fatigue.New techniques for conducting UFT in high-temperature,humid environments,and corrosive environments are summarized.These developments in mechanical loading and environmental building techniques provide the possibility of laboratory construction for real service conditions of blade materials.New techniques that can be used for in situ monitoring of VHCF damage are summarized.Key issues in the UFT field are presented,and countermeasures are collated.Finally,the existing problems and future trends in the field are briefly described.

A complementary and synergistic effect of Fe-Zn binary metal oxide in the process of high-temperature fuel gas desulfurization

57Fe Mossbauer spectroscopy was used to investigate the evolution of Fe-Zn binary metal oxide sorbent in the process of high-temperature fuel gas desulfurization. The results of phase analyses show that Fe-Zn binary metal oxide sorbent is rapidly reduced in hot fuel gas and decomposed to new phases of highly dispersed microcrystalline elemental iron and zinc oxide, both of which become the active desulfurization constituents. A complementary and synergistic effect between active iron acting as a high sulfur capacity constituent and active zinc oxide acting as a deep refining desulfurization constituent exists in this type of sorbent for hot fuel gas desulfurization.

Recovery of zinc from Zn-Al-Fe alloys by gas pressure filtration

The recovery of zinc from galvanizing dross and the removal of iron contained dross particles by gas pressure filtration were investigated using the model of Zn-Fe-Al alloys.The majority of molten zinc was separated after filtration,and the residue intercepted by the filter consisting mostly of dross particles.The effects of the pressure differential(p),separation temperature(T)and alloy composition on the zinc recovery and iron removal were investigated.At p=0.30 MPa and T=723 K,86.2 wt.%zinc was recovered from the Zn-4Al-2Fe alloy,and up to 99.9 wt.%of the iron was concentrated in the residue.Applying a higher pressure differential led to the improved filtration efficiency,and the desired separation temperature was about 723 K.The aluminum content in the Zn-Al-Fe alloy had little effect on separation efficiency,whereas increasing the iron content led to a decrease in the separation efficiency.Our findings demonstrate the potential of the gas pressure filtration method for the recovery of zinc from galvanizing dross.

Flow behavior of high-temperature flue gas in the heat transfer chamber of a pilot-scale coal-water slurry combustion furnace

The flow characteristics of high-temperature flue gas are important in the heat transfer of coal-water slurry（CWS） combustion furnaces.The flow field of a 250 kg/h vertical-type slag tap cyclone furnace was non-intrusively investigated,using two-dimensional particle-image velocimetry（2D PIV）.The method was verified using traceable fly ash particles in high-temperature flue gas.The flow field of the flue gas was analyzed with a time-averaged method,based on which the effects of excess air ratio and loading were investigated.The flue gas separated by a gas separator maintained good rigidity near the furnace wall,rather than eroding the heating surface.Numerical simulations validated the reliability of PIV under the actual circumstances within the furnace.This study provides guidelines for applying 2D PIV in analyzing flue gas in thermal test boilers.

Effect of Gas Bubbling Filtration Treatment on Microporosity Variation in A356 Aluminium Alloy

In the present study, the contribution of the gas bubbling filtration （GBF） process to the microporosity variation, microstructural characteristics and tensile properties of A356 aluminium alloy was investigated. The test specimens were fabricated through gravity casting in terms of the process variables： the degassing time, the impeller rotation and the aperture size of gas inlet hole. The density measurement and scanning electron microscope fractography analyses were conducted to evaluate the variation of the volumetric porosity and fractographic porosity with the GBF process, respec- tively. The fractographic porosity of the specimens can be minimised under specific GBF conditions in terms of the buoyant velocity and the absorbing capacity of gas bubbles, the inclusion of oxide films, whereas the volumetric porosity can be wholly reduced on the lapse of degassing time. The ultimate tensile strength （UTS） and elongation at optimal conditions were improved to approximately 30 MPa and 1.5% compared with no GBF treatment. Even though an extension of the degassing time and/or excessive stirring action of the melt may induce the inclusion of bifilm oxides and the increase of fractographic porosity, the tensile properties of over-treated specimens were maintained to a level which is similar to those that did not undergo GBF treatment due to the grain refinement accompanying with the GBF process. In addition, the defect susceptibility of UTS and elongation to microporosity variation could be remarkably improved at an optimal GBF condition.

Fe-doped olivine and char for in-bed elimination of gasification tars in an air-blown fluidised bed reactor coupled with oxidative hot gas filtration

Gasification experiments were carried out in a pilot scale fluid bed reactor operated under allothermal mode and low fluidisation regime with iron-doped olivine and char as catalyst for in-situ tar abatement.The catalyst combination resulted in a reduction of 50%in the overall tar yield with respect to the reference values.Furthermore,the integration of an oxidative Hot Gas Filtration unit downstream the gasification reactor led to a further reduction in overall tar yield and relatively clean gas was obtained(approx.1 g/Nm3,benzene-free).The tar dew point of the resulting producer gas was estimated to 80℃,only 40℃ above the threshold value recommended for its valorisation in standard internal combustion engines.Moreover,catalyst elutriation and char hold-up took place to a large extent inside the reactor.The analysis of catalyst samples at different Time-On-Stream(TOS)revealed:(i)a considerable loss of iron oxides during the first hour of test because of the interparticle mechanical attrition(mostly surface abrasion)and partial reduction of hematite to magnetite and wustite but,stable composition at higher TOS,(ii)the loss of the iron oxide coverage of Fe/olivine particles and the formation of agglomerates with increasing TOS and,(iii)the amount of carbon deposited in the surface of the Fe/olivine particles increased with TOS,but in any case,these carbon deposits can be completely oxidized above 650℃.

Regeneration of Fe_(2)O_(3)-based high-temperature coal gas desulfurization sorbent in atmosphere with sulfur dioxide

Regeneration of a high-temperature coal gas desulfurization sorbent is a key technology in its industrial applications.A Fe_(2)O_(3)-based high-temperature coal gas desulfurizer was prepared using red mud from steel factory.The influences of regeneration temperature,space velocity and regeneration gas concentration in SO_(2) atmosphere on regeneration performances of the desulfurization sorbent were tested in a fixed bed reactor.The changes of phase and the composition of the Fe_(2)O_(3)-based high-temperature coal gas desulfurization sorbent before and after regeneration were examined by X-ray diffraction(XRD)and X-ray Photoelectron spectroscopy(XPS),and the changes of pore structure were characterized by the mercury intrusion method.The results show that the major products are Fe3O4 and elemental sulfur;the influences of regeneration temperature,space velocity and SO_(2) concentration in inlet on regeneration performances and the changes of pore structure of the desulfurization sorbent before and after regeneration are visible.The desulfurization sorbent cannot be regenerated at 500℃ in SO_(2) atmosphere.Within the range of 600℃-800℃,the time of regeneration becomes shorter,and the regeneration conversion increases as the temperature rises.The time of regeneration also becomes shorter,and the elemental sulfur content of tail gas increases as the SO_(2) concentration in inlet is increased.The increase in space velocity enhances the reactive course;the best VSP is 6000 h^(-1) for regeneration conversion.At 800℃,20 vol-%SO_(2) and 6000 h^(-1),the regeneration conversion can reach nearly to 90%.