FeAl intermetallic compound with different contents of rare earth oxide La2O3 addition was prepared by hot pressing the mechanically alloyed powders.Effect of La2O3 on microstructure and high-temperature wear property...FeAl intermetallic compound with different contents of rare earth oxide La2O3 addition was prepared by hot pressing the mechanically alloyed powders.Effect of La2O3 on microstructure and high-temperature wear property of the sintered FeAl samples was investigated in this paper.The results showed that 1 wt.% La2O3 addition could refine the microstructure and increase the density of the FeAl intermetallic compound,and correspondingly improved the high-temperature wear resistance.SEM and EDS analyses of the wo...展开更多
In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) s...In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) surface alloying of Ti-Fe alloy powder. Microhard- ness tests showed that the surface hardness increased approximately four-fold after the alloying treatment. The microstructure of the MMC coating was mainly composed of residual austenite, acicular martensite, and eutectic ledeburite. Scanning electron microscopy (SEM) and X-ray diffraction analyzes revealed that the in situ TiC particles, which were formed by direct reaction of Ti with carbon originally contained in the GCI, was uniformly distributed at the boundary of residual anstenite in the alloying zone. Pin-on-disc high-temperature wear tests were performed on samples both with and without the MMC coating at room temperature and at elevated temperatures (473 K and 623 K), and the wear behavior and mechanism were investigated. The results showed that, after the PTA alloying treatment, the wear resistance of the sam- ples improved significantly. On the basis of our analysis of the composite coatings by optical microscopy, SEM with energy-dispersive X-ray spectroscopy, and microhardness measurements, we attributed this improvement of wear resistance to the transformation of the microstruc- ture and to the presence of TiC particles.展开更多
MoSi2 was prepared by SHS,pressed at room-temperature and then vacuum sintered at 1 500 ℃ for 1 h. The tribological properties of MoSi2 against Al2O3 were investigated by using an XP-5 type High Temperature Friction ...MoSi2 was prepared by SHS,pressed at room-temperature and then vacuum sintered at 1 500 ℃ for 1 h. The tribological properties of MoSi2 against Al2O3 were investigated by using an XP-5 type High Temperature Friction and Wear Tester. Micrographs and phases of the worn surface of MoSi2 were observed by SEM with EDS and X-ray diffraction. The results show that the wearing process of MoSi2 at high temperature exists three stages:running-in,interim and steady periods. MoSi2 exhibits preferable wear resistance when the load is lower than 50 N. Adhesion and oxidation wear exists widely at elevated temperature;however besides these,with increasing the load,the main wear mechanisms of MoSi2 could be changed from adhesion,plastic forming to fatigue fracture in turn.展开更多
Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature moni...Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature monitoring/warning in industrial and wearable applications remains a great challenge.Herein,a highly elastic,flame-retardant and high-temperature-resistant TE aerogel,made of poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate)/single-walled carbon nanotube(PEDOT:PSS/SWCNT)composites,has been fabricated,displaying attractive compression-induced power factor enhancement.The as-fabricated sensors with the aerogel can achieve accurately pressure stimuli detection and wide temperature range monitoring.Subsequently,a flexible TE generator is assembled,consisting of 25 aerogels connected in series,capable of delivering a maximum output power of 400μW when subjected to a temperature difference of 300 K.This demonstrates its outstanding high-temperature heat harvesting capability and promising application prospects for real-time temperature monitoring on industrial high-temperature pipelines.Moreover,the designed self-powered wearable sensing glove can realize precise wide-range temperature detection,high-temperature warning and accurate recognition of human hand gestures.The aerogel-based intelligent wearable sensing system developed for firefighters demonstrates the desired self-powered and highly sensitive high-temperature fire warning capability.Benefitting from these desirable properties,the elastic and high-temperature-resistant aerogels present various promising applications including self-powered high-temperature monitoring,industrial overheat warning,waste heat energy recycling and even wearable healthcare.展开更多
This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,...This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg alloy.The synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were studied.Results show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the alloy.They can improve the strength of the alloy by hindering dislocation movement and crack propagation.In addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain refinement.The addition of Mo greatly improves the heat resistance of the alloy.The extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy.展开更多
High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,...High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,N2physisorption,27Al magic angle spinning nuclear magnetic resonance(MAS NMR),and temperature-programmed desorption of ammonia results indicated that the hightemperature treatment at 650℃ hardly affected the inherent crystal and texture of HZSM-5zeolites but facilitated the conversion of framework Al to extra-framework Al,reducing the acid site and enhancing the acid strength.Moreover,the high-temperature treatment improved the performance of HZSM-5 zeolites in n-heptane catalytic cracking,promoting the conversion and light olefins yield while inhibiting coke formation.Based on the kinetic and mechanism analysis,the improvement of HZSM-5 performance caused by high-temperature treatment has been attributed to the formation of extra-framework Al,which enhanced the acid strength,facilitated the bimolecular reaction,and promoted the entropy change to overcome a higher energy barrier in n-heptane catalytic cracking.展开更多
Ultra-deep reservoirs play an important role at present in fossil energy exploitation.Due to the related high temperature,high pressure,and high formation fracture pressure,however,methods for oil well stimulation do ...Ultra-deep reservoirs play an important role at present in fossil energy exploitation.Due to the related high temperature,high pressure,and high formation fracture pressure,however,methods for oil well stimulation do not produce satisfactory results when conventional fracturing fluids with a low pumping rate are used.In response to the above problem,a fracturing fluid with a density of 1.2~1.4 g/cm^(3)was developed by using Potassium formatted,hydroxypropyl guanidine gum and zirconium crosslinking agents.The fracturing fluid was tested and its ability to maintain a viscosity of 100 mPa.s over more than 60 min was verified under a shear rate of 1701/s and at a temperature of 175℃.This fluid has good sand-carrying performances,a low viscosity after breaking the rubber,and the residue content is less than 200 mg/L.Compared with ordinary reconstruction fluid,it can increase the density by 30%~40%and reduce the wellhead pressure of 8000 m level reconstruction wells.Moreover,the new fracturing fluid can significantly mitigate safety risks.展开更多
Aviation turbine engine oils require excellent thermal-oxidative stability because of their high-temperature environments.High-temperature bearing deposit testing is a mandatory method for measuring the thermal-oxidat...Aviation turbine engine oils require excellent thermal-oxidative stability because of their high-temperature environments.High-temperature bearing deposit testing is a mandatory method for measuring the thermal-oxidative performance of aviation lubricant oils,and the relevant apparatus was improved in the present study.Two different commercial aviation turbine engine oils were tested,one with standard performance(known as the SL oil)and the other with high thermal stability,and their thermal-oxidative stability characteristics were evaluated.After 100 h of high-temperature bearing testing,the SL oil was analyzed by using various analytical techniques to investigate its thermal-oxidative process in the bearing test,with its thermal-oxidative degradation mechanism also being discussed.The results indicate that the developed high-temperature bearing apparatus easily meets the test requirements of method 3410.1 in standard FED-STD-791D.The viscosity and total acid number(TAN)of the SL oil increased with the bearing test time,and various deposits were produced in the bearing test,with the micro-particles of the carbon deposits being sphere-like,rod-like,and sheet-like in appearance.The antioxidant additives in the oil were consumed very rapidly in the first 30 h of the bearing test,with N-phenyl-1-naphthylamine being consumed faster than dioctyldiphenylamine.Overall,the oil thermal-oxidative process involves very complex physical and chemical mechanisms.展开更多
Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel cells.To overcome these barriers,poly(te...Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel cells.To overcome these barriers,poly(terphenyl piperidinium)s constructed from the m-and p-isomers of terphenyl were synthesized to regulate the microstructure of the membrane.Highly rigid p-terphenyl units prompt the formation of moderate PA aggregates,where the ion-pair interaction between piperidinium and biphosphate is reinforced,leading to a reduction in the plasticizing effect.As a result,there are trade-offs between the proton conductivity,mechanical strength,and PA retention of the membranes with varied m/p-isomer ratios.The designed PA-doped PTP-20m membrane exhibits superior ionic conductivity,good mechanical strength,and excellent PA retention over a wide range of temperature(80–160°C)as well as satisfactory resistance to harsh accelerated aging tests.As a result,the membrane presents a desirable combination of performance(1.462 W cm^(-2) under the H_(2)/O_(2)condition,which is 1.5 times higher than that of PBI-based membrane)and durability(300 h at 160°C and 0.2 A cm^(-2))in the fuel cell.The results of this study provide new insights that will guide molecular design from the perspective of microstructure to improve the performance and robustness of HT-PEMs.展开更多
Second-generation high-temperature superconducting(HTS)conductors,specifically rare earth-barium-copper-oxide(REBCO)coated conductor(CC)tapes,are promising candidates for high-energy and high-field superconducting app...Second-generation high-temperature superconducting(HTS)conductors,specifically rare earth-barium-copper-oxide(REBCO)coated conductor(CC)tapes,are promising candidates for high-energy and high-field superconducting applications.With respect to epoxy-impregnated REBCO composite magnets that comprise multilayer components,the thermomechanical characteristics of each component differ considerably under extremely low temperatures and strong electromagnetic fields.Traditional numerical models include homogenized orthotropic models,which simplify overall field calculation but miss detailed multi-physics aspects,and full refinement(FR)ones that are thorough but computationally demanding.Herein,we propose an extended multi-scale approach for analyzing the multi-field characteristics of an epoxy-impregnated composite magnet assembled by HTS pancake coils.This approach combines a global homogenization(GH)scheme based on the homogenized electromagnetic T-A model,a method for solving Maxwell's equations for superconducting materials based on the current vector potential T and the magnetic field vector potential A,and a homogenized orthotropic thermoelastic model to assess the electromagnetic and thermoelastic properties at the macroscopic scale.We then identify“dangerous regions”at the macroscopic scale and obtain finer details using a local refinement(LR)scheme to capture the responses of each component material in the HTS composite tapes at the mesoscopic scale.The results of the present GH-LR multi-scale approach agree well with those of the FR scheme and the experimental data in the literature,indicating that the present approach is accurate and efficient.The proposed GH-LR multi-scale approach can serve as a valuable tool for evaluating the risk of failure in large-scale HTS composite magnets.展开更多
Wear resistance is a critical consideration in engineering applications.In this study,we demonstrated an Ir-Ta-Ni-Nb bulk metallic glass(BMG)with outstanding high-temperature wear resistance and revealed its promising...Wear resistance is a critical consideration in engineering applications.In this study,we demonstrated an Ir-Ta-Ni-Nb bulk metallic glass(BMG)with outstanding high-temperature wear resistance and revealed its promising applications in extreme environments.The wear behavior and mechanism were systemati-cally investigated from room temperature(RT)to 750℃.The results show that the wear rate increases from∼2.65×10^(-6)mm^(3)N^(-1)m^(-1)to∼10.56×10^(-6)mm^(3)N^(-1)m^(-1)in the temperature span RT to 400℃,following abrasive wear and flash temperature-induced oxidative wear during the friction.However,at the higher temperature of 600℃,further heating due to frictional heat leads to a softening of the wear surface,resulting in a maximum wear rate of∼20.99×10^(-6)mm^(3)N^(-1)m^(-1)under softness-driven abrasive wear as well as oxidative wear.Interestingly,the wear resistance at an even higher temperature of 750℃shows a paradoxical improvement of∼7.08×10^(-6)mm^(3)N^(-1)m^(-1),which is attributed to the formation of an oxide layer with a thickness of several microns,avoiding violent wear of BMG.The re-sults demonstrate the unreported outstanding high-temperature wear resistance of the Ir-Ta-Ni-Nb BMG,especially its excellent capability to resist wear at 750℃,leading to the promising applications of BMG in the fields of aerospace,metallurgy,and nuclear industries.展开更多
In pressurized water reactor(PWR),fretting wear is one of the main causes of fuel assembly failure.Moreover,the operation condition of cladding is complex and harsh.A unique fretting damage test equipment was develope...In pressurized water reactor(PWR),fretting wear is one of the main causes of fuel assembly failure.Moreover,the operation condition of cladding is complex and harsh.A unique fretting damage test equipment was developed and tested to simulate the fretting damage evolution process of cladding in the PWR environment.It can simulate the fretting wear experiment of PWR under different temperatures(maximum temperature is 350℃),displacement amplitude,vibration frequency,and normal force.The fretting wear behavior of Zr-4 alloy under different temperature environments was tested.In addition,the evolution of wear scar morphology,profile,and wear volume was studied using an optical microscope(OM),scanning electron microscopy(SEM),and a 3D white light interferometer.Results show that higher water temperature evidently decreased the cladding wear volume,the wear mechanism of Zr-4 cladding changed from abrasive wear to adhesive wear and the formation of an oxide layer on the wear scar reduced the wear volume and maximum wear depth.展开更多
Réfractory high/medium entropy nitrides(HENs/MENs)exhibit comprehensive application prospects as protective films on mechanical parts,particularly those subjected to sliding contacts at elevated temperatures.In t...Réfractory high/medium entropy nitrides(HENs/MENs)exhibit comprehensive application prospects as protective films on mechanical parts,particularly those subjected to sliding contacts at elevated temperatures.In this study,a new MEN system TiNbWN,forming a single fc solution,is designed and its wear performance at temperatures ranging from 25 to 750℃is explored.The wear mechanisms can be rationalized by examining the subsurface microstructural evolutions using the transmission electron microscopy as well as calculating the phase diagrams and interfacial adhesion behavior employing calculation of phase diagram(CALPHAD)and density functional theory(DFT).To be specific,increased wear losses occur in a temperature range of 25-600℃,being predominantly caused by the thermally-induced hardness degradation;whereas at the ultimate temperature(750℃),the wear loss is refrained due to the formation of nanocrystalline oxides(WnO_(3n-2r)TiO_(2),and TiOx),as synergistically revealed by microscopy and CALPHAD,which not only enhance the mechanical properties of the pristine nitride film,but also act as solid lubricants,reducing the interfacial adhesion.Thus,our work delineates the role of the in situ formed nanocrystalline oxides in the wear mechanism transition of TiNbWN thin films,which could shed light on the high-temperature wear behavior of refractory HEN/MENfilms.展开更多
Understanding the thermal safety evolution of lithium-ion batteries during high-temperature usage conditions bears significant implications for enhancing the safety management of aging batteries.This work investigates...Understanding the thermal safety evolution of lithium-ion batteries during high-temperature usage conditions bears significant implications for enhancing the safety management of aging batteries.This work investigates the thermal safety evolution mechanism of lithium-ion batteries during high-temperature aging.Similarities arise in the thermal safety evolution and degradation mechanisms for lithium-ion batteries undergoing cyclic aging and calendar aging.Employing multi-angle characterization analysis,the intricate mechanism governing the thermal safety evolution of lithium-ion batteries during high-temperature aging is clarified.Specifically,lithium plating serves as the pivotal factor contributing to the reduction in the self-heating initial temperature.Additionally,the crystal structure of the cathode induced by the dissolution of transition metals and the reductive gas generated during aging attacking the crystal structure of the cathode lead to a decrease in thermal runaway triggering temperature.Furthermore,the loss of active materials and active lithium during aging contributes to a decline in both the maximum temperature and the maximum temperature rise rate,ultimately indicating a decrease in the thermal hazards of aging batteries.展开更多
Extreme high temperatures frequently occur in southwestern China,significantly impacting the local ecological system and economic development.However,accurate prediction of extreme high-temperature days(EHDs)in this r...Extreme high temperatures frequently occur in southwestern China,significantly impacting the local ecological system and economic development.However,accurate prediction of extreme high-temperature days(EHDs)in this region is still an unresolved challenge.Based on the spatiotemporal characteristics of EHDs over China,a domain-averaged EHD index over southwestern China(SWC-EHDs)during April-May is defined.The simultaneous dynamic and thermodynamic fields associated with the increased SWC-EHDs are a local upper-level anticyclonic(high-pressure)anomaly and wavy geopotential height anomaly patterns over Eurasia.In tracing the origins of the lower boundary anomalies,two physically meaningful precursors are detected for SWC-EHDs.They are the tripolar SST change tendency from December-January to February-March in the northern Atlantic and the February-March mean snow depth in central Asia.Using these two selected predictors,a physics-based empirical model prediction was applied to the training period of 1961–2005 to obtain a skillful prediction of the EHDs index,attaining a correlation coefficient of 0.76 in the independent prediction period(2006–19),suggesting that 58%of the total SWC-EHDs variability is predictable.This study provides an estimate for the lower bound of the seasonal predictability of EHDs as well as for the hydrological drought over southwestern China.展开更多
Satellited CoNiCrAlY–Al_(2)O_(3)feedstocks with 2wt%, 4wt%, and 6wt% oxide nanoparticles and pure CoNiCrAlY powder were deposited by the high-velocity oxy fuel process on an Inconel738 superalloy substrate. The oxida...Satellited CoNiCrAlY–Al_(2)O_(3)feedstocks with 2wt%, 4wt%, and 6wt% oxide nanoparticles and pure CoNiCrAlY powder were deposited by the high-velocity oxy fuel process on an Inconel738 superalloy substrate. The oxidation test was performed at 1050℃ for 5, 50, 100,150, 200, and 400 h. The microstructure and phase composition of powders and coatings were characterized by scanning electron microscopy and X-ray diffraction, respectively. The bonding strength of the coatings was also evaluated. The results proved that with the increase in the percentage of nanoparticles(from 2wt% to 6wt%), the amount of porosity(from 1vol% to 4.7vol%), unmelted particles, and roughness of the coatings(from 4.8 to 8.8 μm) increased, and the bonding strength decreased from 71 to 48 MPa. The thicknesses of the thermally grown oxide layer of pure and composite coatings(2wt%, 4wt%, and 6wt%) after 400 h oxidation were measured as 6.5, 5.5, 7.6, and 8.1 μm, respectively.The CoNiCrAlY–2wt% Al_(2)O_(3)coating showed the highest oxidation resistance due to the diffusion barrier effect of well-dispersed nanoparticles. The CoNiCrAlY–6wt% Al_(2)O_(3)coating had the lowest oxidation resistance due to its rough surface morphology and porous microstructure.展开更多
The high-temperature molten salt pump is the core equipment in a molten salt reactor that drives the flow of the molten salt coolant.Rotor stability is key to the continuous and reliable operation of the molten salt p...The high-temperature molten salt pump is the core equipment in a molten salt reactor that drives the flow of the molten salt coolant.Rotor stability is key to the continuous and reliable operation of the molten salt pump,and the liquid seal at the wear ring can affect the dynamic characteristics of the rotor system.When the molten salt pump is operated in the hightemperature molten salt medium,thermal deformation of the submerged parts inevitably occurs,changing clearance between the stator and rotor,affecting the leakage and dynamic characteristics of the seal.In this study,the seal leakage,seal dynamic characteristics,and rotor system dynamic characteristics are simulated and analyzed using finite element simulation software based on two cases of considering the effect of seal thermal deformation effect or not.The results show a significant difference in the leakage characteristics and dynamic characteristics of the seal obtained by considering the effect of seal thermal deformation and neglecting the effect of thermal deformation.The leakage flow rate decreases,and the first-order critical speed of the seal-bearing-rotor system decrease after considering the seal’s thermal deformation.展开更多
Cotton(Gossypium spp.) yield is reduced by stress. In this study, high temperature(HT) suppressed the expression of the jasmonic acid(JA) biosynthesis gene allene oxide cyclase 2(GhAOC2), reducing JA content and causi...Cotton(Gossypium spp.) yield is reduced by stress. In this study, high temperature(HT) suppressed the expression of the jasmonic acid(JA) biosynthesis gene allene oxide cyclase 2(GhAOC2), reducing JA content and causing male sterility in the cotton HT-sensitive line H05. Anther sterility was reversed by exogenous application of methyl jasmonate(MeJA) to early buds. To elucidate the role of GhAOC2 in JA biosynthesis and identify its putative contribution to the anther response to HT, we created gene knockout cotton plants using the CRISPR/Cas9 system. Ghaoc2 mutant lines showed male-sterile flowers with reduced JA content in the anthers at the tetrad stage(TS), tapetum degradation stage(TDS), and anther dehiscence stage(ADS). Exogenous application of MeJA to early mutant buds(containing TS or TDS anthers) rescued the sterile pollen and indehiscent anther phenotypes, while ROS signals were reduced in ADS anthers. We propose that HT downregulates the expression of GhAOC2 in anthers, reducing JA biosynthesis and causing excessive ROS accumulation in anthers, leading to male sterility. These findings suggest exogenous JA application as a strategy for increasing male fertility in cotton under HT.展开更多
Al2O3-r2O03/NiCoCrAIYTa coatings were prepared via atmosphere plasma spraying (APS). The microstructure and phase com- position of the coatings were analyzed by X-ray diffraction (XRD), scanning electron microsco...Al2O3-r2O03/NiCoCrAIYTa coatings were prepared via atmosphere plasma spraying (APS). The microstructure and phase com- position of the coatings were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), laser confocal scanning microsco- py (LSCM), and transmission electron microscopy (TEM). The dry frictional wear behavior of the coatings at 500℃ in static air was inves- tigated and compared with that of 0Cr25Ni20 steel. The results show that the coatings comprise the slatted layers of oxide phases, unmelted particles, and pores. The hot abrasive resistance of the coatings is enhanced compared to that of 0Cr25Ni20, and their mass loss is approxi- mately one-fifteenth that of 0Cr25Ni20 steel. The main wear failure mechanisms of the coatings are abrasive wear, fatigue wear, and adhe- sive wear.展开更多
Microstructure and high-temperature dry sliding wear at 600 ~C in ambient air of austenitic heat-resistant steel ZG40Cr25Ni20 with different contents (mass percent) of AI (0 to 7.10~) have been investigated. The r...Microstructure and high-temperature dry sliding wear at 600 ~C in ambient air of austenitic heat-resistant steel ZG40Cr25Ni20 with different contents (mass percent) of AI (0 to 7.10~) have been investigated. The results show that microstructures of 4.68% and 7.10% A1 addition content consist of the matrix and reinforcement of inter- metallic compound y' and carbide, while microstructures of ZG40Cr25Ni20 without A1 and with A1 of 1.68% are ab- sent of y'. Higher wear resistance than the original ZG40Cr25Ni20 alloy is achieved in alloys with higher content of A1 under the same high-temperature wear test condition. The wear rates of Fe-25Cr-20Ni-7.10A1 and Fe-25Cr-20Ni- 4.68A1 are only 20.83% and 45.83% of that of Fe-25Cr-20Ni, respectively. Heat-resistant steels with higher con- tents of AI (4.72% and 7.10%) have higher hardness than those with lower contents of AI (1.68% and 0). Wear mechanisms of ZG40Cr25Ni20 are considered as severe plough plastic deformation and slight adhesive. However, wear mechanisms of Fe-25Cr-20Ni 4.68A1 are light micro-cutting and oxidation-wear, while that of Fe-25Cr-20Ni- 7. 10A1 are severe adhesive transfer and oxidation-wear_展开更多
基金supported by the National Natural Science Foundation of China (50575034)
文摘FeAl intermetallic compound with different contents of rare earth oxide La2O3 addition was prepared by hot pressing the mechanically alloyed powders.Effect of La2O3 on microstructure and high-temperature wear property of the sintered FeAl samples was investigated in this paper.The results showed that 1 wt.% La2O3 addition could refine the microstructure and increase the density of the FeAl intermetallic compound,and correspondingly improved the high-temperature wear resistance.SEM and EDS analyses of the wo...
基金financially supported by the National Science and Technology Major Project of China (No. 2012ZX04010-081)the National High-Tech Research and Development Program of China (No. 2013AA040404)
文摘In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) surface alloying of Ti-Fe alloy powder. Microhard- ness tests showed that the surface hardness increased approximately four-fold after the alloying treatment. The microstructure of the MMC coating was mainly composed of residual austenite, acicular martensite, and eutectic ledeburite. Scanning electron microscopy (SEM) and X-ray diffraction analyzes revealed that the in situ TiC particles, which were formed by direct reaction of Ti with carbon originally contained in the GCI, was uniformly distributed at the boundary of residual anstenite in the alloying zone. Pin-on-disc high-temperature wear tests were performed on samples both with and without the MMC coating at room temperature and at elevated temperatures (473 K and 623 K), and the wear behavior and mechanism were investigated. The results showed that, after the PTA alloying treatment, the wear resistance of the sam- ples improved significantly. On the basis of our analysis of the composite coatings by optical microscopy, SEM with energy-dispersive X-ray spectroscopy, and microhardness measurements, we attributed this improvement of wear resistance to the transformation of the microstruc- ture and to the presence of TiC particles.
基金Project(50405041) supported by the National Natural Science Foundation of ChinaProject(2007) supported by the Opening Research Foundation State Key Laboratory of Powder Metallurgy of China
文摘MoSi2 was prepared by SHS,pressed at room-temperature and then vacuum sintered at 1 500 ℃ for 1 h. The tribological properties of MoSi2 against Al2O3 were investigated by using an XP-5 type High Temperature Friction and Wear Tester. Micrographs and phases of the worn surface of MoSi2 were observed by SEM with EDS and X-ray diffraction. The results show that the wearing process of MoSi2 at high temperature exists three stages:running-in,interim and steady periods. MoSi2 exhibits preferable wear resistance when the load is lower than 50 N. Adhesion and oxidation wear exists widely at elevated temperature;however besides these,with increasing the load,the main wear mechanisms of MoSi2 could be changed from adhesion,plastic forming to fatigue fracture in turn.
基金financially supported by the Guangdong Basic and Applied Basic Research Foundation(2022A1515110296,2022A1515110432)the Shenzhen Science and Technology Program(20231120171032001)the National Natural Science Foundation of China(No.52242305).
文摘Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature monitoring/warning in industrial and wearable applications remains a great challenge.Herein,a highly elastic,flame-retardant and high-temperature-resistant TE aerogel,made of poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate)/single-walled carbon nanotube(PEDOT:PSS/SWCNT)composites,has been fabricated,displaying attractive compression-induced power factor enhancement.The as-fabricated sensors with the aerogel can achieve accurately pressure stimuli detection and wide temperature range monitoring.Subsequently,a flexible TE generator is assembled,consisting of 25 aerogels connected in series,capable of delivering a maximum output power of 400μW when subjected to a temperature difference of 300 K.This demonstrates its outstanding high-temperature heat harvesting capability and promising application prospects for real-time temperature monitoring on industrial high-temperature pipelines.Moreover,the designed self-powered wearable sensing glove can realize precise wide-range temperature detection,high-temperature warning and accurate recognition of human hand gestures.The aerogel-based intelligent wearable sensing system developed for firefighters demonstrates the desired self-powered and highly sensitive high-temperature fire warning capability.Benefitting from these desirable properties,the elastic and high-temperature-resistant aerogels present various promising applications including self-powered high-temperature monitoring,industrial overheat warning,waste heat energy recycling and even wearable healthcare.
基金supported by the Key R&D Program of Shandong Province of China(Grant number 2019QYTPY057)the Natural Science Foundation of Shandong Province of China(Grant numbers ZR2020ME110,ZR2021ME023)。
文摘This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg alloy.The synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were studied.Results show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the alloy.They can improve the strength of the alloy by hindering dislocation movement and crack propagation.In addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain refinement.The addition of Mo greatly improves the heat resistance of the alloy.The extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy.
基金the financial support from the National Natural Science Foundation of China(21908010)Jilin Provincial Department of Science and Technology(20220101089JC)the Education Department of Jilin Province(JJKH20220694KJ)。
文摘High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,N2physisorption,27Al magic angle spinning nuclear magnetic resonance(MAS NMR),and temperature-programmed desorption of ammonia results indicated that the hightemperature treatment at 650℃ hardly affected the inherent crystal and texture of HZSM-5zeolites but facilitated the conversion of framework Al to extra-framework Al,reducing the acid site and enhancing the acid strength.Moreover,the high-temperature treatment improved the performance of HZSM-5 zeolites in n-heptane catalytic cracking,promoting the conversion and light olefins yield while inhibiting coke formation.Based on the kinetic and mechanism analysis,the improvement of HZSM-5 performance caused by high-temperature treatment has been attributed to the formation of extra-framework Al,which enhanced the acid strength,facilitated the bimolecular reaction,and promoted the entropy change to overcome a higher energy barrier in n-heptane catalytic cracking.
文摘Ultra-deep reservoirs play an important role at present in fossil energy exploitation.Due to the related high temperature,high pressure,and high formation fracture pressure,however,methods for oil well stimulation do not produce satisfactory results when conventional fracturing fluids with a low pumping rate are used.In response to the above problem,a fracturing fluid with a density of 1.2~1.4 g/cm^(3)was developed by using Potassium formatted,hydroxypropyl guanidine gum and zirconium crosslinking agents.The fracturing fluid was tested and its ability to maintain a viscosity of 100 mPa.s over more than 60 min was verified under a shear rate of 1701/s and at a temperature of 175℃.This fluid has good sand-carrying performances,a low viscosity after breaking the rubber,and the residue content is less than 200 mg/L.Compared with ordinary reconstruction fluid,it can increase the density by 30%~40%and reduce the wellhead pressure of 8000 m level reconstruction wells.Moreover,the new fracturing fluid can significantly mitigate safety risks.
基金supported by the National Key Research and Development Program of China(2022YFB3809005)by SINOPEC(120060-6,121027,and 122042).
文摘Aviation turbine engine oils require excellent thermal-oxidative stability because of their high-temperature environments.High-temperature bearing deposit testing is a mandatory method for measuring the thermal-oxidative performance of aviation lubricant oils,and the relevant apparatus was improved in the present study.Two different commercial aviation turbine engine oils were tested,one with standard performance(known as the SL oil)and the other with high thermal stability,and their thermal-oxidative stability characteristics were evaluated.After 100 h of high-temperature bearing testing,the SL oil was analyzed by using various analytical techniques to investigate its thermal-oxidative process in the bearing test,with its thermal-oxidative degradation mechanism also being discussed.The results indicate that the developed high-temperature bearing apparatus easily meets the test requirements of method 3410.1 in standard FED-STD-791D.The viscosity and total acid number(TAN)of the SL oil increased with the bearing test time,and various deposits were produced in the bearing test,with the micro-particles of the carbon deposits being sphere-like,rod-like,and sheet-like in appearance.The antioxidant additives in the oil were consumed very rapidly in the first 30 h of the bearing test,with N-phenyl-1-naphthylamine being consumed faster than dioctyldiphenylamine.Overall,the oil thermal-oxidative process involves very complex physical and chemical mechanisms.
基金supported by The National Key Research and Development Program of China(2021YFB4001204)National Natural Science Foundation of China(22379143)。
文摘Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel cells.To overcome these barriers,poly(terphenyl piperidinium)s constructed from the m-and p-isomers of terphenyl were synthesized to regulate the microstructure of the membrane.Highly rigid p-terphenyl units prompt the formation of moderate PA aggregates,where the ion-pair interaction between piperidinium and biphosphate is reinforced,leading to a reduction in the plasticizing effect.As a result,there are trade-offs between the proton conductivity,mechanical strength,and PA retention of the membranes with varied m/p-isomer ratios.The designed PA-doped PTP-20m membrane exhibits superior ionic conductivity,good mechanical strength,and excellent PA retention over a wide range of temperature(80–160°C)as well as satisfactory resistance to harsh accelerated aging tests.As a result,the membrane presents a desirable combination of performance(1.462 W cm^(-2) under the H_(2)/O_(2)condition,which is 1.5 times higher than that of PBI-based membrane)and durability(300 h at 160°C and 0.2 A cm^(-2))in the fuel cell.The results of this study provide new insights that will guide molecular design from the perspective of microstructure to improve the performance and robustness of HT-PEMs.
基金Project supported by the National Natural Science Foundation of China(Nos.11932008 and 12272156)the Fundamental Research Funds for the Central Universities(No.lzujbky-2022-kb06)+1 种基金the Gansu Science and Technology ProgramLanzhou City’s Scientific Research Funding Subsidy to Lanzhou University of China。
文摘Second-generation high-temperature superconducting(HTS)conductors,specifically rare earth-barium-copper-oxide(REBCO)coated conductor(CC)tapes,are promising candidates for high-energy and high-field superconducting applications.With respect to epoxy-impregnated REBCO composite magnets that comprise multilayer components,the thermomechanical characteristics of each component differ considerably under extremely low temperatures and strong electromagnetic fields.Traditional numerical models include homogenized orthotropic models,which simplify overall field calculation but miss detailed multi-physics aspects,and full refinement(FR)ones that are thorough but computationally demanding.Herein,we propose an extended multi-scale approach for analyzing the multi-field characteristics of an epoxy-impregnated composite magnet assembled by HTS pancake coils.This approach combines a global homogenization(GH)scheme based on the homogenized electromagnetic T-A model,a method for solving Maxwell's equations for superconducting materials based on the current vector potential T and the magnetic field vector potential A,and a homogenized orthotropic thermoelastic model to assess the electromagnetic and thermoelastic properties at the macroscopic scale.We then identify“dangerous regions”at the macroscopic scale and obtain finer details using a local refinement(LR)scheme to capture the responses of each component material in the HTS composite tapes at the mesoscopic scale.The results of the present GH-LR multi-scale approach agree well with those of the FR scheme and the experimental data in the literature,indicating that the present approach is accurate and efficient.The proposed GH-LR multi-scale approach can serve as a valuable tool for evaluating the risk of failure in large-scale HTS composite magnets.
基金financially supported by the National Key Research and Development Program of China(Grant No.2018YFA0703605)the Key Basic and Applied Research Pro-gram of Guangdong Province,China(Grant No.2019B030302010)+1 种基金the NSF of China(Grant No.52122105,51971150)the Science and Technology Innovation Commission Shenzhen(Grants No.RCJC20221008092730037,20220804091920001)。
文摘Wear resistance is a critical consideration in engineering applications.In this study,we demonstrated an Ir-Ta-Ni-Nb bulk metallic glass(BMG)with outstanding high-temperature wear resistance and revealed its promising applications in extreme environments.The wear behavior and mechanism were systemati-cally investigated from room temperature(RT)to 750℃.The results show that the wear rate increases from∼2.65×10^(-6)mm^(3)N^(-1)m^(-1)to∼10.56×10^(-6)mm^(3)N^(-1)m^(-1)in the temperature span RT to 400℃,following abrasive wear and flash temperature-induced oxidative wear during the friction.However,at the higher temperature of 600℃,further heating due to frictional heat leads to a softening of the wear surface,resulting in a maximum wear rate of∼20.99×10^(-6)mm^(3)N^(-1)m^(-1)under softness-driven abrasive wear as well as oxidative wear.Interestingly,the wear resistance at an even higher temperature of 750℃shows a paradoxical improvement of∼7.08×10^(-6)mm^(3)N^(-1)m^(-1),which is attributed to the formation of an oxide layer with a thickness of several microns,avoiding violent wear of BMG.The re-sults demonstrate the unreported outstanding high-temperature wear resistance of the Ir-Ta-Ni-Nb BMG,especially its excellent capability to resist wear at 750℃,leading to the promising applications of BMG in the fields of aerospace,metallurgy,and nuclear industries.
基金Supported by National Key R&D Program of China(Grant No.2022YFB3401901)Key Program of National Natural Science Foundation of China(Grant No.U2067221)+2 种基金Sichuan Provincial Science and Technology Planning Project(Grant Nos.2022JDJQ0019 and 2022ZYD0029)Funds for China Postdoctoral Science Foundation(Grant No.2022M713008)Sichuan Provincial Innovative Talent Funding Project for Postdoctoral Fellows(Grant No.BX202225).
文摘In pressurized water reactor(PWR),fretting wear is one of the main causes of fuel assembly failure.Moreover,the operation condition of cladding is complex and harsh.A unique fretting damage test equipment was developed and tested to simulate the fretting damage evolution process of cladding in the PWR environment.It can simulate the fretting wear experiment of PWR under different temperatures(maximum temperature is 350℃),displacement amplitude,vibration frequency,and normal force.The fretting wear behavior of Zr-4 alloy under different temperature environments was tested.In addition,the evolution of wear scar morphology,profile,and wear volume was studied using an optical microscope(OM),scanning electron microscopy(SEM),and a 3D white light interferometer.Results show that higher water temperature evidently decreased the cladding wear volume,the wear mechanism of Zr-4 cladding changed from abrasive wear to adhesive wear and the formation of an oxide layer on the wear scar reduced the wear volume and maximum wear depth.
基金Financial support from the National Natural Science Foundation of China(52142501 and 52101026)the National Key R&D Program of China(2018YFA0703400)+4 种基金Natural Science Foundation of Zhejiang Province(LQ20E010004)China Postdoctoral Science Foundation(2021M693250)Ningbo 3315 Innovation Team(2019A-18-C)CAS PIFI program(2022VEA0005)CAS Pioneer Hundred Talents Program are greatly acknowledged。
文摘Réfractory high/medium entropy nitrides(HENs/MENs)exhibit comprehensive application prospects as protective films on mechanical parts,particularly those subjected to sliding contacts at elevated temperatures.In this study,a new MEN system TiNbWN,forming a single fc solution,is designed and its wear performance at temperatures ranging from 25 to 750℃is explored.The wear mechanisms can be rationalized by examining the subsurface microstructural evolutions using the transmission electron microscopy as well as calculating the phase diagrams and interfacial adhesion behavior employing calculation of phase diagram(CALPHAD)and density functional theory(DFT).To be specific,increased wear losses occur in a temperature range of 25-600℃,being predominantly caused by the thermally-induced hardness degradation;whereas at the ultimate temperature(750℃),the wear loss is refrained due to the formation of nanocrystalline oxides(WnO_(3n-2r)TiO_(2),and TiOx),as synergistically revealed by microscopy and CALPHAD,which not only enhance the mechanical properties of the pristine nitride film,but also act as solid lubricants,reducing the interfacial adhesion.Thus,our work delineates the role of the in situ formed nanocrystalline oxides in the wear mechanism transition of TiNbWN thin films,which could shed light on the high-temperature wear behavior of refractory HEN/MENfilms.
基金supported by the National Natural Science Foundation of China(NSFC,Nos.52176199,and U20A20310)supported by the Program of Shanghai Academic/Technology Research Leader(22XD1423800)。
文摘Understanding the thermal safety evolution of lithium-ion batteries during high-temperature usage conditions bears significant implications for enhancing the safety management of aging batteries.This work investigates the thermal safety evolution mechanism of lithium-ion batteries during high-temperature aging.Similarities arise in the thermal safety evolution and degradation mechanisms for lithium-ion batteries undergoing cyclic aging and calendar aging.Employing multi-angle characterization analysis,the intricate mechanism governing the thermal safety evolution of lithium-ion batteries during high-temperature aging is clarified.Specifically,lithium plating serves as the pivotal factor contributing to the reduction in the self-heating initial temperature.Additionally,the crystal structure of the cathode induced by the dissolution of transition metals and the reductive gas generated during aging attacking the crystal structure of the cathode lead to a decrease in thermal runaway triggering temperature.Furthermore,the loss of active materials and active lithium during aging contributes to a decline in both the maximum temperature and the maximum temperature rise rate,ultimately indicating a decrease in the thermal hazards of aging batteries.
基金supported by the National Natural Science Foundation of China(Grant Nos.42088101 and 42175033)the High-Performance Computing Center of Nanjing University of Information Science&Technology。
文摘Extreme high temperatures frequently occur in southwestern China,significantly impacting the local ecological system and economic development.However,accurate prediction of extreme high-temperature days(EHDs)in this region is still an unresolved challenge.Based on the spatiotemporal characteristics of EHDs over China,a domain-averaged EHD index over southwestern China(SWC-EHDs)during April-May is defined.The simultaneous dynamic and thermodynamic fields associated with the increased SWC-EHDs are a local upper-level anticyclonic(high-pressure)anomaly and wavy geopotential height anomaly patterns over Eurasia.In tracing the origins of the lower boundary anomalies,two physically meaningful precursors are detected for SWC-EHDs.They are the tripolar SST change tendency from December-January to February-March in the northern Atlantic and the February-March mean snow depth in central Asia.Using these two selected predictors,a physics-based empirical model prediction was applied to the training period of 1961–2005 to obtain a skillful prediction of the EHDs index,attaining a correlation coefficient of 0.76 in the independent prediction period(2006–19),suggesting that 58%of the total SWC-EHDs variability is predictable.This study provides an estimate for the lower bound of the seasonal predictability of EHDs as well as for the hydrological drought over southwestern China.
文摘Satellited CoNiCrAlY–Al_(2)O_(3)feedstocks with 2wt%, 4wt%, and 6wt% oxide nanoparticles and pure CoNiCrAlY powder were deposited by the high-velocity oxy fuel process on an Inconel738 superalloy substrate. The oxidation test was performed at 1050℃ for 5, 50, 100,150, 200, and 400 h. The microstructure and phase composition of powders and coatings were characterized by scanning electron microscopy and X-ray diffraction, respectively. The bonding strength of the coatings was also evaluated. The results proved that with the increase in the percentage of nanoparticles(from 2wt% to 6wt%), the amount of porosity(from 1vol% to 4.7vol%), unmelted particles, and roughness of the coatings(from 4.8 to 8.8 μm) increased, and the bonding strength decreased from 71 to 48 MPa. The thicknesses of the thermally grown oxide layer of pure and composite coatings(2wt%, 4wt%, and 6wt%) after 400 h oxidation were measured as 6.5, 5.5, 7.6, and 8.1 μm, respectively.The CoNiCrAlY–2wt% Al_(2)O_(3)coating showed the highest oxidation resistance due to the diffusion barrier effect of well-dispersed nanoparticles. The CoNiCrAlY–6wt% Al_(2)O_(3)coating had the lowest oxidation resistance due to its rough surface morphology and porous microstructure.
基金the Strategic Pilot Technology Chinese Academy of Sciences(No.XDA02010500).
文摘The high-temperature molten salt pump is the core equipment in a molten salt reactor that drives the flow of the molten salt coolant.Rotor stability is key to the continuous and reliable operation of the molten salt pump,and the liquid seal at the wear ring can affect the dynamic characteristics of the rotor system.When the molten salt pump is operated in the hightemperature molten salt medium,thermal deformation of the submerged parts inevitably occurs,changing clearance between the stator and rotor,affecting the leakage and dynamic characteristics of the seal.In this study,the seal leakage,seal dynamic characteristics,and rotor system dynamic characteristics are simulated and analyzed using finite element simulation software based on two cases of considering the effect of seal thermal deformation effect or not.The results show a significant difference in the leakage characteristics and dynamic characteristics of the seal obtained by considering the effect of seal thermal deformation and neglecting the effect of thermal deformation.The leakage flow rate decreases,and the first-order critical speed of the seal-bearing-rotor system decrease after considering the seal’s thermal deformation.
基金funding support from the National Natural Science Foundation of China (32072024)the Fundamental Research Funds for the Central Universities (2021ZKPY019)the National Key Research and Development Program of China (2018YFD0100403, 2016YFD0101402)。
文摘Cotton(Gossypium spp.) yield is reduced by stress. In this study, high temperature(HT) suppressed the expression of the jasmonic acid(JA) biosynthesis gene allene oxide cyclase 2(GhAOC2), reducing JA content and causing male sterility in the cotton HT-sensitive line H05. Anther sterility was reversed by exogenous application of methyl jasmonate(MeJA) to early buds. To elucidate the role of GhAOC2 in JA biosynthesis and identify its putative contribution to the anther response to HT, we created gene knockout cotton plants using the CRISPR/Cas9 system. Ghaoc2 mutant lines showed male-sterile flowers with reduced JA content in the anthers at the tetrad stage(TS), tapetum degradation stage(TDS), and anther dehiscence stage(ADS). Exogenous application of MeJA to early mutant buds(containing TS or TDS anthers) rescued the sterile pollen and indehiscent anther phenotypes, while ROS signals were reduced in ADS anthers. We propose that HT downregulates the expression of GhAOC2 in anthers, reducing JA biosynthesis and causing excessive ROS accumulation in anthers, leading to male sterility. These findings suggest exogenous JA application as a strategy for increasing male fertility in cotton under HT.
基金financially supported by the National High-tech Research and Development Program of China(No.2012AA03A513)the Fundamental Research Funds for the Central Universities(No.N140204001)the National Natural Science Foundation of China(Nos.51371044 and 51301037)
文摘Al2O3-r2O03/NiCoCrAIYTa coatings were prepared via atmosphere plasma spraying (APS). The microstructure and phase com- position of the coatings were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), laser confocal scanning microsco- py (LSCM), and transmission electron microscopy (TEM). The dry frictional wear behavior of the coatings at 500℃ in static air was inves- tigated and compared with that of 0Cr25Ni20 steel. The results show that the coatings comprise the slatted layers of oxide phases, unmelted particles, and pores. The hot abrasive resistance of the coatings is enhanced compared to that of 0Cr25Ni20, and their mass loss is approxi- mately one-fifteenth that of 0Cr25Ni20 steel. The main wear failure mechanisms of the coatings are abrasive wear, fatigue wear, and adhe- sive wear.
文摘Microstructure and high-temperature dry sliding wear at 600 ~C in ambient air of austenitic heat-resistant steel ZG40Cr25Ni20 with different contents (mass percent) of AI (0 to 7.10~) have been investigated. The results show that microstructures of 4.68% and 7.10% A1 addition content consist of the matrix and reinforcement of inter- metallic compound y' and carbide, while microstructures of ZG40Cr25Ni20 without A1 and with A1 of 1.68% are ab- sent of y'. Higher wear resistance than the original ZG40Cr25Ni20 alloy is achieved in alloys with higher content of A1 under the same high-temperature wear test condition. The wear rates of Fe-25Cr-20Ni-7.10A1 and Fe-25Cr-20Ni- 4.68A1 are only 20.83% and 45.83% of that of Fe-25Cr-20Ni, respectively. Heat-resistant steels with higher con- tents of AI (4.72% and 7.10%) have higher hardness than those with lower contents of AI (1.68% and 0). Wear mechanisms of ZG40Cr25Ni20 are considered as severe plough plastic deformation and slight adhesive. However, wear mechanisms of Fe-25Cr-20Ni 4.68A1 are light micro-cutting and oxidation-wear, while that of Fe-25Cr-20Ni- 7. 10A1 are severe adhesive transfer and oxidation-wear_