Highly ordered crystallization of α-FAPbl_(3) films via homogeneous seeds for efficient perovskite solar cells

Formamidine lead triiodide(FAPbI_(3))perovskites have become the most promising photovoltaic materials for perovskite solar cells with record power conversion efficiency(PCE).However,random nucleation,phase transition,and lattice defects are still the key challenges limiting the quality of FAPbI_(3) films.Previous studies show that the introduction or adding of seeds in the precursor is effective to promote the nucleation and crystallization of perovskite films.Nevertheless,the seed-assisted approach focuses on heterogeneous seeds or hetero-composites,which inevitably induce a lattice-mismatch,the genera-tion of strain or defects,and the phase segregation in the perovskite films.Herein,we first demonstrate that high-quality perovskite films are controllably prepared using α-and δ-phases mixed FAPbI_(3) micro-crystal as the homogeneous seeds with the one-step antisolvent method.The partially dissolved seeds with suitable sizes improve the crystallinity of the perovskite flm with preferable orientation,improved carrier lifetime,and increased carrier mobility.More importantly,the α-phase-containing seeds promote the formation of α-phase FAPbI_(3) films,leading to the reduction of residual lattice strain and the suppres-sion of I-ion migration.Besides,the adding of dimethyl 2,6-pyridine dicarboxylate(DPD)into the pre-cursor further suppresses the generation of defects,contributing to the PCE of devices prepared in air ambient being significantly improved to 23.75%,among the highest PCEs for fully air-processed FAPbI_(3) solar cells.The unpackaged target devices possess a high stability,maintaining 80%of the initial PCE under simulated solar illumination exceeding 800 h.

Delineating homogeneous domains of fractured rocks using topological manifolds and deep learning

Determining homogeneous domains statistically is helpful for engineering geological modeling and rock mass stability evaluation.In this text,a technique that can integrate lithology,geotechnical and structural information is proposed to delineate homogeneous domains.This technique is then applied to a high and steep slope along a road.First,geological and geotechnical domains were described based on lithology,faults,and shear zones.Next,topological manifolds were used to eliminate the incompatibility between orientations and other parameters(i.e.trace length and roughness)so that the data concerning various properties of each discontinuity can be matched and characterized in the same Euclidean space.Thus,the influence of implicit combined effect in between parameter sequences on the homogeneous domains could be considered.Deep learning technique was employed to quantify abstract features of the characterization images of discontinuity properties,and to assess the similarity of rock mass structures.The results show that the technique can effectively distinguish structural variations and outperform conventional methods.It can handle multisource engineering geological information and multiple discontinuity parameters.This technique can also minimize the interference of human factors and delineate homogeneous domains based on orientations or multi-parameter with arbitrary distributions to satisfy different engineering requirements.

Adaptive detection of range-spread targets in homogeneous and partially homogeneous clutter plus subspace interference

Adaptive detection of range-spread targets is considered in the presence of subspace interference plus Gaussian clutter with unknown covariance matrix.The target signal and interference are supposed to lie in two linearly independent subspaces with deterministic but unknown coordinates.Relying on the two-step criteria,two adaptive detectors based on Gradient tests are proposed,in homogeneous and partially homogeneous clutter plus subspace interference,respectively.Both of the proposed detectors exhibit theoretically constant false alarm rate property against unknown clutter covariance matrix as well as the power level.Numerical results show that,the proposed detectors have better performance than their existing counterparts,especially for mismatches in the signal steering vectors.

Reviewing Stability Criteria for Positive Homogeneous Systems and Adding One for Discrete-Time Cases with Degree Less Than One

The article synthesizes and presents the results regarding the stability of positive homogeneous systems that have been researched and published in recent years. Next, we provide a sufficient condition for global exponential stability in the case of discrete-time positive homogeneous systems with an order less than one with time-varying delays.

On Enforcing Dyadic-type Homogeneous Binary Function Product Constraints in MatBase

Homogeneous binary function products are frequently encountered in the sub-universes modeled by databases,spanning from genealogical trees and sports to education and healthcare,etc.Their properties must be discovered and enforced by the software applications managing such data to guarantee plausibility.The(Elementary)Mathematical Data Model provides 17 types of dyadic-based homogeneous binary function product constraint categories.MatBase,an intelligent data and knowledge base management system prototype,allows database designers to simply declare them by only clicking corresponding checkboxes and automatically generates code for enforcing them.This paper describes the algorithms that MatBase uses for enforcing all 17 types of homogeneous binary function product constraint,which may also be employed by developers without access to MatBase.

术语“Homogeneous Membrane Electrodes”和“Heterogeneous Membrane Electrodes”的中文译文的商榷

IUPAC在确定"离子选择电极"术语时,指出不能使用"离子特效电极"说明准确命名和术语使用的重要性。作者曾于1983年对术语"homogeneous membrane electrodes"和"heterogeneous membrane electrodes"的中文译文提出商榷并受到"离子选择电极通讯"编辑部的关注。自那以后,仍有不少文献,特别是博士和硕士论文,采用了过去的不恰当的译法。为此再次就对此问题进行商榷。"homogeneous"一词可以指"同一种"或者"同一相",而"heterogeneous"一词可以指"不同种"或者"不同相";根据IUPAC对上述电极的定义,显然应该各取前一含义。

Homogeneous Degradation of Cellulose in Its Aqueous Solution at Mild Temperature under Atmospheric Pressure

Degradation of cellulose to chemicals is one of major routes for biomass conversion. Here, a new simple and two-step method has been developed to convert cellulose in its homogeneously alkaline solution to organic acids under atmospheric pressure at mild temperature. At first, cellulose was degraded to smM1 molecular intermediates at 110 ℃ for 3 h under atmospheric pressure, and then it was oxidized with H202 at 50 ℃ for 4 h. Under the optimal condition, 73.5% conversion of cellulose could be achieved, and the yield of organic acids was 32.8% （formic acid）, 11.6% （lactic acid）, and 2.3% （oxalic acid）, respectively. It is noteworthy that the new strategy reduces energy consumption in the process of reaction, unlike the hydrothermal reaction under high temperature and high pressure.

Synthesis of Ce:YAG Phosphor via Homogeneous Precipitation under Microwave Irradiation

Ultra-fine Ce:YAG phosphors were prepared by homogeneous precipitation under microwave irradiation method . The formation of Ce: YAG was investigated by means of XRD and DTA/TG. The purified YAG crystallized phase was obtained at a lower temperature (1100℃). Basically spherical Ce:YAG powders were indicated from TEM images, and the size of the particles is about 80 nm. Two peaks of 436 and 473 nm can be seen from the excitation spectrum in the range of 402 -510 nm. A broad emission band located at 480 ~ 630 nm shows the phosphors prepared by this method have good emission properties.

AN INEQUALITY OF HOMOGENEOUS EXPANSION FOR BIHOLOMORPHIC QUASI-CONVEX MAPPINGS ON THE UNIT POLYDISK AND ITS APPLICATION

In this article,the authors obtain an inequality of homogeneous expansion for f,where f is a quasi-convex mapping(including quasi-convex mapping of type A and quasi-convex mapping of type B)defined on the open unit polydisk in C n .Meanwhile,the authors also investigate its application.

Effect of Sulfate Ions on YAG Powders Synthesized by Microwave Homogeneous Precipitation

Using A1(NO3)3·9H2O, NH4Al(SO4)2·12H2O, Y(NO3)3as mother salts, and urea as precipitant, YAG nano-powders were synthesized by microwave homogeneous precipitation. The composition, morphology, and phase transformation of precursor were analyzed by IR, XRD and TEM. The size distribution of YAG powders was characterized using laser diffraction method. The results show that sulfate ions influence the dispersion, composition and morphology of the YAG precursors. The addition of moderate sulfate ions can produce YAG powders with nano size and excellent dispersion at 1100℃.

THE SHARP ESTIMATE OF THE THIRD HOMOGENEOUS EXPANSION FOR A CLASS OF STARLIKE MAPPINGS OF ORDER α ON THE UNIT POLYDISK IN C^n

In this article, first, a sufficient condition for a starlike mapping of order a f（x） defined on the unit ball in a complex Banach space is given. Second, the sharp estimate of the third homogeneous expansion for f is established as well, where f（z） = （f1（z）, f2（z）,..., fn（z））＇ is a starlike mapping of order a or a normalized biholomorphic starlike mapping defined on the unit polydisk in Cn, and D2fk（0）（z2） /2i= zk（∑l=1^b akzzl）, k = 2t l=1 k = 1, 2,..., n. Our result states that the Bieberbaeh conjecture in several complex variables （the case of the third homogeneous expansion for starlike mappings of order α and biholomorphic starlike mappings） is partly proved.

Synthesis Yttrium Aluminum Garnet Precursor via Homogeneous Precipitation under Microwave Irradiation

The lowly-agglomerated single-phase YAG nanopowders were synthesized for the first time by the microwave homogeneous precipitation in the presence of urea. The composition and transformations during calcination of YAG precursor were analyzed by IR, DTA/TG and XRD. The size and morphology of YAG powders were characterized by LD and TEM methods. Results show that amorphous precursor synthesized under [urea]/[metal ions] molar ratio of 15 crystallizes directly to single-phase YAG at 900degreesC. The size distribution and sinterability of YAG powders are obviously improved by adding (NH4)(2)SO4 into the reaction solution. YAG powders obtained from precursor with the (NH4)(2)SO4 content of 8% have good sinterability and are highly densified at a temperature of 1500degreesC

One-pot degradation of cellulose into carbon dots and organic acids in its homogeneous aqueous solution

As the abundant biopolymer, cellulose can be used as a feedstock for chemicals and materials. Effective conversion of cellulose by simple processes is a key point. Degradation of cellulose in its homogeneous solution is attractive for the molecular chains are free and spread. Here,microcrystalline cellulose was first dissolved in aqueous solution of Na OH and urea, and then hydrothermal reaction was carried out at various temperature and time. Fluorescence carbon dots(CDs) were generated accompanied with six organic acids: oxalic acid, formic acid, malonic acid, lactic acid, acetic acid, and fumaric acid. The yields of all organic acids and CDs, and the fluorescence quantum yield(QY) of CDs were studied at different reaction conditions. It was found that the maximum yield of organic acids and CDs are 80.1% and 6.03%, respectively, and the highest QY of the CDs is 10.9%. Fluorescence studies reveal that the as-prepared CDs has efficient selectivity and sensitivity toward iron ions in acidic condition, indicating it is a potential fluorescent sensor to the detection of Fe3+. Importantly, it provides a panorama to summary the degradation routes of cellulose in its homogeneous aqueous solution with both organic molecules and CDs as products.

Upconversion luminescence of Y_2O_3:Er^(3+), Yb^(3+) nanoparticles prepared by a homogeneous precipitation method

Y2O3： Er^3＋, Yb^3＋ nanoparticles were synthesized by a homogeneous precipitation method without and with different concentrations of EDTA 2Na. Upconversion luminescence spectra of the samples were studied under 980 nm laser excitation. The results of XRD showed that the obtained Y2O3：Er^3＋,Yb^3＋ nanoparticles were of a cubic structure. The average crystallite sizes calculated were in the range of 28-40 nm. Green and red upconversion emission were observed, and attributed to ^2H11/2,^4S3/2→^4I15/2 and ^4F9/2→^4I15/2 transitions of the ion, respectively. The ratio of the intensity of green emission to that of red emission drastically changed with a change in the EDTA 2Na concentration. In the sample synthesized without EDTA, the relative intensity of the green emission was weaker than that of the red emission. The relative intensities of green emission increased with the increased amount of EDTA 2Na used. The possible upconversion luminescence mechanisms were discussed.

Influence of polymer additives on turbulent energy cascading in forced homogeneous isotropic turbulence studied by direct numerical simulations

Direct numerical simulations （DNS） were performed for the forced homogeneous isotropic turbulence （FHIT） with/without polymer additives in order to elaborate the characteristics of the turbulent energy cascading influenced by drag-reducing effects. The finite elastic non-linear extensibility-Peterlin model （FENE-P） was used as the conformation tensor equation for the viscoelastic polymer solution. Detailed analyses of DNS data were carried out in this paper for the turbulence scaling law and the topological dynamics of FHIT as well as the important turbulent parameters, including turbulent kinetic energy spectra, enstrophy and strain, velocity structure function, small-scale intermittency, etc. A natural and straightforward definition for the drag reduction rate was also proposed for the drag-reducing FHIT based on the decrease degree of the turbulent kinetic energy. It was found that the turbulent energy cascading in the FHIT was greatly modified by the drag-reducing polymer additives. The enstrophy and the strain fields in the FH1T of the polymer solution were remarkably weakened as compared with their Newtonian counterparts. The small-scale vortices and the small-scale intermittency were all inhibited by the viscoelastic effects in the FHIT of the polymer solution. However, the scaling law in a fashion of extended self-similarity for the FHIT of the polymer solution, within the presently simulated range of Weissenberg numbers, had no distinct differences compared with that of the Newtonian fluid case.

HRM: H-tree based reconfiguration mechanism in reconfigurable homogeneous PE array

In order to accommodate the variety of algorithms with different performance in specific application and improve power efficiency,reconfigurable architecture has become an effective methodology in academia and industry.However,existing architectures suffer from performance bottleneck due to slow updating of contexts and inadequate flexibility.This paper presents an H-tree based reconfiguration mechanism(HRM)with Huffman-coding-like and mask addressing method in a homogeneous processing element(PE)array,which supports both programmable and data-driven modes.The proposed HRM can transfer reconfiguration instructions/contexts to a particular PE or associated PEs simultaneously in one clock cycle in unicast,multicast and broadcast mode,and shut down the unnecessary PE/PEs according to the current configuration.To verify the correctness and efficiency,we implement it in RTL synthesis and FPGA prototype.Compared to prior works,the experiment results show that the HRM has improved the work frequency by an average of 23.4%,increased the updating speed by 2×,and reduced the area by 36.9%;HRM can also power off the unnecessary PEs which reduced 51%of dynamic power dissipation in certain application configuration.Furthermore,in the data-driven mode,the system frequency can reach 214 MHz,which is 1.68×higher compared with the programmable mode.

BOUNDEDNESS OF COMMUTATORS ON HOMOGENEOUS MORREY-HERZ SPACES OVER LOCALLY COMPACT VILENKIN GROUPS

This paper studies some boundedness results of commutators on a class of new spaces MKp,q^αλ （G） named as homogenous Morrey-Herz spaces over locally compact Vilenkin groups

Synthesis and luminescence properties of nanocrystalline Gd_3Ga_5O_(12):Eu^(3+) by a homogeneous precipitation method

Nanocrystalline Gd3Ga5O12:Eu3+ with cubic phase was prepared by a urea homogeneous precipitation method. X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric and differential thermal analysis (TG-DTA) and photoluminescence spectra were used to characterize the samples. The effects of the initial solution pH value and urea content on the structure of the sample were studied. The XRD results show that pure phase Gd3Ga5O12 can be obtained at pH =6 and pH =8 of the initial solution. The average crystallite size can be calculated as in the range of 24~33 nm. The average crystallite size decreases with increasing molar ratio of urea to metal ion. The results of excitation spectra and emission spectra show that the emission peaks are ascribed to 5D0→7FJ transitions of Eu3+, and the magnetic dipole transition originated from 5D0 →7F1 of Eu3+ is the strongest; the broad excitation bands belong to change transfer band of Eu?O and the host absorption of Gd3Ga5O12. An efficient energy transfer occurs from Gd3+ to Eu3+.

Homogeneous Acetylation of Cellulose at Relatively High Concentrations in an Ionic Liquid

At relatively high cellulose mass concentrations(8%,10%,and 12%),homogeneous acetylation of cellulose was carried out in an ionic liquid,1-allyl-3-methylimidazolium chloride(AmimCl).Without using any catalyst,cellulose acetates(CAs)with the degree of substitution(DS)in a range from 0.4 to 3.0 were synthesized in one-step.The effects of reaction time,temperature and molar ratio of acetic anhydride/anhydroglucose unit(AGU) in cellulose on DS value of CAs were investigated.The synthesized CAs were characterized by means of FT-IR, NMR,and solubility,mechanical and thermal tests.After the acetylation,the used ionic liquid AmimCl was easily recycled and reused.This study shows the potential of the homogeneous acetylation of cellulose at relatively high concentrations in ionic liquids in future industrial applications.

Simplified Homogeneous Balance Method and Its Applications to the Whitham-Broer-Kaup Model Equations

A nonlinear transformation of the Whitham-Broer-Kaup (WBK) model equations in the shallow water small-amplitude regime is derived by using a simplified homogeneous balance method. The WBK model equations are linearized under the nonlinear transformation. Various exact solutions of the WBK model equations are obtained via the nonlinear transformation with the aid of solutions for the linear equation.