Catalytic effect in lithium metal batteries: From heterogeneous catalyst to homogenous catalyst

Lithium metal batteries are regarded as prominent contenders to address the pressing needs owing to the high theoretical capacity.Toward the broader implementation,the primary obstacle lies in the intricate multi-electron,multi-step redox reaction associated with sluggish conversion kinetics,subsequently giving rise to a cascade of parasitic issues.In order to smooth reaction kinetics,catalysts are widely introduced to accelerate reaction rate via modulating the energy barrier.Over past decades,a large amount of research has been devoted to the catalyst design and catalytic mechanism exploration,and thus the great progress in electrochemical performance has been realized.Therefore,it is necessary to make a comprehensive review toward key progress in catalyst design and future development pathway.In this review,the basic mechanism of lithium metal batteries is provided along with corresponding advantages and existing challenges detailly described.The main catalysts employed to accelerate cathode reaction with emphasis on their catalytic mechanism are summarized as well.Finally,the rational design and innovative direction toward efficient catalysts are suggested for future application in metal-sulfur/gas battery and beyond.This review is expected to drive and benefit future research on rational catalyst design with multi-parameter synergistic impacts on the activity and stability of next-generation metal battery,thus opening new avenue for sustainable solution to climate change,energy and environmental issues,and the potential industrial economy.

COMPLETE KAHLER METRICS WITH POSITIVE HOLOMORPHIC SECTIONAL CURVATURES ON CERTAIN LINE BUNDLES(RELATED TO A COHOMOGENEITY ONE POINT OF VIEW ON A YAU CONJECTURE)

In this article,we study Kahler metrics on a certain line bundle over some compact Kahler manifolds to find complete Kahler metrics with positive holomorphic sectional(or bisectional)curvatures.Thus,we apply a strategy to a famous Yau conjecture with a co-homogeneity one geometry.

Typhoon Case Comparison Analysis Between Heterogeneous Many-Core and Homogenous Multicore Supercomputing Platforms

In this paper,a typical experiment is carried out based on a high-resolution air-sea coupled model,namely,the coupled ocean-atmosphere-wave-sediment transport(COAWST)model,on both heterogeneous many-core(SW)and homogenous multicore(Intel)supercomputing platforms.We construct a hindcast of Typhoon Lekima on both the SW and Intel platforms,compare the simulation results between these two platforms and compare the key elements of the atmospheric and ocean modules to reanalysis data.The comparative experiment in this typhoon case indicates that the domestic many-core computing platform and general cluster yield almost no differences in the simulated typhoon path and intensity,and the differences in surface pressure(PSFC)in the WRF model and sea surface temperature(SST)in the short-range forecast are very small,whereas a major difference can be identified at high latitudes after the first 10 days.Further heat budget analysis verifies that the differences in SST after 10 days are mainly caused by shortwave radiation variations,as influenced by subsequently generated typhoons in the system.These typhoons generated in the hindcast after the first 10 days attain obviously different trajectories between the two platforms.

The Contribution of United States Aircraft Reconnaissance Data to the China Meteorological Administration Tropical Cyclone Intensity Data:An Evaluation of Homogeneity

This paper investigates the homogeneity of United States aircraft reconnaissance data and the impact of these data on the homogeneity of the tropical cyclone(TC)best track data for the seasons 1949-1987 generated by the China Meteorological Administration(CMA).The evaluation of the reconnaissance data shows that the minimum central sea level pressure(MCP)data are relatively homogeneous,whereas the maximum sustained wind(MSW)data show both overestimations and spurious abrupt changes.Statistical comparisons suggest that both the reconnaissance MCP and MSW were well incorporated into the CMA TC best track dataset.Although no spurious abrupt changes were evident in the reconnaissance-related best track MCP data,two spurious changepoints were identified in the remainder of the best-track MCP data.Furthermore,the influence of the reconnaissance MSWs seems to extend to the best track MSWs unrelated to reconnaissance,which might reflect the optimistic confidence in making higher estimates due to the overestimated extreme wind“observations”.In addition,the overestimation of either the reconnaissance MSWs or the best track MSWs was greater during the early decades compared to later decades,which reflects the important influence of reconnaissance data on the CMA TC best track dataset.The wind-pressure relationship(WPR)used in the CMA TC best track dataset is also evaluated and is found to overestimate the MSW,which may lead to inhomogeneity within the dataset between the aircraft reconnaissance era and the satellite era.

Microstructure homogeneity and mechanical properties of laser-arc hybrid welded AZ31B magnesium alloy

Laser-arc hybrid welding of AZ31B magnesium alloy was carried out,the effects of welding parameters on weld formation,microstructure homogeneity and mechanical properties were investigated.The results showed that laser-arc hybrid welding was beneficial to improve the weld formation of magnesium alloy by inhibiting the defect of undercut and pores.The weld microstructure was mainly columnar grains neighboring the fusion line and equiaxed grains at the weld center.It was interesting that the grain size at the upper arc zone was smaller than that at the lower laser zone,with the difference mainly affected by laser power rather than welding current and welding speed.The welding parameters were optimized as laser power of 3.5 kW,welding current of 100 A and welding speed of 1.5 m/min.In this case,the weld was free of undercut and pores,and the tensile strength and elongation rate reached 252 MPa and 11.2%,respectively.Finally,the microstructure homogeneity was illustrated according to the heat distribution,and the evolution law of tensile properties was discussed basing on the weld formation and microstructure characteristics.

Modeling Method of C/C-ZrC Composites and Prediction of Equivalent Thermal Conductivity Tensor Based on Asymptotic Homogenization

This article proposes a modeling method for C/C-ZrC composite materials.According to the superposition of Gaussian random field,the original gray model is obtained,and the threshold segmentation method is used to generate the C-ZrC inclusion model.Finally,the fiber structure is added to construct the microstructure of the three-phase plain weave composite.The reconstructed inclusions can meet the randomness of the shape and have a uniform distribution.Using an algorithm based on asymptotic homogenization and finite element method,the equivalent thermal conductivity prediction of the microstructure finite element model was carried out,and the influence of component volume fraction on material thermal properties was explored.The sensitivity of model parameters was studied,including the size,mesh sensitivity,Gaussian complexity,and correlation length of the RVE model,and the optimal calculation model was selected.The results indicate that the volume fraction of the inclusion phase has a significant impact on the equivalent thermal conductivity of the material.As the volume fraction of carbon fiber and ZrC increases,the equivalent thermal conductivity tensor gradually decreases.This model can be used to explore the impact of materialmicrostructure on the results,and numerical simulations have studied the relationship between structure and performance,providing the possibility of designing microstructure based on performance.

Highly ordered crystallization of α-FAPbl_(3) films via homogeneous seeds for efficient perovskite solar cells

Formamidine lead triiodide(FAPbI_(3))perovskites have become the most promising photovoltaic materials for perovskite solar cells with record power conversion efficiency(PCE).However,random nucleation,phase transition,and lattice defects are still the key challenges limiting the quality of FAPbI_(3) films.Previous studies show that the introduction or adding of seeds in the precursor is effective to promote the nucleation and crystallization of perovskite films.Nevertheless,the seed-assisted approach focuses on heterogeneous seeds or hetero-composites,which inevitably induce a lattice-mismatch,the genera-tion of strain or defects,and the phase segregation in the perovskite films.Herein,we first demonstrate that high-quality perovskite films are controllably prepared using α-and δ-phases mixed FAPbI_(3) micro-crystal as the homogeneous seeds with the one-step antisolvent method.The partially dissolved seeds with suitable sizes improve the crystallinity of the perovskite flm with preferable orientation,improved carrier lifetime,and increased carrier mobility.More importantly,the α-phase-containing seeds promote the formation of α-phase FAPbI_(3) films,leading to the reduction of residual lattice strain and the suppres-sion of I-ion migration.Besides,the adding of dimethyl 2,6-pyridine dicarboxylate(DPD)into the pre-cursor further suppresses the generation of defects,contributing to the PCE of devices prepared in air ambient being significantly improved to 23.75%,among the highest PCEs for fully air-processed FAPbI_(3) solar cells.The unpackaged target devices possess a high stability,maintaining 80%of the initial PCE under simulated solar illumination exceeding 800 h.

Delineating homogeneous domains of fractured rocks using topological manifolds and deep learning

Determining homogeneous domains statistically is helpful for engineering geological modeling and rock mass stability evaluation.In this text,a technique that can integrate lithology,geotechnical and structural information is proposed to delineate homogeneous domains.This technique is then applied to a high and steep slope along a road.First,geological and geotechnical domains were described based on lithology,faults,and shear zones.Next,topological manifolds were used to eliminate the incompatibility between orientations and other parameters(i.e.trace length and roughness)so that the data concerning various properties of each discontinuity can be matched and characterized in the same Euclidean space.Thus,the influence of implicit combined effect in between parameter sequences on the homogeneous domains could be considered.Deep learning technique was employed to quantify abstract features of the characterization images of discontinuity properties,and to assess the similarity of rock mass structures.The results show that the technique can effectively distinguish structural variations and outperform conventional methods.It can handle multisource engineering geological information and multiple discontinuity parameters.This technique can also minimize the interference of human factors and delineate homogeneous domains based on orientations or multi-parameter with arbitrary distributions to satisfy different engineering requirements.

Adaptive detection of range-spread targets in homogeneous and partially homogeneous clutter plus subspace interference

Adaptive detection of range-spread targets is considered in the presence of subspace interference plus Gaussian clutter with unknown covariance matrix.The target signal and interference are supposed to lie in two linearly independent subspaces with deterministic but unknown coordinates.Relying on the two-step criteria,two adaptive detectors based on Gradient tests are proposed,in homogeneous and partially homogeneous clutter plus subspace interference,respectively.Both of the proposed detectors exhibit theoretically constant false alarm rate property against unknown clutter covariance matrix as well as the power level.Numerical results show that,the proposed detectors have better performance than their existing counterparts,especially for mismatches in the signal steering vectors.

Reviewing Stability Criteria for Positive Homogeneous Systems and Adding One for Discrete-Time Cases with Degree Less Than One

The article synthesizes and presents the results regarding the stability of positive homogeneous systems that have been researched and published in recent years. Next, we provide a sufficient condition for global exponential stability in the case of discrete-time positive homogeneous systems with an order less than one with time-varying delays.

Integrated multi-scale approach combining global homogenization and local refinement for multi-field analysis of high-temperature superconducting composite magnets

Second-generation high-temperature superconducting(HTS)conductors,specifically rare earth-barium-copper-oxide(REBCO)coated conductor(CC)tapes,are promising candidates for high-energy and high-field superconducting applications.With respect to epoxy-impregnated REBCO composite magnets that comprise multilayer components,the thermomechanical characteristics of each component differ considerably under extremely low temperatures and strong electromagnetic fields.Traditional numerical models include homogenized orthotropic models,which simplify overall field calculation but miss detailed multi-physics aspects,and full refinement(FR)ones that are thorough but computationally demanding.Herein,we propose an extended multi-scale approach for analyzing the multi-field characteristics of an epoxy-impregnated composite magnet assembled by HTS pancake coils.This approach combines a global homogenization(GH)scheme based on the homogenized electromagnetic T-A model,a method for solving Maxwell's equations for superconducting materials based on the current vector potential T and the magnetic field vector potential A,and a homogenized orthotropic thermoelastic model to assess the electromagnetic and thermoelastic properties at the macroscopic scale.We then identify“dangerous regions”at the macroscopic scale and obtain finer details using a local refinement(LR)scheme to capture the responses of each component material in the HTS composite tapes at the mesoscopic scale.The results of the present GH-LR multi-scale approach agree well with those of the FR scheme and the experimental data in the literature,indicating that the present approach is accurate and efficient.The proposed GH-LR multi-scale approach can serve as a valuable tool for evaluating the risk of failure in large-scale HTS composite magnets.

Homogenization Construction of Three-Level Teaching Bases for General Practice Medicine Under the Internet+Model

With the continuous expansion of medical student enrollment,the number of clinical teaching bases is gradually increasing.However,there are significant differences in clinical teaching management models and teaching levels among different bases.Most clinical teaching bases have incomplete teaching management systems,inadequate teaching management institutions,insufficient teaching personnel,and inadequate implementation of teaching rules and regulations.This article combines the construction practice of three-level clinical teaching base of the General Medicine College and the First Affiliated Hospital of Xi’an Medical University.We establish a standardized management system for the three-level clinical teaching base;implement a teaching supervision system and strengthen the monitoring of teaching quality;adopt multiple evaluations to test the effectiveness of clinical teaching implementation;explore the path of homogenization construction of teaching bases in terms of unified teacher training,promoting the development of teacher teaching abilities with equal quality and excellence,and providing a reference for improving the quality of medical talent training.

On Enforcing Dyadic-type Homogeneous Binary Function Product Constraints in MatBase

Homogeneous binary function products are frequently encountered in the sub-universes modeled by databases,spanning from genealogical trees and sports to education and healthcare,etc.Their properties must be discovered and enforced by the software applications managing such data to guarantee plausibility.The(Elementary)Mathematical Data Model provides 17 types of dyadic-based homogeneous binary function product constraint categories.MatBase,an intelligent data and knowledge base management system prototype,allows database designers to simply declare them by only clicking corresponding checkboxes and automatically generates code for enforcing them.This paper describes the algorithms that MatBase uses for enforcing all 17 types of homogeneous binary function product constraint,which may also be employed by developers without access to MatBase.

Comparison of continuous homogenous azeotropic and pressure-swing distillation for a minimum azeotropic system ethyl acetate/nhexane separation

Continuous homogenous azeotropic distillation(CHAD) and pressure-swing distillation(PSD) are explored to separate a minimum-boiling azeotropic system of ethyl acetate and n-hexane. The CHAD process with acetone as the entrainer and the PSD process with the pressures of 0.1 MPa and 0.6 MPa in two columns are designed and simulated by Aspen Plus. The operating conditions of the two processes are optimized via a sequential modular approach to obtain the minimum total annual cost(TAC). The computational results show that the partially heat integrated pressure-swing distillation(HIPSD) has reduced in the energy cost and TAC by 40.79% and 35.94%, respectively, than the conventional PSD, and has more greatly reduced the energy cost and TAC by 62.61% and 49.26% respectively compared with the CHAD process. The comparison of CHAD process and partially HIPSD process illustrates that the partially HIPSD has more advantages in averting the product pollution, energy saving, and economy.

Finite Indeterminacy of Homogenous Polynomial Germs under Some Subgroups R_(I_r) of R

Using the finite determinacy relation with the regular sequence in the Ring Theory and the complete intersection in Analytic Geometry, the finite indeterminacy of homogeneous polynomial germs under some subgroups R1（r） of R in both real and complex case is proven by the homogeneity of the polynomial germs. It results in the finite determinacy of homogeneous polynomial germs needn＇t be discussed respectively.

Development of Electrospray Laser Chemical Vapour Deposition for Homogenous Alumina Coatings

Electrospray,as a liquid source supply system,has been applied to chemical vapour deposition（CVD）.In thermal CVD,the microstructure of the obtained films changes from dense to coarse granular because of the decreasing surface temperature during deposition.Using the electrospray laser chemical vapour deposition method,we prepared homogenous alumina coatings.We found that laser irradiation was effective in compensating the surface temperature decrease,and an alpha-alumina coating with dense columnar microstructures was obtained at a deposition rate of 200 μm/h using 200 W Nd：YAG laser irradiation.

Homogenous Balance Method and Exact Analytical Solutions for Whitham-Broer-Kaup Equations in Shallow Water

Based on the homogenous balance method and with the help of mathematica, the Backlund transformation and the transfer heat equation are derived. Analyzing the heat-transfer equation, the multiple soliton solutions and other exact analytical solution for Whitham-Broer-Kaup equations(WBK) are derived. These solutions contain Fan's, Xie's and Yan's results and other new types of analytical solutions, such as rational function solutions and periodic solutions. The method can also be applied to solve more nonlinear differential equations.

Interval grey number sequence prediction by using non-homogenous exponential discrete grey forecasting model

This paper aims to study a new grey prediction approach and its solution for forecasting the main system variable whose accurate value could not be collected while the potential value set could be defined. Based on the traditional nonhomogenous discrete grey forecasting model（NDGM）, the interval grey number and its algebra operations are redefined and combined with the NDGM model to construct a new interval grey number sequence prediction approach. The solving principle of the model is analyzed, the new accuracy evaluation indices, i.e. mean absolute percentage error of mean value sequence（MAPEM） and mean percent of interval sequence simulating value set covered（MPSVSC）, are defined and, the procedure of the interval grey number sequence based the NDGM（IG-NDGM） is given out. Finally, a numerical case is used to test the modelling accuracy of the proposed model. Results show that the proposed approach could solve the interval grey number sequence prediction problem and it is much better than the traditional DGM（1,1） model and GM（1,1） model.

Integrability of Hamiltonian Systems with Two Degrees of Freedom and Homogenous Potential of Degree Zero

We provide necessary conditions in order that the Hamiltonian systems with Hamiltonian ,?and one of the following potentials ?are integrable in the Liouville sense.

Influence of second phase precipitates on mechanical and in-vitro corrosion behaviour of Mg-4Zn-0.5Ca-0.8Mn alloy in optimum homogenized conditions

The present study investigates the mechanical and in-vitro corrosion behavior of Mg-4Zn-0.5Ca-0.8Mn alloy in optimum homogenized conditions.The optimization of the homogenization parameters has been carried out employing thermodynamic calculations and kinetic modeling.The model utilizes the inter-diffusivity of the solute elements and predicts that∼6–24 h of homogenization at 633 K effectively redistributes the elements in the Mg matrix.Based on the insights obtained from the simulations,the as-cast Mg-4Zn-0.5Ca-0.8Mn alloy was subjected to homogenization heat treatment process for 6–24h.The microstructural study through optical microscopy and scanning electron microscopy(SEM)revealed that the interconnected network of second phase precipitates substantially dissolve within 24 h,implying adequate homogenization.Moreover,fine Mg-Zn based precipitates with varied morphology and phase fractions also evolved during homogenization treatment,as confirmed through SEM and transmission electron microscopy.In the 12 h homogenized specimen,the highest fraction of uniformly dispersed fine precipitates resulted in the highest strength(∼225 MPa).On the other hand,a substantial disruption in coarse precipitate network and lower aspect ratio of fine Mg-Zn precipitates led to the highest ductility(∼8%)in this specimen.In the 24 h homogenized specimen,the ductility reduced marginally owing to higher aspect ratio of fine precipitates.The immersion and electrochemical tests(viz.,potentiodynamic polarization and electrochemical impedance spectroscopy)carried out in Hank’s solution revealed that the 24 h homogenized specimen exhibits the best corrosion properties.The least fraction of Ca_(2)Mg_(6)Zn_(3)phase with maximum disruption in interconnectivity,in combination with a small fraction of fine equilibrium MgZn_(2)precipitates,resulted in suppression of localized corrosion in this specimen.This promotes the formation of the most stable and compact product layer over the specimen,resulting in the highest corrosion resistance.