Influence of oxide scales on the corrosion behaviors of B510L hot-rolled steel strips

The influence of oxide scales on the corrosion behaviors of B510 L hot-rolled steel strips was investigated in this study. Focused ion beams and scanning electron microscopy were used to observe the morphologies of oxide scales on the surface and cross sections of the hot-rolled steel. Raman spectroscopy and X-ray diffraction were used for the phase analysis of the oxide scales and corrosion products. The corrosion potential and impedance were measured by anodic polarization and electrochemical impedance spectroscopy. According to the results, oxide scales on the hot-rolled strips mainly comprise iron and iron oxides. The correlation between mass gain and test time follows a power exponential rule in the damp-heat test. The corrosion products are found to be mainly composed of γ-Fe OOH, Fe3O4, ？-Fe OOH, and γ-Fe2O3. The contents of the corrosion products are different on the surfaces of the steels with and without oxide scales. The steel with oxide scales is found to show a higher corrosion resistance and lower corrosion rate.

Similarity evaluation model for the internal defect detection of strip steel

An internal defect meter is an instrument to detect the internal inclusion defects of cold-rolled strip steel.The detection accuracy of the equipment can be evaluated based on the similarity of the multiple detection data obtained for the same steel coil.Based on the cosine similarity model and eigenvalue matrix model,a comprehensive evaluation method to calculate the weighted average of similarity is proposed.Results show that the new method is consistent with and can even replace artificial evaluation to realize the automatic evaluation of strip defect detection results.

Deep learning for predictive mechanical properties of hot-rolled strip in complex manufacturing systems

Higher requirements for the accuracy of relevant models are put throughout the transformation and upgrade of the iron and steel sector to intelligent production.It has been difficult to meet the needs of the field with the usual prediction model of mechanical properties of hotrolled strip.Insufficient data and difficult parameter adjustment limit deep learning models based on multi-layer networks in practical applications;besides,the limited discrete process parameters used make it impossible to effectively depict the actual strip processing process.In order to solve these problems,this research proposed a new sampling approach for mechanical characteristics input data of hot-rolled strip based on the multi-grained cascade forest(gcForest)framework.According to the characteristics of complex process flow and abnormal sensitivity of process path and parameters to product quality in the hot-rolled strip production,a three-dimensional continuous time series process data sampling method based on time-temperature-deformation was designed.The basic information of strip steel(chemical composition and typical process parameters)is fused with the local process information collected by multi-grained scanning,so that the next link’s input has both local and global features.Furthermore,in the multi-grained scanning structure,a sub sampling scheme with a variable window was designed,so that input data with different dimensions can get output characteristics of the same dimension after passing through the multi-grained scanning structure,allowing the cascade forest structure to be trained normally.Finally,actual production data of three steel grades was used to conduct the experimental evaluation.The results revealed that the gcForest-based mechanical property prediction model outperforms the competition in terms of comprehensive performance,ease of parameter adjustment,and ability to sustain high prediction accuracy with fewer samples.

“Quartus scale” of hot-rolled strip steels and its formation mechanism

The types and growth of various oxide scales formed during the different phases of the production of hotrolled strip steel products are reviewed. Similarities and differences between the ＂tertiary scale＂ on the surface of carbon steels at high temperatures and the oxide scale on pure iron are compared. The micro-structural features of the ＂final oxide scale＂ on the surface of strip steels at room temperature as well as the relationship between these features and the position of the steel coil （plate） and the subsequent processes of recoiling, temper rolling and trimming, etc. are summarized. The actual oxide scales retained on the commercial hot-rolled strip steels at room temperature have been proposed to define as ＂ quartus scale＂ for the first time. The micro-structural development and phase transformation of the initial ＂tertiary scale＂ during and after cooling and coiling are described. The reasons for the ＂tertiary scale＂ on carbon steels differing from the oxide scale formed on pure iron, and the major influencing factors in the formation of various types of ＂quartus scales＂ are analyzed from both thermodynamic and dynamic viewpoints. The development mechanism of ＂ quartus scales＂ is discussed and the potential effects of the ＂ quartus scale＂ state （thickness, constitution, structure and defects）, on the rusting and pickling properties of commercial hot-rolled strip steel, as well as on the mechanical properties of oxide scales are analyzed.

Microstructures and Mechanical Properties of Nb-Ti Bearing Hot-rolled TRIP Steels

Nb-Tihot-rolled TRIP-assisted steel with high plasticity and appropriate volume percentage of retained austenite based on fine ferrite grain have been developed in the experiment. The test results showed that niobium tend to exist in solution state in matrix with less precipitation, and niobium-titanium could be precipitated in form of （Nb, Ti）C or （Nb, Ti） （C, N）, which play an important role in increasing yield strength （from 495 MPa to 610 MPa）. Besides, the retained austenite had a positive effect on improving the plasticity by transformation into martensite during tensile deformation.

Correlation of morphological anisotropy and Lankford value of deep drawing sheets hot-rolled by compact strip production

Cold-rolled steel sheets in automotive applications require an excellent deep draw ability, which is characterized by the Lankford value （r-value）. In this study, a correlation was identified between r-value and pancake-shaped grain flatness which is indicated as the ratio of grain diameter in the rolling direction （RD） and normal direction （ND） of sheets （dr/dn）. A mathematical model （ r = e^0.345（dn^1/2-dr^1/2） ） was developed to calculate r-value by the microstructure of steel sheets hot-rolled by compact strip production （CSP）. It is shown that the r-value is higher, if the microstructure of steel sheet is of pancake-shaped grains elongated in the rolling direction. The calculated r-value is confirmed to fit exactly to the measured one from the large-scale production.

Properties,Microstructures and Precipitate Morphology of Hot-rolled Interstital-Free(IF)Steel Sheets

In order to simplify production process and to decrease production cost of thicker cold-rolled iF steel sheets for deep drawing applications, a new hot-rolled IF steel sheet is developed through hot-rolling in or region. In this paper, properties, microstructures and precipitate morphology of hot-rolled iF steel sheets are described..

Hot-rolled strips of up to 19 mm in thickness and their processing to helically welded large diameter pipes of grade X80

Hot-rolled wide strip for production of large diameter,heavy gauged(up to 19 mm) helical line pipe grade X80 was a priority development over the last three years.Microstructure,texture and mechanical properties of strips have been characterised.Also the welding conditions have been simulated.The favourable microstructure is achieved by the proper selection of an appropriate chemical composition of low carbon content and increased niobium micro alloying in combination with suitable strictly controlled hot-rolling parameters.The addition of niobium in combination with the adjustment of other alloying elements increases the recrystallisation stop temperature and thus makes it possible to apply a high temperature processing(HTP) concept.The homogeneous bainitic microstructure across the strip gauge is then formed during accelerated cooling on the run-out table of the hot-rolling mill.All results indicated excellent properties of these hot strips which make it suitable for spiral pipes of grade X80 for example 18.9mm×Φ1 220 mm at dimension.

Rusting behavior and preventative measures of hot-rolled steel plates for automobile applications

As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufacturing, transportation and/or storage of the plates. General corrosion often takes place on the surface of a plate in the exterior part of a package, and only reduces the thickness of the plate and slightly increases the roughness of the surface; however, localized corrosion on the surface of a plate inside the package is likely to result in the formation of pit-like defects on the substrate of the plate, which cannot be removed thoroughly by normal acid pickling or sand blasting, and affects the application of the plate. This research report analyzes the phenomena and characteristics of the rusting behavior of hot- rolled steel plates for automobile applications, and the influencing factors are summaried. The corresponding preventative measures are proposed.

Mill scale structure and damp heat corrosion performance of four 510L hot-rolled strips

In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy （OM） ,scanning electron microscopy （SEM） and X-ray diffraction （XRD）. The corrosion behavior of the steels with and without mill scales were investigated by means of hot-humid corrosion tests under the condition of relative humidity （ RH ） of 95% at 50℃ and 70℃, respectively. The results show that the matrix structures, state, composition and thickness of mill scales vary in the strips. The rusting starting time of the specimens with scales is generally a bit longer than that of the specimens without scales, but their corrosion mass-gain is higher. For these two kinds of specimens ,their corrosion rate increases significantly with the increase of temperature. The rusting behavior of the 510L strips produced by various plants is different due to the variations of hot-rolling processes and designed chemical compositions. Various relevant aspects should be taken into account in the evaluation of the corrosion behavior of hot-rolled strips.

THE CHARACTERISTICS OF MICROSTRUCTURES AND PROPERTIES FOR ADVANCED ALUMINUM/SILICON CONTAINED HOT-ROLLED TRIP STEELS

The microstructure characteristics with super fine ferrite grain size less than 5mm, appropriate retained austenite fraction around 5.0% and or removable abundant dislocations have been obtained by controlled rolling and cooling, which leads to well balance com- prehensive properties with high tensile strength of 510 and 615MPa, high elongation of 40% and 27%, low ratio of yield strength to tensile strength 0.83 and 0.80, as well as low ductile- brittle transition temperature less than -80 and -70℃ for advanced aluminum hot-rolled TRIP steel and silicon hot-rolled TRIP steel, respectively.

Thermomechanical controlled processing of hot-rolled multiphase steel containing Nb

Influence of thermo-mechanical controlled processing(TMCP),including two-stage rolling with laminar cooling,air cooling and ultra-fast cooling,on the microstructure and mechanical properties of three kinds of Nb-microalloeyed steels was investigated by hot-rolling experiment.Effect of chemistry compositions and microstructure on mechanical properties and the relationship between the multiphase microstructure' s formation with TMCP were analyzed.The results showed that the mixed microstructure containing ferrite,bainite,martensite and a small amount of retained austenite can be obtained by thermo-mechanical controlled processing.Size, quantity and distribution of the constituents(ferrite grain,bainite packet and M-A islands) significantly affect the mechanical properties of three kinds of Nb-microalloyed steels.Under the condition of similar TMCP parameters, there is a gradually decreasing tendency in tensile strength from high silicon Nb steel,high silicon Nb-Ti steel to low silicon Nb-Ti steel,and an opposite tendency in total elongation and product of tensile strength and ductility. Total elongation and product of tensile strength and ductility reach the maximum values(41%and 25256 MPa% respectively) for low silicon Nb-Ti steel.

Patenting of hot-rolled high-carbon steel and its applications

The patenting process of three hot-rolled steels with carbon mass contents of 0.70%-0. 90% was studied. The effect of the quenching temperature on the cementite lamellar distance in the steel was evaluated on the basis of microstructural characterization and mechanical property tests. The patenting treatment of high-carbon hot- rolled strip and its application in springs were discussed.

Phase transformation behavior of a hot-rolled,titanium microalloyed steel during heating and continuous cooling

The critical transformation temperatures,A_(c1) and A_(c3),of a hot-rolled low-carbon titanium microalloyed steel were determined as a part of an examination of its phase-transformation behavior. Austenite decomposition during the continuous cooling of the titanium microalloyed steel was studied by heating it to 1 250 ℃,cooling it to 880 ℃,holding for 2 s,and then cooling it to room temperature at different cooling rates. The transformation kinetics( CCT curve) was characterized as well.

Research on welding technology of hot-rolled extra-high-strength steel developed by Baosteel

In this study, the welding technology of the hot-rolled extra-high-strength steel, BS960QC, has been comprehensively investigated. Analysis has been made on the weldability ,the different welding procedures ,the mechanical properties, and the fatigue properties, and a set of recommendation guidelines have been proposed for evaluating the welded joints of the extra-high-strength steel. The research and results indicate that the hot-rolled extra-high-strength steel, BS960QC,has good weldability and an excellent adaptability to welding procedures. Further,the excellent mechanical properties and fatigue properties of the welded joints ,which can be achieved by using optimized welding procedures, can completely meet the technical requirements of the construction machinery industry.

Microstructure and mechanical properties of the hot-rolled Fe16Mn0.6C steel plate

Results presented in this study contribute to investigation of the microstructure and mechanical properties of the hot-rolled Fe16Mn0.6C steel plates.The steel plates have been produced by being hot-rolled at temperatures ranging from 1100℃ to 850℃ in seven passes to 97.5% reduction in thickness and then cooled in a furnace of 650℃.Some plates have been annealed at temperatures ranging from 300℃ to 1100℃ for 5min to 60min,and then followed by water quenching.There are annealing twins in the hot-rolled Fe16Mn0.6C steel.Fe16Mn0.6C steel presents similar ductile behavior as X-IPTM steel,but much higher elongation than commercial martensitic steel (MP) 1000,dual phase (DP) 980,and transformation induced plasticity (TRIP) 980 steels.Fe16Mn0.6C steel experiences γε (-α) transformation in some local regions,but remains mostly austenite during the entire deformation process.Fe16Mn0.6C steel with special mechanical properties can be produced by using the appropriate anneal technology.Twinning induced plasticity(TWIP) effect only occurs in the Fe16Mn0.6C steel annealed at temperature higher than 900℃.

Development of Continuous Coating and Plating Strip Steel

The development trend of coated and plated technology for continuous strip steels,which include hot dip plating,electroplating,organic coating and vacuum plating technology,were summarized.

Numerical Simulation of Continuous Tension Leveling Process of Thin Strip Steel and Its Application

Cold-rolled thin strip steel of high flatness quality undergoes multistage deformation during tension leveling. Thus, the parameters of set-up and manipulating are more difficult. With the aid of FE code MSC. MARC, the tension leveling process of thin strip steel was numerically simulated. Concentrating on the influence of the roll intermeshes in 2# anti-cambering on the distribution and magnitude of residual stresses in leveled strip steel, several experiments were clone with the tension leveler based on the results from the simulation. It was found from the simulation that the magnitude of longitudinal residual stresses in the cross-section of the leveled strip steel regularly presents obvious interdependence with the roll intermeshes in 2# anti-cambering. In addition, there is a steady zone as the longitudinal residual stresses of the surface layers in leveled strip steel vary with the roll intermeshes of 2# anticambering, which is of importance in the manipulation of tension levelers. It was also found that the distribution of strains and stresses across the width of strip steel is uneven during leveling or after removing the tension loaded upon the strip, from which it was found that 3D simulation could not be replaced by 2D analysis because 2D analysis in this case cannot represent the physical behavior of strip steel deformation during tension leveling.

Solidification Structure of Low Carbon Steel Strips with Different Phosphorus Contents Produced by Strip Casting

In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail. It was found that the strips possessed a fine microstructure compared with the mould cast steels. With increasing phosphorus content more ferrite has been formed with finer grains.

Effect of hot stamping parameters on the mechanical properties and microstructure of cold-rolled 22MnB5 steel strips

Thermomechanical experiments were carried out to reproduce the hot stamping process and to investigate the effects of process parameters on the microstructure and mechanical properties of stamped parts. The process parameters, such as austenitizing temperature, soaking time, initial deformation temperature and cooling rate, are studied. The resulting microstructures of specimens were observed and analyzed. To evaluate the mechanical properties of specimens, tensile and hardness tests were also performed at room temperature. The op-timum parameters to achieve the highest tensile strength and the desired microstructure were acquired by comparing and analyzing the results. It is indicated that hot deformation changes the transformation characteristics of 22MnB5 steel. Austenite deformation promotes the austen-ite-to-ferrite transformation and elevates the critical cooling rate to induce a fully martensitic transformation.