The types and growth of various oxide scales formed during the different phases of the production of hotrolled strip steel products are reviewed. Similarities and differences between the "tertiary scale" on the surf...The types and growth of various oxide scales formed during the different phases of the production of hotrolled strip steel products are reviewed. Similarities and differences between the "tertiary scale" on the surface of carbon steels at high temperatures and the oxide scale on pure iron are compared. The micro-structural features of the "final oxide scale" on the surface of strip steels at room temperature as well as the relationship between these features and the position of the steel coil (plate) and the subsequent processes of recoiling, temper rolling and trimming, etc. are summarized. The actual oxide scales retained on the commercial hot-rolled strip steels at room temperature have been proposed to define as " quartus scale" for the first time. The micro-structural development and phase transformation of the initial "tertiary scale" during and after cooling and coiling are described. The reasons for the "tertiary scale" on carbon steels differing from the oxide scale formed on pure iron, and the major influencing factors in the formation of various types of "quartus scales" are analyzed from both thermodynamic and dynamic viewpoints. The development mechanism of " quartus scales" is discussed and the potential effects of the " quartus scale" state (thickness, constitution, structure and defects), on the rusting and pickling properties of commercial hot-rolled strip steel, as well as on the mechanical properties of oxide scales are analyzed.展开更多
As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufact...As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufacturing, transportation and/or storage of the plates. General corrosion often takes place on the surface of a plate in the exterior part of a package, and only reduces the thickness of the plate and slightly increases the roughness of the surface; however, localized corrosion on the surface of a plate inside the package is likely to result in the formation of pit-like defects on the substrate of the plate, which cannot be removed thoroughly by normal acid pickling or sand blasting, and affects the application of the plate. This research report analyzes the phenomena and characteristics of the rusting behavior of hot- rolled steel plates for automobile applications, and the influencing factors are summaried. The corresponding preventative measures are proposed.展开更多
In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy (OM) ,scanning electro...In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy (OM) ,scanning electron microscopy (SEM) and X-ray diffraction (XRD). The corrosion behavior of the steels with and without mill scales were investigated by means of hot-humid corrosion tests under the condition of relative humidity ( RH ) of 95% at 50℃ and 70℃, respectively. The results show that the matrix structures, state, composition and thickness of mill scales vary in the strips. The rusting starting time of the specimens with scales is generally a bit longer than that of the specimens without scales, but their corrosion mass-gain is higher. For these two kinds of specimens ,their corrosion rate increases significantly with the increase of temperature. The rusting behavior of the 510L strips produced by various plants is different due to the variations of hot-rolling processes and designed chemical compositions. Various relevant aspects should be taken into account in the evaluation of the corrosion behavior of hot-rolled strips.展开更多
To overcome the inaccuracy problem of the traditional wedge evaluation of steel plates and strips caused by the ran-domness of the thicknesses of two local points and improve the reliability of the wedge index,the dou...To overcome the inaccuracy problem of the traditional wedge evaluation of steel plates and strips caused by the ran-domness of the thicknesses of two local points and improve the reliability of the wedge index,the double-centroid method for the wedge evaluation was proposed,and a model based on the centroid theory was established.Meanwhile,an integral model for the discrete thickness values of the cross-section profiles was derived.The discussion focused on the distinct characteristics of the two-point method,asymmetric method,and double-centroid method in evaluating the asymmetric distribution of cross-sections.The three methods were employed to evaluate the wedge values of both the theoretical and measured cross-sections of steel plates and strips,and the accuracies of three wedge evaluation models were analyzed and discussed.The results showed that the double-centroid method objectively reflects the degree and variation characteristics of the wedge values of the cross-sections of steel plates and strips,and this method is feasible,reliable,and outstanding.展开更多
The development trend of coated and plated technology for continuous strip steels,which include hot dip plating,electroplating,organic coating and vacuum plating technology,were summarized.
A new method,the stream surface strip element method,for simulating the three-dimensional deformation of plate and strip rolling process was proposed.The rolling deformation zone was divided into a number of stream su...A new method,the stream surface strip element method,for simulating the three-dimensional deformation of plate and strip rolling process was proposed.The rolling deformation zone was divided into a number of stream surface(curved surface)strip elements along metal flow traces,and the stream surface strip elements were mapped into the corresponding plane strip elements for analysis and computation.The longitudinal distributions of the lateral displacement and the altitudinal displacement of metal were respectively constructed to be a quartic curve and a quadratic curve,of which the lateral distributions were expressed as the third-power spline function,and the altitudinal distributions were fitted in the quadratic curve.From the flow theory of plastic mechanics,the mathematical models of the three-dimensional deformations and stresses of the deformation zone were constructed.Compared with the streamline strip element method proposed by the first author of this paper,the stream surface strip element method takes into account the uneven distributions of stresses and deformations along altitudinal direction,and realizes the precise three-dimensional analysis and computation.The simulation example of continuous hot rolled strip indicates that the method and the model accord with facts and provide a new reliable engineering-computation method for the three-dimensional mechanics simulation of plate and strip rolling process.展开更多
The development trend of coated and plated technology for continuous strip steels, which include hot dip plating, electroplating, organic coating and vacuum plating technology, were summarized
The non-vacuum roll bonding method of nickel plating on the base materials is put forward in accordance with the primary problems existed in the roll bonding of stainless/carbon steel. After nickel plating test on the...The non-vacuum roll bonding method of nickel plating on the base materials is put forward in accordance with the primary problems existed in the roll bonding of stainless/carbon steel. After nickel plating test on the base materials, the microstructure of nickel cladding is observed by scanning electron microscopy (SEM) at high, and room temperature, and the results show that the nickel cladding on base material can be protected from oxidation in the high temperature. Non-vacuum roll bonding tests of nickel plating on base materials are done by the roll bonding equipment, and the roll bonding plates of stainless/carbon steel are obtained. The microstructure and the elements distribution of non-vacuum roll bonding interface are analyzed by optical microscope (OM) and SEM. The results reflect that the nickel plating layer and the base materials bond well.展开更多
A new hot-dip galvanizing method was employed on hot-rolled low carbon steel.The effects of Al contents on microstructure,micro-hardness and corrosion resistance of Zn-Al alloy coatings were systematically investigate...A new hot-dip galvanizing method was employed on hot-rolled low carbon steel.The effects of Al contents on microstructure,micro-hardness and corrosion resistance of Zn-Al alloy coatings were systematically investigated.Phase composition,microstructure and element distribution in Zn-Al alloy coatings were analyzed using X-ray diffraction(XRD)and electron probe micro analysis(EPMA),respectively.It is found that Al content(0.6-6.0 wt.%)in galvanizing zinc affects surface quality and adhesion between coatings and matrix in the newly developed method.In addition,with increasing Al content,micro-hardness significantly increased due to the increase in Zn-Al eutectoid phases.Potentiodynamic polarization and electrochemical impedance spectroscopy(EIS)also revealed that increase in Al plays a noticeable role in improving the corrosion resistance of Zn-Al alloy coatings.展开更多
文摘The types and growth of various oxide scales formed during the different phases of the production of hotrolled strip steel products are reviewed. Similarities and differences between the "tertiary scale" on the surface of carbon steels at high temperatures and the oxide scale on pure iron are compared. The micro-structural features of the "final oxide scale" on the surface of strip steels at room temperature as well as the relationship between these features and the position of the steel coil (plate) and the subsequent processes of recoiling, temper rolling and trimming, etc. are summarized. The actual oxide scales retained on the commercial hot-rolled strip steels at room temperature have been proposed to define as " quartus scale" for the first time. The micro-structural development and phase transformation of the initial "tertiary scale" during and after cooling and coiling are described. The reasons for the "tertiary scale" on carbon steels differing from the oxide scale formed on pure iron, and the major influencing factors in the formation of various types of "quartus scales" are analyzed from both thermodynamic and dynamic viewpoints. The development mechanism of " quartus scales" is discussed and the potential effects of the " quartus scale" state (thickness, constitution, structure and defects), on the rusting and pickling properties of commercial hot-rolled strip steel, as well as on the mechanical properties of oxide scales are analyzed.
文摘As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufacturing, transportation and/or storage of the plates. General corrosion often takes place on the surface of a plate in the exterior part of a package, and only reduces the thickness of the plate and slightly increases the roughness of the surface; however, localized corrosion on the surface of a plate inside the package is likely to result in the formation of pit-like defects on the substrate of the plate, which cannot be removed thoroughly by normal acid pickling or sand blasting, and affects the application of the plate. This research report analyzes the phenomena and characteristics of the rusting behavior of hot- rolled steel plates for automobile applications, and the influencing factors are summaried. The corresponding preventative measures are proposed.
文摘In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy (OM) ,scanning electron microscopy (SEM) and X-ray diffraction (XRD). The corrosion behavior of the steels with and without mill scales were investigated by means of hot-humid corrosion tests under the condition of relative humidity ( RH ) of 95% at 50℃ and 70℃, respectively. The results show that the matrix structures, state, composition and thickness of mill scales vary in the strips. The rusting starting time of the specimens with scales is generally a bit longer than that of the specimens without scales, but their corrosion mass-gain is higher. For these two kinds of specimens ,their corrosion rate increases significantly with the increase of temperature. The rusting behavior of the 510L strips produced by various plants is different due to the variations of hot-rolling processes and designed chemical compositions. Various relevant aspects should be taken into account in the evaluation of the corrosion behavior of hot-rolled strips.
基金supported by the National Natural Science Foundation of China (Grant No.52305405)the Natural Science Foundation Research Program of Shanxi Province (Grant No.202203021222121)+4 种基金the Major Project of Science and Technology of Shanxi Province (Grant No.20181102016)the Chinese Postdoctoral Science Foundation (Grant No.2021M702544)the Central Government Guides the Special Fund Projects of Local Scientific and Technological Development (YDZX20191400002149)the Open Project of Research Institute of Hai'an-Taiyuan University of Technology (Grant No.2023HA-TYUTKFYF008)the School Fund of Taiyuan University of Technology (Grant No.2022QN007).
文摘To overcome the inaccuracy problem of the traditional wedge evaluation of steel plates and strips caused by the ran-domness of the thicknesses of two local points and improve the reliability of the wedge index,the double-centroid method for the wedge evaluation was proposed,and a model based on the centroid theory was established.Meanwhile,an integral model for the discrete thickness values of the cross-section profiles was derived.The discussion focused on the distinct characteristics of the two-point method,asymmetric method,and double-centroid method in evaluating the asymmetric distribution of cross-sections.The three methods were employed to evaluate the wedge values of both the theoretical and measured cross-sections of steel plates and strips,and the accuracies of three wedge evaluation models were analyzed and discussed.The results showed that the double-centroid method objectively reflects the degree and variation characteristics of the wedge values of the cross-sections of steel plates and strips,and this method is feasible,reliable,and outstanding.
文摘The development trend of coated and plated technology for continuous strip steels,which include hot dip plating,electroplating,organic coating and vacuum plating technology,were summarized.
基金Sponsored by National Natural Science Foundation of China(50175095)Provincial Natural Science Foundation of Hebei of China(502173)
文摘A new method,the stream surface strip element method,for simulating the three-dimensional deformation of plate and strip rolling process was proposed.The rolling deformation zone was divided into a number of stream surface(curved surface)strip elements along metal flow traces,and the stream surface strip elements were mapped into the corresponding plane strip elements for analysis and computation.The longitudinal distributions of the lateral displacement and the altitudinal displacement of metal were respectively constructed to be a quartic curve and a quadratic curve,of which the lateral distributions were expressed as the third-power spline function,and the altitudinal distributions were fitted in the quadratic curve.From the flow theory of plastic mechanics,the mathematical models of the three-dimensional deformations and stresses of the deformation zone were constructed.Compared with the streamline strip element method proposed by the first author of this paper,the stream surface strip element method takes into account the uneven distributions of stresses and deformations along altitudinal direction,and realizes the precise three-dimensional analysis and computation.The simulation example of continuous hot rolled strip indicates that the method and the model accord with facts and provide a new reliable engineering-computation method for the three-dimensional mechanics simulation of plate and strip rolling process.
文摘The development trend of coated and plated technology for continuous strip steels, which include hot dip plating, electroplating, organic coating and vacuum plating technology, were summarized
文摘The non-vacuum roll bonding method of nickel plating on the base materials is put forward in accordance with the primary problems existed in the roll bonding of stainless/carbon steel. After nickel plating test on the base materials, the microstructure of nickel cladding is observed by scanning electron microscopy (SEM) at high, and room temperature, and the results show that the nickel cladding on base material can be protected from oxidation in the high temperature. Non-vacuum roll bonding tests of nickel plating on base materials are done by the roll bonding equipment, and the roll bonding plates of stainless/carbon steel are obtained. The microstructure and the elements distribution of non-vacuum roll bonding interface are analyzed by optical microscope (OM) and SEM. The results reflect that the nickel plating layer and the base materials bond well.
基金the National Science and Technology Pillar Program of China (2011BAE13B04)National Natural Science Foundation of China(51204047and U1660117)Fundamental Research Funds for the Central Universi-ties of China(N130407004)for the financial support
文摘A new hot-dip galvanizing method was employed on hot-rolled low carbon steel.The effects of Al contents on microstructure,micro-hardness and corrosion resistance of Zn-Al alloy coatings were systematically investigated.Phase composition,microstructure and element distribution in Zn-Al alloy coatings were analyzed using X-ray diffraction(XRD)and electron probe micro analysis(EPMA),respectively.It is found that Al content(0.6-6.0 wt.%)in galvanizing zinc affects surface quality and adhesion between coatings and matrix in the newly developed method.In addition,with increasing Al content,micro-hardness significantly increased due to the increase in Zn-Al eutectoid phases.Potentiodynamic polarization and electrochemical impedance spectroscopy(EIS)also revealed that increase in Al plays a noticeable role in improving the corrosion resistance of Zn-Al alloy coatings.