SYNTHESIS,CHARACTERIZATION,THERMAL DEGRADATION AND ELECTRICAL CONDUCTIVITY OF OLIGO[2-(2-HYDROXYPHENYLIMINOMETHYLBENZYLIDENE)AMINOPHENOL]AND OLIGOMER-METAL COMPLEXES

The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP)has been accomplished by using air O_2 and NaOCl oxidants in an aqueous alkaline medium between 50-90℃.The optimum reaction conditions of the oxidative polycondensation and the main parameters of the process were established.At the optimum reaction conditions,yield of the products were found to be 67.72% and 61.49% for air O_2 and NaOCl oxidants respectively.The structures of the monomer ...

The Efficiency of Multi-Range Hydro-Mechanical Stepless Transmission

Aim To determine efficiency of multi-range hydro-mechanical stepless transmis- sion(HMT).Methods Ageneral model of HMT was of HMT was structured.On the basis of power flow analysis, the efficiency was obtained,Results efficiency of multi-range HMT changes continuously with output speed in speed range and is higher than the highest point of the hydraulic efficiency,The volumetric efficiency can potentially result in the speed fluctuation, which can be reduced or eliminated through controlling the ratio of the displacements ofhydraulic unity properly or changing the point of range exchanging .And the mechanical- constant output torque or different output torque under the condition of constant pressure when the transmission works in different parts of a range,Conclusion The multi-range HMT is an ideal stepless transmission with high efficiency.

Effect of aging in an electric field on microstructures and properties of 1420 Al-Li alloy

After solution treatment, the 1420 Al-Li alloy samples were aged at different temperatures in an electric field with different intensity. The measurements made showed that the electric field increased the strength of the 1420 Al-Li alloy, and best properties were obtained when they were aged at 120 ℃ with E=4 kV/cm for 12 hrs. The electric field promoted the nucleation of δ′ phase, increased the quantity of the δ′ phase, and made the size of the δ′ phase particles smaller. The electric field restrained the formation and growth of PFZ, and increased the intensity of the electric field while the width of the PFZ was decreased.

Doping dependent metal to insulator transition in the(Bi,Pb)-2212 system:The evolution of structural and electronic properties with europium substitution

The present work investigates the effect of europium substitution on the （Bi, Pb）-2212 system in the concentration range 0.5 ≤ x ≤1.0. Phase analysis and lattice parameter calculations on the powder diffraction data and the elemental analysis of EDX show that the Eu atoms are successfully substituted into the （Bi, Pb）-2212 system. Resistivity measurements （64-300 K） reveal that the system exhibits superconductivity at x ≤ 0.5 and semiconductivity at x 〉 0.5. With the complete suppression of superconductivity which is known to be a quasi-two dimensional phenomenon in these materials, a metal to insulator transition takes place at x = 0.6 and the predominant conduction mechanism is found to be variable range hopping between localized states, resulting in macroscopic semiconducting behaviour. The results of electrical and structural properties of the doped （Bi, Pb）-2212 compounds suggest that the decrease of charge carrier concentration and the induced structural disorder are the more effective and dominant mechanisms in the origin of the metal to insulator transition and suppression of superconductivity due to Eu substitution at its Sr site.

Thermoelectric properties of Sr_(0.61)Ba_(0.39)Nb_2O_(6-δ) ceramics in different oxygen-reduction conditions

The thermoelectric properties of Sr0.61Ba0.39Nb2O6-δ ceramics, reduced in different conditions, are investigated in the temperature range from 323 K to 1073 K. The electrical transport behaviors of the samples are dominated by the thermal-activated polaron hopping in the low temperature range, the Fermi glass behavior in the middle temperature range, and the Anderson localized behavior in the high temperature range. The thermal conductivity presents a plateau at high- temperatures, indicating a glass-like thermal conduction behavior. Both the thermoelectric power factor and the thermal conductivity increase with the increase of the degree of oxygen-reduction. Taking these two factors into account, the oxygen-reduction can still contribute to promoting the thermoelectric figure of merit. The highest ZT value is obtained to be -0.19 at 1073 K in the heaviest oxygen reduced sample.

Study on Rare Earth Electrolyte of Ce_(0.9)RE_(0.1)O_(2-δ) (RE=Pr, Nd, Sm, Gd, Dy)

The solid solutions Ce_(0.9)RE_(0.1)O_(2-δ)(RE=Pr, Nd,Sm, Gd, Dy) were prepared by sol-gel method. The XRD measurement shows that the solid solution is crystallized in cubic fluorite-type structure and the cell volume of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE. The ionic conduction for Ce_(0.9)RE_(0.1)O_(2-δ) was measured by impedance spectroscopy and Ce_(0.9)Pr_(0.1)O_(2-δ) has better conductivity. The linear thermal expansion of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE.

Off-Shore Sea Surface Electric Field Investigations around the Indian Sub-Continent during 9-20 May 1983

Sea surface electric field observations off the coast from Goa (15°25'N, 73°47'E) to Madras (13°04'N, 80°15'E) around Sri Lanka, in a distance range 25-135 km from coast, during 9-20 May 1983 were taken. In this paper we have examined the diurnal variation of electric field in the Arabian Sea, Indian Ocean and Bay of Bengal regions covered during the cruise of the research ship ORV Gaveshani. An aspect of electric field dependence on coastal distance and Aitken Nuclei concentration has also been studied. An attempt to examine the latitude dependence of field was also made. Results obtained in the above studies are presented and compared with those obtained elsewhere.

SYNTHESIS,CHARACTERIZATION,THERMAL DEGRADATION AND ELECTRICAL CONDUCTIVITY OF OLIGO[2-(THIEN-2-YLMETHYLENE)AMINOPHENOL]AND OLIGOMER-METAL COMPLEXES

The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental analysis.TGA-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for characterization.The ~1H-NMR and ^(13)C-NMR data show that the polymeriz...

DK7732-1 Electric Spark CNC Wire-Cuffing Machine

The machine tool is one of the new products developed and produced by the Shanghai No.8 Machine Tool Plant. It adopts a lift adjustable wiretrame and molybdenum filament tensioning mechanism with large cutting thickness and high machining precision. It is equipped with an advanced IBM-PC 386 microcomputer-controlled system, with strong performance and CRT display. Man/

Elaboration of the Hydro-Geophysics GIS Showing the Volubilis Depression and the Prerifains Ridges Structuration (Morocco North Occidental)

We present a comparative analysis of electrical and gravity data on the Geographic Information System of the prerifaines ridges. At the Meso-Cenozo?c sequence, the geometry of the prerifaines ridges is fairly well known. However, the post-Miocene series remain to be characterized. In this perspective, we use a database composed of gravity and vertical electrical sounding profiles and geo-electrical sections in order to characterize this structuration. These data are calibrated by many oil and hydrogeological boreholes. Preliminary results lead to better understanding of the organization of its underlying structures in this area. The Gravimetric filtering results show that the area may be dissected by tree major faults striking NW-SE, NE-SW and N-S. All these faults have contributed, since Hercynian to Alpines orogenies, to the structuring of this area, being proved to be the deepest and can reach 4500 m. The comparison of gravity maps, geological and structural maps under Geographic Information System allows the identification of major structural directions and trends of the study area. It confirms some structural elements gathered from outcrops and define new ones. Results from this work show the importance of using various filtering and interpretation techniques in the analysis of gravity data. They also provide news insights into the deep structure of the study area.

Optimal Scheduling Strategy for Energy Consumption Minimization of Hydro-Thermal Power Systems

A comparison analysis based method for computing the water consumption volume needed for electric energy production of optimal scheduling in hydro-thermal power systems is presented in this paper. The electric energy produced by hydroelectric plants and coal-fired plants is divided into 4 components: potential energy, kinetic energy, water-deep pressure energy and reservoir energy. A new and important concept, reservoir energy, is proposed, based on which is divided into a number of water bodies, for example 3 water bodies, and a reservoir is analyzed in a new way. This paper presents an optimal scheduling solution of elec-tric energy production of hydro-thermal power systems based on multi-factors analytic method, in which some important factors, such as load demand, reservoir in-flow, water consumption volume increment rate of hydroelectric plants or converted from coal-fired plants, and so on are given to model the objective function and the constraints. A study example with three simulation cases is carried out to illustrate flexibility, adapta-bility, applicability of the proposed method.

Synthesis and Electrical Properties of La_(0.6)M_(0.4)FeO_(3-δ)(M=Ca, Sr, Ba) as Cathodes for SOFCs

A series samples of La0.6M0.4FeO3-δ （M = Ca, Sr, process （GNP）. FTIR, TG-DSC, XRD and TEM techniques Ba） perovskite-type oxides were prepared by glycine nitrate were used to characterize the chemical constitution, thermal stability and phase structure. The electrical conductivity of the samples was investigated by four-probe technique. With the increase of substituted-ionic radius, the temperature of phase formation increases, and the solid solubility decreases gradually, respectively. The La0.6Ca0.4FeO3-δ（LCF）powder is pure cubic perovskite-type crystalline after fired at 850℃ for 2 h. The XRD patterns of La0.6Sr0.4FeO3-δ（LSF） powder shows a small quantity of SrO peaks sintered at 1050℃ for 2 h. The electrical conductivity of LCF and LSF at 500 - 800℃ is over 100 S·cm^ - 1, and the value of LCF is 1170 S·cm^ - 1 at 800℃, which indicate that LCF and LSF may be used as a profitable cathode for IT-SOFCs. The characteristic of La0.6 Ba0.4FeO3-δ（LBF） is poor, and the electrical conductivity at intermediate temperatures is 1/20 less than that of LSF.

Variations in the Atmospheric Electric Field at Tropical Station during 1930-1987

The variations noticed in the atmospheric electric field recorded at Pune (18°32'N, 73°51'E, 559 m ASL), a tropical inland station located in Dcccan Plateau, India, during the period 1930-1987, have been examined in relation to the variations observed in the Angstrom turbidity coefficient (β) and selected meteorological parameters. The monthly and annual mean values of the atmospheric electric field. Angstrom turbidity coefficient (β), rainfall, temperature and relative humidity for the years 1930-1938, 1957-1958, 1964-1965, 1973-1974 and 1987 were considered in the study.The results of the above study indicated gradual increases in the atmospheric electric field over the period of study (1930-1987) which is statistically significant at less than 5%level. The increases noticed during different periods varied from 30 to 109%. The increase noticed during the period (1930-1938) and (1973-1974) was maximum (109%). The Angstrom turbidity coefficient also showed systematic increases during the period of study, which is consistent. The diurnal curve of the atmospheric electric field at the station by and large, showed a double oscillation, which is generally observed in the conlinental environments.

Electrical Properties of La_(0.8)Sr_(0.2)Co_(1-y)Fe_yO_(3-δ) for SOFC Cathodes

La0.8Sr0.2Co1-yFeyO3-δ (y=0.2, 0.4, 0.6, 0.8) powders were synthesized by ethylenediamine tetraacetic acid (EDTA) complexing sol-gel process. The powders were characterized via X-ray diffraction (XRD) and scanning electron microscope and energy dispersive X-ray spectroscopy (SEM-EDS). The results showed that single-phased perovskite-type oxide powders with small particle size were obtained by the process, and the compositions of the productions agreed with the designed molar ratio. The electronic conductivity and ionic conductivity of La0.8Sr0.2Co1-yFeyO3-δ were investigated by DC four-terminal method and AC impedance spectroscopy, respectively. The electronic conductivity of La0.8Sr0.2Co1-yFeyO3-δ is approximately 2～4 orders of magnitude higher than the ionic conductivity. It was confirmed that the conductivities of the materials were strongly influenced by the composition anions, temperature and sample preparing process.

Development of a Full Parameterized FE-modeling Tool for Efficient Vibration Investigations on End Windings of Turbo- and Hydro-Generators

End windings of generators are excited to vibrations due to electromagnetic forces which can cause severe damage and noise. To avoid this, it is important to predict the natural frequencies and modes of the end windings with finite elements. Due to the complex structure and unknown boundary conditions, the conventionally calculation of stator end windings has been very difficult and time consuming up to now. This paper describes the development of a full parameterized modeling tool, which allows a quick calculation of natural frequencies during the design phase of the generator. To keep the computing time low, it is important to find a way to get exact calculation results without detailed modeling of all pans. Additionally, special attention was paid to the active part, which has been replaced by spring-damper elements, and the determination of their stiffness via experimental modal analysis combined with finite element calculations.

Effects of Electrical Stimulation During Absolute Refractory Period on Contraction and Relaxation of Cardiomyocytes from Normal Guinea - pigs

Objectives To investi-gate the effect of electrical stimulation during absolute refractory period on contraction and relaxation of ventricular myocytes from normal guinea - pigs. Methods The guinea - pig ventricular myocytes were obtained by enzyme digesting, and the extent of its contraction and relaxation and Ca2+ transient were recorded through the motion edge detection system. Results (1) The contracting extent of guinea - pig ventricular myocytes increased 15.45±6.48% , and the peak velocity of shorting (contraction) and the peak veloci ty of relengthening (relaxation) increased 15.97 ± 8.37% and 21. 63±8. 06% respectively (n = 10); (2) The extent of ventricular myocytes fluorescence ra tio(360/380) (F360/F380) increased 22. 55±9. 08%, and the peak velocity of ventricular myocytes F360 /F380 increased 36. 75 ± 9. 77% and 23. 62±4. 47% during shorting and relengthening respectively (n = 6) . Conclusions Appropriate electrical stimulation may strengthen the contracting and relaxing function of normal guinea - pig ventricular myocytes.

Visualizing the Spin & Radiation of the Extended Electron in Magnetic Field

This article presents illustrations of an extended model of the electron to visualize how it spins and radiates in the external magnetic field. A time-varying magnetic field B produces a rotational induced electric field E which rotates (spins) the electron about its axis. In time-constant magnetic field: the electron radiates the cyclotron radiation. In time-varying magnetic field: synchrotron radiation is generated. The couplings between spin, acceleration and radiation will be discussed.

电位-pH图在湿法冶金中的应用

阐述电位-pH图在湿法冶金中的应用,同时预测其在湿法冶金中的发展趋势。

基于电力市场背景的风-光-抽水蓄能联合优化运行

为提高可再生能源在电力市场的竞争力,基于风光互补特性构建了风光抽蓄联合运行系统,提出一种可再生能源参与电力市场竞争的策略,进而提出一种基于电力市场背景的风电-光伏-抽水蓄能联合运行优化方法。该方法以风光发电企业经济效益最大为优化目标,考虑抽水蓄能电站机组技术约束和联合系统运行约束,采用改进遗传算法优化计算得到抽水蓄能电站和联合系统的运行方案。基于该优化方法自主开发了一款优化软件作为仿真平台,利用该平台通过算例分析验证了所提出的风光抽水蓄能联合运行优化方法的可行性与有效性。

计入负荷时空转移特性的风-光-水-蓄互补系统容量配置方法

利用梯级水电的快速调节能力和抽蓄机组发电/抽水工况灵活转换的特性,在补偿风/光出力的波动性和不可控性的基础上,建立源端风-光-水-蓄系统互补模型,以增强发电系统的调节能力。同时,在计入现货电价、考虑负荷时间和空间可转移特性的基础上,建立负荷侧模型并在考虑源端风/光出力随机性、系统网络约束基础上,提出基于系统经济性、系统状态均匀度和负荷跟踪等多项系统指标的源-网-荷互动策略。在上述研究基础上,进一步建立互补发电系统多目标容量配置模型。最后通过算例仿真,并利用专业优化软件LINGO进行求解,得到不同规划年和场景下的源端互补系统配置容量,验证了所提方法对系统指标提升的有效性。