Rock-Eval pyrolysis and Py-GC experiments on naturally and artificially matured coal samples were carried out. The results suggest that both depolymerization and defuctionalization exist during the maturation and evol...Rock-Eval pyrolysis and Py-GC experiments on naturally and artificially matured coal samples were carried out. The results suggest that both depolymerization and defuctionalization exist during the maturation and evolution of coal. The patterns of hydrocarbon regeneration are diverse at different stages of the maturation and evolution. When the vitrinite reflectance (R0) is 0.7%-0.9%, bitumen is the richest in coal while activation energy is the minimum, and the temperature of peak yield is lower than that of primary hydrocarbon generation. However, if reflectance is greater than 0.9%, defunctionalization predominates and the temperature of peak regeneration is shown in lagging compared with the primary hydrocarbon generation. When reflectance is out of the “oil window”, the peak temperature of hydrocarbon regeneration and that of the primary hydrocarbon generation seems to be continuous.展开更多
Recently,crystalline porous materials such as metal-organic frameworks（MOFs）and covalent organic frameworks（COFs）have attracted much interest not only in chemistry but also in materials science due to their tunabl...Recently,crystalline porous materials such as metal-organic frameworks（MOFs）and covalent organic frameworks（COFs）have attracted much interest not only in chemistry but also in materials science due to their tunable structures and functional channels.They have some inherent disadvantages of being difficult to solution process and recovery,which might limit their wide usage.展开更多
基金This project was granted financial support from the China Postdoctoral Science FoundationChinese National Key Science and Technology Project(96-110-01-02).
文摘Rock-Eval pyrolysis and Py-GC experiments on naturally and artificially matured coal samples were carried out. The results suggest that both depolymerization and defuctionalization exist during the maturation and evolution of coal. The patterns of hydrocarbon regeneration are diverse at different stages of the maturation and evolution. When the vitrinite reflectance (R0) is 0.7%-0.9%, bitumen is the richest in coal while activation energy is the minimum, and the temperature of peak yield is lower than that of primary hydrocarbon generation. However, if reflectance is greater than 0.9%, defunctionalization predominates and the temperature of peak regeneration is shown in lagging compared with the primary hydrocarbon generation. When reflectance is out of the “oil window”, the peak temperature of hydrocarbon regeneration and that of the primary hydrocarbon generation seems to be continuous.
文摘Recently,crystalline porous materials such as metal-organic frameworks（MOFs）and covalent organic frameworks（COFs）have attracted much interest not only in chemistry but also in materials science due to their tunable structures and functional channels.They have some inherent disadvantages of being difficult to solution process and recovery,which might limit their wide usage.
