Several media report highlight on that the pharmaceutical companies require ultra-low temperatures -80<span style="white-space:nowrap;">°</span>C to transport and store its COVID-19 vaccines...Several media report highlight on that the pharmaceutical companies require ultra-low temperatures -80<span style="white-space:nowrap;">°</span>C to transport and store its COVID-19 vaccines. This research presents the thermodynamic analysis on cascade refrigeration system (CRS) with several refrigerant pairs which are R32/R170, R123/R170, R134a/R170, R404A/R170, R407c/R170, R410/R170, and the hydrocarbon (HC) refrigerant pair Propane/Ethane, namely R290/R170. Besides, the results of R22/R170 pair, which is not recommended to be used due to phase out of R22 as per Montréal Protocol, are included as base case to compare the novel hydrocarbon pairs in CRS and the old trend of refrigerant pairs. Thermodynamic properties of all these pairs were investigated and compared under different intermediate temperature used in CRS heat exchanger, which thermally connected both the Low and High temperature cycles (LTC) and (HTC). By applying the first law of thermodynamics, the coefficients of performance (COPs) and the specific power consumptions (SPC) in kW/TR are presented and compared. In addition, by applying the second law of thermodynamics the exergetic efficiencies were estimated. The results reveal the promising opportunity of using the HC pair (R290/R170). The minimum SPC in kW/TR is recorded for the pair R123/R170. One the other hand, the highest exegetic efficiency values are observed to be 40%, 38%, and 35% for the pairs R123/R170, R290/R170, and R134/R170, respectively. This research concludes that the HC pair (R290/R170) is highly recommended for CRS applications either to transport the COVID-19 or store it in cold storage rooms in hospitals and clinics. All precautionary measures should be carefully applied in design and operation of HC pair (R290/R170) due to its flammability hazard.展开更多
Hydrocarbon source rock obviously controls the formation and distribution of hydrocarbon reservoirs. Based on the geological concept of ＂source control theory＂, the concept of a hydrocarbon distribution threshold wa...Hydrocarbon source rock obviously controls the formation and distribution of hydrocarbon reservoirs. Based on the geological concept of ＂source control theory＂, the concept of a hydrocarbon distribution threshold was put forward. This means the maximum range for hydrocarbon controlled by the source rock conditions to migrate in the hydrocarbon basins. Three quantitative analysis models are proposed on this basis, namely the hydrocarbon accumulation probability, maximum hydrocarbon scale threshold and reserve distribution probability, which respectively refer to the probability of forming a hydrocarbon reservoir, the possible maximum scale of the hydrocarbon reservoir and the percentage of reserve distribution in a certain area within the hydrocarbon distribution threshold. Statistical analysis on 539 hydrocarbon reservoirs discovered in 28 hydrocarbon source kitchens from seven sedimentary basins and sags of eastern China shows the maximum reservoir scale possibly formed in the hydrocarbon basin, hydrocarbon accumulation probability and oil and gas reserve distribution probability are all controlled by the characteristics of the hydrocarbon source rock. Generally, as the distances from the hydrocarbon source rock center and hydrocarbon discharge boundary get longer and the hydrocarbon discharge intensity of hydrocarbon source rock center gets smaller, there will be lower probability of hydrocarbon accumulation. Corresponding quantitative models are established based on single factor statistics and multivariate analysis. Practical application in the Jiyang Depression shows that the prediction from the quantitative analysis model for the hydrocarbon distribution threshold agree well with the actual exploration results, indicating that the quantitative analysis model is likely to be a feasible tool.展开更多
Effective carrier system comprises carrier beds which transport hydrocarbons. The spatial and temporal effectiveness of carrier system is identified according to the relevance of hydrocarbon show, hydrocarbon inclusio...Effective carrier system comprises carrier beds which transport hydrocarbons. The spatial and temporal effectiveness of carrier system is identified according to the relevance of hydrocarbon show, hydrocarbon inclusion and sealing ability of fault to hydrocarbons distribution, together with matching relation of activity history of fault and hydrocarbon generation history of source rock. On the basis of the above considerations, transporting ability of effective carrier system can be evaluated using parameters such as fluid potential, porosity and permeability, spatial coefficient of effective pathway as well as activity rate of fault. Additionally, a new concept of＂transporting threshold porosity＂ was proposed. Five styles of effective carrier systems were established in Gaoyou Sag, displaying either layered or zonal distribution characteristics, and transporting time ranges from the sedimentary time of Ezdz to early stage of sanduo uplift. Effective carrier systems can be described to be lowly-efficient and highly-efficient. Major faults （convex or steep fault plane） with activity rate greater than 20 m/Ma and structure ridges of sand layers with spatial coefficient of effective pathway greater than 25% are defined to be highly-efficient carrier beds. Hydrocarbons are concentrated around high-efficient carrier beds and E1 f traps of northern shanian area are predicted to have great potential.展开更多
Based on the data of 44 samples of hydrocarbon source rocks in Nanpu No.3 buffed-hill region, the kerogen type is judged through the pyrolysis and microscopic identification. At the same time, organic matter maturity ...Based on the data of 44 samples of hydrocarbon source rocks in Nanpu No.3 buffed-hill region, the kerogen type is judged through the pyrolysis and microscopic identification. At the same time, organic matter maturity and hydrocarbon generation threshold are studied by using vitrinite reflectance, pyrolysis yield and hydrocarbon abundance. Meanwhile the hydrocarbon expulsion threshold is calculated. And the characteristics of organic hydrocarbon generation and expulsion are preliminarily revealed and evaluated. The result shows that the No.3 buffed-hill region has abundant hydrocarbon source rocks with high content of organic carbon. And the primary types of kerogen are II, and lI 2. The hydrocarbon source rocks which passed biochemistry, thermolysis and thermal cracking have developed into the mature-postmature phase of different extents. And plenty of oil and gas were expelled out. It is believed the depth of oil-generating window is 3 600 m and the depth of hydro- carbon-expulsion threshold is 4 100 m. The comprehensive analysis indicates that Nanpu No.3 burried-hill region has a certain condition to generate hydrocarbon which is very promising in oil exploration and thus can become an important exploration and development target next.展开更多
文摘Several media report highlight on that the pharmaceutical companies require ultra-low temperatures -80<span style="white-space:nowrap;">°</span>C to transport and store its COVID-19 vaccines. This research presents the thermodynamic analysis on cascade refrigeration system (CRS) with several refrigerant pairs which are R32/R170, R123/R170, R134a/R170, R404A/R170, R407c/R170, R410/R170, and the hydrocarbon (HC) refrigerant pair Propane/Ethane, namely R290/R170. Besides, the results of R22/R170 pair, which is not recommended to be used due to phase out of R22 as per Montréal Protocol, are included as base case to compare the novel hydrocarbon pairs in CRS and the old trend of refrigerant pairs. Thermodynamic properties of all these pairs were investigated and compared under different intermediate temperature used in CRS heat exchanger, which thermally connected both the Low and High temperature cycles (LTC) and (HTC). By applying the first law of thermodynamics, the coefficients of performance (COPs) and the specific power consumptions (SPC) in kW/TR are presented and compared. In addition, by applying the second law of thermodynamics the exergetic efficiencies were estimated. The results reveal the promising opportunity of using the HC pair (R290/R170). The minimum SPC in kW/TR is recorded for the pair R123/R170. One the other hand, the highest exegetic efficiency values are observed to be 40%, 38%, and 35% for the pairs R123/R170, R290/R170, and R134/R170, respectively. This research concludes that the HC pair (R290/R170) is highly recommended for CRS applications either to transport the COVID-19 or store it in cold storage rooms in hospitals and clinics. All precautionary measures should be carefully applied in design and operation of HC pair (R290/R170) due to its flammability hazard.
基金supported by the National Natural Science Foundation Project(Grant No.41102085)the National Key Basic Research and Development 973 Program Project(Grant No.2011CB201105)+1 种基金Supported by Research Fund for the Doctoral Program of Higher Education of China(20110007120001)Supported by Science Foundation of China University of Petroleum, Beijing(No.KYJJ2012-01-08)
文摘Hydrocarbon source rock obviously controls the formation and distribution of hydrocarbon reservoirs. Based on the geological concept of ＂source control theory＂, the concept of a hydrocarbon distribution threshold was put forward. This means the maximum range for hydrocarbon controlled by the source rock conditions to migrate in the hydrocarbon basins. Three quantitative analysis models are proposed on this basis, namely the hydrocarbon accumulation probability, maximum hydrocarbon scale threshold and reserve distribution probability, which respectively refer to the probability of forming a hydrocarbon reservoir, the possible maximum scale of the hydrocarbon reservoir and the percentage of reserve distribution in a certain area within the hydrocarbon distribution threshold. Statistical analysis on 539 hydrocarbon reservoirs discovered in 28 hydrocarbon source kitchens from seven sedimentary basins and sags of eastern China shows the maximum reservoir scale possibly formed in the hydrocarbon basin, hydrocarbon accumulation probability and oil and gas reserve distribution probability are all controlled by the characteristics of the hydrocarbon source rock. Generally, as the distances from the hydrocarbon source rock center and hydrocarbon discharge boundary get longer and the hydrocarbon discharge intensity of hydrocarbon source rock center gets smaller, there will be lower probability of hydrocarbon accumulation. Corresponding quantitative models are established based on single factor statistics and multivariate analysis. Practical application in the Jiyang Depression shows that the prediction from the quantitative analysis model for the hydrocarbon distribution threshold agree well with the actual exploration results, indicating that the quantitative analysis model is likely to be a feasible tool.
基金Project(P08045)supported by Geological Research Institute of Jiangsu Oilfield Company,SINOPEC,China
文摘Effective carrier system comprises carrier beds which transport hydrocarbons. The spatial and temporal effectiveness of carrier system is identified according to the relevance of hydrocarbon show, hydrocarbon inclusion and sealing ability of fault to hydrocarbons distribution, together with matching relation of activity history of fault and hydrocarbon generation history of source rock. On the basis of the above considerations, transporting ability of effective carrier system can be evaluated using parameters such as fluid potential, porosity and permeability, spatial coefficient of effective pathway as well as activity rate of fault. Additionally, a new concept of＂transporting threshold porosity＂ was proposed. Five styles of effective carrier systems were established in Gaoyou Sag, displaying either layered or zonal distribution characteristics, and transporting time ranges from the sedimentary time of Ezdz to early stage of sanduo uplift. Effective carrier systems can be described to be lowly-efficient and highly-efficient. Major faults （convex or steep fault plane） with activity rate greater than 20 m/Ma and structure ridges of sand layers with spatial coefficient of effective pathway greater than 25% are defined to be highly-efficient carrier beds. Hydrocarbons are concentrated around high-efficient carrier beds and E1 f traps of northern shanian area are predicted to have great potential.
文摘Based on the data of 44 samples of hydrocarbon source rocks in Nanpu No.3 buffed-hill region, the kerogen type is judged through the pyrolysis and microscopic identification. At the same time, organic matter maturity and hydrocarbon generation threshold are studied by using vitrinite reflectance, pyrolysis yield and hydrocarbon abundance. Meanwhile the hydrocarbon expulsion threshold is calculated. And the characteristics of organic hydrocarbon generation and expulsion are preliminarily revealed and evaluated. The result shows that the No.3 buffed-hill region has abundant hydrocarbon source rocks with high content of organic carbon. And the primary types of kerogen are II, and lI 2. The hydrocarbon source rocks which passed biochemistry, thermolysis and thermal cracking have developed into the mature-postmature phase of different extents. And plenty of oil and gas were expelled out. It is believed the depth of oil-generating window is 3 600 m and the depth of hydro- carbon-expulsion threshold is 4 100 m. The comprehensive analysis indicates that Nanpu No.3 burried-hill region has a certain condition to generate hydrocarbon which is very promising in oil exploration and thus can become an important exploration and development target next.
