Waste-Derived Catalysts for Water Electrolysis:Circular Economy-Driven Sustainable Green Hydrogen Energy

The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts.By following the circular economy principle,the utilization of waste-derived catalysts significantly promotes the sustainable development of green hydrogen energy.Currently,diverse waste-derived catalysts have exhibited excellent catalytic performance toward hydrogen evolution reaction(HER),oxygen evolution reaction(OER),and overall water electrolysis(OWE).Herein,we systematically examine recent achievements in waste-derived electrocatalysts for water electrolysis.The general principles of water electrolysis and design principles of efficient electrocatalysts are discussed,followed by the illustration of current strategies for transforming wastes into electrocatalysts.Then,applications of waste-derived catalysts(i.e.,carbon-based catalysts,transitional metal-based catalysts,and carbon-based heterostructure catalysts)in HER,OER,and OWE are reviewed successively.An emphasis is put on correlating the catalysts’structure-performance relationship.Also,challenges and research directions in this booming field are finally highlighted.This review would provide useful insights into the design,synthesis,and applications of waste-derived electrocatalysts,and thus accelerate the development of the circular economy-driven green hydrogen energy scheme.

Data-driven source-load robust optimal scheduling of integrated energy production unit including hydrogen energy coupling

A robust low-carbon economic optimal scheduling method that considers source-load uncertainty and hydrogen energy utilization is developed.The proposed method overcomes the challenge of source-load random fluctuations in integrated energy systems(IESs)in the operation scheduling problem of integrated energy production units(IEPUs).First,to solve the problem of inaccurate prediction of renewable energy output,an improved robust kernel density estimation method is proposed to construct a data-driven uncertainty output set of renewable energy sources statistically and build a typical scenario of load uncertainty using stochastic scenario reduction.Subsequently,to resolve the problem of insufficient utilization of hydrogen energy in existing IEPUs,a robust low-carbon economic optimal scheduling model of the source-load interaction of an IES with a hydrogen energy system is established.The system considers the further utilization of energy using hydrogen energy coupling equipment(such as hydrogen storage devices and fuel cells)and the comprehensive demand response of load-side schedulable resources.The simulation results show that the proposed robust stochastic optimization model driven by data can effectively reduce carbon dioxide emissions,improve the source-load interaction of the IES,realize the efficient use of hydrogen energy,and improve system robustness.

Historical Review of Hydrogen Energy Storage Technology

Hydrogen energy as a sustainable energy source has most recently become an increasingly important renewable energy resource due to its ability to power fuel cells in zero-emission vehicles and its help in lowering the levels of CO2 emissions. Also, hydrogen has a high energy density and can be utilized in a wide range of applications. It is indeed the fuel of the future but, it is still not entirely apparent how to analyze the most successful ways for hydrogen storage based on technological configuration, nature, and efficiency mechanisms. The historical hydrogen storage technologies as they are presented by the current research have been evaluated, analyzed, and examined in this study. The two categories of hydrogen storage systems are physical-based and material-based.The first category involves storing hydrogen as liquid, cold/cryo-compressed, and compressed gas. Chemical sorption/chemisorption and physical sorption/physisorption are the two primary sub-groups of material-based storage, respectively. The quantitative and qualitative analyses of storage technologies for hydrogen are evaluated in this paper. Also, this report reviews the major safety and reliability issues currently facing hydrogen storage systems. Suggestions are made to assist lay the groundwork for future risk and reliability analysis to ensure safe, dependable operation.

The Impact of Hydrogen Energy Storage on the Electricity Harvesting

The economics,infrastructure,transportation,and level of living of a country are all influenced by energy.The gap between energy usage and availabil-ity is a global issue.Currently,all countries rely on fossil fuels for energy genera-tion,and these fossil fuels are not sustainable.The hydrogen proton exchange membrane fuel cell(PEMFC)power system is both clean and efficient.The fuel delivery system and the PEMFC make up the majority of the PEMFC power sys-tem.The lack of an efficient,safe,and cost-effective hydrogen storage system is still a major barrier to its widespread use.Solid hydrogen storage has the large capacity,safety and good reversibility.As a hydrogen source system,the hydro-gen supply characteristics affect the characteristics of the PEMFC at the output.In this paper,a mathematical model of a hydrogen source reactor and PEMFC based on chemical absorption/desorption of solid hydrogen storage is established,and a simulation model of a PEMFC power system coupled with solid hydrogen storage is established using MATLAB/SIMULINK software,and the hydrogen supply of the reactor is analyzed in detail.The influence of prominent factors is evaluated.The research results show that the proposed method improved the system perfor-mance.At the same time,increasing the PEMFC temperature,increasing the area of the proton exchange membrane and the oxygen supply pressure can increase the output power of the power system.

Perspective of hydrogen energy and recent progress in electrocatalytic water splitting

As a secondary energy with great commercialization potential,hydrogen energy has been widely studied due to the high calorific value,clean combustion products and various reduction methods.At present,the blueprint of hydrogen energy economy in the world is gradually taking shape.Compared with the traditional high-energy consuming methane steam reforming hydrogen production method,the electrocatalytic water splitting hydrogen production stands out among other process of hydrogen production owning to the mild reaction conditions,high-purity hydrogen generation and sustainable production process.Basing on current technical economy situation,the highly electric power cost limits the further promotion of electrocatalytic water splitting hydrogen production process.Consequently,the rational design and development of low overpotential and high stability electrocatalytic water splitting catalysts are critical toward the realization of low-cost hydrogen production technology.In this review,we summarize the existing hydrogen production methods,elaborate the reaction mechanism of the electrocatalytic water splitting reaction under acidic and alkaline conditions and the recent progress of the respective catalysts for the two half-reactions.The structure-activity relationship of the catalyst was deep-going discussed,together with the prospects of electrocatalytic water splitting and the current challenges,aiming at provide insights for electrocatalytic water splitting catalyst development and its industrial applications.

Development of a gaseous and solid-state hybrid system for stationary hydrogen energy storage

Hydrogen can serve as a carrier to store renewable energy in large scale.However,hydrogen storage still remains a challenge in the current stage.It is difficult to meet the technical requirements applying the conventional storage of compressed gaseous hydrogen in high-pressure tanks or the solid-state storage of hydrogen in suitable materials.In the present work,a gaseous and solid-state(G-S)hybrid hydrogen storage system with a low working pressure below 5 MPa for a 10 kW hydrogen energy storage experiment platform is developed and validated.A Ti-Mn type hydrogen storage alloy with an effective hydrogen capacity of 1.7 wt%was prepared for the G-S hybrid hydrogen storage system.The G-S hybrid hydrogen storage tank has a high volumetric hydrogen storage density of 40.07 kg H_(2)m^(-3) and stores hydrogen under pressure below5 MPa.It can readily release enough hydrogen at a temperature as low as-15C when the FC system is not fully activated and hot water is not available.The energy storage efficiency of this G-S hybrid hydrogen storage system is calculated to be 86.4%-95.9%when it is combined with an FC system.This work provides a method on how to design a G-S hydrogen storage system based on practical demands and demonstrates that the G-S hybrid hydrogen storage is a promising method for stationary hydrogen storage application.

Progress of Palladium Alloy Membranes in Hydrogen Energy

Palladium and palladium alloy membranes have attracted wide attention in hydrogen permeation areas for their excellent permeability, perm -selectivity and thermal stability. This paper review the principle of hydrogen permeation, type of alloys and the fabrication methods. At last, the progress and achievements on palladium alloy membranes by Northwest Institute for Non-Ferrous Metal Research are emphasized.

The Work of NAHE on Promotion of Achievements in Hydrogen Energy in Russia and of Advantages of Using Platinoids in the Energy Sector

National Association for Hydrogen Energy (NAHE) was established in 2003 to facilitate the effective integration of the Russian Federation into the world hydrogen economy. The priority for the Association is to create legislation and basic standards which necessary for the successful development of hydrogen energy, promote this sector to a large public and to support the development of those priority areas, where Russia has the best prospects to take a rightful place in the international division of labour (atomic hydrogen energy, fuel cells, hydrogen vehicles). Hydrogen Energy, National Association for Hydrogen Energy By now the Association has developed a draft technical regulation on security devices and systems

Standards highlighted in China's first “hydrogen energy week”

The 2nd Hydrogen and Fuel Cell Industry Development Summit and ISO/TC 197 Strategic Planning Meeting,the1st International Expo on Hydrogen and Fuel Cell Technology and Product,hosted by China National Institute of Standardization and ISO/TC 197,was inaugurated in Foshan city,Guangdong province on December 6,2017.The event lasted for four days,and it is the first series of＂Hydrogen Energy Week＂activities in China.The theme of the event is＂hydrogen industry,hydrogen life,hydrogen tomorrow＂.

Modeling and Simulation of Hydrogen Energy Storage System for Power-to-gas and Gas-to-power Systems

By collecting and organizing historical data and typical model characteristics,hydrogen energy storage system(HESS)-based power-to-gas(P2G)and gas-to-power systems are developed using Simulink.The energy transfer mechanisms and numerical modeling methods of the proposed systems are studied in detail.The proposed integrated HESS model covers the following system components:alkaline electrolyzer(AE),highpressure hydrogen storage tank with compressor(CM&H_(2) tank),and proton-exchange membrane fuel cell(PEMFC)stack.The unit models in the HESS are established based on typical U-I curves and equivalent circuit models,which are used to analyze the operating characteristics and charging/discharging behaviors of a typical AE,an ideal CM&H_(2) tank,and a PEMFC stack.The validities of these models are simulated and verified in the MicroGrid system,which is equipped with a wind power generation system,a photovoltaic power generation system,and an auxiliary battery energy storage system(BESS)unit.Simulation results in MATLAB/Simulink show that electrolyzer stack,fuel cell stack and system integration model can operate in different cases.By testing the simulation results of the HESS under different working conditions,the hydrogen production flow,stack voltage,state of charge(SOC)of the BESS,state of hydrogen pressure(SOHP)of the HESS,and HESS energy flow paths are analyzed.The simulation results are consistent with expectations,showing that the integrated HESS model can effectively absorb wind and photovoltaic power.As the wind and photovoltaic power generations increase,the HESS current increases,thereby increasing the amount of hydrogen production to absorb the surplus power.The results show that the HESS responds faster than the traditional BESS in the microgrid,providing a solid theoretical foundation for later wind-photovoltaic-HESS-BESS integration.

Overview of hydrogen-resistant alloys for high-pressure hydrogen environment:on the hydrogen energy structural materials

With the progressive expansion of hydrogen fuel demand,hydrogen pipelines,hydrogen storage cylinders and hydrogen refuelling stations(HRSs)are the primary components of hydrogen energy systems that face high-pressure hydrogen environments.Hydrogen embrittlement(HE)is a typical phenomenon in metallic materials,particularly in the high-pressure hydrogen environment,that causes loss of ductility and potentially catastrophic failure.HE is associated with materials,the service environment and stress.The primary mechanisms for explaining the HE of materials are hydrogen-enhanced decohesion,hydrogen-induced phase transformation,hydrogen-enhanced local plasticity,adsorption-induced dislocation emission and hydrogen-enhanced strain-induced vacancy.To reduce the risk of HE for metallic structural materials used in hydrogen energy systems,it is crucial to reasonably select hydrogen-resistant materials for high-pressure hydrogen environments.This paper summarizes HE phenomena,mechanisms and current problems for the metallic structural materials of hydrogen energy systems.A research perspective is also proposed,mainly focusing on metal structural materials for hydrogen pipelines,hydrogen storage cylinders and hydrogen compressors in HRSs from an application perspective.

Multi-stage Co-planning Model for Power Distribution System and Hydrogen Energy System Under Uncertainties

The increased deployment of electricity-based hydrogen production strengthens the coupling of power distribution system(PDS)and hydrogen energy system(HES).Considering that power to hydrogen(PtH)has great potential to facilitate the usage of renewable energy sources(RESs),the coordination of PDS and HES is important for planning purposes under high RES penetration.To this end,this paper proposes a multi-stage co-planning model for the PDS and HES.For the PDS,investment decisions on network assets and RES are optimized to supply the growing electric load and PtHs.For the HES,capacities of PtHs and hydrogen storages(HSs)are optimally determined to satisfy hydrogen load considering the hydrogen production,tube trailer transportation,and storage constraints.The overall planning problem is formulated as a multistage stochastic optimization model,in which the investment decisions are sequentially made as the uncertainties of electric and hydrogen load growth states are revealed gradually over periods.Case studies validate that the proposed co-planning model can reduce the total planning cost,promote RES consumption,and obtain more flexible decisions under long-term load growth uncertainties.

Development and prospects of degradable magnesium alloys for structural and functional applications in the fields of environment and energy

Magnesium and its alloys have such advantages with lightweight, high specific strength, good damping, high castability and machinability,which make them an attractive choice for applications where weight reduction is important, such as in the aerospace and automotive industries.However, their practical applications are still limited because of their poor corrosion resistance, low high temperature strength and ambient formability. Based on such their property shortcomings, recently degradable magnesium alloys were developed for broadening their potential applications. Considering the degradable Mg alloys for medical applications were well reviewed, the present review put an emphasis on such degradable magnesium alloys for structural and functional applications, especially the applications in the environmental and energy fields. Their applications as fracture ball in fossil energy, sacrificial anode, washing ball, and as battery anodes, transient electronics, were summarized. The roles of alloying elements in magnesium and the design concept of such degradable magnesium alloys were discussed. The existing challenges for extending their future applications are explored.

Decarbonising energy: The developing international activity in hydrogen technologies and fuel cells

Hydrogen technologies and fuel cells offer an alternative and improved solution for a decarbonised energy future.Fuel cells are electrochemical converters;transforming hydrogen (or energy sources containing hydrogen) and oxygen directly into electricity.The hydrogen fuel cell,invented in 1839,permits the generation of electrical energy with high efficiency through a non-combustion,electrochemical process and,importantly,without the emission ofits point of use.Hitherto,despite numerous efforts to exploit the obvious attractions of hydrogen technologies and hydrogen fuel cells,various challenges have been encountered,some of which are reviewed here.Now,however,given the exigent need to urgently seek low-carbon paths for humankind’s energy future,numerous countries are advancing the deployment of hydrogen technologies and hydrogen fuel cells not only for transport,but also as a means of the storage of excess renewable energy from,for example,wind and solar farms.Furthermore,hydrogen is also being blended into the natural gas supplies used in domestic heating and targeted in the decarbonisation of critical,large-scale industrial processes such as steel making.We briefly review specific examples in countries such as Japan,South Korea and the People’s Republic of China,as well as selected examples from Europe and North America in the utilization of hydrogen technologies and hydrogen fuel cells.

Recent progress of mesoscience in design of electrocatalytic materials for hydrogen energy conversion

Electrocatalytic materials with different morphologies,sizes,and components show different catalytic behavior in various heterogeneous catalytic reactions.It has been proved that the catalytic properties of these materials are strongly influenced by several factors at different levels,including the electrode morphology,reaction channels,three-phase interface,and surface active sites.Recent developments of mesoscience allow one to study the relationship between the apparent catalytic performance of electro-catalytic materials with these factors from different levels.In this review,following a brief introduction of new mesoscience,we summarize the effect of mesoscience on electrocatalytic material design,including modulating the geometric and electronic structures of materials focusing on morphology(particulate,fiber,film,array,monolith,and superlattice),pore structure(microporous,mesoporous,and hierarchical),size(single atoms,nanoclusters,and nanoparticles),multiple components(alloys,heterostructures,and multiple ligands),and crystal structures(crystalline,amorphous,and multiple crystal phases).By evaluating the electrocatalytic performance of catalytic materials tuned at the mesoscale,we paint a picture of how these factors at different levels affect the final system performance and then provide a new direction to better understand and design catalytic materials from the viewpoint of mesoscience.

Modeling of Hydrogen Blending on the Leakage and Diffusion of Urban Buried Hydrogen-Enriched Natural Gas Pipeline

With the introduction of various carbon reduction policies around the world,hydrogen energy,as a kind of clean energy with zero carbon emission,has attracted much attention.The safe and economical transportation of hydrogen is of great significance to the development of hydrogen energy industries.Utilizing natural gas pipelines to transport hydrogen is considered to be an efficient and economical way.However,hydrogen has a higher risk of leakage due to its strong diffusion capacity and lower explosive limit than conventional natural gas.Therefore,it is of great significance to study the leakage and diffusion law of hydrogen-enriched natural gas(HENG)pipelines for the safe transportation of hydrogen energy.In this study,the leakage and diffusion characteristics of urban buried HENG pipelines are investigated numerically,and the dangerous degree of leakage is analyzed based on the time and area when the gas concentration reaches the lower explosive limit.The influences of hydrogen blending ratio(HBR),operating pressure,leakage hole size and direction,as well as soil type on the leakage and diffusion law of HENG are analyzed.Results show that the hydrogen mixing is not the key factor in increasing the degree of risk after gas leakage for urban buried HENG pipelines.When the HBR is 5%,10%,15% and 20%,the corresponding first dangerous time is 1053,1041,1019 and 998 s,respectively.Thiswork is expected to provide a valuable reference for the safe operation and risk prevention of HENG pipelines in the future.

Dual‑Doped Nickel Sulfide for Electro‑Upgrading Polyethylene Terephthalate into Valuable Chemicals and Hydrogen Fuel

Electro-upcycling of plastic waste into value-added chemicals/fuels is an attractive and sustainable way for plastic waste management.Recently,electrocatalytically converting polyethylene terephthalate(PET)into formate and hydrogen has aroused great interest,while developing low-cost catalysts with high efficiency and selectivity for the central ethylene glycol(PET monomer)oxidation reaction(EGOR)remains a challenge.Herein,a high-performance nickel sulfide catalyst for plastic waste electro-upcycling is designed by a cobalt and chloride co-doping strategy.Benefiting from the interconnected ultrathin nanosheet architecture,dual dopants induced upshifting d band centre and facilitated in situ structural reconstruction,the Co and Cl co-doped Ni_(3)S_(2)(Co,Cl-NiS)outperforms the singledoped and undoped analogues for EGOR.The self-evolved sulfide@oxyhydroxide heterostructure catalyzes EG-to-formate conversion with high Faradic efficiency(>92%)and selectivity(>91%)at high current densities(>400 mA cm^(−2)).Besides producing formate,the bifunctional Co,Cl-NiS-assisted PET hydrolysate electrolyzer can achieve a high hydrogen production rate of 50.26 mmol h^(−1)in 2 M KOH,at 1.7 V.This study not only demonstrates a dual-doping strategy to engineer cost-effective bifunctional catalysts for electrochemical conversion processes,but also provides a green and sustainable way for plastic waste upcycling and simultaneous energy-saving hydrogen production.

Study on critical technologies and development routes of coal-based hydrogen energy

Hydrogen is considered a secondary source of energy,commonly referred to as an energy carrier.It has the highest energy content when compared to other common fuels by weight,having great potential for further development.Hydrogen can be produced from various domestic resources but,based on the fossil resource conditions in China,coal-based hydrogen energy is considered to be the most valuable,because it is not only an effective way to develop clean energy,but also a proactive exploration of the clean usage of traditional coal resources.In this article,the sorption-enhanced water-gas shift technology in the coal-to-hydrogen section and the hydrogen-storage and transport technology with liquid aromatics are introduced and basic mechanisms,technical advantages,latest progress and future R&D focuses of hydrogen-production and storage processes are listed and discussed.As a conclusion,after considering the development frame and the business characteristics of CHN Energy Group,a conceptual architecture for developing coal-based hydrogen energy and the corresponding supply chain,is proposed.

Investigation of Highly Designable Dented Structures in HP Model with Hydrogen Bond Energy

Some highly designable protein structures have dented on the surface of their native structures, and are not full compactly folded. According to hydrophobic-polar （HP） model the most designable structures are full compactly folded. To investigate the designability of the dented structures, we introduce the hydrogen bond energy in the secondary structures by using the secondary-structure-favored HP model proposed by Ou-yang etc. The result shows that the average designability increases with the strength of the hydrogen bond. The designabilities of the structures with same dented shape increase exponentially with the number of secondary structure sites. The dented structures can have the highest designabilities for a certain value of hydrogen bond energy density.

The Quantum Condition That Should Have Been Assumed by Bohr When Deriving the Energy Levels of a Hydrogen Atom

Bohr assumed a quantum condition when deriving the energy levels of a hydrogen atom. This famous quantum condition was not derived logically, but it beautifully explained the energy levels of the hydrogen atom. Therefore, Bohr’s quantum condition was accepted by physicists. However, the energy levels predicted by the eventually completed quantum mechanics do not match perfectly with the predictions of Bohr. For this reason, it cannot be said that Bohr’s quantum condition is a perfectly correct assumption. Since the mass of an electron which moves inside a hydrogen atom varies, Bohr’s quantum condition must be revised. However, the newly derived relativistic quantum condition is too complex to be assumed at the beginning. The velocity of an electron in a hydrogen atom is known as the Bohr velocity. This velocity can be derived from the formula for energy levels derived by Bohr. The velocity v of an electron including the principal quantum number n is given by αc/n. This paper elucidates the fact that this formula is built into Bohr’s quantum condition. It is also concluded in this paper that it is precisely this velocity formula that is the quantum condition that should have been assumed in the first place by Bohr. From Bohr’s quantum condition, it is impossible to derive the relativistic energy levels of a hydrogen atom, but they can be derived from the new quantum condition. This paper proposes raising the status of the previously-known Bohr velocity formula.