In order to investigate the influences of the stoichiometric ratio of B/A (A: gross A-site elements, B: gross B-site elements) and the substitution of Co for Ni on the structures and electrochemical performances of th...In order to investigate the influences of the stoichiometric ratio of B/A (A: gross A-site elements, B: gross B-site elements) and the substitution of Co for Ni on the structures and electrochemical performances of the AB3.5-4.1-type electrode alloys, the La-Mg-Ni-Co system La0.75Mg0.25Ni3.5Mx (M=Ni, Co; x= 0, 0.2, 0.4, 0.6) alloys were prepared by induction melting in a helium atmosphere. The structures and electrochemical performances of the alloys were systemically measured. The results show that the structures and electrochemical performances of the alloys are closely relevant to the B/A ratio. All the alloys exhibit a multiphase structure, including two major phases, (La, Mg)2Ni7 and LaNi5, and a residual phase LaNi2, and with rising ratio B/A, the (La,Mg)2Ni7 phase decreases and the LaNi5 phase increases significantly. When ratio B/A=3.7, the alloys obtain the maximum discharge capacities. The high rate discharge(HRD) capability of the alloy (M=Ni) monotonously rises with growing B/A ratio, but that of the alloy (M=Co) first mounts up then declines. The cycle stability of the alloy (M=Co) monotonously increases with rising B/A ratio, but it first decreases slightly then increases for the alloy (M=Ni). The discharge potential of the alloy (M=Ni) declines with increasing B/A ratio (x>0.2), but for the alloy (M=Co), the result is contrary. The substitution of Co for Ni significantly ameliorates the electrochemical performances. For a fixed ratio B/A=3.7, the Co substitution enhances the discharge capacity from 365.7 to 401.8 mA·h/g, the capacity retention ratio (S100) after 100 charging-discharging cycles from 50.32% to 53.26% and the HRD from 88.65% to 90.69%.展开更多
New oxygen and hydrogen isotope ratios of chert from middle, intraformational breccias, and upper breccia members of the Sixtymile Formation(SMF) in eastern Grand Canyon National Park(AZ) yield palaeoclimate estimates...New oxygen and hydrogen isotope ratios of chert from middle, intraformational breccias, and upper breccia members of the Sixtymile Formation(SMF) in eastern Grand Canyon National Park(AZ) yield palaeoclimate estimates between 27 and 33 °C. The isotopic compositions of cherts define a domain approximately parallel to the meteoric water line when plotted on a δD–δ^(18)O diagram; these data indicate that meteoric water was involved during formation of the chert. In thin section, the absence of interlocking mega quartz(>35 lm) and silicafilled fractures and veins, along with preserved micromorphological silica fabrics, suggest that the chert has not been permeated by later hydrothermal fluids. Petrographic observations in thin section such as cyclic silica precipitation phases and glaebular micromorphologic fabrics lend support to the interpretation that meteoric waters were involved during chert precipitation. The post 742 Ma SMF has been correlated with diamictite(transition) beds of the Kingston Peak Formation(CA), which in turn have been interpreted to have been deposited during the Sturtian Ice Age(~750–700 Ma). Absence of facetted and striated clasts and other diagnostic glaciogenic features in the SMF,an unconformable contact with the stratigraphically older Chuar Group, coupled with warm palaeotemperature data inferred from stable isotope values of chert, tentatively suggest that deposition of sediment in the SMF likely did not take place during the Sturtian Ice Age.展开更多
Amorphous Ga_(2)O_(3)(a-Ga_(2)O_(3))has been attracting more and more attention due to its unique merits such as wide bandgap(∼4.9 eV),low growth temperature,large-scale uniformity,low cost and energy efficient,makin...Amorphous Ga_(2)O_(3)(a-Ga_(2)O_(3))has been attracting more and more attention due to its unique merits such as wide bandgap(∼4.9 eV),low growth temperature,large-scale uniformity,low cost and energy efficient,making it a powerful competitor in flexible deep ultraviolet(UV)photodetection.Although the responsivity of the ever-reported a-Ga_(2)O_(3)UV photodetectors(PDs)is usually in the level of hundreds of A/W,it is often accompanied by a large dark current due to the presence of abundant oxygen vacancy(VO)defects,which severely limits the possibility to detect weak signals and achieve versatile applications.In this work,the VO defects in a-Ga_(2)O_(3)thin films are successfully passivated by in-situ hydrogen doping during the magnetron sputtering process.As a result,the dark current of a-Ga_(2)O_(3)UV PD is remarkably suppressed to 5.17×10^(-11) A at a bias of 5 V.Importantly,the photocurrent of the corresponding device is still as high as 1.37×10^(-3)A,leading to a high photo-to-dark current ratio of 2.65×107 and the capability to detect the UV light with the intensity below 10 nW cm^(-2).Moreover,the H-doped a-Ga_(2)O_(3)thin films have also been deposited on polyethylene naphtholate substrates to construct flexible UV PDs,which exhibit no great degradation in bending states and fatigue tests.These results demonstrate that hydrogen doping can effectively improve the performance of a-Ga_(2)O_(3)UV PDs,further promoting its practical application in various areas.展开更多
基金Project(2006AA05Z132) supported by High-tech Research and Development Program of ChinaProject(50642033) supported by the National Natural Science Foundation of China+1 种基金Project(200711020703) supported by the Natural Science Foundation of Inner Mongolia, ChinaProject (20050205) supported by Science and Technology Planned Project of Inner Mongolia, China
文摘In order to investigate the influences of the stoichiometric ratio of B/A (A: gross A-site elements, B: gross B-site elements) and the substitution of Co for Ni on the structures and electrochemical performances of the AB3.5-4.1-type electrode alloys, the La-Mg-Ni-Co system La0.75Mg0.25Ni3.5Mx (M=Ni, Co; x= 0, 0.2, 0.4, 0.6) alloys were prepared by induction melting in a helium atmosphere. The structures and electrochemical performances of the alloys were systemically measured. The results show that the structures and electrochemical performances of the alloys are closely relevant to the B/A ratio. All the alloys exhibit a multiphase structure, including two major phases, (La, Mg)2Ni7 and LaNi5, and a residual phase LaNi2, and with rising ratio B/A, the (La,Mg)2Ni7 phase decreases and the LaNi5 phase increases significantly. When ratio B/A=3.7, the alloys obtain the maximum discharge capacities. The high rate discharge(HRD) capability of the alloy (M=Ni) monotonously rises with growing B/A ratio, but that of the alloy (M=Co) first mounts up then declines. The cycle stability of the alloy (M=Co) monotonously increases with rising B/A ratio, but it first decreases slightly then increases for the alloy (M=Ni). The discharge potential of the alloy (M=Ni) declines with increasing B/A ratio (x>0.2), but for the alloy (M=Co), the result is contrary. The substitution of Co for Ni significantly ameliorates the electrochemical performances. For a fixed ratio B/A=3.7, the Co substitution enhances the discharge capacity from 365.7 to 401.8 mA·h/g, the capacity retention ratio (S100) after 100 charging-discharging cycles from 50.32% to 53.26% and the HRD from 88.65% to 90.69%.
基金provided by a grant from Chuck Baltzer,Environmental Support Servicesgraciously awarded by Grand Canyon National Park officials
文摘New oxygen and hydrogen isotope ratios of chert from middle, intraformational breccias, and upper breccia members of the Sixtymile Formation(SMF) in eastern Grand Canyon National Park(AZ) yield palaeoclimate estimates between 27 and 33 °C. The isotopic compositions of cherts define a domain approximately parallel to the meteoric water line when plotted on a δD–δ^(18)O diagram; these data indicate that meteoric water was involved during formation of the chert. In thin section, the absence of interlocking mega quartz(>35 lm) and silicafilled fractures and veins, along with preserved micromorphological silica fabrics, suggest that the chert has not been permeated by later hydrothermal fluids. Petrographic observations in thin section such as cyclic silica precipitation phases and glaebular micromorphologic fabrics lend support to the interpretation that meteoric waters were involved during chert precipitation. The post 742 Ma SMF has been correlated with diamictite(transition) beds of the Kingston Peak Formation(CA), which in turn have been interpreted to have been deposited during the Sturtian Ice Age(~750–700 Ma). Absence of facetted and striated clasts and other diagnostic glaciogenic features in the SMF,an unconformable contact with the stratigraphically older Chuar Group, coupled with warm palaeotemperature data inferred from stable isotope values of chert, tentatively suggest that deposition of sediment in the SMF likely did not take place during the Sturtian Ice Age.
基金supported by Guangdong Basic and Applied Basic Research Foundation(Grant Nos.2022A1515110607 and 2019B1515120057)the National Natural Science Foundation of China(Grant Nos.62174113,12174275,61874139,61904201 and 11875088).
文摘Amorphous Ga_(2)O_(3)(a-Ga_(2)O_(3))has been attracting more and more attention due to its unique merits such as wide bandgap(∼4.9 eV),low growth temperature,large-scale uniformity,low cost and energy efficient,making it a powerful competitor in flexible deep ultraviolet(UV)photodetection.Although the responsivity of the ever-reported a-Ga_(2)O_(3)UV photodetectors(PDs)is usually in the level of hundreds of A/W,it is often accompanied by a large dark current due to the presence of abundant oxygen vacancy(VO)defects,which severely limits the possibility to detect weak signals and achieve versatile applications.In this work,the VO defects in a-Ga_(2)O_(3)thin films are successfully passivated by in-situ hydrogen doping during the magnetron sputtering process.As a result,the dark current of a-Ga_(2)O_(3)UV PD is remarkably suppressed to 5.17×10^(-11) A at a bias of 5 V.Importantly,the photocurrent of the corresponding device is still as high as 1.37×10^(-3)A,leading to a high photo-to-dark current ratio of 2.65×107 and the capability to detect the UV light with the intensity below 10 nW cm^(-2).Moreover,the H-doped a-Ga_(2)O_(3)thin films have also been deposited on polyethylene naphtholate substrates to construct flexible UV PDs,which exhibit no great degradation in bending states and fatigue tests.These results demonstrate that hydrogen doping can effectively improve the performance of a-Ga_(2)O_(3)UV PDs,further promoting its practical application in various areas.
