Small high-quality Au/P-Si Schottky barrier diodes(SBDs) with an extremely low reverse leakage current using wet lithography were produced.Their effective barrier heights(BHs) and ideality factors from current-vol...Small high-quality Au/P-Si Schottky barrier diodes(SBDs) with an extremely low reverse leakage current using wet lithography were produced.Their effective barrier heights(BHs) and ideality factors from current-voltage (Ⅰ-Ⅴ) characteristics were measured by a conducting probe atomic force microscope(C-AFM).In spite of the identical preparation of the diodes there was a diode-to-diode variation in ideality factor and barrier height parameters.By extrapolating the plots the built in potential of the Au /p-Si contact was obtained as V_(bi)=0.5425 V and the barrier height valueΦ_(b(c-V)) was calculated to beΦ_(B(C-V))=0.7145 V for Au/p-Si.It is found that for the diodes with diameters smaller than 100μm,the diode barrier height and ideality factor dependency to their diameters and correlation between the diode barrier height and its ideality factor are nonlinear,where similar to the earlier reported different metal semiconductor diodes in the literature,these parameters for the here manufactured diodes with diameters more than 100μm are also linear.Based on the very obvious sub-nanometer C-AFM produced pictures the scientific evidence behind this controversy is also explained.展开更多
Photovoltaic solar energy can be obtained by using several types of technologies, including silicon solar cells. The characterization of its solar cells makes it possible to know them better. This article presents, on...Photovoltaic solar energy can be obtained by using several types of technologies, including silicon solar cells. The characterization of its solar cells makes it possible to know them better. This article presents, on the one hand, the work that has been carried out on these cells. On the other hand, a theoretical study of the cell under illumination using Lambert’s W function. On the basis of the electrical parameters provided by the manufacturer, the parameters such as the series and shunt resistances and the electrical quantities such as the photocurrent and the photovoltage, are determined and studied according to the ideality factor of the diode. From the results obtained the shunt resistance increases when the ideality factor increases, the series resistance decreases very weakly.展开更多
This paper describes the fabrication and electrical characteristics of Ti/4H-SiC Schottky barrier diodes (SBDs). The ideality factor n = 1.08 and effective Schottky barrier heightφ= 1.05eV of the SBDs were measured...This paper describes the fabrication and electrical characteristics of Ti/4H-SiC Schottky barrier diodes (SBDs). The ideality factor n = 1.08 and effective Schottky barrier heightφ= 1.05eV of the SBDs were measured with the method of forward current density-voltage (J-V). A low reverse leakage current below 5.96 ×10^-3A/cm^2 at a bias voltage of - 1. 1kV was obtained. By using B^+ implantation,an amorphous layer as the edge termination was formed. We used the PECVD SiO2 as the field plate dielectric. The SBDs have an on-state current density of 430A/cm^2 at a forward voltage drop of about 4V. The specific on-resistance Ro, was found to be 6. 77mΩ2 · cm^2 .展开更多
In order to investigate their electrical characteristics, high-voltage light-emitting-diodes (HV-LEDs) each contain- ing four cells in series are fabricated. The electrical parameters including varying voltage and p...In order to investigate their electrical characteristics, high-voltage light-emitting-diodes (HV-LEDs) each contain- ing four cells in series are fabricated. The electrical parameters including varying voltage and parasitic effect are studied. It is shown that the ideality factors (IFs) of the HV-LEDs with different numbers of cells are 1.6, 3.4, 4.7, and 6.4. IF increases linearly with the number of cells increasing. Moreover, the performance of the HV-LED with failure cells is examined, The analysis indicates that the failure cell has a parallel resistance which induces the leakage of the failure cell. The series resistance of the failure cell is 76.8 Ω, while that of the normal cell is 21.3 Ω. The scanning electron microscope (SEM) image indicates that different metal layers do not contact well. It is hard to deposit the metal layers in the deep isolation trenches. The fabrication process of HV-LEDs needs to be optimized.展开更多
Recently GaN-based high electron mobility transistors (HEMTs) have revealed the superior properties of a high breakdown field and high electron saturation velocity. Reduction of the gate leakage current is one of th...Recently GaN-based high electron mobility transistors (HEMTs) have revealed the superior properties of a high breakdown field and high electron saturation velocity. Reduction of the gate leakage current is one of the key issues to be solved for their further improvement. This paper reports that an Al layer as thin as 3 nm was inserted between the conventional Ni/Au Schottky contact and n-GaN epilayers, and the Schottky behaviour of Al/Ni/Au contact was investigated under various annealing conditions by current-voltage (I-V) measurements. A non-linear fitting method was used to extract the contact parameters from the I-V characteristic curves. Experimental results indicate that reduction of the gate leakage current by as much as four orders of magnitude was successfully recorded by thermal annealing. And high quality Schottky contact with a barrier height of 0.875 eV and the lowest reverse-bias leakage current, respectively, can be obtained under 12 min annealing at 450 ℃ in N2 ambience.展开更多
In this work, a dislocation-related tunneling leakage current model is developed to explain the temperature-dependent reverse current–voltage(I–V –T) characteristics of a Schottky barrier diode fabricated on free...In this work, a dislocation-related tunneling leakage current model is developed to explain the temperature-dependent reverse current–voltage(I–V –T) characteristics of a Schottky barrier diode fabricated on free-standing GaN substrate for reverse-bias voltages up to-150 V. The model suggests that the reverse leakage current is dominated by the direct tunneling of electrons from Schottky contact metal into a continuum of states associated with conductive dislocations in GaN epilayer.A reverse leakage current ideality factor, which originates from the scattering effect at metal/GaN interface, is introduced into the model. Good agreement between the experimental data and the simulated I–V curves is obtained.展开更多
Fundamentals of the Schottky contacts and the high-temperature current conduction through three kinds of Schottky diodes are studied. N-Si Schottky diodes, GaN Schottky diodes and AlGaN/GaN Schottky diodes are investi...Fundamentals of the Schottky contacts and the high-temperature current conduction through three kinds of Schottky diodes are studied. N-Si Schottky diodes, GaN Schottky diodes and AlGaN/GaN Schottky diodes are investigated by I-V-T measurements ranging from 300 to 523 K. For these Schottky diodes, a rise in temperature is accompanied with an increase in barrier height and a reduction in ideality factor. Mechanisms are suggested, including thermionic emission, field emission, trap-assisted tunnelling and so on. The most remarkable finding in the present paper is that these three kinds of Schottky diodes are revealed to have different behaviours of high-temperature reverse currents. For the n-Si Schottky diode, a rise in temperature is accompanied by an increase in reverse current. The reverse current of the GaN Schottky diode decreases first and then increases with rising temperature. The AlGaN/GaN Schottky diode has a trend opposite to that of the GaN Schottky diode, and the dominant mechanisms are the effects of the piezoelectric polarization field and variation of two-dimensional electron gas charge density.展开更多
In this paper, the electrical parameters of Au/n-Si (MS) and Au/Si3N4/n-Si (MIS) Schottky diodes are obtained from the forward bias current-voltage (I-V) and capacitance-voltage (C-V) measurements at room temp...In this paper, the electrical parameters of Au/n-Si (MS) and Au/Si3N4/n-Si (MIS) Schottky diodes are obtained from the forward bias current-voltage (I-V) and capacitance-voltage (C-V) measurements at room temperature. Experimental results show that the rectifying ratios of the MS and MIS diodes at ± 5 V are found to be 1.25 ×103 and 1.27 ×104, respectively. The main electrical parameters of the MS and MIS diodes, such as the zero-bias barrier height (rbBo) and ideality factor (n), are calculated to be 0.51 eV (I-V), 0.53 eV (C-V), and 4.43, and 0.65 eV (I-V), 0.70 eV (C-V), and 3.44, respectively. In addition, the energy density distribution profile of the interface states (Nss) is obtained from the forward bias I-V, and the series resistance (Rs) values for the two diodes are calculated from Cheung's method and Ohm's law.展开更多
The I-V characteristic of GaN-based p-i-n ultraviolet detector is presented. It is measured at different temperatures and analyzed with changing temperature. The ideality factor of the device is 2.09 at room temperatu...The I-V characteristic of GaN-based p-i-n ultraviolet detector is presented. It is measured at different temperatures and analyzed with changing temperature. The ideality factor of the device is 2.09 at room temperature. The maximum ideality factor is 2.14 at 100 ℃, which declines above 100 ℃, and the minimum ideality factor is 1.26 at 300 ℃. The coefficient of forward voltage vs. temperature is -1.97 mV/℃ with a forward current of 1 mA. Based on double injection model, the deep lying impurity activation energy in the i-region is 0.1 343 eV.展开更多
A single diode model for a photovoltaic solar module is the most ideal and quick way of analyzing the module characteristics before implementing them in a solar plant. Solar modules manufacturers provide information f...A single diode model for a photovoltaic solar module is the most ideal and quick way of analyzing the module characteristics before implementing them in a solar plant. Solar modules manufacturers provide information for three critical points that are essential in I-V, P-V or P-I curves. In this study, we propose four separate simulation procedures to estimate the five-model parameters of an analogous single diode equivalent circuit by utilizing three cardinal points of the photovoltaic module I-V curve, described from experimental data using a solar simulator and manufacturer’s datasheet. The main objective is to extract and use the five unknown parameters of a single diode model to describe the photovoltaic system using I-V ad P-V plots under different environmental conditions. The most influential parameters that greatly alter the cardinal points defined at short circuit point (SCP), the maximum power point (MPP) and the open circuit point(OCP) are the ideality factor (</span><i><span style="font-family:Verdana;">n</span></i><span style="font-family:Verdana;">) and the diode saturation current (</span><i><span style="font-family:Verdana;">I<sub>o</sub></span></i><span style="font-family:Verdana;">). For a quick and fast convergence, we have determined the optimal ideality factor (</span><i><span style="font-family:Verdana;">n<sub>o</sub></span></i><span style="font-family:Verdana;">) and optimal saturation current (</span><i><span style="font-family:Verdana;">I<sub>oopt</sub></span></i><span style="font-family:Verdana;">) as the primary parameters by first assuming the optimal values of </span><i><span style="font-family:Verdana;">R<sub>sh</sub></span></i><span style="font-family:Verdana;">, </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">I<sub>ph</sub> </span></i><span style="font-family:Verdana;">at standard test conditions (STC). Further, we evaluated the effects of </span><i><span style="font-family:Verdana;">I<sub>ph</sub></span></i><span style="font-family:Verdana;">, </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">R<sub>sh</sub> </span></i><span style="font-family:Verdana;">on I-V and P-V curves by considering the values of </span><i><span style="font-family:Verdana;">n </span></i><span style="font-family:Verdana;">below </span><i><span style="font-family:Verdana;">n</span><sub><span style="font-family:Verdana;">o</span></sub></i><span style="font-family:Verdana;">. We have evaluated different iterative procedures of determining </span><i><span style="font-family:Verdana;">R<sub>sh</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">at open-circuit, short-circuit point and the maximum-power points. These procedures have been classified into four approaches that guarantees positive shunt and series resistance for </span><i><span style="font-family:Verdana;">n </span></i><span style="font-family:Verdana;">≤</span><i><span style="font-family:Verdana;"> n<sub>o</sub></span></i><span style="font-family:Verdana;">. These approaches have been categorized by deriving the saturation current as a dependent variable at each cardinal point with or without </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">R<sub>sh</sub> </span></i><span style="font-family:Verdana;">pair. The values obtained for the five parameters have been used to simulate the photovoltaic solar module characteristic curves with great precision at different air temperatures and irradiances, considering the effect of Nominal Operating Cell Temperature (NOCT).展开更多
Despite the rapid development of power conversion efficiency(PCE)for halide perovskite solar cells(PSCs),the lattice strain engineering in perovskite thin films has been rarely probed in recent years.Herein,a strain c...Despite the rapid development of power conversion efficiency(PCE)for halide perovskite solar cells(PSCs),the lattice strain engineering in perovskite thin films has been rarely probed in recent years.Herein,a strain compensation by homogeneous crystallization in perovskite films is achieved with the aid of precursor aging in the mixed-cation perovskite of Cs_(0.05)(FA_(0.83)MA_(0.17))Pb(I_(0.90)Br_(0.10))_(3)with near 20%PCE in inverted devices.The homogeneous crystallization releases the residual tensile stress and induces more compressive stress at the edges of perovskite films,thus elongating the carrier lifetime and reducing the trap-assisted carrier recombination.The high dependence on the perovskite components in strain engineering strategy was systematically revealed,wherein MAPbI_(3)and Cs_(0.05)(FA_(0.83)MA_(0.17))PbI_(3)film showed an increased compressive strain and FAPbI3 film showed adverse tensile strain after aging.The density functional theory(DFT)calculations are further performed to reveal the change of electronic features.The precursor aging-induced strain modulation was correlated with a systematic characterization of the charge carrier transport and recombination dynamics in the mixed-cation perovskite films.We believe that this facile approach provides a novel strain engineering strategy for PSCs technology.展开更多
Organic light-emitting diodes(OLEDs)have demonstrated remarkable advancements in both device lifetime and luminous efficiency.However,insufficient operation lifetime due to device degradation remains a major hurdle,es...Organic light-emitting diodes(OLEDs)have demonstrated remarkable advancements in both device lifetime and luminous efficiency.However,insufficient operation lifetime due to device degradation remains a major hurdle,especially for brighter devices.Understanding the degradation mechanisms of OLEDs due to the degradation of functional materials and the formation of defects in device architectures continues to be a significant challenge.Herein,we evaluate the degradation characteristics by scrutinizing the electrical and optical properties,as well as analyzing the charge carrier dynamics in pristine and aged states of phosphorescent OLEDs(PhOLEDs).We show that degradation mechanisms in PhOLEDs can be elucidated in terms of the ideality factors of current and luminance in pristine and aged device states.The consistent shifts in distinct ideality factors across various states points out that the device degradation is attributed to the deterioration of the guest material,i.e.green-light-emitting phosphorescent material.Conversely,the incongruity in ideality factor changes between the two states indicates that the degradation results from the deterioration of non-light-emitting material.Subsequent characterization experiments provide further evidence that this degradation is primarily attributed to the deterioration of CBP-host material.The thorough understanding of degradation mechanisms established in this study can contribute to realizing the highly reliable PhOLEDs with a long lifetime.展开更多
The linear cofactor difference operator(LCDO) method,a direct parameter extraction method for general diodes,is presented.With the developed LCDO method,the extreme spectral characteristic of the diode voltage-curre...The linear cofactor difference operator(LCDO) method,a direct parameter extraction method for general diodes,is presented.With the developed LCDO method,the extreme spectral characteristic of the diode voltage-current curves is revealed,and its extreme positions are related to the diode characteristic parameters directly.The method is applied to diodes with different sizes and temperatures,and the related characteristic parameters,such as reverse saturation current,series resistance and non-ideality factor,are extracted directly.The extraction result shows good agreement with the experimental data.展开更多
The influence of temperature on the intensity of light emitted by as well as the carrier life time r of a standard A1GaAs based light emitting diode has been investigated in the temperature range from 345 to 136 K. Th...The influence of temperature on the intensity of light emitted by as well as the carrier life time r of a standard A1GaAs based light emitting diode has been investigated in the temperature range from 345 to 136 K. The open-circuit voltage decay (OCVD) technique has been used for measured the carrier lifetime. Our experimental results reveal a 16% average increase in intensity and a 163.482-19.765 ns variation in carrier lifetime in the above temperature range. Further, theoretical and experimental analysis show that for negligible carrier density the intensity is inversely proportional to carrier lifetime for this sample.展开更多
We investigate the dominant dark current transport mechanism in Si based p-i-n photodiodes, namely, BPW 21R, SFH 205FA and BPX 61 photodiodes in the temperature range of 350 to 139 K. The forward current- voltage char...We investigate the dominant dark current transport mechanism in Si based p-i-n photodiodes, namely, BPW 21R, SFH 205FA and BPX 61 photodiodes in the temperature range of 350 to 139 K. The forward current- voltage characteristics of these photodiodes are explained via the tunneling enhanced recombination model, which gives a quantitative description of the electronic mechanism in the p-i-n junction photodiodes. The observed tem- perature dependence of the saturation current and the diode ideality factor of these devices agree well with theo- retical predictions; the analysis also indicates the importance of doping for enhancement of tunneling. The present study will be helpful in applying the devices at low temperature ambience.展开更多
The influence of single walled carbon nanotube(SWCNT)on the series resistanceof Rose Bengal(RB)and Methyl Red(MR)dye-based organic diodes has been studied.It has been revealed from experimental results that SWCN...The influence of single walled carbon nanotube(SWCNT)on the series resistanceof Rose Bengal(RB)and Methyl Red(MR)dye-based organic diodes has been studied.It has been revealed from experimental results that SWCNT has a significant effect on Rs.The values of Rs are measured from current–voltage(I–V)characteristics and also by utilizing the Cheung method.Obtained values from the Cheung method have been verified using H(I)–I plots for all dye-based devices.The extracted values using these two processes show a good consistency with each other.It is observed that Rs is reduced significantly by incorporating SWCNT for both dyes.The estimated amounts of reduction of Rs using SWCNT are 76.08%and 64.23%obtained from the I–V relationship whereas the value of Rs shows a reduction of 83.5%and 67.1%when measured by using the Cheung method for RB and MR dyes respectively.The ideality factor and barrier height of the diodes have also been extracted.The ideality factor has decreased with incorporation of SWCNT.A reduction in barrier height for the devices has also been observed in the presence of SWCNT.展开更多
An analytical model is used to predict the effects of surface recombination current on the gain and transit time of GalnP/GaAs heterojunction bipolar transistors(HBTs).The present analysis shows that consideration o...An analytical model is used to predict the effects of surface recombination current on the gain and transit time of GalnP/GaAs heterojunction bipolar transistors(HBTs).The present analysis shows that consideration of the recombination current gives current gain values that are comparable to those of the experimental results.The dependence of current gain on temperature,base doping and emitter area are also analyzed,and the variation in collector current with emitter-base voltage,temperature and doping is considered.展开更多
In this work,the electrical property of Au/graphene oxide/p-InP hetero-structure has been evaluated by 1-V and C-V measure-ments in dark and iluminated conditions(visible light).The diode exhibited significant rectify...In this work,the electrical property of Au/graphene oxide/p-InP hetero-structure has been evaluated by 1-V and C-V measure-ments in dark and iluminated conditions(visible light).The diode exhibited significant rectifying behavior,thus indicating the heterojunction-lype diode.The key electrical parameters of heterojunction diode including ideality factor(n),series resistance(R),shunt resistance(Rsh),and barrier height(Фb)are estimated from I-V data based on the theory of thermionic emission.The modifed Norde and Cheung's methods were utilized to evaluate the electrical parameters and compared the results.The current conduction mechanism at different voltage regions of I-V has also been investigated.The variation of 1/C versus voltage signifies linearity at high frequency(1 MHz),indicating that the type of heterojunction can be abrupt.The experimental outcomes of this study revealed that the performance of heterojunction diode in dark is considerably good as compared to the ilumination condition with respect to the lower values of Фp,n,R,and interface state density(Nss).展开更多
Based on current voltage(I-Vg) and capacitance voltage(C-Vg) measurements,a reliable procedure is proposed to determine the effective surface potential Vd(Vg) in Schottky diodes.In the framework of thermionic em...Based on current voltage(I-Vg) and capacitance voltage(C-Vg) measurements,a reliable procedure is proposed to determine the effective surface potential Vd(Vg) in Schottky diodes.In the framework of thermionic emission,our analysis includes both the effect of the series resistance and the ideality factor,even voltage dependent. This technique is applied to n-type indium phosphide(n-InP) Schottky diodes with and without an interfacial layer and allows us to provide an interpretation of the observed peak on the C-Vg measurements.The study clearly shows that the depletion width and the flat band barrier height deduced from C-Vg,which are important parameters directly related to the surface potential in the semiconductor,should be estimated within our approach to obtain more reliable information.展开更多
The CuInGeSe_4 thin film was deposited onto n-type single crystal silicon wafers by the electron beam deposition technique. The Au/CuInGeSe_4/n-Si/Al heterojunction device has been fabricated. The structure of the CuI...The CuInGeSe_4 thin film was deposited onto n-type single crystal silicon wafers by the electron beam deposition technique. The Au/CuInGeSe_4/n-Si/Al heterojunction device has been fabricated. The structure of the CuInGeSe_4 thin film was characterized by X-ray diffraction(XRD), scanning electron microscope(SEM), and energy dispersive X-ray analysis(EDX). The dark current-voltage characteristics of the Au/CuInGeSe_4/n-Si/Al heterojunction diode have been studied at a temperature range of 303-383 K. Also, the photovoltaic properties were examined at different illumination intensities. The capacitance-voltage characteristics of the CuInGeSe_4/n-Si heterojunction were studied at different temperatures in the dark.展开更多
文摘Small high-quality Au/P-Si Schottky barrier diodes(SBDs) with an extremely low reverse leakage current using wet lithography were produced.Their effective barrier heights(BHs) and ideality factors from current-voltage (Ⅰ-Ⅴ) characteristics were measured by a conducting probe atomic force microscope(C-AFM).In spite of the identical preparation of the diodes there was a diode-to-diode variation in ideality factor and barrier height parameters.By extrapolating the plots the built in potential of the Au /p-Si contact was obtained as V_(bi)=0.5425 V and the barrier height valueΦ_(b(c-V)) was calculated to beΦ_(B(C-V))=0.7145 V for Au/p-Si.It is found that for the diodes with diameters smaller than 100μm,the diode barrier height and ideality factor dependency to their diameters and correlation between the diode barrier height and its ideality factor are nonlinear,where similar to the earlier reported different metal semiconductor diodes in the literature,these parameters for the here manufactured diodes with diameters more than 100μm are also linear.Based on the very obvious sub-nanometer C-AFM produced pictures the scientific evidence behind this controversy is also explained.
文摘Photovoltaic solar energy can be obtained by using several types of technologies, including silicon solar cells. The characterization of its solar cells makes it possible to know them better. This article presents, on the one hand, the work that has been carried out on these cells. On the other hand, a theoretical study of the cell under illumination using Lambert’s W function. On the basis of the electrical parameters provided by the manufacturer, the parameters such as the series and shunt resistances and the electrical quantities such as the photocurrent and the photovoltage, are determined and studied according to the ideality factor of the diode. From the results obtained the shunt resistance increases when the ideality factor increases, the series resistance decreases very weakly.
文摘This paper describes the fabrication and electrical characteristics of Ti/4H-SiC Schottky barrier diodes (SBDs). The ideality factor n = 1.08 and effective Schottky barrier heightφ= 1.05eV of the SBDs were measured with the method of forward current density-voltage (J-V). A low reverse leakage current below 5.96 ×10^-3A/cm^2 at a bias voltage of - 1. 1kV was obtained. By using B^+ implantation,an amorphous layer as the edge termination was formed. We used the PECVD SiO2 as the field plate dielectric. The SBDs have an on-state current density of 430A/cm^2 at a forward voltage drop of about 4V. The specific on-resistance Ro, was found to be 6. 77mΩ2 · cm^2 .
基金Project supported by the National Natural Science Foundation of China(Grant No.11002013201102)the National Key Technology R & D Program of China(Grant No.2011BAE01B14)
文摘In order to investigate their electrical characteristics, high-voltage light-emitting-diodes (HV-LEDs) each contain- ing four cells in series are fabricated. The electrical parameters including varying voltage and parasitic effect are studied. It is shown that the ideality factors (IFs) of the HV-LEDs with different numbers of cells are 1.6, 3.4, 4.7, and 6.4. IF increases linearly with the number of cells increasing. Moreover, the performance of the HV-LED with failure cells is examined, The analysis indicates that the failure cell has a parallel resistance which induces the leakage of the failure cell. The series resistance of the failure cell is 76.8 Ω, while that of the normal cell is 21.3 Ω. The scanning electron microscope (SEM) image indicates that different metal layers do not contact well. It is hard to deposit the metal layers in the deep isolation trenches. The fabrication process of HV-LEDs needs to be optimized.
文摘Recently GaN-based high electron mobility transistors (HEMTs) have revealed the superior properties of a high breakdown field and high electron saturation velocity. Reduction of the gate leakage current is one of the key issues to be solved for their further improvement. This paper reports that an Al layer as thin as 3 nm was inserted between the conventional Ni/Au Schottky contact and n-GaN epilayers, and the Schottky behaviour of Al/Ni/Au contact was investigated under various annealing conditions by current-voltage (I-V) measurements. A non-linear fitting method was used to extract the contact parameters from the I-V characteristic curves. Experimental results indicate that reduction of the gate leakage current by as much as four orders of magnitude was successfully recorded by thermal annealing. And high quality Schottky contact with a barrier height of 0.875 eV and the lowest reverse-bias leakage current, respectively, can be obtained under 12 min annealing at 450 ℃ in N2 ambience.
文摘In this work, a dislocation-related tunneling leakage current model is developed to explain the temperature-dependent reverse current–voltage(I–V –T) characteristics of a Schottky barrier diode fabricated on free-standing GaN substrate for reverse-bias voltages up to-150 V. The model suggests that the reverse leakage current is dominated by the direct tunneling of electrons from Schottky contact metal into a continuum of states associated with conductive dislocations in GaN epilayer.A reverse leakage current ideality factor, which originates from the scattering effect at metal/GaN interface, is introduced into the model. Good agreement between the experimental data and the simulated I–V curves is obtained.
基金Project supported by the Foundation of Key Laboratory of General Armament Department, China (Grant No 5132030102QT0101)
文摘Fundamentals of the Schottky contacts and the high-temperature current conduction through three kinds of Schottky diodes are studied. N-Si Schottky diodes, GaN Schottky diodes and AlGaN/GaN Schottky diodes are investigated by I-V-T measurements ranging from 300 to 523 K. For these Schottky diodes, a rise in temperature is accompanied with an increase in barrier height and a reduction in ideality factor. Mechanisms are suggested, including thermionic emission, field emission, trap-assisted tunnelling and so on. The most remarkable finding in the present paper is that these three kinds of Schottky diodes are revealed to have different behaviours of high-temperature reverse currents. For the n-Si Schottky diode, a rise in temperature is accompanied by an increase in reverse current. The reverse current of the GaN Schottky diode decreases first and then increases with rising temperature. The AlGaN/GaN Schottky diode has a trend opposite to that of the GaN Schottky diode, and the dominant mechanisms are the effects of the piezoelectric polarization field and variation of two-dimensional electron gas charge density.
基金supported by Gazi University Scientific Research Project (BAP),FEF. 05/2012-15
文摘In this paper, the electrical parameters of Au/n-Si (MS) and Au/Si3N4/n-Si (MIS) Schottky diodes are obtained from the forward bias current-voltage (I-V) and capacitance-voltage (C-V) measurements at room temperature. Experimental results show that the rectifying ratios of the MS and MIS diodes at ± 5 V are found to be 1.25 ×103 and 1.27 ×104, respectively. The main electrical parameters of the MS and MIS diodes, such as the zero-bias barrier height (rbBo) and ideality factor (n), are calculated to be 0.51 eV (I-V), 0.53 eV (C-V), and 4.43, and 0.65 eV (I-V), 0.70 eV (C-V), and 3.44, respectively. In addition, the energy density distribution profile of the interface states (Nss) is obtained from the forward bias I-V, and the series resistance (Rs) values for the two diodes are calculated from Cheung's method and Ohm's law.
文摘The I-V characteristic of GaN-based p-i-n ultraviolet detector is presented. It is measured at different temperatures and analyzed with changing temperature. The ideality factor of the device is 2.09 at room temperature. The maximum ideality factor is 2.14 at 100 ℃, which declines above 100 ℃, and the minimum ideality factor is 1.26 at 300 ℃. The coefficient of forward voltage vs. temperature is -1.97 mV/℃ with a forward current of 1 mA. Based on double injection model, the deep lying impurity activation energy in the i-region is 0.1 343 eV.
文摘A single diode model for a photovoltaic solar module is the most ideal and quick way of analyzing the module characteristics before implementing them in a solar plant. Solar modules manufacturers provide information for three critical points that are essential in I-V, P-V or P-I curves. In this study, we propose four separate simulation procedures to estimate the five-model parameters of an analogous single diode equivalent circuit by utilizing three cardinal points of the photovoltaic module I-V curve, described from experimental data using a solar simulator and manufacturer’s datasheet. The main objective is to extract and use the five unknown parameters of a single diode model to describe the photovoltaic system using I-V ad P-V plots under different environmental conditions. The most influential parameters that greatly alter the cardinal points defined at short circuit point (SCP), the maximum power point (MPP) and the open circuit point(OCP) are the ideality factor (</span><i><span style="font-family:Verdana;">n</span></i><span style="font-family:Verdana;">) and the diode saturation current (</span><i><span style="font-family:Verdana;">I<sub>o</sub></span></i><span style="font-family:Verdana;">). For a quick and fast convergence, we have determined the optimal ideality factor (</span><i><span style="font-family:Verdana;">n<sub>o</sub></span></i><span style="font-family:Verdana;">) and optimal saturation current (</span><i><span style="font-family:Verdana;">I<sub>oopt</sub></span></i><span style="font-family:Verdana;">) as the primary parameters by first assuming the optimal values of </span><i><span style="font-family:Verdana;">R<sub>sh</sub></span></i><span style="font-family:Verdana;">, </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">I<sub>ph</sub> </span></i><span style="font-family:Verdana;">at standard test conditions (STC). Further, we evaluated the effects of </span><i><span style="font-family:Verdana;">I<sub>ph</sub></span></i><span style="font-family:Verdana;">, </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">R<sub>sh</sub> </span></i><span style="font-family:Verdana;">on I-V and P-V curves by considering the values of </span><i><span style="font-family:Verdana;">n </span></i><span style="font-family:Verdana;">below </span><i><span style="font-family:Verdana;">n</span><sub><span style="font-family:Verdana;">o</span></sub></i><span style="font-family:Verdana;">. We have evaluated different iterative procedures of determining </span><i><span style="font-family:Verdana;">R<sub>sh</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">at open-circuit, short-circuit point and the maximum-power points. These procedures have been classified into four approaches that guarantees positive shunt and series resistance for </span><i><span style="font-family:Verdana;">n </span></i><span style="font-family:Verdana;">≤</span><i><span style="font-family:Verdana;"> n<sub>o</sub></span></i><span style="font-family:Verdana;">. These approaches have been categorized by deriving the saturation current as a dependent variable at each cardinal point with or without </span><i><span style="font-family:Verdana;">R<sub>s</sub> </span></i><span style="font-family:Verdana;">and </span><i><span style="font-family:Verdana;">R<sub>sh</sub> </span></i><span style="font-family:Verdana;">pair. The values obtained for the five parameters have been used to simulate the photovoltaic solar module characteristic curves with great precision at different air temperatures and irradiances, considering the effect of Nominal Operating Cell Temperature (NOCT).
基金financially supported by the National Natural Science Foundation of China(51702038)the Science&Technology Department of Sichuan Province(2020YFG0061)the Recruitment Program for Young Professionals.
文摘Despite the rapid development of power conversion efficiency(PCE)for halide perovskite solar cells(PSCs),the lattice strain engineering in perovskite thin films has been rarely probed in recent years.Herein,a strain compensation by homogeneous crystallization in perovskite films is achieved with the aid of precursor aging in the mixed-cation perovskite of Cs_(0.05)(FA_(0.83)MA_(0.17))Pb(I_(0.90)Br_(0.10))_(3)with near 20%PCE in inverted devices.The homogeneous crystallization releases the residual tensile stress and induces more compressive stress at the edges of perovskite films,thus elongating the carrier lifetime and reducing the trap-assisted carrier recombination.The high dependence on the perovskite components in strain engineering strategy was systematically revealed,wherein MAPbI_(3)and Cs_(0.05)(FA_(0.83)MA_(0.17))PbI_(3)film showed an increased compressive strain and FAPbI3 film showed adverse tensile strain after aging.The density functional theory(DFT)calculations are further performed to reveal the change of electronic features.The precursor aging-induced strain modulation was correlated with a systematic characterization of the charge carrier transport and recombination dynamics in the mixed-cation perovskite films.We believe that this facile approach provides a novel strain engineering strategy for PSCs technology.
基金he National Research Foundation of Korea(NRF)grant funded by the Korean Government(2020R1A2C3003958)the Basic Science Research Program(Priority Research Institute)through the NRF grant funded by the Ministry of Education(2021R1A6A1A10039823)the Korea Basic Science Institute(National Research Facilities and Equipment Center)grant funded by the Ministry of Education(2020R1A6C101B194).
文摘Organic light-emitting diodes(OLEDs)have demonstrated remarkable advancements in both device lifetime and luminous efficiency.However,insufficient operation lifetime due to device degradation remains a major hurdle,especially for brighter devices.Understanding the degradation mechanisms of OLEDs due to the degradation of functional materials and the formation of defects in device architectures continues to be a significant challenge.Herein,we evaluate the degradation characteristics by scrutinizing the electrical and optical properties,as well as analyzing the charge carrier dynamics in pristine and aged states of phosphorescent OLEDs(PhOLEDs).We show that degradation mechanisms in PhOLEDs can be elucidated in terms of the ideality factors of current and luminance in pristine and aged device states.The consistent shifts in distinct ideality factors across various states points out that the device degradation is attributed to the deterioration of the guest material,i.e.green-light-emitting phosphorescent material.Conversely,the incongruity in ideality factor changes between the two states indicates that the degradation results from the deterioration of non-light-emitting material.Subsequent characterization experiments provide further evidence that this degradation is primarily attributed to the deterioration of CBP-host material.The thorough understanding of degradation mechanisms established in this study can contribute to realizing the highly reliable PhOLEDs with a long lifetime.
基金Project supported by the State Key Development Program for Basic Research of China and the National Natural Science Foundation of China(Nos.60936005,60976066)
文摘The linear cofactor difference operator(LCDO) method,a direct parameter extraction method for general diodes,is presented.With the developed LCDO method,the extreme spectral characteristic of the diode voltage-current curves is revealed,and its extreme positions are related to the diode characteristic parameters directly.The method is applied to diodes with different sizes and temperatures,and the related characteristic parameters,such as reverse saturation current,series resistance and non-ideality factor,are extracted directly.The extraction result shows good agreement with the experimental data.
基金the Defence Research Development Organization(DRDO),India
文摘The influence of temperature on the intensity of light emitted by as well as the carrier life time r of a standard A1GaAs based light emitting diode has been investigated in the temperature range from 345 to 136 K. The open-circuit voltage decay (OCVD) technique has been used for measured the carrier lifetime. Our experimental results reveal a 16% average increase in intensity and a 163.482-19.765 ns variation in carrier lifetime in the above temperature range. Further, theoretical and experimental analysis show that for negligible carrier density the intensity is inversely proportional to carrier lifetime for this sample.
文摘We investigate the dominant dark current transport mechanism in Si based p-i-n photodiodes, namely, BPW 21R, SFH 205FA and BPX 61 photodiodes in the temperature range of 350 to 139 K. The forward current- voltage characteristics of these photodiodes are explained via the tunneling enhanced recombination model, which gives a quantitative description of the electronic mechanism in the p-i-n junction photodiodes. The observed tem- perature dependence of the saturation current and the diode ideality factor of these devices agree well with theo- retical predictions; the analysis also indicates the importance of doping for enhancement of tunneling. The present study will be helpful in applying the devices at low temperature ambience.
基金the University Grants Commission (UGC) Indiathe Council of Scientific and Industrial Research (CSIR) India Jadavpur University,India for providing the required support for the experiment
文摘The influence of single walled carbon nanotube(SWCNT)on the series resistanceof Rose Bengal(RB)and Methyl Red(MR)dye-based organic diodes has been studied.It has been revealed from experimental results that SWCNT has a significant effect on Rs.The values of Rs are measured from current–voltage(I–V)characteristics and also by utilizing the Cheung method.Obtained values from the Cheung method have been verified using H(I)–I plots for all dye-based devices.The extracted values using these two processes show a good consistency with each other.It is observed that Rs is reduced significantly by incorporating SWCNT for both dyes.The estimated amounts of reduction of Rs using SWCNT are 76.08%and 64.23%obtained from the I–V relationship whereas the value of Rs shows a reduction of 83.5%and 67.1%when measured by using the Cheung method for RB and MR dyes respectively.The ideality factor and barrier height of the diodes have also been extracted.The ideality factor has decreased with incorporation of SWCNT.A reduction in barrier height for the devices has also been observed in the presence of SWCNT.
文摘An analytical model is used to predict the effects of surface recombination current on the gain and transit time of GalnP/GaAs heterojunction bipolar transistors(HBTs).The present analysis shows that consideration of the recombination current gives current gain values that are comparable to those of the experimental results.The dependence of current gain on temperature,base doping and emitter area are also analyzed,and the variation in collector current with emitter-base voltage,temperature and doping is considered.
基金The authors would like to thank the National Science Fund for Excellent Young Scholars(51722509)National Key Research and Development Program of China(2017YFB1104700)+1 种基金Program for Science and Technology Innovation Group of Shaanxi Province(2019TD-011)Key Research and Development Program of Shaanxi Province(2020ZDLGY04-02)for support.
文摘In this work,the electrical property of Au/graphene oxide/p-InP hetero-structure has been evaluated by 1-V and C-V measure-ments in dark and iluminated conditions(visible light).The diode exhibited significant rectifying behavior,thus indicating the heterojunction-lype diode.The key electrical parameters of heterojunction diode including ideality factor(n),series resistance(R),shunt resistance(Rsh),and barrier height(Фb)are estimated from I-V data based on the theory of thermionic emission.The modifed Norde and Cheung's methods were utilized to evaluate the electrical parameters and compared the results.The current conduction mechanism at different voltage regions of I-V has also been investigated.The variation of 1/C versus voltage signifies linearity at high frequency(1 MHz),indicating that the type of heterojunction can be abrupt.The experimental outcomes of this study revealed that the performance of heterojunction diode in dark is considerably good as compared to the ilumination condition with respect to the lower values of Фp,n,R,and interface state density(Nss).
文摘Based on current voltage(I-Vg) and capacitance voltage(C-Vg) measurements,a reliable procedure is proposed to determine the effective surface potential Vd(Vg) in Schottky diodes.In the framework of thermionic emission,our analysis includes both the effect of the series resistance and the ideality factor,even voltage dependent. This technique is applied to n-type indium phosphide(n-InP) Schottky diodes with and without an interfacial layer and allows us to provide an interpretation of the observed peak on the C-Vg measurements.The study clearly shows that the depletion width and the flat band barrier height deduced from C-Vg,which are important parameters directly related to the surface potential in the semiconductor,should be estimated within our approach to obtain more reliable information.
文摘The CuInGeSe_4 thin film was deposited onto n-type single crystal silicon wafers by the electron beam deposition technique. The Au/CuInGeSe_4/n-Si/Al heterojunction device has been fabricated. The structure of the CuInGeSe_4 thin film was characterized by X-ray diffraction(XRD), scanning electron microscope(SEM), and energy dispersive X-ray analysis(EDX). The dark current-voltage characteristics of the Au/CuInGeSe_4/n-Si/Al heterojunction diode have been studied at a temperature range of 303-383 K. Also, the photovoltaic properties were examined at different illumination intensities. The capacitance-voltage characteristics of the CuInGeSe_4/n-Si heterojunction were studied at different temperatures in the dark.