A total of 45 alkylbenzenes were detected and identified in crude oils with different depositional environments and thermal maturities from the Tarim Basin,Beibuwan Basin,and Songliao Basin using comprehensive two-dim...A total of 45 alkylbenzenes were detected and identified in crude oils with different depositional environments and thermal maturities from the Tarim Basin,Beibuwan Basin,and Songliao Basin using comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry(GC×GCTOFMS).By analyzing the distribution characteristics of C0-C5alkylbenzenes,it is found that the content of some alkylbenzenes varies greatly in crude oils.Based on the distribution characteristics of 1,2,4,5-tetramethylbenzene(Te MB)and 1,2,3,4-Te MB,the ratio of 1,2,4,5-Te MB to 1,2,3,4-Te MB is proposed to indicate the organic matter origin and depositional environment of ancient sediments.Oil samples originated mainly from lower hydrobiont,algae,bacteria and source rocks deposited under reducing/anoxic conditions have low 1,2,4,5-/1,2,3,4-Te MB values(less than 0.6),while oil samples originated mainly from terrestrial higher plants and source rocks deposited under oxic/sub-oxic conditions have higher 1,2,4,5-/1,2,3,4-Te MB values(greater than 1.0).The significant difference of 1,2,4,5-/1,2,3,4-Te MB values is controlled by 1,2,4,5-Te MB content.1,2,4,5-Te MB content in oils derived from source rocks deposited in oxidized sedimentary environment(greater than 1.0 mg/g whole oil)is higher than that in oils from source rocks deposited in reduced sedimentary environment(less than 1.0 mg/g whole oil).1,2,4,5-/1,2,3,4-Te MB ratio might not or slightly be affected by evaporative fractionation,biodegradation and thermal maturity.1,2,4,5-/1,2,3,4-Te MB ratio and 1,2,4,5-Te MB content can be used as supplementary parameter for the identification of sedimentary environment and organic matter input.It should be noted that compared to the identification of organic matter sources,the 1,2,4,5-/1,2,3,4-Te MB parameter is more effective in identifying sedimentary environments.展开更多
The effect of various depositional parameters including paleoclimate,paleosalinity and provenance,on the depositional mechanism of lacustrine shale is very important in reconstructing the depositional environment.The ...The effect of various depositional parameters including paleoclimate,paleosalinity and provenance,on the depositional mechanism of lacustrine shale is very important in reconstructing the depositional environment.The classification of shale lithofacies and the interpretation of shale depositional environment are key features used in shale oil and gas exploration and development activity.The lower 3rd member of the Eocene Shahejie Formation(Es_(3)^(x)shale)was selected for this study,as one of the main prospective intervals for shale oil exploration and development in the intracratonic Bohai Bay Basin.Mineralogically,it is composed of quartz(avg.9.6%),calcite(avg.58.5%),dolomite(avg.7%),pyrite(avg.3.3%)and clay minerals(avg.20%).An advanced methodology(thin-section petrography,total organic carbon and total organic sulfur contents analysis,X-ray diffraction(XRD),X-ray fluorescence(XRF),field-emission scanning electron microscopy(FE-SEM))was adopted to establish shale lithofacies and to interpret the depositional environment in the lacustrine basin.Six different types of lithofacies were recognized,based on mineral composition,total organic carbon(TOC)content and sedimentary structures.Various inorganic geochemical proxies(Rb/Sr,Ca/(Ca+Fe),Ti/Al,Al/Ca,Al/Ti,Zr/Rb)have been used to interpret and screen variations in depositional environmental parameters during the deposition of the Es_(3)^(x)shale.The experimental results indicate that the environment during the deposition of the Es_(3)^(x)shale was warm and humid with heightened salinities,moderate to limited detrital input,higher paleohydrodynamic settings and strong oxygen deficient(reducing)conditions.A comprehensive depositional model of the lacustrine shale was developed.The interpretations deduced from this research work are expected to not only expand the knowledge of shale lithofacies classification for lacustrine fine-grained rocks,but can also offer a theoretical foundation for lacustrine shale oil exploration and development.展开更多
Tonle Sap sedimentary basin was considered a favorable geological condition for hydrocarbon accumulation in the onshore Cambodia. Two exposure outcrops in Battambang province, called Somlout and Takream, were selected...Tonle Sap sedimentary basin was considered a favorable geological condition for hydrocarbon accumulation in the onshore Cambodia. Two exposure outcrops in Battambang province, called Somlout and Takream, were selected to represent sediments in this basin. The sedimentology and geochemistry studies provide insights into the depositional environment of sediments using field investigation, lithological, sedimentological, paleontological, and geochemical analysis. The redox condition, water column, and depositional setting were analyzed by plotting the ratio of V vs. Cr, Uauthigenic vs. V/Cr, Sr vs. Ba, Ca vs. (Fe + Ca), and Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> vs. Al<sub>2</sub>O<sub>3</sub>/(Al<sub>2</sub>O<sub>3</sub> + Fe<sub>2</sub>O<sub>3</sub>) diagram. Moreover, these diagrams can be used to predict depositional conditions as well. Based on the results, Somlout and Takream comprise calcareous shale and limestone facies. The geochemical analysis showed that Somlout calcareous shale samples were deposited in the dysoxic freshwater of the lake setting during the regression, while Somlout limestones and Takream were deposited in high salinity seawater, oxic condition of shallow-marine water. In addition, Somlout limestones consist of fragmental fusulinid foraminifera, bivalve shelve, and bryozoan, which suggest a barrier environment. Meanwhile, Teakream consists of fine-grained calcareous shale, and lime-mudstone, which are presented to form in the quiet marine setting of the lagoon environment. Therefore, the Tonle Sap basin sediments were deposited in the Somlout area’s barrier and lake environment, and the lagoon environment for Takream.展开更多
The southern margin of the Gurbantunggut Desert,China,is characterized by alternating layers of aeolian and alluvial deposits.Investigating the characteristics of arenaceous sediment in this area is of significant imp...The southern margin of the Gurbantunggut Desert,China,is characterized by alternating layers of aeolian and alluvial deposits.Investigating the characteristics of arenaceous sediment in this area is of significant importance for understanding the interactive processes of wind and water forces,as well as the provenance of sediment.However,there are relatively few investigations on the characteristics of such sediment at present.In this study,we researched three aeolian-alluvial interactive stratigraphic profiles and different types of surface sediment on the desert-oasis transitional zone of southern margin of the Gurbantunggut Desert.Based on the optically stimulated luminescence(OSL)dating of aeolian sand and analyses of quartz sand grain size and surface micro-texture,we explored the aeolian-alluvial environmental change at southern margin of the desert in Holocene,as well as the provenance of sediment.The results indicated that the grain size characteristics of different types of sediment in the stratigraphic profiles were similar to those of modern dune sand,interdune sand,muddy desert surface soil,and riverbed sand.Their frequency curves were unimodal or bimodal,and cumulative probability curves were two-segment or three-segment,mainly composed of suspension load and saltation load.The quartz sand in the sediment at southern margin of the desert had undergone alternating transformation of various exogenic forces,with short transportation distance and time,and sedimentary environment was relatively humid.In Holocene,southern margin of the desert primarily featured braided river deposits,and during intermittent period of river activity,there were also aeolian deposits such as sand sheet deposits,stabilized dune deposits,and mobile dune deposits.The provenance for Holocene alluvial deposits at southern margin of the desert remains relatively constant,with the debris of the Tianshan Mountains being the primary provenance.Aeolian sand is mainly near-source recharge,which is formed by in situ deposition of fluvial or lacustrine materials in southern margin of the desert transported by wind erosion,and its provenance was still the weathered debris of the Tianshan Mountains.In addition,the sand in interior of the desert may be transported by northwest wind in desert-scale,thus affecting the development of dunes in southern margin of the desert.The results of this study provide a reference for understanding the composition and provenance changes of desert sand in the context of global climate change.展开更多
The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these i...The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these issues,based on Rock-Eval pyrolysis,kerogen macerals,H/C and O/C ratios,GC-MS,major and trace elements,the Dongying Formation Member(Mbr)3(E_(3)d_(3)),the Shahejie Formation mbrs 1 and 2(E_(2)s_(1+2)),and the Shahejie Mbr 3(E_(2)s_(3))source rocks in the western Bozhong Sag were studied.The above methods were used to reveal their geochemical properties,OM origins and depositional environments,all of which indicate that E_(2)s_(1+2)and E_(2)s_(3)are excellent source rocks,and that E_(3)d_(3)is of the second good quality.E_(3)d_(3)source rocks were formed under a warm and humid climate,mainly belong to fluvial/delta facies,the E_(3)d_(3)sediments formed under weakly oxidizing and freshwater conditions.Comparatively,the depositional environments of E_(2)s_(1+2)source rocks were arid and cold climate,representing saline or freshwater lacustrine facies,and the sediments of E_(2)s_(1+2)belong to anoxic or suboxic settings with large evaporation and salinity.During the period of E_(2)s_(3),the climate became warm and humid,indicating the freshwater lacustrine facies,and E_(2)s_(3)was characterized by freshwater and abundant algae.Moreover,compared with other intervals,the OM origin of E_(3)d_(3)source rocks has noticeable terrestrial input.The OM origin of the E_(2)s_(1+2)and E_(2)s_(3)are mainly plankton and bacteria.Tectonic subsidence and climate change have affected the changes of the depositional environment in the western Bozhong Sag,thus controlling the distribution of the source rocks,the geochemical characteristics in the three intervals of lacustrine source rocks have distinct differences.Overall,these factors are effective to evaluate the paleoenvironmental characteristics of source rocks by biomarkers,major and trace elements.The established models may have positive implications for research of lacustrine source rocks in offshore areas with few drillings.展开更多
The Dunhuang–Golmud railway passes through different deserts in arid areas,especially drifting-sand desert and sandy-gravel Gobi.The near-surface wind environment and wind-sand transport process vary due to different...The Dunhuang–Golmud railway passes through different deserts in arid areas,especially drifting-sand desert and sandy-gravel Gobi.The near-surface wind environment and wind-sand transport process vary due to different external factors,such as topography,vegetation,and regional climate,resulting in evident spatial differences in surface erosion and deposition.Consequently,the measures for preventing wind-sand hazards will differ.However,the mechanism and control theory of sand damage remain poorly understood.In this study,we used meteorological observation,three-dimensional(3D)laser scanning,and grain-size analysis to compare and evaluate the spatial distribution of wind conditions,sand erosion and deposition patterns,and grain composition in the drifting-sand desert and sandy-gravel Gobi along the Dunhuang–Golmud railway in China.Results show that the annual mean wind speed,the frequency of sand-driving wind,and the drift potential of sandy-gravel Gobi are higher than those of drifting-sand desert,indicating a greater wind strength in the sandy-gravel Gobi,which exhibits spatial heterogeneity in wind conditions.The major sediment components in sandy-gravel Gobi are very fine sand,fine sand,and medium sand,and that in drifting-sand desert are very fine sand and fine sand.We found that the sediment in the sandy-gravel Gobi is coarser than that in the drifting-sand desert based on mean grain size and sediment component.The spatial distributions of sand erosion and deposition in the sandy-gravel Gobi and drifting-sand desert are consistent,with sand deposition mainly on the west side of the railway and sand erosion on the east side of the railway.The area of sand deposition in the drifting-sand desert accounts for 75.83%of the total area,with a mean deposition thickness of 0.032 m;while the area of sand deposition in the sandy-gravel Gobi accounts for 65.31%of the total area,with a mean deposition thickness of 0.028 m,indicating greater deposition amounts in the drifting-sand desert due to the presence of more fine sediment components.However,the sand deposition is more concentrated with a greater thickness on the embankment and track in the sandy-gravel Gobi and is dispersed with a uniform thickness in the drifting-sand desert.The sand deposition on the track of the sandy-gravel Gobi mainly comes from the east side of the railway.The results of this study are helpful in developing the preventive measures and determining appropriate selection and layout measures for sand control.展开更多
In the southwestern Tianshan,the geologic ages of many strata and their depositional environments are still poorly constrained because of complex structures.The Mada'er area is located in the Kuokesaleling belt,South...In the southwestern Tianshan,the geologic ages of many strata and their depositional environments are still poorly constrained because of complex structures.The Mada'er area is located in the Kuokesaleling belt,Southwestern Tianshan.The cherts from the former Wupata'erkan Group contain abundant radiolarian fossils,including 10 species which are identified as late Devonian to early Carboniferous in age.Eleven chert samples have SiO_2 contents ranging from 88.80 wt%to 93.28 wt%, and 2.02 wt%to 3.72 wt%for Al_2O_3.The SiO_2/Al_2O_3 ratios of all samples vary from 23.84 to 46.11, much lower than those of the pure cherts(80-1400).These values suggest that the cherts contain high ratios of terrigenous materials.The Al_2O_3/(Al_2O_3+Fe_2O_3)ratios vary between 0.64 and 0.77,whereas V and Cu concentrations range from 10.92 ppm to 26.7 ppm and from 2.15 ppm to 34.1 ppm respectively. The Ti/V ratios vary from 25.53 to 44.93.The total REE concentrations of the cherts are between 30.78 ppm and 59.26 ppm,averaging 45.46 ppm.The(La/Ce)_N ratios range from 0.81 to 1.12,and 0.88-1.33 for(La/Yb)_N,averaging 1.09,which suggests a continental margin environment.Consequently,it is inferred that the cherts formed in a residual sea environment during the late Devonian to early Carboniferous time,which suggests that the collision between the Karakum-Tarim and Kazakhstan-Junggar plates did not occur at the time.In addition,the regional geological information indicates that the study area experienced a post-collision stage during the early Permian,and thus it is likely that the collision between the two plates took place in the late Carboniferous.展开更多
Gas-bearing deposits in the Lower Mingyuefeng Formation of Paleogene, Lishui Sag, East China Sea Shelf Basin consist of shoreface sandstones of the highstand systems tract(HST) and transgressive systems tract(TST)...Gas-bearing deposits in the Lower Mingyuefeng Formation of Paleogene, Lishui Sag, East China Sea Shelf Basin consist of shoreface sandstones of the highstand systems tract(HST) and transgressive systems tract(TST), and deltaic sandstones of the lowstand systems tract(LST) and falling stage systems tract(FSST).Detailed petrographic observations suggest that the diagenetic features and related evolution of these deposits cannot be simply characterized and demonstrated in the depth domain.However, the occurrence of diagenetic minerals systematically depends on the studied interval within the HST, TST, LST, and FSST; therefore, diagenesis in this region can be better constrained when studied in the context of the depositional environments and sequence stratigraphic framework.The eogenetic processes in such settings include:(1) microcrystalline siderite precipitated as concretions in almost all environments and systems tracts, which inhibited further mechanical compaction;(2) grain dissolution and kaolinitization occurred in shoreface HST sandstones and deltaic LST and FSST sandstones;(3) glaucony was locally observed, which did not clearly reflect the controls of facies or sequence stratigraphy; and(4) cementation by pyrite aggregates occurred in the shoreface HST sandstones and deltaic LST sandstones.The mesogenetic diagenesis includes:(1) partial conversion of kaolinite into dickite in deltaic LST sandstones, and minor chlorite cementation in deltaic FSST sandstones;(2) transformation of kaolinite into illite and quartz cementation in deltaic LST and FSST sandstones;(3) frequent precipitation of ankerite and ferroan calcite in shoreface TST sandstones and early HST sandstones, forming baffles and barriers for fluid flow, with common calcite in shoreface HST sandstones as a late diagenetic cement; and(4) formation of dawsonite in the deltaic LST and FSST sandstones, which is interpreted to be a product of the invasion of a CO2-rich fluid, and acts as a good indicator of CO2-bearing reservoirs.This study has thus constructed a reliable conceptual model to describe the spatial and temporal distribution of diagenetic alterations.The results may provide an entirely new conceptual framework and methodology for successful gas exploration in the continental margins of offshore China, thus allowing us to predict and unravel the distribution and quality evolution of clastic reservoirs at a more detailed and reliable scale.展开更多
The present study is based on the sedimentological data from a piston core KCES1 off the southern Ulleung Basin margin,the East Sea(Sea of Japan).The data include sediment color(L^*),X-ray radiographs,grain size ...The present study is based on the sedimentological data from a piston core KCES1 off the southern Ulleung Basin margin,the East Sea(Sea of Japan).The data include sediment color(L^*),X-ray radiographs,grain size distribution and AMS^14C date.Four kinds of sediments(homogeneous,laminated,crudely laminated and hybrid sediments) are identified according to the characters of the sedimentary structures that were considered to reflect changes in bottom-water oxygenation.Alternations of dark laminated/crudely laminated sediments and light homogeneous sediments represent millennial-scale variations that are possibly associated with the high-resolution changes in the East Asian monsoon(EAM).The relative contributions of the East China Sea Coastal Water(ECSCW) and the Tsushima Warm Current(TWC) were likely the main reasons for the repetition of the anoxic and oxic depositional conditions in the East Sea since the last 48 ka BP.During the interstadial,the strengthen summer EAM was attributed to the expansion of the ECSCW because of more humid climate in central Asia,and then more strongly low-salinity,nutrient-enriched water was introduced into the East Sea.The ventilation of deep water was restricted and therefore the dark laminated layer deposited under the anoxic bottom water condition.During the lowest stand of sea level in the last glacial maximum(LGM),the isolated East Sea dominated by stratified water masses and the euxinic depositional environment formed.The homogenous sediments have been predominating since 17.5 ka BP indicating that the TWC has intruded into the East Sea gradually with the stepwise rise of sea level and the bottom water oxygen level was high.During the late Younger Dryas(YD) period,the last dark laminated layer deposited because the ventilation of bottom water was restricted by stronger summer EAM.The TWC strengthened and the bottom water became oxic again from 10.5 ka BP.展开更多
A deeper understanding of the mechanisms by which geological factors(depositional environment and tectonic evolution) control the occurrence of coalbed methane(CBM) is important for the utilization of CBM resources vi...A deeper understanding of the mechanisms by which geological factors(depositional environment and tectonic evolution) control the occurrence of coalbed methane(CBM) is important for the utilization of CBM resources via surface-drilled wells and the elimination of coal-methane outbursts, the latter of which is a key issue for coal mine safety. Based on drill core data, high-pressure isothermal adsorption experiments, scanning electron microscopy experiments, mercury intrusion porosimetry, and X-ray diffraction experiments, the impact of the depositional environment and tectonic evolution on CBM occurrence of the II-1 coal seam of the Shanxi Formation in West Henan was analyzed. Results showed that the depositional environment led to the epigenetic erosion of tidal flat coal-accumulating structures by shallow-delta distributary channel strata. This resulted in the replacement of the original mudstonesandy mudstone coal seam immediate roof with fine-to-medium grained sandstones, reducing methane storage capacity. Epigenetic erosion by the depositional environment also increased coal body ash content(from 6.9% to 21.4%) and mineral content, filling the cleat system and reducing porosity, reducing methane storage capacity. The maximum methane adsorption capacity of the coal body reduced from35.7 cm3/g to 30.30 cm3/g, and Langmuir pressure decreased from 1.39 MPa to 0.909 MPa. Hence, the methane adsorption capacity of the coal body decreased while its capacity for methane desorption increased. Owing to the tectonic evolution of West Henan, tectonically deformed coal is common; as it evolves from primary cataclastic coal to granulitic coal, the angle of the diffraction peak increases, d002 decreases, and La, Lc, and Nc increase; these traits are generally consistent with dynamic metamorphism.This is accompanied by increases in the total pore volume and specific surface area of the coal body, further increasing the capacity for methane storage. Increases in micropore volume and specific surface area also increase the ability of the coal body to adsorb methane.展开更多
The Luconia Province-offshore Sarawak-is a key geological unit for understanding the distribution of hydrocarbon resources in Malaysia. Nevertheless, little effort has been made to address the palaeoenvironmental char...The Luconia Province-offshore Sarawak-is a key geological unit for understanding the distribution of hydrocarbon resources in Malaysia. Nevertheless, little effort has been made to address the palaeoenvironmental characteristics of the Tertiary carbonates in the key sector of Central Luconia.We study the sedimentology and petrography of core samples from a well in Central Luconia, for which thirteen microfacies have been identified reflecting different depositional settings. This is the first microfacies scheme elaborated for Luconian carbonates. Lithofacies and microfacies distribution are compatible with deposition in a reef complex, originating around a framework reef, within the euphotic zone. Sediments were deposited in environments of backreef, reef crest, and forereef. The fair weather wave base is marked by the presence of coralline red algae, foraminifera, decreasing degree of bioclast fragmentation and other microfacies features. As a result, a depositional-environmental model is constructed, depicting a reef complex built around a framework reef developed on the margin of an isolated platform. In addition, an innovative, preliminary time series analysis of facies, microfacies and depositional environment data reveal the existence of seasonal cycles in the stacking patterns of facies and microfacies.展开更多
Shuidonggou site has abundant Paleolithic remains of Late Pleistocene deposition. Studying the evolution of depositional environments is essential to the comprehensive understanding of the living conditions of ancient...Shuidonggou site has abundant Paleolithic remains of Late Pleistocene deposition. Studying the evolution of depositional environments is essential to the comprehensive understanding of the living conditions of ancient populations. To reconstruct the depositional environment at Shuidonggou, we carried out archaeological excavations and collected systematic deposition samples at the key position of Shuidonggou Locality 2 for grain size analysis and sporopollen statistics. The environmental evolution around the Shuidonggou site generally underwent four stages at ~72-18 kaBP. During the first stage (~72-41 kaBP), the river developed with gravel and sand stratums. During the second stage (41-34 kaBP), a swamp with numerous aquatic plants formed. In the third stage (34-29 kaBP), site formation was characterized by shallow lake depositional conditions; the climate was relatively warm and humid. The marginal bank depositional conditions deteriorated during the fourth stage (29-18 kaBP), and the site underwent several dry events; the climate also became drier and colder.展开更多
Objective The Yubei area is located in the mid-east Maigaiti slope of southwestern Tarim Basin, China, with an exploration history of several years. Recent exploration has preliminarily indicated that the Ordovician ...Objective The Yubei area is located in the mid-east Maigaiti slope of southwestern Tarim Basin, China, with an exploration history of several years. Recent exploration has preliminarily indicated that the Ordovician carbonate formations in this area have some oil and gas potential. Carbonate microfacies provides material basis for reservoir development, seal formation and hydrocarbon generation. Therefore, this work utilized the standard microfacies (SMF) types to study the microfacies of the Ordovician formations in the Yubei area in order to provide theoretical basis for the next exploration.展开更多
The Sarvak Formation is the second major oil-bearing reservoir in the south and south west of Iran. The Middle Cretaceous Sarvak formation in the Zagros Mountains (Zagros Basin) is mainly composed of carbonate sequenc...The Sarvak Formation is the second major oil-bearing reservoir in the south and south west of Iran. The Middle Cretaceous Sarvak formation in the Zagros Mountains (Zagros Basin) is mainly composed of carbonate sequences. Based on facies studied, thirteen microfacies were recognized in the studied area, which were categorized in the three facies groups: including inner ramp, mid ramp and outer ramp. Evidences such as the gradual changes in the facies (basin slope), the absence of extensive uninterrupted barrier reef, the lack of calciturbidite and gravity sediments as well as the high proportion of grain-supported indicated that the Sarvak Formation was deposited in the ramp like depositional system, particularly on an inner ramp setting. Inner ramp facies group is the principal setting and subdivided to tidal flat, restricted and unrestricted lagoon as well as shoal sub-environments.展开更多
The Asmari Formation is a thick carbonate sequence of the Oligocene-Miocene in the Zagros Basin, southwest of Iran. This formation is located in Bandar Abbas and Coastal Fars regions on the following two sections: Ang...The Asmari Formation is a thick carbonate sequence of the Oligocene-Miocene in the Zagros Basin, southwest of Iran. This formation is located in Bandar Abbas and Coastal Fars regions on the following two sections: Anguro anticline (west-northwest of Bandar Abbas) and Gavbast anticline (southwest of Lar County). The Asmari Formation has diameters of 68 and 26 m in the Anguro and Gavbast sections, respectively. This formation is composed of limestone, dolomitic limestone and an altered form of marl. Based on the results of petrographic analyses, 7 facies were identified in the Anguro and Gavbast sections in the study region. The facies were deposited on the following 3 belts: tidal flat (MF 1 - 3), lagoon (MF 4 - 5) and open marine (MF 6, 7). According to evidence such as the gradual change of microfacies, the lack of main reef barriers, and the lack of slumping and sliding features, the Asmari Formation was formed in a marine environment of carbonate homoclinal ramp type. This environment is composed of the following two subenvironments: the inner ramp and the middle ramp. The comparison of the facies identified in the Anguro and Gavbast sections indicates that Gavbast section is mainly composed of lagoon facies. Moreover, the Anguro section demonstrates more facies diversity than Gavbast section.展开更多
Early Permian deposits in north of Kalmard region recognize with formal group of Khan;they have various features in the different place. This group includes four different formations from lower to the upper part: Chil...Early Permian deposits in north of Kalmard region recognize with formal group of Khan;they have various features in the different place. This group includes four different formations from lower to the upper part: Chili, Sartakht and Hermez. These formations consist of carbonate rocks. Chili Formation has 104 m, thickness in Darin section and consists of limestone with intermediates of shale and marland sandstone. Lower boundary of this formation is disconformable with Gachal formation. The upper boundary is separated by unconformity from the upper part Sartakht formation according to the lithological characters and microscopic studies, cause identifications of beach, intertidal, open and semi-restricted lagoon, shoals and bar and open marine sub-environ- ments for the Chili Formation. Vertical changes of microfacies and depth changes curve show much more thickness of shoals and bar microfacies, and little thickness of open and semi-re- stricted lagoon and open marine microfacies. Deposits of Chili Formation in Darin section deposited in the gentle gradient Homoclinal ramp in the south of Paleotethys Ocean. Two depositional sequences have been identified in this formation, based on recognized Fusulinid, show age of Sakmarian, which has adaptation with Lower Absaroka III.展开更多
Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatograph...Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry.The bulk carbon isotopic values of the whole rock extracts,saturate and aromatic fractions range from–28.7‰to–26.8‰,–29.2‰to–27.2‰and–28.5‰to–26.7‰,respectively while the bulk carbon isotopic values of the whole oils,saturate and aromatic fractions range from–25.4‰to–27.8‰,–25.9‰to–28.4‰and–23.5‰to–26.9‰,respectively.The average carbon isotopic compositions of individual alkanes(nC12-nC33)in the rock samples range from–34.9‰to–28.2‰whereas the average isotopic values of individual n-alkanes in the oils range from–31.1‰to–23.8‰.Theδ13C isotope ratios of pristane and phytane in the rock samples range from–29.2‰to–28.2‰and–30.2‰to–27.4‰respectively while the pristane and phytane isotopic values range from–32.1‰to–21.9‰and–30.5‰to–26.9‰,respectively.The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments.The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.展开更多
The mechanisms of lacustrine organic-rich shale formation have attracted attention due to its association with global shale oil and shale gas exploration.Samples of general-quality and excellent-quality source rocks,a...The mechanisms of lacustrine organic-rich shale formation have attracted attention due to its association with global shale oil and shale gas exploration.Samples of general-quality and excellent-quality source rocks,and oil shale from the Beibu Gulf Basin were analyzed to investigate their organic geochemistry,palynofacies,and trace elements.Hydrocarbon potential was higher in the oil shale(29.79 mg/g)than in the general-quality source rock(3.82 mg/g),and its kerogen type wasⅠ-Ⅱ2.Hydrogen-rich liptinite(cutinite and sporinite)components derived from terrigenous higher plants provided most of the hydrocarbon potential of excellent-quality source rock and oil shale.Under the influence of depressioncontrolling fault activity,a deeper subsidence center promotes the deposition of excellent-quality source rock and oil shale in brackish-hypoxic bottom water.A shallower subsidence center,due to subsag-controlling fault activity,promotes the formation of excellent-quality source rock under freshbrackish and weak oxidation-weak reducing conditions.The local uplift and shallow-slope led to the formation of general-quality source rock,under freshwater weak-oxidation conditions.A model was established for organic matter(OM)accumulation in organic-rich shales,accounting for fault activity,terrigenous hydrogen-rich OM,and the preservation conditions,to predict the development of excellent-quality source rock from areas with low levels of exploration.展开更多
In this study, to identify and analyze facies of depositional environment and depositional model of Qom Formation, stratigraphic Saran Section (southwest of Semnan) was selected. Qom Formation in Saran section include...In this study, to identify and analyze facies of depositional environment and depositional model of Qom Formation, stratigraphic Saran Section (southwest of Semnan) was selected. Qom Formation in Saran section includes about 380 meters of conglomerate at the base, chalk, limestone, marl, and shale. Petrographic studies with facies analysis have led to the identification of 12 microfacies, these microfacies have been deposited in four facies groups including tidal flat, lagoon, barrier and open marine. Study of horizontal and vertical facies changes and their comparison with recent and ancient environments reveals that Qom Formation in this section relates to shallow marine environment and its facies were deposited in a shelf carbonate platform and are comparable with contemporary shelf platforms such as Florida and old shelf platforms such as Mozduran. The most important diagenetic processes affecting the studied section include micritization, bioturbation, cementation, dissolution, neomorphism, fracturing, mechanical and chemical compaction, hematitization and dolomitization. These processes have formed in marine, meteoric and burial diagenetic environments.展开更多
Differences in rare earth elements and other trace elements in bedded chens reflect the deposihonal settings of the sediments. Based on cerium anomaly (Ce/Ce ), total REE (ΣREE) and other trace element abundance var...Differences in rare earth elements and other trace elements in bedded chens reflect the deposihonal settings of the sediments. Based on cerium anomaly (Ce/Ce ), total REE (ΣREE) and other trace element abundance variahons preserved in the bedded cherts in the Paleo-Tethys, Western Yunnan, three deposihonal regimes can be recotwzed: spreading ridge proximal, ocean-basin floor and conhnental margin. This geochemical method of discriminating deposihonal environments for thine marine sedimentary rocks which are physically indistinct provides a powerful new tool for paleotectonic and paleogeographic recondruchons.展开更多
基金supported by Doctor’s Scientific Research Initiation Project of Yan’an University(YAU202213093)National Natural Science Foundation of China(Grant No.41503029)。
文摘A total of 45 alkylbenzenes were detected and identified in crude oils with different depositional environments and thermal maturities from the Tarim Basin,Beibuwan Basin,and Songliao Basin using comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry(GC×GCTOFMS).By analyzing the distribution characteristics of C0-C5alkylbenzenes,it is found that the content of some alkylbenzenes varies greatly in crude oils.Based on the distribution characteristics of 1,2,4,5-tetramethylbenzene(Te MB)and 1,2,3,4-Te MB,the ratio of 1,2,4,5-Te MB to 1,2,3,4-Te MB is proposed to indicate the organic matter origin and depositional environment of ancient sediments.Oil samples originated mainly from lower hydrobiont,algae,bacteria and source rocks deposited under reducing/anoxic conditions have low 1,2,4,5-/1,2,3,4-Te MB values(less than 0.6),while oil samples originated mainly from terrestrial higher plants and source rocks deposited under oxic/sub-oxic conditions have higher 1,2,4,5-/1,2,3,4-Te MB values(greater than 1.0).The significant difference of 1,2,4,5-/1,2,3,4-Te MB values is controlled by 1,2,4,5-Te MB content.1,2,4,5-Te MB content in oils derived from source rocks deposited in oxidized sedimentary environment(greater than 1.0 mg/g whole oil)is higher than that in oils from source rocks deposited in reduced sedimentary environment(less than 1.0 mg/g whole oil).1,2,4,5-/1,2,3,4-Te MB ratio might not or slightly be affected by evaporative fractionation,biodegradation and thermal maturity.1,2,4,5-/1,2,3,4-Te MB ratio and 1,2,4,5-Te MB content can be used as supplementary parameter for the identification of sedimentary environment and organic matter input.It should be noted that compared to the identification of organic matter sources,the 1,2,4,5-/1,2,3,4-Te MB parameter is more effective in identifying sedimentary environments.
基金supported by the National Science and Technology Major Project of China(Grant No.2017ZX05009-002)the National Natural Science Foundation of China(Nos.U1762217,41702139,42072164 and 41821002)+2 种基金Taishan Scholars Program(No.TSQN201812030)the Fundamental Research Funds for the Central Universities(19CX07003A)the School of Geosciences,China University of Petroleum,East China,for analytical support and financial support。
文摘The effect of various depositional parameters including paleoclimate,paleosalinity and provenance,on the depositional mechanism of lacustrine shale is very important in reconstructing the depositional environment.The classification of shale lithofacies and the interpretation of shale depositional environment are key features used in shale oil and gas exploration and development activity.The lower 3rd member of the Eocene Shahejie Formation(Es_(3)^(x)shale)was selected for this study,as one of the main prospective intervals for shale oil exploration and development in the intracratonic Bohai Bay Basin.Mineralogically,it is composed of quartz(avg.9.6%),calcite(avg.58.5%),dolomite(avg.7%),pyrite(avg.3.3%)and clay minerals(avg.20%).An advanced methodology(thin-section petrography,total organic carbon and total organic sulfur contents analysis,X-ray diffraction(XRD),X-ray fluorescence(XRF),field-emission scanning electron microscopy(FE-SEM))was adopted to establish shale lithofacies and to interpret the depositional environment in the lacustrine basin.Six different types of lithofacies were recognized,based on mineral composition,total organic carbon(TOC)content and sedimentary structures.Various inorganic geochemical proxies(Rb/Sr,Ca/(Ca+Fe),Ti/Al,Al/Ca,Al/Ti,Zr/Rb)have been used to interpret and screen variations in depositional environmental parameters during the deposition of the Es_(3)^(x)shale.The experimental results indicate that the environment during the deposition of the Es_(3)^(x)shale was warm and humid with heightened salinities,moderate to limited detrital input,higher paleohydrodynamic settings and strong oxygen deficient(reducing)conditions.A comprehensive depositional model of the lacustrine shale was developed.The interpretations deduced from this research work are expected to not only expand the knowledge of shale lithofacies classification for lacustrine fine-grained rocks,but can also offer a theoretical foundation for lacustrine shale oil exploration and development.
文摘Tonle Sap sedimentary basin was considered a favorable geological condition for hydrocarbon accumulation in the onshore Cambodia. Two exposure outcrops in Battambang province, called Somlout and Takream, were selected to represent sediments in this basin. The sedimentology and geochemistry studies provide insights into the depositional environment of sediments using field investigation, lithological, sedimentological, paleontological, and geochemical analysis. The redox condition, water column, and depositional setting were analyzed by plotting the ratio of V vs. Cr, Uauthigenic vs. V/Cr, Sr vs. Ba, Ca vs. (Fe + Ca), and Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> vs. Al<sub>2</sub>O<sub>3</sub>/(Al<sub>2</sub>O<sub>3</sub> + Fe<sub>2</sub>O<sub>3</sub>) diagram. Moreover, these diagrams can be used to predict depositional conditions as well. Based on the results, Somlout and Takream comprise calcareous shale and limestone facies. The geochemical analysis showed that Somlout calcareous shale samples were deposited in the dysoxic freshwater of the lake setting during the regression, while Somlout limestones and Takream were deposited in high salinity seawater, oxic condition of shallow-marine water. In addition, Somlout limestones consist of fragmental fusulinid foraminifera, bivalve shelve, and bryozoan, which suggest a barrier environment. Meanwhile, Teakream consists of fine-grained calcareous shale, and lime-mudstone, which are presented to form in the quiet marine setting of the lagoon environment. Therefore, the Tonle Sap basin sediments were deposited in the Somlout area’s barrier and lake environment, and the lagoon environment for Takream.
基金the National Natural Science Foundation of China(42071011)the 2023 Annual Postgraduate Research and Innovation Foundation of Fujian Normal University,China.
文摘The southern margin of the Gurbantunggut Desert,China,is characterized by alternating layers of aeolian and alluvial deposits.Investigating the characteristics of arenaceous sediment in this area is of significant importance for understanding the interactive processes of wind and water forces,as well as the provenance of sediment.However,there are relatively few investigations on the characteristics of such sediment at present.In this study,we researched three aeolian-alluvial interactive stratigraphic profiles and different types of surface sediment on the desert-oasis transitional zone of southern margin of the Gurbantunggut Desert.Based on the optically stimulated luminescence(OSL)dating of aeolian sand and analyses of quartz sand grain size and surface micro-texture,we explored the aeolian-alluvial environmental change at southern margin of the desert in Holocene,as well as the provenance of sediment.The results indicated that the grain size characteristics of different types of sediment in the stratigraphic profiles were similar to those of modern dune sand,interdune sand,muddy desert surface soil,and riverbed sand.Their frequency curves were unimodal or bimodal,and cumulative probability curves were two-segment or three-segment,mainly composed of suspension load and saltation load.The quartz sand in the sediment at southern margin of the desert had undergone alternating transformation of various exogenic forces,with short transportation distance and time,and sedimentary environment was relatively humid.In Holocene,southern margin of the desert primarily featured braided river deposits,and during intermittent period of river activity,there were also aeolian deposits such as sand sheet deposits,stabilized dune deposits,and mobile dune deposits.The provenance for Holocene alluvial deposits at southern margin of the desert remains relatively constant,with the debris of the Tianshan Mountains being the primary provenance.Aeolian sand is mainly near-source recharge,which is formed by in situ deposition of fluvial or lacustrine materials in southern margin of the desert transported by wind erosion,and its provenance was still the weathered debris of the Tianshan Mountains.In addition,the sand in interior of the desert may be transported by northwest wind in desert-scale,thus affecting the development of dunes in southern margin of the desert.The results of this study provide a reference for understanding the composition and provenance changes of desert sand in the context of global climate change.
基金funded by the“Key Scientific Issues and Innovative Technology Research on Oil and Gas Resource Exploration in China Sea Risk Exploration Area”(Grant No.CCL2022RCPS2017XNN)from CNOOC Research Institute,Beijing.
文摘The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these issues,based on Rock-Eval pyrolysis,kerogen macerals,H/C and O/C ratios,GC-MS,major and trace elements,the Dongying Formation Member(Mbr)3(E_(3)d_(3)),the Shahejie Formation mbrs 1 and 2(E_(2)s_(1+2)),and the Shahejie Mbr 3(E_(2)s_(3))source rocks in the western Bozhong Sag were studied.The above methods were used to reveal their geochemical properties,OM origins and depositional environments,all of which indicate that E_(2)s_(1+2)and E_(2)s_(3)are excellent source rocks,and that E_(3)d_(3)is of the second good quality.E_(3)d_(3)source rocks were formed under a warm and humid climate,mainly belong to fluvial/delta facies,the E_(3)d_(3)sediments formed under weakly oxidizing and freshwater conditions.Comparatively,the depositional environments of E_(2)s_(1+2)source rocks were arid and cold climate,representing saline or freshwater lacustrine facies,and the sediments of E_(2)s_(1+2)belong to anoxic or suboxic settings with large evaporation and salinity.During the period of E_(2)s_(3),the climate became warm and humid,indicating the freshwater lacustrine facies,and E_(2)s_(3)was characterized by freshwater and abundant algae.Moreover,compared with other intervals,the OM origin of E_(3)d_(3)source rocks has noticeable terrestrial input.The OM origin of the E_(2)s_(1+2)and E_(2)s_(3)are mainly plankton and bacteria.Tectonic subsidence and climate change have affected the changes of the depositional environment in the western Bozhong Sag,thus controlling the distribution of the source rocks,the geochemical characteristics in the three intervals of lacustrine source rocks have distinct differences.Overall,these factors are effective to evaluate the paleoenvironmental characteristics of source rocks by biomarkers,major and trace elements.The established models may have positive implications for research of lacustrine source rocks in offshore areas with few drillings.
基金This research was supported by the National Natural Science Foundation of China(42171083,41871016)the Natural Science Foundation of Gansu Province,China(22JR5RA066).
文摘The Dunhuang–Golmud railway passes through different deserts in arid areas,especially drifting-sand desert and sandy-gravel Gobi.The near-surface wind environment and wind-sand transport process vary due to different external factors,such as topography,vegetation,and regional climate,resulting in evident spatial differences in surface erosion and deposition.Consequently,the measures for preventing wind-sand hazards will differ.However,the mechanism and control theory of sand damage remain poorly understood.In this study,we used meteorological observation,three-dimensional(3D)laser scanning,and grain-size analysis to compare and evaluate the spatial distribution of wind conditions,sand erosion and deposition patterns,and grain composition in the drifting-sand desert and sandy-gravel Gobi along the Dunhuang–Golmud railway in China.Results show that the annual mean wind speed,the frequency of sand-driving wind,and the drift potential of sandy-gravel Gobi are higher than those of drifting-sand desert,indicating a greater wind strength in the sandy-gravel Gobi,which exhibits spatial heterogeneity in wind conditions.The major sediment components in sandy-gravel Gobi are very fine sand,fine sand,and medium sand,and that in drifting-sand desert are very fine sand and fine sand.We found that the sediment in the sandy-gravel Gobi is coarser than that in the drifting-sand desert based on mean grain size and sediment component.The spatial distributions of sand erosion and deposition in the sandy-gravel Gobi and drifting-sand desert are consistent,with sand deposition mainly on the west side of the railway and sand erosion on the east side of the railway.The area of sand deposition in the drifting-sand desert accounts for 75.83%of the total area,with a mean deposition thickness of 0.032 m;while the area of sand deposition in the sandy-gravel Gobi accounts for 65.31%of the total area,with a mean deposition thickness of 0.028 m,indicating greater deposition amounts in the drifting-sand desert due to the presence of more fine sediment components.However,the sand deposition is more concentrated with a greater thickness on the embankment and track in the sandy-gravel Gobi and is dispersed with a uniform thickness in the drifting-sand desert.The sand deposition on the track of the sandy-gravel Gobi mainly comes from the east side of the railway.The results of this study are helpful in developing the preventive measures and determining appropriate selection and layout measures for sand control.
基金supported by National 305 Project(2007BAB25B05,2011BAB06B02- 04)NSFC grant(40925006,40772045,40572047)111 Project(B07011)
文摘In the southwestern Tianshan,the geologic ages of many strata and their depositional environments are still poorly constrained because of complex structures.The Mada'er area is located in the Kuokesaleling belt,Southwestern Tianshan.The cherts from the former Wupata'erkan Group contain abundant radiolarian fossils,including 10 species which are identified as late Devonian to early Carboniferous in age.Eleven chert samples have SiO_2 contents ranging from 88.80 wt%to 93.28 wt%, and 2.02 wt%to 3.72 wt%for Al_2O_3.The SiO_2/Al_2O_3 ratios of all samples vary from 23.84 to 46.11, much lower than those of the pure cherts(80-1400).These values suggest that the cherts contain high ratios of terrigenous materials.The Al_2O_3/(Al_2O_3+Fe_2O_3)ratios vary between 0.64 and 0.77,whereas V and Cu concentrations range from 10.92 ppm to 26.7 ppm and from 2.15 ppm to 34.1 ppm respectively. The Ti/V ratios vary from 25.53 to 44.93.The total REE concentrations of the cherts are between 30.78 ppm and 59.26 ppm,averaging 45.46 ppm.The(La/Ce)_N ratios range from 0.81 to 1.12,and 0.88-1.33 for(La/Yb)_N,averaging 1.09,which suggests a continental margin environment.Consequently,it is inferred that the cherts formed in a residual sea environment during the late Devonian to early Carboniferous time,which suggests that the collision between the Karakum-Tarim and Kazakhstan-Junggar plates did not occur at the time.In addition,the regional geological information indicates that the study area experienced a post-collision stage during the early Permian,and thus it is likely that the collision between the two plates took place in the late Carboniferous.
基金Financial support was provided by the National Science and Technology Major Project of China (No.2011ZX05023-002-003)
文摘Gas-bearing deposits in the Lower Mingyuefeng Formation of Paleogene, Lishui Sag, East China Sea Shelf Basin consist of shoreface sandstones of the highstand systems tract(HST) and transgressive systems tract(TST), and deltaic sandstones of the lowstand systems tract(LST) and falling stage systems tract(FSST).Detailed petrographic observations suggest that the diagenetic features and related evolution of these deposits cannot be simply characterized and demonstrated in the depth domain.However, the occurrence of diagenetic minerals systematically depends on the studied interval within the HST, TST, LST, and FSST; therefore, diagenesis in this region can be better constrained when studied in the context of the depositional environments and sequence stratigraphic framework.The eogenetic processes in such settings include:(1) microcrystalline siderite precipitated as concretions in almost all environments and systems tracts, which inhibited further mechanical compaction;(2) grain dissolution and kaolinitization occurred in shoreface HST sandstones and deltaic LST and FSST sandstones;(3) glaucony was locally observed, which did not clearly reflect the controls of facies or sequence stratigraphy; and(4) cementation by pyrite aggregates occurred in the shoreface HST sandstones and deltaic LST sandstones.The mesogenetic diagenesis includes:(1) partial conversion of kaolinite into dickite in deltaic LST sandstones, and minor chlorite cementation in deltaic FSST sandstones;(2) transformation of kaolinite into illite and quartz cementation in deltaic LST and FSST sandstones;(3) frequent precipitation of ankerite and ferroan calcite in shoreface TST sandstones and early HST sandstones, forming baffles and barriers for fluid flow, with common calcite in shoreface HST sandstones as a late diagenetic cement; and(4) formation of dawsonite in the deltaic LST and FSST sandstones, which is interpreted to be a product of the invasion of a CO2-rich fluid, and acts as a good indicator of CO2-bearing reservoirs.This study has thus constructed a reliable conceptual model to describe the spatial and temporal distribution of diagenetic alterations.The results may provide an entirely new conceptual framework and methodology for successful gas exploration in the continental margins of offshore China, thus allowing us to predict and unravel the distribution and quality evolution of clastic reservoirs at a more detailed and reliable scale.
基金The National Natural Science Foundation of China under contract Nos 40431002,40606016 and 40710069004the China-Korea joint research programme and the Primary Science Foundation of First Institute of Oceanography under contract No. 2007T09
文摘The present study is based on the sedimentological data from a piston core KCES1 off the southern Ulleung Basin margin,the East Sea(Sea of Japan).The data include sediment color(L^*),X-ray radiographs,grain size distribution and AMS^14C date.Four kinds of sediments(homogeneous,laminated,crudely laminated and hybrid sediments) are identified according to the characters of the sedimentary structures that were considered to reflect changes in bottom-water oxygenation.Alternations of dark laminated/crudely laminated sediments and light homogeneous sediments represent millennial-scale variations that are possibly associated with the high-resolution changes in the East Asian monsoon(EAM).The relative contributions of the East China Sea Coastal Water(ECSCW) and the Tsushima Warm Current(TWC) were likely the main reasons for the repetition of the anoxic and oxic depositional conditions in the East Sea since the last 48 ka BP.During the interstadial,the strengthen summer EAM was attributed to the expansion of the ECSCW because of more humid climate in central Asia,and then more strongly low-salinity,nutrient-enriched water was introduced into the East Sea.The ventilation of deep water was restricted and therefore the dark laminated layer deposited under the anoxic bottom water condition.During the lowest stand of sea level in the last glacial maximum(LGM),the isolated East Sea dominated by stratified water masses and the euxinic depositional environment formed.The homogenous sediments have been predominating since 17.5 ka BP indicating that the TWC has intruded into the East Sea gradually with the stepwise rise of sea level and the bottom water oxygen level was high.During the late Younger Dryas(YD) period,the last dark laminated layer deposited because the ventilation of bottom water was restricted by stronger summer EAM.The TWC strengthened and the bottom water became oxic again from 10.5 ka BP.
文摘A deeper understanding of the mechanisms by which geological factors(depositional environment and tectonic evolution) control the occurrence of coalbed methane(CBM) is important for the utilization of CBM resources via surface-drilled wells and the elimination of coal-methane outbursts, the latter of which is a key issue for coal mine safety. Based on drill core data, high-pressure isothermal adsorption experiments, scanning electron microscopy experiments, mercury intrusion porosimetry, and X-ray diffraction experiments, the impact of the depositional environment and tectonic evolution on CBM occurrence of the II-1 coal seam of the Shanxi Formation in West Henan was analyzed. Results showed that the depositional environment led to the epigenetic erosion of tidal flat coal-accumulating structures by shallow-delta distributary channel strata. This resulted in the replacement of the original mudstonesandy mudstone coal seam immediate roof with fine-to-medium grained sandstones, reducing methane storage capacity. Epigenetic erosion by the depositional environment also increased coal body ash content(from 6.9% to 21.4%) and mineral content, filling the cleat system and reducing porosity, reducing methane storage capacity. The maximum methane adsorption capacity of the coal body reduced from35.7 cm3/g to 30.30 cm3/g, and Langmuir pressure decreased from 1.39 MPa to 0.909 MPa. Hence, the methane adsorption capacity of the coal body decreased while its capacity for methane desorption increased. Owing to the tectonic evolution of West Henan, tectonically deformed coal is common; as it evolves from primary cataclastic coal to granulitic coal, the angle of the diffraction peak increases, d002 decreases, and La, Lc, and Nc increase; these traits are generally consistent with dynamic metamorphism.This is accompanied by increases in the total pore volume and specific surface area of the coal body, further increasing the capacity for methane storage. Increases in micropore volume and specific surface area also increase the ability of the coal body to adsorb methane.
基金financial assistance throughout the research under the grant YUTP 0153AAA14financial support from UTP through the grant URIF 2014-00735
文摘The Luconia Province-offshore Sarawak-is a key geological unit for understanding the distribution of hydrocarbon resources in Malaysia. Nevertheless, little effort has been made to address the palaeoenvironmental characteristics of the Tertiary carbonates in the key sector of Central Luconia.We study the sedimentology and petrography of core samples from a well in Central Luconia, for which thirteen microfacies have been identified reflecting different depositional settings. This is the first microfacies scheme elaborated for Luconian carbonates. Lithofacies and microfacies distribution are compatible with deposition in a reef complex, originating around a framework reef, within the euphotic zone. Sediments were deposited in environments of backreef, reef crest, and forereef. The fair weather wave base is marked by the presence of coralline red algae, foraminifera, decreasing degree of bioclast fragmentation and other microfacies features. As a result, a depositional-environmental model is constructed, depicting a reef complex built around a framework reef developed on the margin of an isolated platform. In addition, an innovative, preliminary time series analysis of facies, microfacies and depositional environment data reveal the existence of seasonal cycles in the stacking patterns of facies and microfacies.
基金supported by the National Natural Science Foundation of China (Grant No. 40902013)"Strategic Priority Research Program - Climate Change:Carbon Budget and Relevant Issues" of the ChineseAcademy of Sciences (Grant No.XDA05130202)
文摘Shuidonggou site has abundant Paleolithic remains of Late Pleistocene deposition. Studying the evolution of depositional environments is essential to the comprehensive understanding of the living conditions of ancient populations. To reconstruct the depositional environment at Shuidonggou, we carried out archaeological excavations and collected systematic deposition samples at the key position of Shuidonggou Locality 2 for grain size analysis and sporopollen statistics. The environmental evolution around the Shuidonggou site generally underwent four stages at ~72-18 kaBP. During the first stage (~72-41 kaBP), the river developed with gravel and sand stratums. During the second stage (41-34 kaBP), a swamp with numerous aquatic plants formed. In the third stage (34-29 kaBP), site formation was characterized by shallow lake depositional conditions; the climate was relatively warm and humid. The marginal bank depositional conditions deteriorated during the fourth stage (29-18 kaBP), and the site underwent several dry events; the climate also became drier and colder.
基金funded by the National Natural Science Foundation of China(grant No.41572117)Technological&Developmental Department of China Petroleum&Chemical Corporation(grants No.P13040 and P14128)China Geological Survey(grant No.DD20160175-1-1)
文摘Objective The Yubei area is located in the mid-east Maigaiti slope of southwestern Tarim Basin, China, with an exploration history of several years. Recent exploration has preliminarily indicated that the Ordovician carbonate formations in this area have some oil and gas potential. Carbonate microfacies provides material basis for reservoir development, seal formation and hydrocarbon generation. Therefore, this work utilized the standard microfacies (SMF) types to study the microfacies of the Ordovician formations in the Yubei area in order to provide theoretical basis for the next exploration.
文摘The Sarvak Formation is the second major oil-bearing reservoir in the south and south west of Iran. The Middle Cretaceous Sarvak formation in the Zagros Mountains (Zagros Basin) is mainly composed of carbonate sequences. Based on facies studied, thirteen microfacies were recognized in the studied area, which were categorized in the three facies groups: including inner ramp, mid ramp and outer ramp. Evidences such as the gradual changes in the facies (basin slope), the absence of extensive uninterrupted barrier reef, the lack of calciturbidite and gravity sediments as well as the high proportion of grain-supported indicated that the Sarvak Formation was deposited in the ramp like depositional system, particularly on an inner ramp setting. Inner ramp facies group is the principal setting and subdivided to tidal flat, restricted and unrestricted lagoon as well as shoal sub-environments.
文摘The Asmari Formation is a thick carbonate sequence of the Oligocene-Miocene in the Zagros Basin, southwest of Iran. This formation is located in Bandar Abbas and Coastal Fars regions on the following two sections: Anguro anticline (west-northwest of Bandar Abbas) and Gavbast anticline (southwest of Lar County). The Asmari Formation has diameters of 68 and 26 m in the Anguro and Gavbast sections, respectively. This formation is composed of limestone, dolomitic limestone and an altered form of marl. Based on the results of petrographic analyses, 7 facies were identified in the Anguro and Gavbast sections in the study region. The facies were deposited on the following 3 belts: tidal flat (MF 1 - 3), lagoon (MF 4 - 5) and open marine (MF 6, 7). According to evidence such as the gradual change of microfacies, the lack of main reef barriers, and the lack of slumping and sliding features, the Asmari Formation was formed in a marine environment of carbonate homoclinal ramp type. This environment is composed of the following two subenvironments: the inner ramp and the middle ramp. The comparison of the facies identified in the Anguro and Gavbast sections indicates that Gavbast section is mainly composed of lagoon facies. Moreover, the Anguro section demonstrates more facies diversity than Gavbast section.
文摘Early Permian deposits in north of Kalmard region recognize with formal group of Khan;they have various features in the different place. This group includes four different formations from lower to the upper part: Chili, Sartakht and Hermez. These formations consist of carbonate rocks. Chili Formation has 104 m, thickness in Darin section and consists of limestone with intermediates of shale and marland sandstone. Lower boundary of this formation is disconformable with Gachal formation. The upper boundary is separated by unconformity from the upper part Sartakht formation according to the lithological characters and microscopic studies, cause identifications of beach, intertidal, open and semi-restricted lagoon, shoals and bar and open marine sub-environ- ments for the Chili Formation. Vertical changes of microfacies and depth changes curve show much more thickness of shoals and bar microfacies, and little thickness of open and semi-re- stricted lagoon and open marine microfacies. Deposits of Chili Formation in Darin section deposited in the gentle gradient Homoclinal ramp in the south of Paleotethys Ocean. Two depositional sequences have been identified in this formation, based on recognized Fusulinid, show age of Sakmarian, which has adaptation with Lower Absaroka III.
文摘Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry.The bulk carbon isotopic values of the whole rock extracts,saturate and aromatic fractions range from–28.7‰to–26.8‰,–29.2‰to–27.2‰and–28.5‰to–26.7‰,respectively while the bulk carbon isotopic values of the whole oils,saturate and aromatic fractions range from–25.4‰to–27.8‰,–25.9‰to–28.4‰and–23.5‰to–26.9‰,respectively.The average carbon isotopic compositions of individual alkanes(nC12-nC33)in the rock samples range from–34.9‰to–28.2‰whereas the average isotopic values of individual n-alkanes in the oils range from–31.1‰to–23.8‰.Theδ13C isotope ratios of pristane and phytane in the rock samples range from–29.2‰to–28.2‰and–30.2‰to–27.4‰respectively while the pristane and phytane isotopic values range from–32.1‰to–21.9‰and–30.5‰to–26.9‰,respectively.The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments.The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.
基金supported by the Certificate of National Science and Technology Major Project of the Ministry of Science and Technology of China(2016ZX05006-007-004)National Natural Science Foundation of China(41702139,41772138,41602142,42072130)the Fundamental Research Funds for the Central Universities(18CX02008A)。
文摘The mechanisms of lacustrine organic-rich shale formation have attracted attention due to its association with global shale oil and shale gas exploration.Samples of general-quality and excellent-quality source rocks,and oil shale from the Beibu Gulf Basin were analyzed to investigate their organic geochemistry,palynofacies,and trace elements.Hydrocarbon potential was higher in the oil shale(29.79 mg/g)than in the general-quality source rock(3.82 mg/g),and its kerogen type wasⅠ-Ⅱ2.Hydrogen-rich liptinite(cutinite and sporinite)components derived from terrigenous higher plants provided most of the hydrocarbon potential of excellent-quality source rock and oil shale.Under the influence of depressioncontrolling fault activity,a deeper subsidence center promotes the deposition of excellent-quality source rock and oil shale in brackish-hypoxic bottom water.A shallower subsidence center,due to subsag-controlling fault activity,promotes the formation of excellent-quality source rock under freshbrackish and weak oxidation-weak reducing conditions.The local uplift and shallow-slope led to the formation of general-quality source rock,under freshwater weak-oxidation conditions.A model was established for organic matter(OM)accumulation in organic-rich shales,accounting for fault activity,terrigenous hydrogen-rich OM,and the preservation conditions,to predict the development of excellent-quality source rock from areas with low levels of exploration.
文摘In this study, to identify and analyze facies of depositional environment and depositional model of Qom Formation, stratigraphic Saran Section (southwest of Semnan) was selected. Qom Formation in Saran section includes about 380 meters of conglomerate at the base, chalk, limestone, marl, and shale. Petrographic studies with facies analysis have led to the identification of 12 microfacies, these microfacies have been deposited in four facies groups including tidal flat, lagoon, barrier and open marine. Study of horizontal and vertical facies changes and their comparison with recent and ancient environments reveals that Qom Formation in this section relates to shallow marine environment and its facies were deposited in a shelf carbonate platform and are comparable with contemporary shelf platforms such as Florida and old shelf platforms such as Mozduran. The most important diagenetic processes affecting the studied section include micritization, bioturbation, cementation, dissolution, neomorphism, fracturing, mechanical and chemical compaction, hematitization and dolomitization. These processes have formed in marine, meteoric and burial diagenetic environments.
文摘Differences in rare earth elements and other trace elements in bedded chens reflect the deposihonal settings of the sediments. Based on cerium anomaly (Ce/Ce ), total REE (ΣREE) and other trace element abundance variahons preserved in the bedded cherts in the Paleo-Tethys, Western Yunnan, three deposihonal regimes can be recotwzed: spreading ridge proximal, ocean-basin floor and conhnental margin. This geochemical method of discriminating deposihonal environments for thine marine sedimentary rocks which are physically indistinct provides a powerful new tool for paleotectonic and paleogeographic recondruchons.