Prestressed anchor cables are widely used for slope reinforcement,but the loss of prestress makes it difficult to guarantee the reinforcement effect.Anchor cable prestress degradation was considered as a stochastic pr...Prestressed anchor cables are widely used for slope reinforcement,but the loss of prestress makes it difficult to guarantee the reinforcement effect.Anchor cable prestress degradation was considered as a stochastic process,and the probability density function of this process was established using gamma theory and impact theory respectively.Combined with the failure threshold,the probability density was integrated to find the time-dependent reliability of the anchor cable.Based on the monitoring data of the prestress degradation of the anchor cable,parameters in the probability density function were solved by the maximum likelihood method,and the time-varying reliability and service life of the anchor cable were obtained analytically.The applicability of two degradation theories,gamma stochastic process and impact theory,was compared.The results showed that the probability density curves of both degradation models were normally distributed and the error of reliability results did not exceed 0.06.The life prediction results of the gamma stochastic process were closer to the actual life of 400 h than the 500 h of the impact theory,and the probability curves of the anchor cable life also indicated that the impact theory overestimated the service life probability of the anchor cable.Taking the anchor cable reinforcement within the slope of the Dagushan open-pit mine as an example,and the results verify the feasibility of using gamma theory to predict the degradation of anchor cables and provides theoretical support for prevention of the degradation of anchor cables in the slope of an open-pit mine under the action of external forces.展开更多
The nitrate ester substitution derivatives of prismane were studied at the B3LYP/6-311G** level. The sublimation enthalpies and heats of formation in gas phase and solid state were calculated. The detonation perform...The nitrate ester substitution derivatives of prismane were studied at the B3LYP/6-311G** level. The sublimation enthalpies and heats of formation in gas phase and solid state were calculated. The detonation performances were also predicted by using the famous Kamlet-Jacbos equation. Our calculated results show that introducing nitrate ester group into prismane is helpful to enhance its detonation properties. Stabilities were evaluated through the bond dissociation energies, bond order, characteristic heights(H50) and band gap calculations. The trigger bonds in the pyrolysis process of prismane derivatives were confirmed as O–ON2 bond. The BDEs of all compounds were large, so these prismane derivatives have excellent stability consistent with the results of H50 and band gap.展开更多
Engineering construction has major influence on the permafrost environment.This paper analyzes the interaction between engineering construction and permafrost environment along the Chaidaer-Muli Railway(simply,CMR) ba...Engineering construction has major influence on the permafrost environment.This paper analyzes the interaction between engineering construction and permafrost environment along the Chaidaer-Muli Railway(simply,CMR) based on the press-state-response(PSR) framework.The permafrost environmental system is divided into three subsystems,consisting of permafrost thermal stability,proneness to the freeze-thawing erosion and permafrost ecological fragility.Each subsystem considers its most important influencing factors.Catastrophe Progression Method(CPM) is applied to calculate the current environment condition along the railway.The result indicates that:(1) as far as the thermal stability is concerned,most sections along the CMR are mainly concentrated in rank Ⅲ(fair situation),and a few in Ⅱ(good situation) and Ⅳ(bad situation),respectively;(2) for the proneness tothe freeze-thawing erosion,the entire railway route falls largely in rank Ⅱ(good situation);(3) along the CMR,the ecological fragility of the permafrost environment is in rank Ⅱ(good situation),or slightly fragile;(4) overall,the permafrost environments along the CMR are in rank Ⅲ(fair situation) or Ⅱcondition(good situation).In general,the permafrost environment along the CMR is fair.It is mainly because a series of active measures of protecting permafrost were taken for stabilizing the CMR foundation soils.On the one hand,we should try our best to minimize the influences that engineering activities have exerted on ecology and environment,on the other hand,the positive measures have made improvements to prevent the permafrost environment from deterioration.展开更多
基金supported by the National Natural Science Foundation of China(No.52074292)National Key Research and Development Program(No.2017YFC1503103)。
文摘Prestressed anchor cables are widely used for slope reinforcement,but the loss of prestress makes it difficult to guarantee the reinforcement effect.Anchor cable prestress degradation was considered as a stochastic process,and the probability density function of this process was established using gamma theory and impact theory respectively.Combined with the failure threshold,the probability density was integrated to find the time-dependent reliability of the anchor cable.Based on the monitoring data of the prestress degradation of the anchor cable,parameters in the probability density function were solved by the maximum likelihood method,and the time-varying reliability and service life of the anchor cable were obtained analytically.The applicability of two degradation theories,gamma stochastic process and impact theory,was compared.The results showed that the probability density curves of both degradation models were normally distributed and the error of reliability results did not exceed 0.06.The life prediction results of the gamma stochastic process were closer to the actual life of 400 h than the 500 h of the impact theory,and the probability curves of the anchor cable life also indicated that the impact theory overestimated the service life probability of the anchor cable.Taking the anchor cable reinforcement within the slope of the Dagushan open-pit mine as an example,and the results verify the feasibility of using gamma theory to predict the degradation of anchor cables and provides theoretical support for prevention of the degradation of anchor cables in the slope of an open-pit mine under the action of external forces.
基金supported by the Natural Science Foundation of Guizhou Province(QKJ[2014]2140 and QJTD[2012]052)
文摘The nitrate ester substitution derivatives of prismane were studied at the B3LYP/6-311G** level. The sublimation enthalpies and heats of formation in gas phase and solid state were calculated. The detonation performances were also predicted by using the famous Kamlet-Jacbos equation. Our calculated results show that introducing nitrate ester group into prismane is helpful to enhance its detonation properties. Stabilities were evaluated through the bond dissociation energies, bond order, characteristic heights(H50) and band gap calculations. The trigger bonds in the pyrolysis process of prismane derivatives were confirmed as O–ON2 bond. The BDEs of all compounds were large, so these prismane derivatives have excellent stability consistent with the results of H50 and band gap.
基金supported by the Major State Basic Research Development Program of China (No.2013CBA01803)the National Natural Science Foundation of China (No.41271084 and 41501079)+1 种基金the Project Funded by China Postdoctoral Science Foundation (No.2015M582724 and 2016T90962)the Chinese Academy of Sciences (CAS) Key Research Program (No.KZZD-EW-13)
文摘Engineering construction has major influence on the permafrost environment.This paper analyzes the interaction between engineering construction and permafrost environment along the Chaidaer-Muli Railway(simply,CMR) based on the press-state-response(PSR) framework.The permafrost environmental system is divided into three subsystems,consisting of permafrost thermal stability,proneness to the freeze-thawing erosion and permafrost ecological fragility.Each subsystem considers its most important influencing factors.Catastrophe Progression Method(CPM) is applied to calculate the current environment condition along the railway.The result indicates that:(1) as far as the thermal stability is concerned,most sections along the CMR are mainly concentrated in rank Ⅲ(fair situation),and a few in Ⅱ(good situation) and Ⅳ(bad situation),respectively;(2) for the proneness tothe freeze-thawing erosion,the entire railway route falls largely in rank Ⅱ(good situation);(3) along the CMR,the ecological fragility of the permafrost environment is in rank Ⅱ(good situation),or slightly fragile;(4) overall,the permafrost environments along the CMR are in rank Ⅲ(fair situation) or Ⅱcondition(good situation).In general,the permafrost environment along the CMR is fair.It is mainly because a series of active measures of protecting permafrost were taken for stabilizing the CMR foundation soils.On the one hand,we should try our best to minimize the influences that engineering activities have exerted on ecology and environment,on the other hand,the positive measures have made improvements to prevent the permafrost environment from deterioration.