Phosphor yttrium aluminum garnet Y3A15O12 （YAG）, activated with trivalent cerium （Ce^3＋）, was synthesized by T-tube impinging streams, T-type vortex impinging streams co-precipitation method （IS-CP） and direct ...Phosphor yttrium aluminum garnet Y3A15O12 （YAG）, activated with trivalent cerium （Ce^3＋）, was synthesized by T-tube impinging streams, T-type vortex impinging streams co-precipitation method （IS-CP） and direct co-precipitation method （D-CP）, respectively. The crystallization, morphologies, particle size and particle size distribution of the phosphors obtained under different experimental conditions were studied. The influence of various factors on the luminescence intensity of the phosphor was also investigated, such as feeding methods, volume flow rate, contents of Ce and initial reactant concentration. The results show that the precursors synthesized by T-tube impinging streams co-precipitation reaction transform to Y3A15O12 （YAG） phosphor at about 1 000 ℃. The particles are far smaller and narrower than those prepared by D-CP. In the impinging streams co-precipitation system, the luminescent intensity of YAG：Ce phosphor increases with the increase of liquid flow rate. The intensity firstly increases then decreases with the increasing Ce^3＋ doping content, and the maximum intensity is shown at 1.67% （molar fraction） Ce. Luminescent intensity gradually decreases with the increase of initial concentration of reactants. At the same operational condition, the luminescent intensity of the phosphors prepared by T-tube impinging streams reactor is higher than that by D-CP, and the luminescent intensity of the phosphors prepared by T-type vortex impinging streams is higher than that by T-tube impinging streams reactor.展开更多
The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of ma...The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of macromixing time and micromixing time are quantitatively discussed. The results show that under a continuous and stable operating condition, as the paddle speed increases, the macromixing time and micromixing time calculated by the two models both decrease, even in a linkage equilibrium state. Simultaneously, as the paddle speed increases, the results figured by the two models tend to be consistent. It indicates that two models both are more suitable for calculation of mixing time in high paddle speed. Compared with the existing experimental results of this type of reactor, the mixing time computed in the speed of 1500 r/min is closer to it. These conclusions can provide an important reference for systematically studying the strengthening mechanism of LISR under continuous mixing conditions.展开更多
Micromixing in the submerged circulative impinging stream reactor (SCISR) developed by the authors is investigated with the Bourne's reaction scheme. The values measured for the impinging velocity, u0, under the ...Micromixing in the submerged circulative impinging stream reactor (SCISR) developed by the authors is investigated with the Bourne's reaction scheme. The values measured for the impinging velocity, u0, under the conditions of SCISR normal operation, only is of the order of 0.1m·s^-1, are much slower than that inferred,suggesting low power requirement for operation. The values of the characteristic time constant for micromixing,tM, determined in the impinging velocity range of 0.184m·s^-1 < u0 < 0.326m·s^-1 are ranged from 192ms to 87 ms, showing that impinging streams promotes micromixing very efficiently. The data follow approximately the relationship of tM∝ u0^-1.5. A comparative study shows that the micromixing performance of SCISR is much better than that of the traditional stirred tank reactor. The tM values predicted with the existing theoretical model are systematically longer than those measured by about 2--3 times, implying that the regularity of impinging streams promoting micromixing is unclear yet.展开更多
Cerium carbonate powders were produced in a submerged circulation impinging stream reactor （SCISR） from Ce（NO3）3· 6H2O. NH4HCO3 was used as a precipitant in the reaction. Cerium carbonate powders were roasted...Cerium carbonate powders were produced in a submerged circulation impinging stream reactor （SCISR） from Ce（NO3）3· 6H2O. NH4HCO3 was used as a precipitant in the reaction. Cerium carbonate powders were roasted to produce ultra-fine cerium dioxide （CeO2） powders. The optimal conditions of such production process were obtained by orthogonal and one-factor experiments. The results showed that ultra-fine and narrowly distributed cerium carbonate powders were produced under the optimal flowing conditions. The concentrations of Ce（NO3）3 and NH4HCO3 solutions were 02,5 and 0.3 mol · L^-1, respectively. The concentration of PEG4000 added in these two solutions was 4 g · L^-1. The stirring ratio, reaction temperature, feeding time, solution pH, reaction time and digestion time were 900 r · min^- 1,80 ℃, 20 min, 5 - 6, 5 min and 1 h, respectively. The final product, CeO2 powders, was obtained by roasting the produced cerium carbonate in air for 3 h at 500 ℃. The finally produced CeO2 powders were torispherical particles with a narrow size distribution of 0.8 -2.5 μm. The crystal structure of CeO2 powders belonged to cubic crystal system and its space point 5 group was OH^5-FM3M. Under optimal conditions, powders produced by SCISR were finer and more narrowly distributed than that by Stirred Tank Reactor （STR）.展开更多
Pressure fluctuation in the submerged circulative impinging stream reactor （SCISR） is studied by measuring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Exper...Pressure fluctuation in the submerged circulative impinging stream reactor （SCISR） is studied by measuring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Experimental results show that the maximum amplitude of fluctuation can be up to about 1.6kPa. On the power spectra the fluctuation is relatively concentrated in the range of 〈1000Hz, with some weak peeks in acoustic wave range. The space profile of intensive fluctuation region in the reactor is determined. The region is found to take the form of a couple truncated cones of empty core, with coincided bottoms, and is symmetrical with respect to the impinging plane and approximately symmetrical about the axis, essentially independent of u0. The integral intensity of fluctuation increases as the impinging velocity, Uo increasing.展开更多
Pressure fluctuation in the submerged circulative impinging stream reactor (SCISR) is studied by meas- uring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Ex- p...Pressure fluctuation in the submerged circulative impinging stream reactor (SCISR) is studied by meas- uring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Ex- perimental results show that the maximum amplitude of fluctuation can be up to about 1.6kPa. On the power spectra the fluctuation is relatively concentrated in the range of <1000Hz, with some weak peeks in acoustic wave range. The space profile of intensive fluctuation region in the reactor is determined. The region is found to take the form of a couple truncated cones of empty core, with coincided bottoms, and is symmetrical with respect to the impinging plane and approximately symmetrical about the axis, essentially independent of u0. The integral intensity of fluctua- tion increases as the impinging velocity, u0 increasing.展开更多
The experiments of one-stage semi-circular and two-stage semi-circular impinging stream drying as well as the vertical and semi-circular combined impinging stream drying were carried out. The velocity distribution and...The experiments of one-stage semi-circular and two-stage semi-circular impinging stream drying as well as the vertical and semi-circular combined impinging stream drying were carried out. The velocity distribution and the mean residence time of particles, and the influence of various factors on drying characteristics were studied. A mathematical model of granular material drying in a semi-circular impinging stream dryer was proposed, in which the flow characteristics as well as the heat and mass transfer mechanisms were considered. Reasonable numerical methods were used to solve the equations. Under various conditions, the calculated results agree well with the experimental data. The unsteady-state drying dynamic equation, as well as the variations of drying rate and moisture content versus time were obtained. The results indicate that constant drying rate period does not exist in a semi-circular impinging stream dryer. Appropriate semi-circular stage number and curvature radius, flow-rate ratio, air velocity, and higher inlet air temperature should be used for enhancing the drying process.展开更多
1 INTRODUCTIONAs mentioned in our previous paper impinging stream contactor(ISC)is aninnovative device for phase contact operations and has proved itself capable to en-hance transfer processes in heterogeneous systems...1 INTRODUCTIONAs mentioned in our previous paper impinging stream contactor(ISC)is aninnovative device for phase contact operations and has proved itself capable to en-hance transfer processes in heterogeneous systems effectively,and thus is of poten-tial application in many chemical engineering processes,such as drying of solidparticles,solid-solid,liquid-liquid and gas-gas mixing,absorption and desorptionof gases into or from liquids with or without chemical reactions,combustion展开更多
Based on the experimental investigation of one-stage semi-circular impinging stream drying, the experiments with the two-stage semi-circular, as well as the vertical and semi-circular combined impinging stream drying ...Based on the experimental investigation of one-stage semi-circular impinging stream drying, the experiments with the two-stage semi-circular, as well as the vertical and semi-circular combined impinging stream drying were conducted. The variations of system pressure drop, the mean residence time of particles with the mass flow-rate ratio and air velocity etc, were determined. The influences of inlet air temperature, mass flow-rate ratio, initial moisture content of particles and air velocity etc. on drying characteristics were also studied. The results indicate that the vertical and semi-circular combined impinging stream drying can make full use of the advantages of both the vertical and semi-circular impinging stream drying. Reasonable mass flow-rate ratio, air velocity, and higher inlet air temperature should be used for less energy consumption and cost during drying process.展开更多
This paper presents an experimental investiga-tion of a novel impinging stream reactor(ISR)with the aim of high mixing intensity.The integral mixing quality in the reactor was measured with the iodide-iodate reaction ...This paper presents an experimental investiga-tion of a novel impinging stream reactor(ISR)with the aim of high mixing intensity.The integral mixing quality in the reactor was measured with the iodide-iodate reaction and showed excellent mixing performance.The impact of the operating parameters,such asfluxes,circulation and inter-nozzle distances,was investigated in terms of segregation index.The results showed that the increase offlux,the decrease of inter-nozzle distance and a suitable circulation can improve the micro-mixing efficiency.Based on turbulence theory,it was estimated that the characteristic micro-mixing time was 0.002–0.02 s,which was much shorter than that in the stirred tank reactor.The micro-mixing time was related to the segregation index,which was in good agreement with those in the literature.展开更多
Previous works on impinging streams mainly focused on the structures of flow field,but paid less attention to the structures of temperature field,which are very important in practical applications.In this paper,the in...Previous works on impinging streams mainly focused on the structures of flow field,but paid less attention to the structures of temperature field,which are very important in practical applications.In this paper,the influences of the Reynolds number(Re)and Prandtl number(Pr)on the structures of flow and temperature fields of non-isothermal laminar impinging streams are both studied numerically with the lattice Boltzmann method,and two cases with and without buoyancy effect are considered.Numerical results show that the structures are quite different in these cases.Moreover,in the case with buoyancy effect,some new deflection and periodic structures are found,and their independence on the outlet boundary condition is also verified.These findings may help to understand the flow and temperature structures of non-isothermal impinging streams further.展开更多
Based on some experimental investigations of liquid phase residence time distribution(RTD)in an impinging stream reactor,a two-dimensional plug-flow dispersion model for predicting the liquid phase RTD in the reactor ...Based on some experimental investigations of liquid phase residence time distribution(RTD)in an impinging stream reactor,a two-dimensional plug-flow dispersion model for predicting the liquid phase RTD in the reactor was proposed.The calculation results of the model can be in good agreement with the experimental RTD under different operating conditions.The axial liquid dispersion coefficient increases monotonously with the increasing liquid flux,but is almost independent of gas flux.As the liquid flux and the gas flux increase,the liquid dispersion coefficient of center-to-wall decreases.The axial liquid dispersion coefficient is much larger than that of center-to-wall,which indicates that the liquid RTD is dominated mainly by axial liquid dispersion in the impinging stream reactor.展开更多
基金Project(200805330032)supported by the Natural Educative Doctoral Foundation of ChinaProjects(20080440987,200902475)supported by the China Postdoctoral Science Foundation
文摘Phosphor yttrium aluminum garnet Y3A15O12 （YAG）, activated with trivalent cerium （Ce^3＋）, was synthesized by T-tube impinging streams, T-type vortex impinging streams co-precipitation method （IS-CP） and direct co-precipitation method （D-CP）, respectively. The crystallization, morphologies, particle size and particle size distribution of the phosphors obtained under different experimental conditions were studied. The influence of various factors on the luminescence intensity of the phosphor was also investigated, such as feeding methods, volume flow rate, contents of Ce and initial reactant concentration. The results show that the precursors synthesized by T-tube impinging streams co-precipitation reaction transform to Y3A15O12 （YAG） phosphor at about 1 000 ℃. The particles are far smaller and narrower than those prepared by D-CP. In the impinging streams co-precipitation system, the luminescent intensity of YAG：Ce phosphor increases with the increase of liquid flow rate. The intensity firstly increases then decreases with the increasing Ce^3＋ doping content, and the maximum intensity is shown at 1.67% （molar fraction） Ce. Luminescent intensity gradually decreases with the increase of initial concentration of reactants. At the same operational condition, the luminescent intensity of the phosphors prepared by T-tube impinging streams reactor is higher than that by D-CP, and the luminescent intensity of the phosphors prepared by T-type vortex impinging streams is higher than that by T-tube impinging streams reactor.
基金Project(51276131)supported by the National Natural Science Foundation of ChinaProject(ZRZ0316)supported by the Natural Science Foundation of Hubei Province,ChinaProject(2013070104010025)supported by the Morning Glory Project of Wuhan Science and Technology Bureau,China
文摘The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of macromixing time and micromixing time are quantitatively discussed. The results show that under a continuous and stable operating condition, as the paddle speed increases, the macromixing time and micromixing time calculated by the two models both decrease, even in a linkage equilibrium state. Simultaneously, as the paddle speed increases, the results figured by the two models tend to be consistent. It indicates that two models both are more suitable for calculation of mixing time in high paddle speed. Compared with the existing experimental results of this type of reactor, the mixing time computed in the speed of 1500 r/min is closer to it. These conclusions can provide an important reference for systematically studying the strengthening mechanism of LISR under continuous mixing conditions.
基金Supported by the National Natural Science Foundation of China (No. 29276260, No. 20176043).
文摘Micromixing in the submerged circulative impinging stream reactor (SCISR) developed by the authors is investigated with the Bourne's reaction scheme. The values measured for the impinging velocity, u0, under the conditions of SCISR normal operation, only is of the order of 0.1m·s^-1, are much slower than that inferred,suggesting low power requirement for operation. The values of the characteristic time constant for micromixing,tM, determined in the impinging velocity range of 0.184m·s^-1 < u0 < 0.326m·s^-1 are ranged from 192ms to 87 ms, showing that impinging streams promotes micromixing very efficiently. The data follow approximately the relationship of tM∝ u0^-1.5. A comparative study shows that the micromixing performance of SCISR is much better than that of the traditional stirred tank reactor. The tM values predicted with the existing theoretical model are systematically longer than those measured by about 2--3 times, implying that the regularity of impinging streams promoting micromixing is unclear yet.
基金Project supported by the National Natural Science Foundation of China (50474022 and 50574069 )
文摘Cerium carbonate powders were produced in a submerged circulation impinging stream reactor （SCISR） from Ce（NO3）3· 6H2O. NH4HCO3 was used as a precipitant in the reaction. Cerium carbonate powders were roasted to produce ultra-fine cerium dioxide （CeO2） powders. The optimal conditions of such production process were obtained by orthogonal and one-factor experiments. The results showed that ultra-fine and narrowly distributed cerium carbonate powders were produced under the optimal flowing conditions. The concentrations of Ce（NO3）3 and NH4HCO3 solutions were 02,5 and 0.3 mol · L^-1, respectively. The concentration of PEG4000 added in these two solutions was 4 g · L^-1. The stirring ratio, reaction temperature, feeding time, solution pH, reaction time and digestion time were 900 r · min^- 1,80 ℃, 20 min, 5 - 6, 5 min and 1 h, respectively. The final product, CeO2 powders, was obtained by roasting the produced cerium carbonate in air for 3 h at 500 ℃. The finally produced CeO2 powders were torispherical particles with a narrow size distribution of 0.8 -2.5 μm. The crystal structure of CeO2 powders belonged to cubic crystal system and its space point 5 group was OH^5-FM3M. Under optimal conditions, powders produced by SCISR were finer and more narrowly distributed than that by Stirred Tank Reactor （STR）.
基金the National Natural Science Foundation of China （No.29276260, No.20176043）.ACKN0WLEDGEMENT The authors would like to thank Dr. Zhang Jian- wei who worked a lot in preparation of the apparatus for pressure fluctuation measurements.
文摘Pressure fluctuation in the submerged circulative impinging stream reactor （SCISR） is studied by measuring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Experimental results show that the maximum amplitude of fluctuation can be up to about 1.6kPa. On the power spectra the fluctuation is relatively concentrated in the range of 〈1000Hz, with some weak peeks in acoustic wave range. The space profile of intensive fluctuation region in the reactor is determined. The region is found to take the form of a couple truncated cones of empty core, with coincided bottoms, and is symmetrical with respect to the impinging plane and approximately symmetrical about the axis, essentially independent of u0. The integral intensity of fluctuation increases as the impinging velocity, Uo increasing.
基金Supported by the National Natural Science Foundation of China (No.29276260, No.20176043).
文摘Pressure fluctuation in the submerged circulative impinging stream reactor (SCISR) is studied by meas- uring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Ex- perimental results show that the maximum amplitude of fluctuation can be up to about 1.6kPa. On the power spectra the fluctuation is relatively concentrated in the range of <1000Hz, with some weak peeks in acoustic wave range. The space profile of intensive fluctuation region in the reactor is determined. The region is found to take the form of a couple truncated cones of empty core, with coincided bottoms, and is symmetrical with respect to the impinging plane and approximately symmetrical about the axis, essentially independent of u0. The integral intensity of fluctua- tion increases as the impinging velocity, u0 increasing.
基金Supported by the State Key Fundamental Research Plan of China (No. G20000263) and the Director Foundation of Institute of Engineering Thermophysics, Chinese Academy of Sciences.
文摘The experiments of one-stage semi-circular and two-stage semi-circular impinging stream drying as well as the vertical and semi-circular combined impinging stream drying were carried out. The velocity distribution and the mean residence time of particles, and the influence of various factors on drying characteristics were studied. A mathematical model of granular material drying in a semi-circular impinging stream dryer was proposed, in which the flow characteristics as well as the heat and mass transfer mechanisms were considered. Reasonable numerical methods were used to solve the equations. Under various conditions, the calculated results agree well with the experimental data. The unsteady-state drying dynamic equation, as well as the variations of drying rate and moisture content versus time were obtained. The results indicate that constant drying rate period does not exist in a semi-circular impinging stream dryer. Appropriate semi-circular stage number and curvature radius, flow-rate ratio, air velocity, and higher inlet air temperature should be used for enhancing the drying process.
基金Supported by the National Natural Science Foundation of China and Natural Science Foundation of Zhejiang Province.
文摘1 INTRODUCTIONAs mentioned in our previous paper impinging stream contactor(ISC)is aninnovative device for phase contact operations and has proved itself capable to en-hance transfer processes in heterogeneous systems effectively,and thus is of poten-tial application in many chemical engineering processes,such as drying of solidparticles,solid-solid,liquid-liquid and gas-gas mixing,absorption and desorptionof gases into or from liquids with or without chemical reactions,combustion
基金supported by the National Natural Science Foundation of China(Key Project No.5873610)Chinese Academy Sciences(Key Project No.KJ951-131-704)+1 种基金Chinese National Key Foundation Research Subject(No.G2000026305)the Director Foundation of Institute of Engineering Thermophysics,Chinese Academy Sciences.
文摘Based on the experimental investigation of one-stage semi-circular impinging stream drying, the experiments with the two-stage semi-circular, as well as the vertical and semi-circular combined impinging stream drying were conducted. The variations of system pressure drop, the mean residence time of particles with the mass flow-rate ratio and air velocity etc, were determined. The influences of inlet air temperature, mass flow-rate ratio, initial moisture content of particles and air velocity etc. on drying characteristics were also studied. The results indicate that the vertical and semi-circular combined impinging stream drying can make full use of the advantages of both the vertical and semi-circular impinging stream drying. Reasonable mass flow-rate ratio, air velocity, and higher inlet air temperature should be used for less energy consumption and cost during drying process.
文摘This paper presents an experimental investiga-tion of a novel impinging stream reactor(ISR)with the aim of high mixing intensity.The integral mixing quality in the reactor was measured with the iodide-iodate reaction and showed excellent mixing performance.The impact of the operating parameters,such asfluxes,circulation and inter-nozzle distances,was investigated in terms of segregation index.The results showed that the increase offlux,the decrease of inter-nozzle distance and a suitable circulation can improve the micro-mixing efficiency.Based on turbulence theory,it was estimated that the characteristic micro-mixing time was 0.002–0.02 s,which was much shorter than that in the stirred tank reactor.The micro-mixing time was related to the segregation index,which was in good agreement with those in the literature.
基金supported by National Natural Science Foundation of China(Grant Nos.51006040,51006039)the Fundamental Research Funds for the Central Universities,HUST(Grant Nos.2010JC005,2010MS131 and 2010QN057).
文摘Previous works on impinging streams mainly focused on the structures of flow field,but paid less attention to the structures of temperature field,which are very important in practical applications.In this paper,the influences of the Reynolds number(Re)and Prandtl number(Pr)on the structures of flow and temperature fields of non-isothermal laminar impinging streams are both studied numerically with the lattice Boltzmann method,and two cases with and without buoyancy effect are considered.Numerical results show that the structures are quite different in these cases.Moreover,in the case with buoyancy effect,some new deflection and periodic structures are found,and their independence on the outlet boundary condition is also verified.These findings may help to understand the flow and temperature structures of non-isothermal impinging streams further.
基金supported financially by the National Basic Research Program of China(No.2004CB217703)New Century Excellent Talents in University(NCET-05-0413).
文摘Based on some experimental investigations of liquid phase residence time distribution(RTD)in an impinging stream reactor,a two-dimensional plug-flow dispersion model for predicting the liquid phase RTD in the reactor was proposed.The calculation results of the model can be in good agreement with the experimental RTD under different operating conditions.The axial liquid dispersion coefficient increases monotonously with the increasing liquid flux,but is almost independent of gas flux.As the liquid flux and the gas flux increase,the liquid dispersion coefficient of center-to-wall decreases.The axial liquid dispersion coefficient is much larger than that of center-to-wall,which indicates that the liquid RTD is dominated mainly by axial liquid dispersion in the impinging stream reactor.
