Groundwater contamination becomes a great concern in many countries. One of the most important pollutants is hydrocarbons. Sources of Hydrocarbons pollutants in Gazacan be a result of accidental spills of petroleum pr...Groundwater contamination becomes a great concern in many countries. One of the most important pollutants is hydrocarbons. Sources of Hydrocarbons pollutants in Gazacan be a result of accidental spills of petroleum products on the surface and uncontrolled disposal of wastewater. One of the common technologies for groundwater aquifer remediation from hydrocarbons is known as air sparging. In this study, a120 cm×100 cm×80 cmlaboratory scale aquifer model was implemented in order to investigate the effectiveness of air sparging technology in removal of petroleum products from contaminated site. Four pilot scale wells were installed at different depths and different spatial distribution. The central well was used for injecting air and the surrounding three wells were used for monitoring. The contaminated water and soil were tested for total organic carbon, lead, dissolved Oxygen and pH;one time before the start of treatment and four times through the treatment process. Total organic carbon in water and soil before air injection were 980 ppm and 0.08775 ppm, respectively. After air injection for three weeks (six hours daily) at flow rate range from 15 to20 L/min and at pressure range from 300 to 400 kPa, the concentration of pollutant was decreased to 4.0 ppm and 0.0 ppm in water and soil, respectively. Based on the results, it was clearly demonstrated that air sparging is a simple, effective and affordable technology that can be applied forGazaaquifer remediation in case of gasoline spill accidents.展开更多
BTEX contaminants in groundwater seriously impact the ecological environment and human health that has become one of the urgent problems needed to be solved.Due to its low density,low solubility and strong volatility,...BTEX contaminants in groundwater seriously impact the ecological environment and human health that has become one of the urgent problems needed to be solved.Due to its low density,low solubility and strong volatility,BTEX in groundwater usually form non-aqueous phase liquid(NAPL) contaminants and exist in three phases:gas,aqueous and oil phase.Air sparging(AS) is an in situ treatment technology展开更多
Air sparging is a remedial method for groundwater. The remedial region is similar to the air flow region in the saturated zone. If soil particles are transported during air sparging, the porosity distributions in the ...Air sparging is a remedial method for groundwater. The remedial region is similar to the air flow region in the saturated zone. If soil particles are transported during air sparging, the porosity distributions in the saturated zone change, which may alter the flow path of the air. To understand better the particle movement, this study performed a sandbox test to estimate the soil porosity change during air sparging. A clear fracture was formed and the phenomenon of particle movement was observed when the air injection was started. The moved sand filled the porous around the fracture and the reparked sand filled the fracture, reducing the porosity around the fracture. The results obtained from the photographs of the sandbox, the current measurements and the direct sand sample measurements were close to each other and are credible. Therefore, air injection during air sparging causes sand particle movement of sand, altering the characteristic of the sand matrix and the air distribution.展开更多
Air sparging(AS) is an emerging method to remove VOCs from saturated soils and groundwater. Air sparging performance highly depends on the air distribution resulting in the aquifer. In order to study gas flow characte...Air sparging(AS) is an emerging method to remove VOCs from saturated soils and groundwater. Air sparging performance highly depends on the air distribution resulting in the aquifer. In order to study gas flow characterization, a two-dimensional experimental chamber was designed and installed. In addition, the method by using acetylene as the tracer to directly image the gas distribution results of AS process has been put forward. Experiments were performed with different injected gas flow rates. The gas flow patterns were found to depend significantly on the injected gas flow rate, and the characterization of gas flow distributions in porous media was very different from the acetylene tracing study. Lower and higher gas flow rates generally yield more irregular in shape and less effective gas distributions.展开更多
An in situ coupling strategy to prepare Co_9S_8/S and N dual?doped graphene composite(Co_9S_8/NSG) has been proposed. The key point of this strategy is the function?oriented design of organic compounds. Herein, cobalt...An in situ coupling strategy to prepare Co_9S_8/S and N dual?doped graphene composite(Co_9S_8/NSG) has been proposed. The key point of this strategy is the function?oriented design of organic compounds. Herein, cobalt porphyrin derivatives with sulfo groups are employed as not only the coupling agents to form and anchor Co_9S_8 on the graphene in situ, but also the heteroatom?doped agent to generate S and N dual?doped graphene. The tight coupling of multiple active sites endows the composite materials with fast electrochemical kinetics and excellent stability for both oxygen reduction reaction(ORR) and oxygen evolution reaction(OER). The obtained electrocatalyst exhibits better activity parameter(ΔE = 0.82 V) and smaller Tafel slope(47.7 mV dec^(-1) for ORR and 69.2 mV dec^(-1) for OER) than commercially available Pt/C and RuO_2. Most importantly, as electrocatalyst for rechargeable Zn–air battery, Co_9S_8/NSG displays low charge–discharge voltage gap and outstanding long?term cycle stability over 138 h compared to Pt/C–RuO_2. To further broaden its application scope, a homemade all?solid?state Zn–air battery is also prepared, which displays good charge–discharge performance and cycle performance. The function?oriented design of N_4?metallomacrocycle derivatives might open new avenues to strategic construction of high?performance and long?life multifunctional electrocatalysts for wider electro?chemical energy applications.展开更多
From a time value of revenue point of view,it is preferred that the time between reservoir stimulation and oil production response is small.Heavy oil combustion processes have a lag time between air injection and liqu...From a time value of revenue point of view,it is preferred that the time between reservoir stimulation and oil production response is small.Heavy oil combustion processes have a lag time between air injection and liquid production,but the common practice in production data analysis uses simultaneous injection and production data when seeking a relationship between them.In this research,the time scales of production for the Kerrobert toe-to-heel air injection(THAI)heavy oil project in Saskatchewan,Canada,is analyzed by using cross correlation analysis,i.e.time delay analysis between air injection and oil production.The results reveal two time scales with respect to production response with two distinctive recovery mechanisms:(1)a short time scale response(nearly instantaneous)where oil production peaks right after air injection(directly after opening production well)reflecting cold heavy oil production mechanisms,and(2)a longer time scale(of order of 100-300 days)response where peak production occurs associated with the collective phenomena of air injection,heat generating reactions,heat transfer,and finally,heated mobilized heavy oil drainage to the production well.This understanding of the two time scales and associated production mechanisms provides a basis for improving the performance of THAI.展开更多
The unquenchable demand for rock materials has attracted many companies within the building and construction sector to invest in stone quarrying. However, this has brought about environmental impacts with health threa...The unquenchable demand for rock materials has attracted many companies within the building and construction sector to invest in stone quarrying. However, this has brought about environmental impacts with health threats to people. There is a paucity of information about the magnitude of pollution on air and water and how it varies with quarry sites. This study, therefore, investigated the physical impacts of quarrying on air and water and explored the in-situ mitigations to undesirable effects due to stone quarrying. Four active quarry sites were identified. Field measurements of dust (particulate matter) were conducted within the four quarry sites and in the nearby community. Water samples were collected from quarry pits and nearby shallow wells for laboratory analysis of water quality. Statistical Analysis of Variance (ANOVA) was used to test for differences in pollution across the four studied sites. Results revealed that, amidst the use of wet crushing and water sprinkling on bare surfaces, dust emission was higher than the recommended permissible standards levels with a significant variation across the quarry sites with ANOVA (P-value = 0.003) for PM 2.5 and (P-value = 0.04366) for PM 10. Water pollution was mainly contributed by the non-permissive levels of nitrates, chromium, and pH. Polluted air and water are associated with sparking off health threats to the users in the community. In conclusion, quarry companies should strengthen the already existing mitigation of dust suppression. The study recommends additional measures such as treating quarry pit water before discharging to the open environment to enhance environmental protection against the accumulating undesirable quarry impacts.展开更多
文摘Groundwater contamination becomes a great concern in many countries. One of the most important pollutants is hydrocarbons. Sources of Hydrocarbons pollutants in Gazacan be a result of accidental spills of petroleum products on the surface and uncontrolled disposal of wastewater. One of the common technologies for groundwater aquifer remediation from hydrocarbons is known as air sparging. In this study, a120 cm×100 cm×80 cmlaboratory scale aquifer model was implemented in order to investigate the effectiveness of air sparging technology in removal of petroleum products from contaminated site. Four pilot scale wells were installed at different depths and different spatial distribution. The central well was used for injecting air and the surrounding three wells were used for monitoring. The contaminated water and soil were tested for total organic carbon, lead, dissolved Oxygen and pH;one time before the start of treatment and four times through the treatment process. Total organic carbon in water and soil before air injection were 980 ppm and 0.08775 ppm, respectively. After air injection for three weeks (six hours daily) at flow rate range from 15 to20 L/min and at pressure range from 300 to 400 kPa, the concentration of pollutant was decreased to 4.0 ppm and 0.0 ppm in water and soil, respectively. Based on the results, it was clearly demonstrated that air sparging is a simple, effective and affordable technology that can be applied forGazaaquifer remediation in case of gasoline spill accidents.
文摘BTEX contaminants in groundwater seriously impact the ecological environment and human health that has become one of the urgent problems needed to be solved.Due to its low density,low solubility and strong volatility,BTEX in groundwater usually form non-aqueous phase liquid(NAPL) contaminants and exist in three phases:gas,aqueous and oil phase.Air sparging(AS) is an in situ treatment technology
文摘Air sparging is a remedial method for groundwater. The remedial region is similar to the air flow region in the saturated zone. If soil particles are transported during air sparging, the porosity distributions in the saturated zone change, which may alter the flow path of the air. To understand better the particle movement, this study performed a sandbox test to estimate the soil porosity change during air sparging. A clear fracture was formed and the phenomenon of particle movement was observed when the air injection was started. The moved sand filled the porous around the fracture and the reparked sand filled the fracture, reducing the porosity around the fracture. The results obtained from the photographs of the sandbox, the current measurements and the direct sand sample measurements were close to each other and are credible. Therefore, air injection during air sparging causes sand particle movement of sand, altering the characteristic of the sand matrix and the air distribution.
基金The National Natural Science Foundation of China(No. 20276048)
文摘Air sparging(AS) is an emerging method to remove VOCs from saturated soils and groundwater. Air sparging performance highly depends on the air distribution resulting in the aquifer. In order to study gas flow characterization, a two-dimensional experimental chamber was designed and installed. In addition, the method by using acetylene as the tracer to directly image the gas distribution results of AS process has been put forward. Experiments were performed with different injected gas flow rates. The gas flow patterns were found to depend significantly on the injected gas flow rate, and the characterization of gas flow distributions in porous media was very different from the acetylene tracing study. Lower and higher gas flow rates generally yield more irregular in shape and less effective gas distributions.
基金supported by the National Natural Science Foundation of China (Grant No. 21404014)the Science & Technology Department of Jilin Province (No. 20170101177JC)
文摘An in situ coupling strategy to prepare Co_9S_8/S and N dual?doped graphene composite(Co_9S_8/NSG) has been proposed. The key point of this strategy is the function?oriented design of organic compounds. Herein, cobalt porphyrin derivatives with sulfo groups are employed as not only the coupling agents to form and anchor Co_9S_8 on the graphene in situ, but also the heteroatom?doped agent to generate S and N dual?doped graphene. The tight coupling of multiple active sites endows the composite materials with fast electrochemical kinetics and excellent stability for both oxygen reduction reaction(ORR) and oxygen evolution reaction(OER). The obtained electrocatalyst exhibits better activity parameter(ΔE = 0.82 V) and smaller Tafel slope(47.7 mV dec^(-1) for ORR and 69.2 mV dec^(-1) for OER) than commercially available Pt/C and RuO_2. Most importantly, as electrocatalyst for rechargeable Zn–air battery, Co_9S_8/NSG displays low charge–discharge voltage gap and outstanding long?term cycle stability over 138 h compared to Pt/C–RuO_2. To further broaden its application scope, a homemade all?solid?state Zn–air battery is also prepared, which displays good charge–discharge performance and cycle performance. The function?oriented design of N_4?metallomacrocycle derivatives might open new avenues to strategic construction of high?performance and long?life multifunctional electrocatalysts for wider electro?chemical energy applications.
基金support from the Department of Chemical and Petroleum Engineering at the University of Calgary,the University of Calgary’s Canada First Research Excellence Fund program(the Global Research Initiative for Sustainable Low-Carbon Unconventional Resources)
文摘From a time value of revenue point of view,it is preferred that the time between reservoir stimulation and oil production response is small.Heavy oil combustion processes have a lag time between air injection and liquid production,but the common practice in production data analysis uses simultaneous injection and production data when seeking a relationship between them.In this research,the time scales of production for the Kerrobert toe-to-heel air injection(THAI)heavy oil project in Saskatchewan,Canada,is analyzed by using cross correlation analysis,i.e.time delay analysis between air injection and oil production.The results reveal two time scales with respect to production response with two distinctive recovery mechanisms:(1)a short time scale response(nearly instantaneous)where oil production peaks right after air injection(directly after opening production well)reflecting cold heavy oil production mechanisms,and(2)a longer time scale(of order of 100-300 days)response where peak production occurs associated with the collective phenomena of air injection,heat generating reactions,heat transfer,and finally,heated mobilized heavy oil drainage to the production well.This understanding of the two time scales and associated production mechanisms provides a basis for improving the performance of THAI.
文摘The unquenchable demand for rock materials has attracted many companies within the building and construction sector to invest in stone quarrying. However, this has brought about environmental impacts with health threats to people. There is a paucity of information about the magnitude of pollution on air and water and how it varies with quarry sites. This study, therefore, investigated the physical impacts of quarrying on air and water and explored the in-situ mitigations to undesirable effects due to stone quarrying. Four active quarry sites were identified. Field measurements of dust (particulate matter) were conducted within the four quarry sites and in the nearby community. Water samples were collected from quarry pits and nearby shallow wells for laboratory analysis of water quality. Statistical Analysis of Variance (ANOVA) was used to test for differences in pollution across the four studied sites. Results revealed that, amidst the use of wet crushing and water sprinkling on bare surfaces, dust emission was higher than the recommended permissible standards levels with a significant variation across the quarry sites with ANOVA (P-value = 0.003) for PM 2.5 and (P-value = 0.04366) for PM 10. Water pollution was mainly contributed by the non-permissive levels of nitrates, chromium, and pH. Polluted air and water are associated with sparking off health threats to the users in the community. In conclusion, quarry companies should strengthen the already existing mitigation of dust suppression. The study recommends additional measures such as treating quarry pit water before discharging to the open environment to enhance environmental protection against the accumulating undesirable quarry impacts.
