The hydrothermal synthesis of In_(2)O_(3)and CeO_(2)–In_(2)O_(3)is investigated as well as the properties of sensor layers based on these compounds.During the synthesis of In_(2)O_(3),intermediate products In(OH)_(3)...The hydrothermal synthesis of In_(2)O_(3)and CeO_(2)–In_(2)O_(3)is investigated as well as the properties of sensor layers based on these compounds.During the synthesis of In_(2)O_(3),intermediate products In(OH)_(3)and InOOH are formed,which are the precursors of stable cubic(c-In_(2)O_(3))and metastable rhombohedral(rh-In_(2)O_(3))phases,respectively.A transition from c-In_(2)O_(3)to rh-In_(2)O_(3)is observed with the addition of CeO_(2).The introduction of cerium into rh-In_(2)O_(3)results in a decrease in the sensor response to hydrogen,while it increases in composites based on c-In_(2)O_(3).The data on the sensor activity of the composites correlate with XPS results in which CeO_(2)causes a decrease in the concentrations of chemisorbed oxygen and oxygen vacancies in rh-In_(2)O_(3).The reverse situation is observed in composites based on c-In_(2)O_(3).Compared to In_(2)O_(3)and CeO_(2)–In_(2)O_(3)obtained by other methods,the synthesized composites demonstrate maximum response to H_(2)at low temperatures by 70–100℃,and have short response time(0.2–0.5 s),short recovery time(6–7 s),and long-term stability.A model is proposed for the dependence of sensitivity on the direction of electron transfer between In_(2)O_(3)and CeO_(2).展开更多
In this work,we extend the recently proposed adaptive phase field method to model fracture in orthotropic functionally graded materials(FGMs).A recovery type error indicator combined with quadtree decomposition is emp...In this work,we extend the recently proposed adaptive phase field method to model fracture in orthotropic functionally graded materials(FGMs).A recovery type error indicator combined with quadtree decomposition is employed for adaptive mesh refinement.The proposed approach is capable of capturing the fracture process with a localized mesh refinement that provides notable gains in computational efficiency.The implementation is validated against experimental data and other numerical experiments on orthotropic materials with different material orientations.The results reveal an increase in the stiffness and the maximum force with increasing material orientation angle.The study is then extended to the analysis of orthotropic FGMs.It is observed that,if the gradation in fracture properties is neglected,the material gradient plays a secondary role,with the fracture behaviour being dominated by the orthotropy of the material.However,when the toughness increases along the crack propagation path,a substantial gain in fracture resistance is observed.展开更多
基金supported by the Russian Science Foundation(grant No.22-19-00037),https://rscf.ru/project/22-19-00037/.
文摘The hydrothermal synthesis of In_(2)O_(3)and CeO_(2)–In_(2)O_(3)is investigated as well as the properties of sensor layers based on these compounds.During the synthesis of In_(2)O_(3),intermediate products In(OH)_(3)and InOOH are formed,which are the precursors of stable cubic(c-In_(2)O_(3))and metastable rhombohedral(rh-In_(2)O_(3))phases,respectively.A transition from c-In_(2)O_(3)to rh-In_(2)O_(3)is observed with the addition of CeO_(2).The introduction of cerium into rh-In_(2)O_(3)results in a decrease in the sensor response to hydrogen,while it increases in composites based on c-In_(2)O_(3).The data on the sensor activity of the composites correlate with XPS results in which CeO_(2)causes a decrease in the concentrations of chemisorbed oxygen and oxygen vacancies in rh-In_(2)O_(3).The reverse situation is observed in composites based on c-In_(2)O_(3).Compared to In_(2)O_(3)and CeO_(2)–In_(2)O_(3)obtained by other methods,the synthesized composites demonstrate maximum response to H_(2)at low temperatures by 70–100℃,and have short response time(0.2–0.5 s),short recovery time(6–7 s),and long-term stability.A model is proposed for the dependence of sensitivity on the direction of electron transfer between In_(2)O_(3)and CeO_(2).
基金E.Martínez-Paneda acknowledges financial support from the Royal Commission for the 1851 Exhibition through their Research Fellowship programme(RF496/2018).
文摘In this work,we extend the recently proposed adaptive phase field method to model fracture in orthotropic functionally graded materials(FGMs).A recovery type error indicator combined with quadtree decomposition is employed for adaptive mesh refinement.The proposed approach is capable of capturing the fracture process with a localized mesh refinement that provides notable gains in computational efficiency.The implementation is validated against experimental data and other numerical experiments on orthotropic materials with different material orientations.The results reveal an increase in the stiffness and the maximum force with increasing material orientation angle.The study is then extended to the analysis of orthotropic FGMs.It is observed that,if the gradation in fracture properties is neglected,the material gradient plays a secondary role,with the fracture behaviour being dominated by the orthotropy of the material.However,when the toughness increases along the crack propagation path,a substantial gain in fracture resistance is observed.
