Assessing mixing uniformity in microreactors via in-line spectroscopy

Mixing behavior is critical for enhancing the selectivity of fast chemical reactions in microreactors.A high Reynolds number(Re)improves the mixing rate and selectivity of the reactions,but some exceptions of increasing side product yield with the higher Re have been reported.This study investigated the mixing uniformity in microreactors with in-line UV-vis spectroscopy to clarify the relationship between reaction selectivity and chaotic mixing with the higher Re.A colorization experiment of thymolphthalein in an acidic solution was conducted with an excess acid amount to the base to indicate a non-uniformly mixed region.Non-uniformity significantly increased with Re.At the same time,the degree of mixing,which was measured by a usual decolorization experiment,showed that the mixing rate increased with Re.The in-line analysis of the Villermaux-Dushman reaction during the mixing clarified that side product yield significantly increased with Re at around 300 and then decreased at around 1100.These results suggest the compensation effect between the mixing uniformity and mixing rate on the selectivity of the mixing-sensitive reactions.Faster mixing,characterized by a larger Re,can disturb mixing uniformity and,in some cases,decrease reaction selectivity.

Fracture propagation law of temporary plugging and diversion fracturing in shale reservoirs under completion experiments of horizontal well with multi-cluster sand jetting perforation

This study conducted temporary plugging and diversion fracturing(TPDF)experiments using a true triaxial fracturing simulation system within a laboratory setting that replicated a lab-based horizontal well completion with multi-cluster sand jetting perforation.The effects of temporary plugging agent(TPA)particle size,TPA concentration,single-cluster perforation number and cluster number on plugging pressure,multi-fracture diversion pattern and distribution of TPAs were investigated.A combination of TPAs with small particle sizes within the fracture and large particle sizes within the segment is conducive to increasing the plugging pressure and promoting the diversion of multi-fractures.The addition of fibers can quickly achieve ultra-high pressure,but it may lead to longitudinal fractures extending along the wellbore.The temporary plugging peak pressure increases with an increase in the concentration of the TPA,reaching a peak at a certain concentration,and further increases do not significantly improve the temporary plugging peak pressure.The breaking pressure and temporary plugging peak pressure show a decreasing trend with an increase in single-cluster perforation number.A lower number of single-cluster perforations is beneficial for increasing the breaking pressure and temporary plugging peak pressure,and it has a more significant control on the propagation of multi-cluster fractures.A lower number of clusters is not conducive to increasing the total number and complexity of artificial fractures,while a higher number of clusters makes it difficult to achieve effective plugging.The TPAs within the fracture is mainly concentrated in the complex fracture areas,especially at the intersections of fractures.Meanwhile,the TPAs within the segment are primarily distributed near the perforation cluster apertures which initiated complex fractures.

A novel responsive stabilizing Janus nanosilica as a nanoplugging agent in water-based drilling fluids for exploiting hostile shale environments

Thermo-responsive nanocomposites have recently emerged as potential nanoplugging agents for shale stabilization in high-temperature water-based drilling fluids(WBDFs). However, their inhibitory properties have not been very effective in high-temperature drilling operations. Thermo-responsive Janus nanocomposites are expected to strongly interact with clay particles from the inward hemisphere of nanomaterials, which drive the establishment of a tighter hydrophobic membrane over the shale surface at the outward hemisphere under geothermal conditions for shale stabilization. This work combines the synergistic benefits of thermo-responsive and zwitterionic nanomaterials to synchronously enhance the chemical inhibitions and plugging performances in shale under harsh conditions. A novel thermoresponsive Janus nanosilica(TRJS) exhibiting zwitterionic character was synthesized, characterized,and assessed as shale stabilizer for WBDFs at high temperatures. Compared to pristine nanosilica(Si NP)and symmetrical thermo-responsive nanosilica(TRS), TRJS exhibited anti-polyelectrolyte behaviour, in which electrolyte ions screened the electrostatic attraction between the charged particles, potentially stabilizing nanomaterial in hostile shaly environments(i.e., up to saturated brine or API brine). Macroscopically, TRJS exhibited higher chemical inhibition than Si NP and TRS in brine, prompting a better capability to control pressure penetration. TRJS adsorbed onto the clay surface via chemisorption and hydrogen bonding, and the interactions became substantial in brine, according to the results of electrophoretic mobility, surface wettability, and X-ray diffraction. Thus, contributing to the firm trapping of TRJS into the nanopore structure of the shale, triggering the formation of a tight hydrophobic membrane over the shale surface from the outward hemisphere. The addition of TRJS into WBDF had no deleterious effect on fluid properties after hot-treatment at 190℃, implying that TRJS could find potential use as a shale stabilizer in WBDFs in hostile environments.

A Gel-Based Solidification Technology for Large Fracture Plugging

Fault fractures usually have large openings and considerable extension. Accordingly, cross-linked gel materials aregenerally considered more suitable plugging agents than water-based gels because the latter often undergo contaminationvia formation water, which prevents them from being effective over long times. Hence, in this study, aset of oil-based composite gels based on waste grease and epoxy resin has been developed. These materials havebeen observed to possess high compressive strength and resistance to the aforementioned contamination, therebyleading to notable increase in plugging success rate. The compressive strength, thickening time, and resistance toformation water pollution of these gels have been evaluated indoors. The results show that the compressivestrength of the gel can reach 11 MPa;additionally, the related gelation time can be controlled to be more than3 h, thereby providing a safe construction time;Invasion of formation water has a small effect on the gel strengthand does not shorten the thickening time. All considered performance indicators of the oil-based gel confirm itssuitability as a plugging agent for fault fractures.

Dynamic plugging regulating strategy of pipeline robot based on reinforcement learning

Pipeline isolation plugging robot (PIPR) is an important tool in pipeline maintenance operation. During the plugging process, the violent vibration will occur by the flow field, which can cause serious damage to the pipeline and PIPR. In this paper, we propose a dynamic regulating strategy to reduce the plugging-induced vibration by regulating the spoiler angle and plugging velocity. Firstly, the dynamic plugging simulation and experiment are performed to study the flow field changes during dynamic plugging. And the pressure difference is proposed to evaluate the degree of flow field vibration. Secondly, the mathematical models of pressure difference with plugging states and spoiler angles are established based on the extreme learning machine (ELM) optimized by improved sparrow search algorithm (ISSA). Finally, a modified Q-learning algorithm based on simulated annealing is applied to determine the optimal strategy for the spoiler angle and plugging velocity in real time. The results show that the proposed method can reduce the plugging-induced vibration by 19.9% and 32.7% on average, compared with single-regulating methods. This study can effectively ensure the stability of the plugging process.

Plugging behaviors of temporary plugging particles in hydraulic fractures

Using the visualized experimental device of temporary plugging in hydraulic fractures, the plugging behaviors of temporary plugging particles with different sizes and concentrations in hydraulic fractures were experimentally analyzed under the conditions of different carrier fluid displacements and viscosities. The results show that the greater the carrier fluid viscosity and displacement, the more difficult it is to form a plugging layer, and that the larger the size and concentration of the temporary plugging particle, the less difficult it is to form a plugging layer. When the ratio of particle size to fracture width is 0.45, the formation of the plugging layer is mainly controlled by the mass concentration of the temporary plugging particle and the viscosity of the carrier fluid, and a stable plugging layer cannot form if the mass concentration of the temporary plugging particle is less than 20 kg/m^(3)or the viscosity of the carrier fluid is greater than 3 mPa·s. When the ratio of particle size to fracture width is 0.60, the formation of the plugging layer is mainly controlled by the mass concentration of the temporary plugging particle, and a stable plugging layer cannot form if the mass concentration of the temporary plugging particle is less than 10 kg/m^(3). When the ratio of particle size to fracture width is 0.75, the formation of the plugging layer is basically not affected by other parameters, and a stable plugging layer can form within the experimental conditions. The formation process of plugging layer includes two stages and four modes. The main controlling factors affecting the formation mode are the ratio of particle size to fracture width, carrier fluid displacement and carrier fluid viscosity.

Complex fracture propagation model and plugging timing optimization for temporary plugging fracturing in naturally fractured shale

In this paper,a viscoelasticity-plastic damage constitutive equation for naturally fractured shale is deduced,coupling nonlinear tensile-shear mixed fracture mode.Dynamic perforation-erosion on fluid re-distribution among multi-clusters are considered as well.DFN-FEM(discrete fracture network combined with finite element method)was developed to simulate the multi-cluster complex fractures propagation within temporary plugging fracturing(TPF).Numerical results are matched with field injection and micro-seismic monitoring data.Based on geomechanical characteristics of Weiyuan deep shale gas reservoir in Sichuan Basin,SW China,a multi-cluster complex fractures propagation model is built for TPF.To study complex fractures propagation and the permeability-enhanced region evolution,intersecting and competition mechanisms between the fractures before and after TPF treatment are revealed.Simulation results show that:fracture from middle cluster is restricted by the fractures from side-clusters,and side-clusters plugging is benefit for multi fractures propagation in uniformity;optimized TPF timing should be delayed within a higher density or strike of natural fractures;Within a reservoir-featured natural fractures distribution,optimized TPF timing for most clustered method is 2/3 of total fluid injection time as the optimal plugging time under different clustering modes.

Numerical Analysis of Dynamical Effects Associated with a Plugging String in a Horizontal Well

The finite element method has been applied to simulate the dynamics of a water plugging string in a complex horizontal well of a low-permeability oilfield.The force associated with the pipe string and the packer has been determined under the sucking action of the oil well pump.Such analysis has been conducted for a real drilling well,taking into account the process of lifting,lowering,unblocking and water plugging.Comparison between field measured data and simulation data indicates that the model is reliable and accurate.The packer creep effect under different pressure differences has also been investigated in the framework of the same model.

Experimental study of the temporary plugging capability of diverters to block hydraulic fractures in high-temperature geothermal reservoirs

The effective plugging of artificial fractures is key to the success of temporary plugging and diverting fracturing technology,which is one of the most promising ways to improve the heat recovery efficiency of hot dry rock.At present,how temporary plugging agents plug artificial fractures under high temperature remains unclear.In this paper,by establishing an improved experimental system for the evaluation of temporary plugging performance at high temperature,we clarified the effects of high temperature,injection rate,and fracture width on the pressure response and plugging efficiency of the fracture.The results revealed that the temporary plugging process of artificial fractures in hot dry rock can be divided into four main stages:the initial stage of temporary plugging,the bridging stage of the particles,the plugging formation stage,and the high-pressure dense plugging stage.As the temperature increases,the distribution distance of the temporary plugging agent,the number of pressure fluctuations,and the time required for crack plugging increases.Particularly,when the temperature increases by 100℃,the complete plugging time increases by 90.7%.

Optimization of the Plugging Agent Dosage for High Temperature Salt Profile Control in Heavy Oil Reservoirs

After steam discharge in heavy oil reservoirs,the distribution of temperature,pressure,and permeability in different wells becomes irregular.Flow channels can easily be produced,which affect the sweep efficiency of the oil displacement.Previous studies have shown that the salting-out plugging method can effectively block these channels in high-temperature reservoirs,improve the suction profile,and increase oil production.In the present study,the optimal dosage of the plugging agent is determined taking into account connection transmissibility and inter-well volumes.Together with the connectivity model,a water flooding simulation model is introduced.Moreover,a non-gradient stochastic disturbance algorithm is used to obtain the optimal plugging agent dosage,which provides the basis for the high-temperature salting-out plugging agent adjustment in the field.

Fatigue Life Analysis of Coiled Tubing in Deep Well Jet Plugging Removal

The coiled tubing plugging has become the main means of plugging in gas Wells in Xinjiang. These Wells are deep and have high pressure, which can easily affect the fatigue life of the operating coiled tubing. In order to improve the life of coiled tubing in high-pressure gas Wells, this paper studies the plugging conditions of coiled tubing in high-pressure ultra-deep Wells. Firstly, the cross section deformation of coiled tubing under high internal pressure is analyzed. Secondly, the factors influencing the fatigue life of coiled tubing and the influence of surface damage on the fatigue life of coiled tubing were studied. Finally, the mechanism of furrow damage caused by coiled tubing and the main measures to reduce furrow damage are analyzed. The following suggestions are made to improve the life of coiled tubing: select the right material and the right size coiled tubing;Use appropriate measures to prevent premature coiled tubing failure and reduce operating costs.

Influence of Incomplete Soil Plugs on Bearing Capacities of Bucket Foundations in Clay

Due to the uneven seabed and heaving of soil during pumping,incomplete soil plugs may occur during the installation of bucket foundations,and the impacts on the bearing capacities of bucket foundations need to be evaluated.In this paper,the contact ratio(the ratio of the top diameter of the soil plug to the diameter of the bucket)and the soil plug ratio(the ratio of the soil heave height to the skirt height)are defined to describe the shape and size of the incomplete soil plug.Then,finite element models are established to investigate the bearing capacities of bucket foundations with incomplete soil plugs and the influences of the contact ratios,and the soil plug ratios on the bearing capacities are analyzed.The results show that the vertical bearing capacity of bucket foundations in homogeneous soil continuously improves with the increase of the contact ratio.However,in normally consolidated soil,the vertical bearing capacity barely changes when the contact ratio is smaller than 0.75,while the bearing capacity suddenly increases when the contact ratio increases to 1 due to the change of failure mode.The contact ratio hardly affects the horizontal bearing capacity of bucket foundations.Moreover,the moment bearing capacity improves with the increase of the contact ratio for small aspect ratios,but hardly varies with increasing contact ratio for aspect ratios larger than 0.5.Consequently,the reduction coefficient method is proposed based on this analysis to calculate the bearing capacities of bucket foundations considering the influence of incomplete soil plugs.The comparison results show that the proposed reduction coefficient method can be used to evaluate the influences of incomplete soil plug on the bearing capacities of bucket foundations.

Feasibility of Plug Production Utilizing Digestate from Home-Waste to Energy Systems (H-WEF)

The integration of sustainable technologies in waste management systems has become imperative in addressing the escalating challenges of agricultural productivity and sustainability. Plugs are essential when starting crop production in controlled environment agriculture (CEA) setups and greenhouses. Horticultural crops such as vegetables, fruiting, and ornamental plants that utilize plugs have demonstrated higher success rates, healthier plants, and higher total yields. The APS Laboratory for Sustainable Agriculture explored the innovative utilization of digestate from the Home Water-Energy-Food Systems (H-WEF). The H-WEF system converts household food waste into biogas, electricity, and nutrient-rich digestate. The digestate from the H-WEF system was used to produce agricultural plugs, presenting a novel approach to circular resource utilization. We carried out the growth of Rex Butterhead Lettuce Latuca sativa plugs with 1) control system (synthetic fertilizer) and seven different treatments, 2) 5% Digestate—95% RO Water (5D–95RO);3) 10% Digestate—90% RO Water (10D–90RO);4) 15% Digestate—85% RO Water (15D–85RO);5) 20% Digestate—80% RO Water (20D–80RO);6) 25% Digestate—75% RO Water (25D–75RO);7) 30% Digestate—70% RO Water (30D–70RO);8) 35% Digestate—65% RO Water (35D–65RO). The plugs were cultivated for 15 days in a controlled environment until two leaves had developed after the cotyledon. After 15 days, we collected data on wet weight (g), plug head area (cm2), total leaf area (cm2), total chlorophyll content (mg/cm2), and dry weight (g). In addition, we collected data on the Leaf Area Index (LAI, cm2/cm2) and Specific Leaf Area (SLA, cm2/g). The synthetic fertigation yielded a higher wet weight than the following treatments: 5D–95RO, 10D–90RO, and 35D–65RO. While the 30D–70RO treatment produced a larger plug head than all other treatments. The digestate-based fertilizers were comparable to the synthetic fertilizer at dilutions of 25D–75RO and 30D–70RO. This study underscores the viability of using digestate for plug production, providing crucial insights for growers navigating the challenges of sustainable agricultural practices.

Study on Chrome-free Purging Plugs for Steel Ladles

Purging plug refractories in China typically contain around 3 mass% of super-fine chromium oxide in the matrix in order to improve the performance of the purging plugs, primarily, slag corrosion and wear resistance. Alternatives to chromium oxide containing refractories have gained interest due to health concerns related to the formation of soluble chromium compounds over long storage periods of refractory wastes. Super-ground reactive alumina can replace chromium oxide in purging plug refractories and this paper discussed the new reactive alumina E-SY 88 in comparison to chromium oxide in a typical purging plug castable. The mixing behaviour, wet castable properties, as well as cured, dried, and fired properties at different temperatures up to 1 600 ℃ were compared. In addition, the hot modulus of rupture, creep behaviour, thermal shock resistance and slag corrosion resistance were tested. The microstructure after slag corrosion was investigated by SEM. The results prove that E-SY 88 is an economically viable technical alternative to chromium oxide in purging plug refractories.

Combination of Plugging and Acidization Improves Injection Profile

Plugging agent treatment and acid stimulation have completely different mechanisms for improving injection profiles. In this paper, a hybrid procedure is introduced to reduce the damage of the plugging agent to low and medium permeability zones and the penetration radius of acid into high permeability zones. The procedure is: First inject plugging agent to block high permeability zones, and then inject acid to remove plugging agent damage from the low and medium permeability zones and stimulate them. To perform this procedure successfully, three kinds of plugging agents, namely strong strength plugging agent for the wells with fractures or high permeability streaks, weak gel for those with thick layer in which serious heterogeneity exists, temporary plugging agent for those in which the absorption ability of high permeability zones needs maintaining, were screened out for use in different reservoirs. Several acid systems were evaluated to be compatible with the three kinds of plugging agents. The objectives of this paper are:(1)To show the screen results about the compatible plugging agent and acid; 2 To show how to optimize the operation process;(3)To tell some experience gained ( ) from the oilfield applications of this technique. From Jan. 2001 to Dec. 2002, 46 operations using this procedure were carried out in Weicheng and Mazhai Oilfields of SINOPEC. Results show that the average benefit/cost ratio is over 3.5. Experience acquired from these applications was summarized in the paper.

Experimental investigation of enhancement of carbon dioxide foam stability, pore plugging, and oil recovery in the presence of silica nanoparticles

The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated from the pressure drop induced during foam propagation in porous media. The results clearly showed that the modified Si02 nanoparticlestabilized foam exhibited high stability, and the differential pressure increased in porous media by as much as three times.The addition of SiO_2 nanoparticles to the foaming dispersions further mitigated the adverse effect of oil toward the foam pore plugging ability. Consequently, the oil recovery increased in the presence of nanoparticles by approximately 15%during the enhanced oil recovery experiment. The study suggested that the addition of surface-modified silica nanoparticles to the surfactant solution could considerably improve the conventional foam stability and pore plugging performance in porous media.

Analysis and Online Diagnosis on Plugging Fault of Servo Valve in Electro-hydraulic Regulating System of Steam Turbine

Through the study on the output signals of the electro-hydraulic regulating system in the thermal power plant, a novel method for online diagnosis of the plugging fault in the servo valve is presented. With the use of the AMESIM software, the changes of the piston displacement, the oil pressure, the magnitude attenuation and the phase lag of the system under different plugging states are studied after simulation. Besides, the influences of the symmetrical and unsymmetrical plugging on the system are also compared and the characteristic table is given. The duo-neural network is put forward to achieve an online diagnosis on the plugging fault of the servo valve. The first level of network helps to make the qualitative diagnosis of the plugging position while the second level is for the quantitative diagnosis of the degree of the plugged position. The research results show that plugging at different positions exerts different influences on the performance of the system. The unsymmetrical plugging mainly affects the regulation time while the symmetrical plugging leads to great changes in the magnitude attenuation and the phase lag.

Thermo-sensitive polymer nanospheres as a smart plugging agent for shale gas drilling operations

Emulsifier-free poly（methyl methacrylate-styrene） [P（MMA-St）] nanospheres with an average particle size of 100 nm were synthesized in an isopropyl alcoholwater medium by a solvothermal method. Then, through radical graft copolymerization of thermo-sensitive mono- mer N-isopropylacrylamide （NIPAm） and hydrophilic monomer acrylic acid （AA） onto the surface of P（MMA- St） nanospheres at 80 ℃, a series of thermo-sensitive polymer nanospheres, named SD-SEAL with different lower critical solution temperatures （LCST）, were prepared by adjusting the mole ratio of NIPAm to AA. The products were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, thermogravimetric analysis, particle size distribution, and specific surface area analysis. The temperature-sensitive behavior was studied by light transmittance tests, while the sealing performance was investigated by pressure transmission tests with Lungmachi Formation shales. The experimental results showed that the synthesized nanoparticles are sensitive to temperature and had apparent LCST values which increased with an increase in hydrophilic monomer AA. When the temperature was higher than its LCST value, SD- SEAL played a dual role of physical plugging and chemical inhibition, slowed down pressure transmission, and reduced shale permeability remarkably. The plugged layer of shale was changed to being hydrophobic, which greatly improved the shale stability

The prediction on in-line vortex-induced vibration of slender marine structures

The in-line （IL） vortex-induced vibration （VIV） that occurs frequently in ocean engineering may cause severe fatigue damage in slender marine structures. To the best knowledge of the authors, in existing literatures, there is no efficient analytical model for predicting pure IL VIV. In this paper, a wake oscillator model capable of analyzing the IL VIV of slender marine structures has been developed. Two different kinds of van der Pol equations are used to describe the near wake dynamics related to the fluctuating nature of symmetric vortex shedding in the first excitation region and alternate vortex shedding in the second one. Some comparisons are carried out between the present model results and experimental data. It is found that many phenomena observed in experiments could be reproduced by the present wake oscillator model.

Experimental Study on Coupled Cross-Flow and in-Line Vortex-Induced Vibration of Flexible Risers

In this work, we study the coupled cross-flow and in-line vortex-induced vibration （VIV） of a fixedly mounted flexible pipe, which is free to move in cross-flow （ Y- ） and in-line （ X- ） direction in a fluid flow where the mass and natural frequencies are precisely the same in both X- and Y-direction. The fluid speed varies from low to high with the corresponding vortex shedding frequency varying from below the first natural frequency to above the second natural frequency of the flexible pipe. Particular emphasis was placed on the investigation of the relationship between in-line and cross-flow vibration. The experimental results analyzed by using these measurements exhibits several valuable features.