In this study,wearable triboelectric nanogenerators comprising bar-printed polyvinylidene fluoride(PVDF)films incorporated with cobalt-based metal-organic framework(Co-MOF)were developed.The enhanced output performanc...In this study,wearable triboelectric nanogenerators comprising bar-printed polyvinylidene fluoride(PVDF)films incorporated with cobalt-based metal-organic framework(Co-MOF)were developed.The enhanced output performance of the TENGs was attributed to the phase transition of PVDF from a-crystals toβ-crystals,as facilitated by the incorporation of the MOF.The synthesis conditions,including metal ion,concentration,and particle size of the MOF,were optimized to increase open-circuit voltage(VOC)and open-circuit current(I_(SC))of PVDF-based TENGs.In addition to high operational stability,mechanical robustness,and long-term reliability,the developed TENG consisting of PVDF incorporated with Co-MOF(Co-MOF@PVDF)achieved a VOC of 194 V and an I_(SC)of 18.8μA.Furthermore,the feasibility of self-powered mobile electronics was demonstrated by integrating the developed wearable TENG with rectifier and control units to power a global positioning system(GPS)device.The local position of the user in real-time through GPS was displayed on a mobile interface,powered by the battery charged through friction-induced electricity generation.展开更多
Using cetyl-trimethyl-ammonium bromide (CTMAB) as template and tetraethylortho-silicate (TEOS) as silica source, the MCM-41 mesoporous materials incorporated in framework by Y, Nd and Sm were synthesized by hydrot...Using cetyl-trimethyl-ammonium bromide (CTMAB) as template and tetraethylortho-silicate (TEOS) as silica source, the MCM-41 mesoporous materials incorporated in framework by Y, Nd and Sm were synthesized by hydrothermal synthesis method. The structure, morphology of materials and the state of Y, Nd, Sm in materials were investigated by means of XRD, nitrogen adsorption-desorption, SEM, IR spectrometry, TG-DTA. The XRD results indicate that the samples possess the mesoporous MCM-41 structures with ordered hexagonal arrangements. Y, Nd and Sm ions can get into the framework of mesoporous materials. Nitrogen adsorption desorption isotherms show that the samples have typical mesopores characteristics. SEM micrographs reveal that incorporated sampies show a spherical morphology and the diameters are averagely 0. l0 to 0.15 μm. In IR spectrum of samples, there are the feature adsorption peaks about Si-O-Ln(Ln=Y, Sm, Nd)at 960-985 cm^-1, which affirm that Y, Nd, Sm ions locate in the framework of several mesoporous materials. Results from TG-DTA analysis suggest that two different template sorption sites exist in the framework of YMCM-41, SmMCM-41, NdMCM-41, which powerfully proves that the presence of Y, Nd and Sm in Si framework of the materials.展开更多
Carbonaceous nanomaterials such as carbon nanotubes (CNTs), magnetic metal nanomaterials and semicon- ductor nanomaterials are superior candidates for microwave absorbers. Taking full advantage of the features of CN...Carbonaceous nanomaterials such as carbon nanotubes (CNTs), magnetic metal nanomaterials and semicon- ductor nanomaterials are superior candidates for microwave absorbers. Taking full advantage of the features of CNTs, nanophase cobalt and nanophase zinc oxide, whose main microwave absorption mechanisms are based on resistance loss, magnetic loss and dielectric loss, we fabricate CNT/Co and CNT/ZnO heterostructure nanocom- posites, respectively. By using the CNTs, CNT/Co nanocomposites and CNT/ZnO nanocomposites as nanofillers, composites with polyester as matrix are prepared by in situ polymerization, and their microwave absorption per- formance is studied. It is indicated that the synergetic effects of the physic properties of different components in nano-heterostructures result in greatly enhanced microwave absorption performance in a wide frequency range. The absorption peak is increased, the absorption bandwidth is broadened, and the maximum peak shifts to a lower frequency.展开更多
0 Introduction From a sociolinguistic perspective,competence in language use is determined not only by the ability to use language with grammatical accuracy,but also to use language appropriate to particular contexts....0 Introduction From a sociolinguistic perspective,competence in language use is determined not only by the ability to use language with grammatical accuracy,but also to use language appropriate to particular contexts.Thus,successful language learning requires language users to know the culture that underlies language.However,in foreign language teaching practice,culture teaching is often neglected,or introduced as no more than a supplementary diversion to language instruction.And the methods on how to teach the cultural knowledge is attached even less importance to.展开更多
Using cetyl-trimethyl-ammonium bromide (CTMAB) as template agent and tetraethylorthosilicate (TEOS) as silica Source, the MCM-41 mesoporous materials were synthesized with Y, Nd and Sm incorporated in the framewor...Using cetyl-trimethyl-ammonium bromide (CTMAB) as template agent and tetraethylorthosilicate (TEOS) as silica Source, the MCM-41 mesoporous materials were synthesized with Y, Nd and Sm incorporated in the framework under hydrothermal conditions. The structure and the micro-morphology of the materials and the state of Y, Nd and Sm were investigated through the analyses of XRD, nitrogen adsorption-desorption isotherm, SEM, IR and TG-DTA. The XRD resuits indicate that the synthetic samples are of typical structure of mesoporous MCM-41 with ordered hexagonal arrangements, and Y, Nd and Sm can be incorporated into the framework of these mesoporous materials. Nitrogen adsorption-desorption isotherms show that the samples possess the typical mesopores character. SEM micrographs reveal that the incorporated samples show a well-defined spherical morphology with the diameter ranging 0.10 - 0.15μm. The occurrence of two different template sorption sites in the framework as revealed by TG-DTA analysis further suggests the presence of Y, Nd and Sm in siliceous framework.展开更多
Several gelatin-silicate composites, with or without incorporation of Ca2+ ions, were synthesized through sol-gel processing starting from gelatin and 3- (glycidoxypropyl) trimethoxysilane. The structure around the Si...Several gelatin-silicate composites, with or without incorporation of Ca2+ ions, were synthesized through sol-gel processing starting from gelatin and 3- (glycidoxypropyl) trimethoxysilane. The structure around the Si atoms was similar for all the samples. The measurement of viscoelastic properties indicated that the glass transition temperature and activation energy decreased with the incorporation of Ca2+ ions. The Ca2+ ion-containing composites were bioactive as they spontaneously deposited apatite when soaked in a simulated body fluid of the Kokubo recipe.展开更多
The immobilization of SiW_(12)O_(40)^(4-)in poly(4-aminoazobenzene)film was done by electrochemical method.According to the continuous cyclic voltammograms of the modified electrode,it can be determined that SiW_(12)O...The immobilization of SiW_(12)O_(40)^(4-)in poly(4-aminoazobenzene)film was done by electrochemical method.According to the continuous cyclic voltammograms of the modified electrode,it can be determined that SiW_(12)O_(40)^(4-) in the polymer is very stable.The paper reports the elecctrochemical pro- perties of the modified electrode,Moreover,it was found that the modified electrode exhibits electrocatalysis for the reaction of oxygen.展开更多
Recent price movement Most benchmark prices decreased over the past month. Chinese prices moved sharply lower.Open interest has shifted from July and into the December contract. After moving lower in early May, values...Recent price movement Most benchmark prices decreased over the past month. Chinese prices moved sharply lower.Open interest has shifted from July and into the December contract. After moving lower in early May, values for the July contract were volatile but rangebound between 65 and 70 cents/lb for most of the past month. Values for the December contract also moved lower in early May. While they had been rangebound, December prices have been testing the lower end of their recent range, briefly dropping below 65 cents/lb in the latest trading.展开更多
Recent price movement Benchmark prices were flat or slightly higherover the pastmonth. Prices for the May NY futures contract increased over past month,climbing from levels just below 70 cents/lb in mid-February to th...Recent price movement Benchmark prices were flat or slightly higherover the pastmonth. Prices for the May NY futures contract increased over past month,climbing from levels just below 70 cents/lb in mid-February to those near 74 cents/lb recently.展开更多
September 25th-27th, 2019 - Cotton Incorporated (“CI”) promotes sustainability and innovation at the 2019 Shanghai Intertextile Apparel Fabrics Show at National Exhibition Center. With research and develop-ment effo...September 25th-27th, 2019 - Cotton Incorporated (“CI”) promotes sustainability and innovation at the 2019 Shanghai Intertextile Apparel Fabrics Show at National Exhibition Center. With research and develop-ment efforts through the entire supply chain, Cotton In-corporated presents the cotton fiber’s sustainability and cotton products’ competitiveness in the market to Shanghai Intertextile.展开更多
Daredevil·Gladiator·Cherry Red·Whirlwind·Flash·Grit·Spider Grass·MercuryWith less to lose,we take a risk,creating challenges and pushingourselves in ways we only fantasized about whi...Daredevil·Gladiator·Cherry Red·Whirlwind·Flash·Grit·Spider Grass·MercuryWith less to lose,we take a risk,creating challenges and pushingourselves in ways we only fantasized about while living in the safezone.Self-tested,defying limits,we feel invigorated.Each stepwe take towards our wildest dreams brings us one step closer tothe edge.This dynamic palette merges bold and muted tones.Itschameleon nature applies from active to formal wear.展开更多
Editor’s note:Cotton Incorporated has recently published its FW17/SS18 Denim Trend Forecast and 18/19 Active Trend Forecast respectively, which are presented here to share with our dear readers.FW17/SS18 Denim Trend ...Editor’s note:Cotton Incorporated has recently published its FW17/SS18 Denim Trend Forecast and 18/19 Active Trend Forecast respectively, which are presented here to share with our dear readers.FW17/SS18 Denim Trend Forecast Denim color shifts slightly away from all indigo to a more playful approach this season. Indigo remains essential but is shown in a less conventional way - being interspersed amongst four mini palettes.展开更多
Cotton University^TM adds four new courses to the College of Nonwovens Cotton Incorporated,the research and promotion company for U.S.cotton producers and importers,expands offerings on its Cotton University?platform...Cotton University^TM adds four new courses to the College of Nonwovens Cotton Incorporated,the research and promotion company for U.S.cotton producers and importers,expands offerings on its Cotton University?platform with four new courses in the College of Nonwovens section.Cotton University^TM is an online resource aimed at supporting today’s industry professionals,while nurturing the next generation through education and engagement.展开更多
Exploration of cost-effective electrocatalysts for boosting the overall water-splitting efficiency is vitally important for obtaining renewable fuels such as hydrogen.Here,earth-abundant CoxNi1-xO nanowire arrays were...Exploration of cost-effective electrocatalysts for boosting the overall water-splitting efficiency is vitally important for obtaining renewable fuels such as hydrogen.Here,earth-abundant CoxNi1-xO nanowire arrays were used as a structural framework to dilute Ir incorporation for fabricating electrocatalysts for water splitting.Minimal Ir-incorporated CoxNi1-xO nanowire arrays were synthesized through the facile hydrothermal method with subsequent calcination by using Ni foam(NF)as both the substrate and source of Ni.The electrocatalytic water-splitting performance was found to crucially depend on the Ir content of the parent CoxNi1-xO nanowire arrays.As a result,for a minimal Ir content,as low as 0.57 wt%,the obtained Ir-CoxNi1-xO/NF electrodes exhibited optimal catalytic activity in terms of a low overpotential of 260 mV for the oxygen evolution reaction and 53 mV for the hydrogen evolution reaction at 10 mA cm?2 in 1 mol L–1 KOH.When used as bifunctional electrodes in water splitting,the current density of 10 mA cm–2 was obtained at a low cell voltage of 1.55 V.Density functional theory calculations revealed that the Ir-doped CoxNi1-xO arrays exhibited enhanced electrical conductivity and low Gibbs free energy,which contributed to the improved electrocatalytic activity.The present study presents a new strategy for the development of transition metal oxide electrocatalysts with low levels of Ir incorporation for efficient water splitting.展开更多
Graphitic carbon nitride(g-C3N4)-based photocatalysts have shown great potential in the splitting of water.However,the intrinsic drawbacks of g-C3N4,such as low surface area,poor diffusion,and charge separation effici...Graphitic carbon nitride(g-C3N4)-based photocatalysts have shown great potential in the splitting of water.However,the intrinsic drawbacks of g-C3N4,such as low surface area,poor diffusion,and charge separation efficiency,remain as the bottleneck to achieve highly efficient hydrogen evolution.Here,a hollow oxygen-incorporated g-C3N4 nanosheet(OCN)with an improved surface area of 148.5 m2 g^−1 is fabricated by the multiple thermal treatments under the N2/O2 atmosphere,wherein the C–O bonds are formed through two ways of physical adsorption and doping.The physical characterization and theoretical calculation indicate that the O-adsorption can promote the generation of defects,leading to the formation of hollow morphology,while the O-doping results in reduced band gap of g-C3N4.The optimized OCN shows an excellent photocatalytic hydrogen evolution activity of 3519.6μmol g^−1 h^−1 for~20 h,which is over four times higher than that of g-C3N4(850.1μmol g^−1 h^−1)and outperforms most of the reported g-C3N4 catalysts.展开更多
In the present investigation, we fabricated strontium (Sr2+) incorporated CsPbI2Br-based inorganic perovskite solar cells in ambient conditions. The morphology, crystallinity, absorption, elemental composition and pho...In the present investigation, we fabricated strontium (Sr2+) incorporated CsPbI2Br-based inorganic perovskite solar cells in ambient conditions. The morphology, crystallinity, absorption, elemental composition and photoluminescence analysis of the bare CsPbI2Br and CsPb1-xSrxI2Br perovskite thin films were studied systematically to investigate the role of Sr2+ incorporation. It is observed that the surface morphology of the CsPbI2Br perovskite thin film has been improved by partial substitution of Pb2+ by Sr2+ which facilitates photoactive black phase-stabilization and defect passivation. The champion device having CsPb0.98Sr0.02I2Br composition exhibited a power conversion efficiency (PCE) of 16.61% which is much higher than the bare device (13.65%). Furthermore, our CsPb0.98Sr0.02I2Br-based devices maintain > 85% of its initial efficiency over 100 h in ambient conditions.展开更多
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(NRF-2021R1A2C2012855)
文摘In this study,wearable triboelectric nanogenerators comprising bar-printed polyvinylidene fluoride(PVDF)films incorporated with cobalt-based metal-organic framework(Co-MOF)were developed.The enhanced output performance of the TENGs was attributed to the phase transition of PVDF from a-crystals toβ-crystals,as facilitated by the incorporation of the MOF.The synthesis conditions,including metal ion,concentration,and particle size of the MOF,were optimized to increase open-circuit voltage(VOC)and open-circuit current(I_(SC))of PVDF-based TENGs.In addition to high operational stability,mechanical robustness,and long-term reliability,the developed TENG consisting of PVDF incorporated with Co-MOF(Co-MOF@PVDF)achieved a VOC of 194 V and an I_(SC)of 18.8μA.Furthermore,the feasibility of self-powered mobile electronics was demonstrated by integrating the developed wearable TENG with rectifier and control units to power a global positioning system(GPS)device.The local position of the user in real-time through GPS was displayed on a mobile interface,powered by the battery charged through friction-induced electricity generation.
文摘Using cetyl-trimethyl-ammonium bromide (CTMAB) as template and tetraethylortho-silicate (TEOS) as silica source, the MCM-41 mesoporous materials incorporated in framework by Y, Nd and Sm were synthesized by hydrothermal synthesis method. The structure, morphology of materials and the state of Y, Nd, Sm in materials were investigated by means of XRD, nitrogen adsorption-desorption, SEM, IR spectrometry, TG-DTA. The XRD results indicate that the samples possess the mesoporous MCM-41 structures with ordered hexagonal arrangements. Y, Nd and Sm ions can get into the framework of mesoporous materials. Nitrogen adsorption desorption isotherms show that the samples have typical mesopores characteristics. SEM micrographs reveal that incorporated sampies show a spherical morphology and the diameters are averagely 0. l0 to 0.15 μm. In IR spectrum of samples, there are the feature adsorption peaks about Si-O-Ln(Ln=Y, Sm, Nd)at 960-985 cm^-1, which affirm that Y, Nd, Sm ions locate in the framework of several mesoporous materials. Results from TG-DTA analysis suggest that two different template sorption sites exist in the framework of YMCM-41, SmMCM-41, NdMCM-41, which powerfully proves that the presence of Y, Nd and Sm in Si framework of the materials.
基金Supported by the National Natural Science Foundation of China under Grant No 10332020
文摘Carbonaceous nanomaterials such as carbon nanotubes (CNTs), magnetic metal nanomaterials and semicon- ductor nanomaterials are superior candidates for microwave absorbers. Taking full advantage of the features of CNTs, nanophase cobalt and nanophase zinc oxide, whose main microwave absorption mechanisms are based on resistance loss, magnetic loss and dielectric loss, we fabricate CNT/Co and CNT/ZnO heterostructure nanocom- posites, respectively. By using the CNTs, CNT/Co nanocomposites and CNT/ZnO nanocomposites as nanofillers, composites with polyester as matrix are prepared by in situ polymerization, and their microwave absorption per- formance is studied. It is indicated that the synergetic effects of the physic properties of different components in nano-heterostructures result in greatly enhanced microwave absorption performance in a wide frequency range. The absorption peak is increased, the absorption bandwidth is broadened, and the maximum peak shifts to a lower frequency.
文摘0 Introduction From a sociolinguistic perspective,competence in language use is determined not only by the ability to use language with grammatical accuracy,but also to use language appropriate to particular contexts.Thus,successful language learning requires language users to know the culture that underlies language.However,in foreign language teaching practice,culture teaching is often neglected,or introduced as no more than a supplementary diversion to language instruction.And the methods on how to teach the cultural knowledge is attached even less importance to.
文摘Using cetyl-trimethyl-ammonium bromide (CTMAB) as template agent and tetraethylorthosilicate (TEOS) as silica Source, the MCM-41 mesoporous materials were synthesized with Y, Nd and Sm incorporated in the framework under hydrothermal conditions. The structure and the micro-morphology of the materials and the state of Y, Nd and Sm were investigated through the analyses of XRD, nitrogen adsorption-desorption isotherm, SEM, IR and TG-DTA. The XRD resuits indicate that the synthetic samples are of typical structure of mesoporous MCM-41 with ordered hexagonal arrangements, and Y, Nd and Sm can be incorporated into the framework of these mesoporous materials. Nitrogen adsorption-desorption isotherms show that the samples possess the typical mesopores character. SEM micrographs reveal that the incorporated samples show a well-defined spherical morphology with the diameter ranging 0.10 - 0.15μm. The occurrence of two different template sorption sites in the framework as revealed by TG-DTA analysis further suggests the presence of Y, Nd and Sm in siliceous framework.
文摘Several gelatin-silicate composites, with or without incorporation of Ca2+ ions, were synthesized through sol-gel processing starting from gelatin and 3- (glycidoxypropyl) trimethoxysilane. The structure around the Si atoms was similar for all the samples. The measurement of viscoelastic properties indicated that the glass transition temperature and activation energy decreased with the incorporation of Ca2+ ions. The Ca2+ ion-containing composites were bioactive as they spontaneously deposited apatite when soaked in a simulated body fluid of the Kokubo recipe.
文摘The immobilization of SiW_(12)O_(40)^(4-)in poly(4-aminoazobenzene)film was done by electrochemical method.According to the continuous cyclic voltammograms of the modified electrode,it can be determined that SiW_(12)O_(40)^(4-) in the polymer is very stable.The paper reports the elecctrochemical pro- perties of the modified electrode,Moreover,it was found that the modified electrode exhibits electrocatalysis for the reaction of oxygen.
文摘Recent price movement Most benchmark prices decreased over the past month. Chinese prices moved sharply lower.Open interest has shifted from July and into the December contract. After moving lower in early May, values for the July contract were volatile but rangebound between 65 and 70 cents/lb for most of the past month. Values for the December contract also moved lower in early May. While they had been rangebound, December prices have been testing the lower end of their recent range, briefly dropping below 65 cents/lb in the latest trading.
文摘Recent price movement Benchmark prices were flat or slightly higherover the pastmonth. Prices for the May NY futures contract increased over past month,climbing from levels just below 70 cents/lb in mid-February to those near 74 cents/lb recently.
文摘September 25th-27th, 2019 - Cotton Incorporated (“CI”) promotes sustainability and innovation at the 2019 Shanghai Intertextile Apparel Fabrics Show at National Exhibition Center. With research and develop-ment efforts through the entire supply chain, Cotton In-corporated presents the cotton fiber’s sustainability and cotton products’ competitiveness in the market to Shanghai Intertextile.
文摘Daredevil·Gladiator·Cherry Red·Whirlwind·Flash·Grit·Spider Grass·MercuryWith less to lose,we take a risk,creating challenges and pushingourselves in ways we only fantasized about while living in the safezone.Self-tested,defying limits,we feel invigorated.Each stepwe take towards our wildest dreams brings us one step closer tothe edge.This dynamic palette merges bold and muted tones.Itschameleon nature applies from active to formal wear.
文摘Editor’s note:Cotton Incorporated has recently published its FW17/SS18 Denim Trend Forecast and 18/19 Active Trend Forecast respectively, which are presented here to share with our dear readers.FW17/SS18 Denim Trend Forecast Denim color shifts slightly away from all indigo to a more playful approach this season. Indigo remains essential but is shown in a less conventional way - being interspersed amongst four mini palettes.
文摘Cotton University^TM adds four new courses to the College of Nonwovens Cotton Incorporated,the research and promotion company for U.S.cotton producers and importers,expands offerings on its Cotton University?platform with four new courses in the College of Nonwovens section.Cotton University^TM is an online resource aimed at supporting today’s industry professionals,while nurturing the next generation through education and engagement.
基金financially supported by the National Natural Science Foundation of China (51772255)the Hunan Provincial Innovation Foundation For Postgraduate (CX2017B274)+1 种基金the National Basic Research Program of China (2015CB921103)the Program for Changjiang Scholars and Innovative Research Team in University (IRT13093)~~
文摘Exploration of cost-effective electrocatalysts for boosting the overall water-splitting efficiency is vitally important for obtaining renewable fuels such as hydrogen.Here,earth-abundant CoxNi1-xO nanowire arrays were used as a structural framework to dilute Ir incorporation for fabricating electrocatalysts for water splitting.Minimal Ir-incorporated CoxNi1-xO nanowire arrays were synthesized through the facile hydrothermal method with subsequent calcination by using Ni foam(NF)as both the substrate and source of Ni.The electrocatalytic water-splitting performance was found to crucially depend on the Ir content of the parent CoxNi1-xO nanowire arrays.As a result,for a minimal Ir content,as low as 0.57 wt%,the obtained Ir-CoxNi1-xO/NF electrodes exhibited optimal catalytic activity in terms of a low overpotential of 260 mV for the oxygen evolution reaction and 53 mV for the hydrogen evolution reaction at 10 mA cm?2 in 1 mol L–1 KOH.When used as bifunctional electrodes in water splitting,the current density of 10 mA cm–2 was obtained at a low cell voltage of 1.55 V.Density functional theory calculations revealed that the Ir-doped CoxNi1-xO arrays exhibited enhanced electrical conductivity and low Gibbs free energy,which contributed to the improved electrocatalytic activity.The present study presents a new strategy for the development of transition metal oxide electrocatalysts with low levels of Ir incorporation for efficient water splitting.
基金This work was supported by the National Science Foundation of China(51772152,51702129,51572114,51972150,21908110,and 51902161)Fundamental Research Funds for the Central Universities(30919011269,30919011110,and 1191030558)+3 种基金Y.W.thanks the Key University Science Research Project of Jiangsu province(16KJB430009)Y.Z.thanks for the support from the Postdoctoral Science Foundation(2018M630527)China Scholarship Council(201708320150)J.S.thanks the Natural Science Foundation of Jiangsu Province(BK20190479,1192261031693).
文摘Graphitic carbon nitride(g-C3N4)-based photocatalysts have shown great potential in the splitting of water.However,the intrinsic drawbacks of g-C3N4,such as low surface area,poor diffusion,and charge separation efficiency,remain as the bottleneck to achieve highly efficient hydrogen evolution.Here,a hollow oxygen-incorporated g-C3N4 nanosheet(OCN)with an improved surface area of 148.5 m2 g^−1 is fabricated by the multiple thermal treatments under the N2/O2 atmosphere,wherein the C–O bonds are formed through two ways of physical adsorption and doping.The physical characterization and theoretical calculation indicate that the O-adsorption can promote the generation of defects,leading to the formation of hollow morphology,while the O-doping results in reduced band gap of g-C3N4.The optimized OCN shows an excellent photocatalytic hydrogen evolution activity of 3519.6μmol g^−1 h^−1 for~20 h,which is over four times higher than that of g-C3N4(850.1μmol g^−1 h^−1)and outperforms most of the reported g-C3N4 catalysts.
基金This work was supported by Priority Research Centre Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education,Science,and Technology(NRF-2018R1A6A1A03024334)Also,this work was supported by Priority Research Centre Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education,Science,and Technology(2020R1A2C2004880).
文摘In the present investigation, we fabricated strontium (Sr2+) incorporated CsPbI2Br-based inorganic perovskite solar cells in ambient conditions. The morphology, crystallinity, absorption, elemental composition and photoluminescence analysis of the bare CsPbI2Br and CsPb1-xSrxI2Br perovskite thin films were studied systematically to investigate the role of Sr2+ incorporation. It is observed that the surface morphology of the CsPbI2Br perovskite thin film has been improved by partial substitution of Pb2+ by Sr2+ which facilitates photoactive black phase-stabilization and defect passivation. The champion device having CsPb0.98Sr0.02I2Br composition exhibited a power conversion efficiency (PCE) of 16.61% which is much higher than the bare device (13.65%). Furthermore, our CsPb0.98Sr0.02I2Br-based devices maintain > 85% of its initial efficiency over 100 h in ambient conditions.