As the characteristic pollutant, terephthalic acid(TA)was in charge of 40%—78% of the total COD of terylene artificial silk printing and dyeing wastewater(TPW-water). The studies on biodegradability of TA were conduc...As the characteristic pollutant, terephthalic acid(TA)was in charge of 40%—78% of the total COD of terylene artificial silk printing and dyeing wastewater(TPW-water). The studies on biodegradability of TA were conducted in a serial of activated sludge reactors with TPW-water. TA appeared to be readily biodegradable with removal efficiency over 96.5% under aerobic conditions, hardly biodegradable with removal efficiency below 10% under anoxic conditions and slowly biodegradable with a turnover between 31.4% and 56.0% under anaerobic conditions. TA also accounted for the majority of BOD in TPW-water. The process combined by anoxic, anaerobic and aerobic activated sludge reactor was suitable for TA degradation and TPW-water treatment. Further, the aerobic process was essentially much more effective than the anaerobic or anoxic one to degrade TA in TPW-water.展开更多
Terylene artificial silk printing and dyeing wastewater(TPD wastewater), containing averaged 710 mg/L terephthalic acid(TA) as the main carbon source and the character pollutant, was subjected to expanded granular slu...Terylene artificial silk printing and dyeing wastewater(TPD wastewater), containing averaged 710 mg/L terephthalic acid(TA) as the main carbon source and the character pollutant, was subjected to expanded granular sludge bed(EGSB) process. The stability of the EGSB process was firstly conducted by laboratory experiment. TA ionization was the predominated factor influencing the acid-base balance of the system. High concentration of TA in wastewater resulted in sufficient buffering capacity to neutralize the volatile fatty acids(VFA) generated from substrate degradation and provided strong base for anaerobic system to resist the pH decrease below 6.5. VFA and UFA caused almost no inhibition on the anaerobic process and biogas production except that pH was below 6.35 and VFA was at its maximum value. Along with the granulating of the activated sludge, the efficiency of organic removal and production rate of biogas increased gradually and became more stable. After start-up, the efficiency of COD removal increased to 57%—64%, pH stabilized in a range of 7.99—8.04, and production rate of biogas was relatively high and stable. Sludge granulating, suitable influent of pH and loading were responsible for the EGSB stability. The variation of VFA concentration only resulted in neglectable rebound of pH, and the inhibition from VFA could be ignored in EGSB. The EGSB reactor was stable for TPD wastewater treatment.展开更多
Printing and dyeing industry is a considerable source of environmental contamination. In this study treatment of printing and dyeing wastewater with a new type of sewage treatment agent, fly-ash coated with chitosan p...Printing and dyeing industry is a considerable source of environmental contamination. In this study treatment of printing and dyeing wastewater with a new type of sewage treatment agent, fly-ash coated with chitosan particles (FCCP), was examined. The effects ofpH, stirring time, sedimentation time and temperature on color, COD, turbidity and NH3-N removal were determined. The optimum dosage of FCCP and the influence of individual factors on removal efficiency were tested. The optimum parameters determined using the L16 (45) orthogonal experiment were as follows: FCCP (weight ratio of chitosan to fly-ash 1:6) dosage, 4 g.L^-1; temperature, 35℃; pH, 4. The stirring time and sedimentation time were 20 min and 5 h, respectively. Under these optimum conditions, the color, COD and NH3-N removal ratios were 97%, 80% and 75%, respectively.展开更多
In order to protect quality of Baiyangdian surface water and Gaoyang groundwater,the project is applied to process printing and dyeing wastewater that contains complicated compositions,high concentrations of organics ...In order to protect quality of Baiyangdian surface water and Gaoyang groundwater,the project is applied to process printing and dyeing wastewater that contains complicated compositions,high concentrations of organics and SS,and lots of pollutants difficult to degrade by microorganism. The process and operating parameters of project are optimized and debugged,and its economic and environmental benefits are analyzed.The results show that the process of coagulation sedimentation-hydrolytic acidification with aeration tank-biological aerated filter-active sand filter is applied in Gaoyang Sewage Treatment Plant. The design scale of sewage treatment plant is 120000 m^3/d. The influent is as following: COD is 669mg/L; SS is 424mg/L; NH_3-N is 8.83mg/L; TP is 6.03mg/L. After the process,the best removal rates of COD,SS,NH_3-N and TP are 93. 5%,98. 8%,97. 1% and 96. 2%,respectively. The various indexes of effluent water complied with standard A of the first order in Pollutants Emission Standard of Urban Wastewater Treatment Plant( GB 18918-2002). The processing cost is only 0. 807 yuan/m^3. As a result,the project construction and operation not only improve the environment,but also promote regional economic development. Process design and operating parameters provide an important reference value for the printing and dyeing wastewater treatment industry.展开更多
The problem of colority control of printing and dyeing wastewater has become a technical problem that plagues related companies.Bentonite is an adsorbent with excellent properties.Modification of bentonite with enviro...The problem of colority control of printing and dyeing wastewater has become a technical problem that plagues related companies.Bentonite is an adsorbent with excellent properties.Modification of bentonite with environmentally friendly substances can improve its decolorization performance.In this experiment,the simulated printing and dyeing wastewater was taken as the control object,and the bentonite was modified with environmentally friendly materials such as sodium carboxymethyl cellulose(CMC)and lignin to prepare a new modified bentonite;then the modified bentonite was used to adsorb the simulated wastewater to reduce the water colority and COD;finally the relevant design of the adsorption process was made.Results indicate that M lignin∶M CMC∶M original bentonite=1∶2∶97 had the optimum treatment effect,the optimum modification temperature was 30℃ and the modification time was 4 h;the optimum conditions for the adsorption process were:pH=5,temperature=30℃,reaction time=60 min,dosage=0.05 g of modified bentonite/mL simulated dye solution.The final removal rate of colority and COD reached 95.0% and 98.2%,respectively.Compared with the original bentonite,this new modified bentonite has greater adsorption capacity and thus has greater application value.展开更多
[ Object] The study aimed to discuss the decolorization on indigo dyeing wastewater by laccase from Coriolus versicolor. [ Method ] Firstly, the effects of temperature, pH, indigo concentration, HBT concentration, lac...[ Object] The study aimed to discuss the decolorization on indigo dyeing wastewater by laccase from Coriolus versicolor. [ Method ] Firstly, the effects of temperature, pH, indigo concentration, HBT concentration, laccase dosage on the decolorization of indigo dyeing wastewater by laccase/HBT, and then the synergism of laccase and acid cellulase was analyzed. [Result] Using ABTS as the substrate, the kinetic parame- ters, K,, and Vmax, were 0.318 mmol/L and 0.035 5 mmol/( L . min) respectively. The decolorization rate of indigo reached 96.5% when the lacca- se acted on indigo for 40 min with HBT as an introducer at temperature 50 ℃, pH =4.5, indigo concentration 100 mg/L, HBT concentration 0.1% and laccase dosage 100 lU/L. Due to the synergism of laccase and acid cellulase during the bio-finishing of blue jeans, the backstaining degree of blue jeans reduced by 85% when the amount of laccase added was 15 000 IU/kg. Menawhile, the synergism of the laccase and acid cellulase de- creased indigo concentration in wastewater by 83.8%. [ Conclusion ] The laccase from Coriolus versicolor had a good prospect in the bio-finishing of blue jeans and the decolorization of indigo dyeing wastewater.展开更多
Considering that Fe,Al elements in bauxite residue are active components for water purification,an effective polyaluminum ferric chloride(PAFC)coagulant derived from bauxite residue,with Fe2O3 content>5.1%,Al2O3%&g...Considering that Fe,Al elements in bauxite residue are active components for water purification,an effective polyaluminum ferric chloride(PAFC)coagulant derived from bauxite residue,with Fe2O3 content>5.1%,Al2O3%>6.5%,basicity>65%,was successfully prepared.The effect of as-prepared PAFC on the zeta potential for printing and dyeing wastewater was investigated.Comparing with polyferric chloride(PFC)and polyferric sulfate(PFS)for printing and dyeing wastewater treatment,prepared bauxite residue-based PAFC exhibited the optimal performance in the aspects of chromaticity and chemical oxygen demand(COD)removal rate.Furthermore,the combination of bauxite residue-based PAFC and PFS for synergy coagulation of such wastewater demonstrated an obvious positive effect.With the proportion between as-prepared PAFC and PFS to be 2.5:1,the COD of treated wastewater could be further reduced to meet the national level A standard of China,providing a promising route to solve the problem of substandard printing and dyeing sewage outfall by a simple coagulation strategy.展开更多
To remove effectively the pollutants from printing and dyeing wastewater, a new complex adsorption-coagulation agent was developed and employed in dyeing wastewater treatment. The experimental results showed that bett...To remove effectively the pollutants from printing and dyeing wastewater, a new complex adsorption-coagulation agent was developed and employed in dyeing wastewater treatment. The experimental results showed that better removals of COD, turbidity and color could be efficiently realized under the operating conditions of mixing at 150 r/min, reacting within 5 min and dosing at 15 g/L and 20 g/L, respectively. Combined with the settled sludge, the agent could be recycled for further adsorption and coagulation within 10 times. Compared to the conventional coagulants, the newly-developed agent had such merits as suitability for wide pH range of wastewater, less sludge production, reutilization of the condensed sludge and low operation cost.展开更多
The flocculating activity of a novel bioflocculant MMF1 produced by multiple-microorganism consortia MM1 was investigated. MM1 was composed of strain BAFRT4 identified as Staphylococcus sp. and strain CYGS1 identified...The flocculating activity of a novel bioflocculant MMF1 produced by multiple-microorganism consortia MM1 was investigated. MM1 was composed of strain BAFRT4 identified as Staphylococcus sp. and strain CYGS1 identified as Pseudomonas sp. The flocculating activity of MMF1 isolated from the screening medium was 82.9%, which is remarkably higher than that of the bioflocculant produced by either of the strains under the same condition. Brewery wastewater was also used as the carbon source for MM1, and the cost-effective production medium for MM1 mainly comprised 1.0 L brewery water (chemical oxygen demand (COD) 5000 mg/L), 0.5 g/L urea, 0.5 g/L yeast extract, and 0.2 g/L (NH4)2SO4. The optimal conditions for the production of MMF1 was inoculum size 2%, initial pH 6.0, cultivating temperature 30℃, and shaking speed 160 r/min, under which the flocculating activity of the MMF1 reached 96.8%. Fifteen grams of purified bioflocculant could be recovered from 1.0 L of fermentation broth. MMF1 was identified as a macromolecular substance containing both protein and polysaccharide. It showed good flocculating performance in treating indigotin printing and dyeing wastewater, and the maximal removal efficiencies of COD and chroma were 79.2% and 86.5%, respectively.展开更多
Experiments were conducted to study the role of micro-electrolysis in removing chromaticity and COD and improving the biodegradability of wastewater from pharmaceutical, dye-printing and papermaking plants. Results sh...Experiments were conducted to study the role of micro-electrolysis in removing chromaticity and COD and improving the biodegradability of wastewater from pharmaceutical, dye-printing and papermaking plants. Results showed that the use of micro-electrolysis technology could remove more than 90% of chromaticity and more than 50% of COD and greatly improved the biodegradability of pharmaceutical wastewater. Lower initial pH could be advantageous to the removal of chromaticity. A retention time of 30 minutes was recommended for the process design of micro-electrolysis. For the use of micro-electrolysis in treatment of dye-printing wastewater, the removal rates of both chromaticity and COD were increased from neutral condition to acid condition for disperse blue wastewater; more than 90% of chromaticity and more than 50% of COD could be removed in neutral condition for vital red wastewater.展开更多
Dyeing/printing wastewater contains substancesthat are not biodegradable or nearlynot,such as dyes,slurry,additives,oilfinishes,acids and bases,fiber impuritiesas well as inorganic salts.Domestic dyeing/printing enter...Dyeing/printing wastewater contains substancesthat are not biodegradable or nearlynot,such as dyes,slurry,additives,oilfinishes,acids and bases,fiber impuritiesas well as inorganic salts.Domestic dyeing/printing enterprises are located mostly inprovinces like Zhejiang,Jiangsu andGuangdong.Most of these enterprises treatwastewater inside their own plants,while展开更多
文摘As the characteristic pollutant, terephthalic acid(TA)was in charge of 40%—78% of the total COD of terylene artificial silk printing and dyeing wastewater(TPW-water). The studies on biodegradability of TA were conducted in a serial of activated sludge reactors with TPW-water. TA appeared to be readily biodegradable with removal efficiency over 96.5% under aerobic conditions, hardly biodegradable with removal efficiency below 10% under anoxic conditions and slowly biodegradable with a turnover between 31.4% and 56.0% under anaerobic conditions. TA also accounted for the majority of BOD in TPW-water. The process combined by anoxic, anaerobic and aerobic activated sludge reactor was suitable for TA degradation and TPW-water treatment. Further, the aerobic process was essentially much more effective than the anaerobic or anoxic one to degrade TA in TPW-water.
文摘Terylene artificial silk printing and dyeing wastewater(TPD wastewater), containing averaged 710 mg/L terephthalic acid(TA) as the main carbon source and the character pollutant, was subjected to expanded granular sludge bed(EGSB) process. The stability of the EGSB process was firstly conducted by laboratory experiment. TA ionization was the predominated factor influencing the acid-base balance of the system. High concentration of TA in wastewater resulted in sufficient buffering capacity to neutralize the volatile fatty acids(VFA) generated from substrate degradation and provided strong base for anaerobic system to resist the pH decrease below 6.5. VFA and UFA caused almost no inhibition on the anaerobic process and biogas production except that pH was below 6.35 and VFA was at its maximum value. Along with the granulating of the activated sludge, the efficiency of organic removal and production rate of biogas increased gradually and became more stable. After start-up, the efficiency of COD removal increased to 57%—64%, pH stabilized in a range of 7.99—8.04, and production rate of biogas was relatively high and stable. Sludge granulating, suitable influent of pH and loading were responsible for the EGSB stability. The variation of VFA concentration only resulted in neglectable rebound of pH, and the inhibition from VFA could be ignored in EGSB. The EGSB reactor was stable for TPD wastewater treatment.
基金Supported by the Science and Technology Development Foundation of Foshan (No.2005060071)
文摘Printing and dyeing industry is a considerable source of environmental contamination. In this study treatment of printing and dyeing wastewater with a new type of sewage treatment agent, fly-ash coated with chitosan particles (FCCP), was examined. The effects ofpH, stirring time, sedimentation time and temperature on color, COD, turbidity and NH3-N removal were determined. The optimum dosage of FCCP and the influence of individual factors on removal efficiency were tested. The optimum parameters determined using the L16 (45) orthogonal experiment were as follows: FCCP (weight ratio of chitosan to fly-ash 1:6) dosage, 4 g.L^-1; temperature, 35℃; pH, 4. The stirring time and sedimentation time were 20 min and 5 h, respectively. Under these optimum conditions, the color, COD and NH3-N removal ratios were 97%, 80% and 75%, respectively.
基金Supported by Key Project of National Water Pollution Control and Treatment Science and Technology(2014ZX07211-001)Demonstration Study on Integration Model of Environmental Public Utilities in Industrial Parks of Key Watershed(2014ZX07211-001-04)
文摘In order to protect quality of Baiyangdian surface water and Gaoyang groundwater,the project is applied to process printing and dyeing wastewater that contains complicated compositions,high concentrations of organics and SS,and lots of pollutants difficult to degrade by microorganism. The process and operating parameters of project are optimized and debugged,and its economic and environmental benefits are analyzed.The results show that the process of coagulation sedimentation-hydrolytic acidification with aeration tank-biological aerated filter-active sand filter is applied in Gaoyang Sewage Treatment Plant. The design scale of sewage treatment plant is 120000 m^3/d. The influent is as following: COD is 669mg/L; SS is 424mg/L; NH_3-N is 8.83mg/L; TP is 6.03mg/L. After the process,the best removal rates of COD,SS,NH_3-N and TP are 93. 5%,98. 8%,97. 1% and 96. 2%,respectively. The various indexes of effluent water complied with standard A of the first order in Pollutants Emission Standard of Urban Wastewater Treatment Plant( GB 18918-2002). The processing cost is only 0. 807 yuan/m^3. As a result,the project construction and operation not only improve the environment,but also promote regional economic development. Process design and operating parameters provide an important reference value for the printing and dyeing wastewater treatment industry.
基金Supported by Project of Shandong Province Natural Science Foundation of China(ZR2015PC022&BS2014HZ011)
文摘The problem of colority control of printing and dyeing wastewater has become a technical problem that plagues related companies.Bentonite is an adsorbent with excellent properties.Modification of bentonite with environmentally friendly substances can improve its decolorization performance.In this experiment,the simulated printing and dyeing wastewater was taken as the control object,and the bentonite was modified with environmentally friendly materials such as sodium carboxymethyl cellulose(CMC)and lignin to prepare a new modified bentonite;then the modified bentonite was used to adsorb the simulated wastewater to reduce the water colority and COD;finally the relevant design of the adsorption process was made.Results indicate that M lignin∶M CMC∶M original bentonite=1∶2∶97 had the optimum treatment effect,the optimum modification temperature was 30℃ and the modification time was 4 h;the optimum conditions for the adsorption process were:pH=5,temperature=30℃,reaction time=60 min,dosage=0.05 g of modified bentonite/mL simulated dye solution.The final removal rate of colority and COD reached 95.0% and 98.2%,respectively.Compared with the original bentonite,this new modified bentonite has greater adsorption capacity and thus has greater application value.
基金Supported by the Foundation for Young Scholars of Educational Commission of Jiangxi Province,China (Foundation)National Natural Science Foundation of China (51064011)
文摘[ Object] The study aimed to discuss the decolorization on indigo dyeing wastewater by laccase from Coriolus versicolor. [ Method ] Firstly, the effects of temperature, pH, indigo concentration, HBT concentration, laccase dosage on the decolorization of indigo dyeing wastewater by laccase/HBT, and then the synergism of laccase and acid cellulase was analyzed. [Result] Using ABTS as the substrate, the kinetic parame- ters, K,, and Vmax, were 0.318 mmol/L and 0.035 5 mmol/( L . min) respectively. The decolorization rate of indigo reached 96.5% when the lacca- se acted on indigo for 40 min with HBT as an introducer at temperature 50 ℃, pH =4.5, indigo concentration 100 mg/L, HBT concentration 0.1% and laccase dosage 100 lU/L. Due to the synergism of laccase and acid cellulase during the bio-finishing of blue jeans, the backstaining degree of blue jeans reduced by 85% when the amount of laccase added was 15 000 IU/kg. Menawhile, the synergism of the laccase and acid cellulase de- creased indigo concentration in wastewater by 83.8%. [ Conclusion ] The laccase from Coriolus versicolor had a good prospect in the bio-finishing of blue jeans and the decolorization of indigo dyeing wastewater.
基金Project(BE2015628)supported by Jiangsu Province Science and Technology Support Program,China
文摘Considering that Fe,Al elements in bauxite residue are active components for water purification,an effective polyaluminum ferric chloride(PAFC)coagulant derived from bauxite residue,with Fe2O3 content>5.1%,Al2O3%>6.5%,basicity>65%,was successfully prepared.The effect of as-prepared PAFC on the zeta potential for printing and dyeing wastewater was investigated.Comparing with polyferric chloride(PFC)and polyferric sulfate(PFS)for printing and dyeing wastewater treatment,prepared bauxite residue-based PAFC exhibited the optimal performance in the aspects of chromaticity and chemical oxygen demand(COD)removal rate.Furthermore,the combination of bauxite residue-based PAFC and PFS for synergy coagulation of such wastewater demonstrated an obvious positive effect.With the proportion between as-prepared PAFC and PFS to be 2.5:1,the COD of treated wastewater could be further reduced to meet the national level A standard of China,providing a promising route to solve the problem of substandard printing and dyeing sewage outfall by a simple coagulation strategy.
文摘To remove effectively the pollutants from printing and dyeing wastewater, a new complex adsorption-coagulation agent was developed and employed in dyeing wastewater treatment. The experimental results showed that better removals of COD, turbidity and color could be efficiently realized under the operating conditions of mixing at 150 r/min, reacting within 5 min and dosing at 15 g/L and 20 g/L, respectively. Combined with the settled sludge, the agent could be recycled for further adsorption and coagulation within 10 times. Compared to the conventional coagulants, the newly-developed agent had such merits as suitability for wide pH range of wastewater, less sludge production, reutilization of the condensed sludge and low operation cost.
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education(No.20050247016)the Program forNew Century Excellent Talents in University(NCET-05-0387).
文摘The flocculating activity of a novel bioflocculant MMF1 produced by multiple-microorganism consortia MM1 was investigated. MM1 was composed of strain BAFRT4 identified as Staphylococcus sp. and strain CYGS1 identified as Pseudomonas sp. The flocculating activity of MMF1 isolated from the screening medium was 82.9%, which is remarkably higher than that of the bioflocculant produced by either of the strains under the same condition. Brewery wastewater was also used as the carbon source for MM1, and the cost-effective production medium for MM1 mainly comprised 1.0 L brewery water (chemical oxygen demand (COD) 5000 mg/L), 0.5 g/L urea, 0.5 g/L yeast extract, and 0.2 g/L (NH4)2SO4. The optimal conditions for the production of MMF1 was inoculum size 2%, initial pH 6.0, cultivating temperature 30℃, and shaking speed 160 r/min, under which the flocculating activity of the MMF1 reached 96.8%. Fifteen grams of purified bioflocculant could be recovered from 1.0 L of fermentation broth. MMF1 was identified as a macromolecular substance containing both protein and polysaccharide. It showed good flocculating performance in treating indigotin printing and dyeing wastewater, and the maximal removal efficiencies of COD and chroma were 79.2% and 86.5%, respectively.
文摘Experiments were conducted to study the role of micro-electrolysis in removing chromaticity and COD and improving the biodegradability of wastewater from pharmaceutical, dye-printing and papermaking plants. Results showed that the use of micro-electrolysis technology could remove more than 90% of chromaticity and more than 50% of COD and greatly improved the biodegradability of pharmaceutical wastewater. Lower initial pH could be advantageous to the removal of chromaticity. A retention time of 30 minutes was recommended for the process design of micro-electrolysis. For the use of micro-electrolysis in treatment of dye-printing wastewater, the removal rates of both chromaticity and COD were increased from neutral condition to acid condition for disperse blue wastewater; more than 90% of chromaticity and more than 50% of COD could be removed in neutral condition for vital red wastewater.
文摘Dyeing/printing wastewater contains substancesthat are not biodegradable or nearlynot,such as dyes,slurry,additives,oilfinishes,acids and bases,fiber impuritiesas well as inorganic salts.Domestic dyeing/printing enterprises are located mostly inprovinces like Zhejiang,Jiangsu andGuangdong.Most of these enterprises treatwastewater inside their own plants,while