A New Approach of Studying Correlation between Outdoor Exposure and Indoor Accelerated Corrosion Test for High Polymer Materials

The correlation between outdoor exposure and indoor accelerated corrosion test for high polymer materials was investigated according to the variation of the functional group of exposure models aged. Environment aging intensities at different zones （ Wuhan and Lasa with the same latitude ） and the influences of indoor accelerating factors including water and ultraviolet on weathering performant.e of high polymer materials were also studied by comparing different indoor accelerated corrosion testing results. The experimental results show that ： by testing variations of carbonyl exponent of polythene （ which represented the degradation behavior of high polymer materials due to ultraviolet oxidation of douIole bond） and ultraviolet absorbance of polycarbonate （which represented the degradation behavior of high polymer materials due to abevacuation of branched chain ）, the degradation behavior of high polymer materials could be studied. Carbonyl exponent of polythene exposed in Wuhan and Lasa for 1 year was equal to that exposed in indoor cycle ultraviolet for 128 h anti 170 It, respectively, the ultraviolet absorbance of polycarbonate exposed in Wuhan for 1 year was equal to that exposed in indoor cycle ultraviolet for 240 h. The ratio of environment aging intensity of Lasa to Wuhan was around 1.2. With the prolongation of cycle accelerated ultraviolet exposure time, the variations of carbonyl exponent of polythene and the ultraviolet absorbance of polycarbonate were in the same shape of first order exponential decay curiae. Accompanied with ultraviolet, the effect of water condensated on the sample on weathering performance of polythene was more .significant than that of polycarbonate.

Correlation between indoor and outdoor corrosion tests for coal train body steel in a coal medium environment

Q345B carbon steel as well as Q450NQR1 and S500AW weathering steels were subjected to outdoor exposure corrosion tests in coal environments and indoor periodic immersion accelerated corrosion tests with a simulated coal leaching solution.The corrosion kinetics were studied by the weight loss method,and the corrosion morphology and corrosion product composition were observed and analyzed by scanning electron microscopy,energy-dispersive spectroscopy and X-ray diffraction.Afterward,correlation analysis of the indoor and outdoor tests was carried out by the gray correlation analysis method.The results show that the relationship between the corrosion weight loss and corrosion time of the three steels conforms to follow the exponent power law.In particular,Q450NQR1 steel has the best corrosion resistance.The types of corrosion products and the distribution of elements in the rust layer of the three steels are similar in the indoor and outdoor tests.The gray correlation degrees of the three steels in the indoor and outdoor tests are all greater than 0.6;thus,the two corrosion tests have a good correlation.Based on this,the accelerated simulation test method of the coal leaching solution is determined,and life prediction models of three steels in coal leaching solution are established to simulate the corrosion of the bottom board and side board.