Stress-induced deformation at A_p～M_p and thermal cycling behavior of Cu-Al-Ni single crystals

Stress induced deformation in A p～ M p and concomitant shape recovery behavior of Cu 13.4Al 4.0Ni single crystals were studied. Abnormal high stress induced deformation exists in A p～ M p under the conditions of either heating with load or cooling with load. The recovered deformation is successively composed of four parts, the recoveries from superelasticity, normal reverse transformation, thermally activated reverse transformation of partially stabilized martensite and reverse transformation of stabilized martensite by over heating. With increasing cycling number, the recovery part from normal reverse transformation decreases, while that from reverse transformation of stabilized martensite by over heating increases, which shows a typical stabilization of martensite.

Effect of V and V-N Microalloying on Deformation-Induced Ferrite Transformation in Low Carbon Steels

Deformation-induced ferrite transformation （DIFT） has been proved to be an effective approach to refine ferrite grains. This paper shows that the ferrite grains can further be refined through combination of DIFT and V or V-N microalloying. Vanadium dissolved in γ matrix restrains DIFT. During deformation, vanadium carbonitrides rapidly precipitate due to strain-induced precipitation, which causes decrease in vanadium dissolved in matrix and indirectly accelerates DIFT. Under heavy deformation, deformation induced ferrite （DIF） grains in V microalloyed steel were finer than those in V free steel. The more V added to steel, the finer DIF grains obtained. Moreover, the addition of N to V microalloyed steels can remarkably accelerate precipitation of V, and then promote DIFT. However, DIF grains in V-N microalloyed steel easily coarsen.

Electron Microscopy Analysis of Deformation Induced ε Martensite Transformation in an Fe-Mn-Si-Cr-Ni Alloy

The configurations of stacking faults and morphologies of strain induced ε martensite plates in an FeMnSiCrNi alloy were investigated through electron microscopy analysis. The Shockley partial dislocation structures. sensitive to external stress. determine the configurations of stacking faults in γphase Partial dislocations at the front sides of stacking faults are usetul for the nucleation of εmartensite plates. The growth of ε martensite plates is accompanied with the disappearance of local pre-existing stacking faults, The ε martensite vanants behave in three morphologies of respective stopping. continuous penetrating and intersections with the formation of secondary ε martensite plates

VISCOELASTIC BEHAVIOR OF THE NON-HOOKE DEFORMATION BEFORE YIELDING IN UNIAXIAL DRAWING OF AMORPHOUS POLY(ETHYLENE TEREPHTHALATE)

Viscoelastic behavior of the non-Hooke deformation of amorphous PET film before yield was investigated in the temperature region 74-80.5 degreesC around the glass transition temperature. The film specimen was drawn to yield point followed by unloading to zero stress, then the residual deformation was held constant; while the subsequent evolution of the stress was recorded. An induction period was found in the course of stress evolution followed by a stress step-increase. The induction period decreases with increasing drawing temperature with an activation energy of 1.10 MJ/mol.K, which is attributed to the time needed for the relaxation of rubbery deformation through cooperative internal rotations. At temperatures lower than 74 degreesC, there is no stress increase or the induction period becomes too long to be observed. Thus the nature of anelasticity in the non-Hooke region before yielding is attributed to stress induced rubbery deformation. The experimental results are interpreted in terms of Perez' theological model of a series connected Hooks spring and a Voigt element consisting of a parallel connected elastic spring and a dashpot.

Effect of Dissolved and Precipitated Niobium in Microalloyed Steel on Deformation Induced Ferrite Transformation(DIFT)

Hot deformation processing was designed to study the effects of niobium （Nb） on DIFT. A prestrain of 0.51 at 880 ℃ for different isothermal time was used for adjusting the deformed austenite constitution and Nb existing state, followed by a secondary heavy deformation at 780 ℃ for inducing the ferrite transformation. The volume fraction and grain size of deformation induced ferrite （DIF） obtained at different isothermal time between double hits were investigated. It was found that Nb dissolved in austenite is adverse to DIFT; however, the precipitation of Nb is beneficial to DIFT. As Nb plays the role in the conventional TMCP, Nb retards the recrystallization of deformed austenite and enhances the deformation stored energy in the multipass deformation, and in result, Nb promotes DIFT.

The precipitation behavior of MgZn_(2) and Mg_(4)Zn_(7) phase in Mg-6Zn(wt.%)alloy during equal-channel angular pressing

As-extruded Mg-6Zn(wt.%)Alloy was subjected to severe plastic deformation(SPD)by the equal-channel angular pressing(ECAP)at 160 ℃.The results of tensile tests at room temperature showed that two passes ECAP resulted in a remarkable improvement of strength,yield strength from 200 to 265 MPa and ultimate tensile strength from 260 to 340 MPa.However,with the deformation increasing,the samples processed by ECAP for four or six passes had insignificant difference than that processed by two-pass ECAP.Massive precipitates were observed in all the Mg-6Zn alloys specimens processed by ECAP.Transmission electron microscope and X-ray diffraction results indicated that ECAP treatment induced the precipitation of laves MgZn_(2) phase and transition Mg_(4)Zn_(7) phase.The spherical MgZn_(2) particles and irregular shape Mg_(4)Zn_(7) particles coexist in the microstructure of Mg-6Zn alloy after six pass ECAP.

Study on temper embrittlement control technique in steel 12Cr1MoV

Failure may occur catastrophically by fracture along grain boundaries when temper embrittlement induced by non-equilibrium grain-boundary segregation (NGS) of phosphorus atoms. Temper embrittlement control technigue based on the theory of NGS and deformation induced phase transformation method was studied in this paper. Grain refinement technique by deformation induced phase transformation in low-alloy steel,12Cr1MoV( which is used in steam pipeline of ships),was experimentally investigated. A single-pass hot rolling process by using a Gleeble-1500 system was performed and the experimental results showed that the grain sizes were obviously affected by the deforming temperature,strain,strain rate and the quenching cooling rate. Temper embrittlement may be controlled and obviously improved by grain refinement.

An ultrahigh strength steel produced through deformation-induced ferrite transformation and Q&P process

In this work,DIFT technology and Q&P process were combined in order to introduce ultrafine-grained ferrite into the matrix of martensite and retained austenite to develop a new kind of advanced high strength steel,and two kinds of steels were investigated by this novel combined process.The newly designed process resulted in a sophisticated microstructure of a large amount of ferrite(about 5 m in diameter),martensite and a considerable amount of retained austenite for TRIP 780 steel.The ultimate tensile strength can reach about 1200 MPa with elongation above 16% for TRIP 780,that is much higher than the one solely treated by Q&P process.Tensile tests showed that both steels with the novel combined process achieved a good combination of strength and ductility,indicating that the new process is promising for the new generation of advanced high strength steels.

Computer Simulation of Ferrite Transformation during Hot Working of Low Carbon Steel

On the basis of transformation kinetics and thermodynamics, the austenite-ferrite transformation start temperature during deformation was predicted for several grades of low-carbon steels under different processing conditions. Results indicate that Ar3d temperature mostly depended on alloying composition and processing parameters. Ar3d increased as strain rate or strain increased for the same steel grade. In view of enhancement of deformation on transformation, the basic kinetics model was established to simulate deformation induced transformation behavior, using which the influence of the deformation stored energy and effective deformation ledge on the nucleation and growth can be considered. The simulated results are in good agreement with experiment results.

High Temperature Ductility Loss of 16MnCr5 Pinion Steels

A wide ductility trough covering from 700 to 1100 is observed in the curve of Reduction of Area (RA) vs.tempetature for 16MnCr5 pinion steel. At 750℃, corresponding to the minimum of RA, it is grain boundary slidingthat controls its hot ductility rather than usual Deforming Induced Ferrite (DIF), which can only appear just below750℃ and slightly improve hot ductility. The volume fraction of ferrite is dependent on the strain and strain rate.Firstly a critical strain must be necessary for formation of DIF then with strain rate increasing, the volume fractionof DIF decreases but RA is elevated. In the γ phase region, hot ductility is seriously deteriorated because of grainboundary sliding promoted by oxidcs and sulfides at the grain boundary and recovered because of dynamic recrystal-lization at higher temperature; when strain rate increases, ductility is improved as there is insufficient time for cracksto propagate along the γ grain boundary as well as dynamically precipitating, and ductility trough becomes narrowerbecause the temperature for onset of dynamic recrystallization decreases. In addition, γ→α phase transformationintroduced by temperature drop before the tensile test encourages precipitation of AlN and impairs ductility.

Phase stability in an austenitic Fe-Cr-Mn (W,V) alloy

By means of deformation and long term aging, the stability and phaseequilibrim characteristic of the C + N synthetically strengthening austenitic Fe-Cr-Mn (W, V) alloywere investigated. Experimental results indicate that he austenitic alloy remains stability and nogamma - > alpha transformation occurs under 500 deg C. Synthetic addition of C and N cause thegrains to refine and powerfully retards formation of epsilon martensite and precipitation of sigmaphase. M_s point is elevated with long term aging at elevated temperature (500-700 deg C) due to alarge number of strain induced carbides precipitate. Along with accelerated decomposition of straininduced alpha' martensite and occurrence of recrystallization gamma - > alpha transformation andsigma phase precipitation are promoted s that austenite becomes unstable.

Hetero-deformation promoted strengthening and toughening in BCC rich eutectic and near eutectic high entropy alloys

Heterostructured eutectic high-entropy alloys(EHEAs)have attracted significant attention owing to their novel properties,such as balanced combinations of strength and fracture toughness.However,the toughening/strengthening mechanisms of these EHEAs have not been thoroughly investigated.In this study,we developed a series of dual-phase Al_((18–2x))Co_(30)Cr_((11+x))Fe_((11+x))Ni_(3)0(x=-1,0,1)eutectic and neareutectic HEAs containing face-centered cubic(FCC)and body-centered cubic(BCC)phases.Despite the high amount of BCC,which is referred to as the brittle phase,newly developed EHEAs exhibited superior fracture toughness.Interestingly,we discovered that a fully eutectic HEA exhibited further improvements in both yield stress and fracture toughness,outperforming our off-eutectic and other previously reported HEAs.By combining experiments and theoretical models,we demonstrated that the synergistic increase in both strength and toughness in our fully eutectic HEA was derived from the high hetero-deformationinduced(HDI)strengthening/toughening associated with a high misorientation angle at the grain/phase boundaries.

The concept and realization of nanostructure fabrication using free-standing metallic wires with rapid thermal annealing

Free-standing metallic nanostructures are considered to be highly relevant to many branches of science and technology with applications of three dimensional metallic nanostructures ranging from optical reflectors,actuators,and antenna,to free-standing electrodes,mechanical,optical,and electrical resonators and sensors.Strain-induced out-of-plane fabrication has emerged as an effective method which uses relaxation of strain-mismatched materials.In this work,we report a study of the thermal annealing-induced shape modification of free-standing nanostructures,which was achieved by introducing compositional or microstructural nonuniformity to the nanowires.In particular gradient,segmented and striped hetero-nanowires were grown by focused-ion-beam-induced chemical vapor deposition,followed by rapid thermal annealing in a N2 atmosphere.Various free-standing nanostructures were produced as a result of the crystalline/grain growth and stress relief.

Repetitive Thermomechanical Processing towards Ultra Fine Grain Structure in 301,304 and 304L Stainless Steels

Thermomechanical processing as a combination of cold rolling and annealing was performed on austenitic stainless steels 301,304 and 304L. Two cold rolling steps each one up to a reduction of 75% were combined with an intermediate annealing at 800℃ for 20 min. The final annealing was performed at.the same temperature and time. Cold rolling contributed to martensite formation at the expense of metastable austenite in the studied materials. Austenite in 301 was found to be less stable than that in 304 and 304L. Hence, higher strength characteristics in the as-quenched 301 stainless steels were attributed to the higher volume fraction of martensite. Both α′-martensite and ε-martensite were found to form as induced by deformation. However, the intensity of ε-martensite increased as the stability of austenite decreased. Annealing after cold rolling led to the reversion of austenite with an ultra fine grained structure in the order of 0.5-1 μm from the strain induced martensite. The final grain size was found to be an inverse function of the amount of strain induced martensite. The thermomechanical processing considerably improved the strength characteristics while the simultaneous decrease of elongation was rather low.