Waste heat recovery from hot steel slag on the production line:Numerical simulation,validation and industrial test

Waste heat recovery from hot steel slag was determined in a granular bed through the combination of numerical simulation and an industrial test method.First,the effective thermal conductivity of the granular bed was calculated.Then,the unsteady-state model was used to simulate the heat recovery under three different flow fields(O-type,S-type,and nonshielding type(Nontype)).Second,the simulation results were validated by in-situ industrial experiments.The two methods confirmed that the heat recovery efficiencies of the flow fields from high to low followed the order of Nontype,S-type,and O-type.Finally,heat recovery was carried out under the Nontype flow field in an industrial test.The heat recovery efficiency increased from~76%and~78%to~81%when the steel slag thickness decreased from 400 and 300 to 200 mm,corresponding to reductions in the steel slag mass from 3.96 and 2.97 to 1.98 t with a blower air volume of 14687 m^(3)/h.Therefore,the research results showed that numerical simulation can not only guide experiments on waste heat recovery but also optimize the flow field.Most importantly,the method proposed in this paper has achieved higher waste heat recovery from hot steel slag in industrial scale.

Significant Breakthrough in Industrial Test of the "Methanol to Olefins" Process Developed by Dalian Institute of Chemical Physics,Chinese Academy of Sciences

A process of ＂Methanol or Dimethylether to Olefins＂ developed by Dalian Institute of Chemical Physics （DICP）, designated as the DMTO process, has attained great success in industrial scaling up testing. DICP, by collaborating with the Xinxing Coal Chemical Co., Ltd. of Shaanxi Province and the Luoyang Petrochemical Engineering Co. of the SINOPEC Group, operated successfully a 50t（methanol）/d unit for the conversion of methanol to lower olefins, with a methanol conversion of close to 100%, and a selectivity to lower olefins（ethylene, propylene and butylenes） of higher than 90%. On 23rd August, the industrial test project has passed a state appraisal. The experts of the Appraisal Group, headed by Prof. YUAN Qingtang, academician of Chinese Academy of Engineering, drew the conclusions that the DMTO process, by utilizing a proprietary SAPO-34 catalyst system and a recycling fluidized bed reaction system for the production of lower olefins from methanol, is the first unit in the world having a capacity of producing nearly ten thousand tons lower olefins per year. The technological level of the industrial test is at a leading position internationally. This accomplishment will provide a sound base for the subsequent commercialization of the DMTO process.

Performance and Industrial Application of New-Type Sulfur Tolerant CO Shift Catalyst QDB-04

This paper presents the performance and characteristics of new-type sulfur tolerant shift catalyst QDB-04 and its industrial side-line test as well as the first-time industrial application in Lunan Chemical Fertilizer Plant of Shandong in China. The results show that the catalyst has high strength and strength stability, good low temperature activity and stability as well as low potassium bleeding ratio which well meet for the requirements of the methanol plant on catalyst performance in Lunan Chemical Fertilizer Plant.

Cemented backfilling technology with unclassified tailings based on vertical sand silo

A new technology characterized by rapidly non-mechanical settlement of unclassified tailings was developed based on a large number of tests, and dynamic settlement and continual slurry preparation without hardening in vertical sand silo were eventually realized by the addition of an effective flocculating agent (NPA). The results show that the sedimentation velocity of interface between unclassified tailings and water after the addition of NPA increases by 10-20 times, the sedimentation mass fraction of unclassified tailings at the bottom of vertical sand silo is up to 64%, the solid particle content of waste water meets the national standard, and the side influences of NPA can be removed by the addition of fly ash. The industrial test result shows that the system, the addition manner and the equipments are rational, and the vertical sand silo is used efficiently. This developed system is simple with large throughput, and the processing cost is 2.2 yuan(RMB)/m3, only 10%-20% of that by mechanical settlement.

An Innovative Non-Pillar Coal-Mining Technology with Automatically Formed Entry: A Case Study

A non-pillar coal-mining technology with an automatically formed entry is proposed,which reduces the waste of coal resources and the underground entry drivage workload.Three key techniques in this technology cooperate to achieve automatic formation and retaining of the gob-side entry,and to realize nonpillar mining.Constant-resistance large deformation(CRLD)support ensures the stability of the entry roof;directional presplitting blasting(DPB)separates the entry roof and the gob roof;and a blockinggangue support system(BGSS)integrates the caved rock material as an effective entry rib.An industrial test was conducted to verify the engineering effects of these key techniques.The field application results showed that the retained entry was under the pressure-relief zone due to the broken-expansion nature of the caved rock mass within the DPB height.After going through a provisional dynamic pressure-bearing zone,the retained entry entered the stability zone.The final stable entry meets the requirements of safety and production.The research results demonstrate the good engineering applicability of this technology.By taking the framework of the technology design principles into consideration and adjusting the measures according to different site conditions,it is expected that the proposed non-pillar coal-mining technology can be popularized on a large scale.

Ministries Design Exchange Rate Stress Test for Labor-Intensive Industries

China’s Ministry of Commerce(MOFCOM)and the Ministry of Industry and Information Technology(MIIT)have designed a stress-test for China’s labor-intensive industries,

CHARACTERIZATION OF POWDER FLOWABILITY USING MEASUREMENT OF ANGLE OF REPOSE

In response to the need in industry for a quick and reproducible method of measuring the flowability of powders in processes involving transport and storage, the apparently simple idea of measuring angle of repose has been revived. The simple tester first used has evolved over a number of years into the present version which is shown to be capable of handling quite small samples of powders that are even slightly cohesive. Experimental data are presented and results shown to compare consistently with the better known Hausner ratio.

Establishment of Optimal Blade Clearance of Stainless Steel Rolling-Cut Shear and Test of Shearing Force Parameters

The purpose aims to improve the plate shearing section quality and metal yield by means of optimal blade clearance adjustment model of rolling-cut shear and accurate calculation of the maximum shearing force , as well as for the system optimization design , structure optimization design to provide important basis.A 3 500mm rolling shear of a large stainless steel factory was taken as the test object , and the blade clearance under different influence factors of the clearance value and the shearing section were tested.The optimized production accumulated data regression analysis and the rolling shear process of stainless steel shear test.The test results show that the optimal blade clearance adjustment module is a comprehensive function , which include steel plate thickness , material , temperature and shear plate volume.The shear stress at starting stage with the relative penetration depth increases affected by the above factors , and the fracture peak decreases rapidly after being cut into the roll phase constant.

Novel method for improving iron recovery from electric arc furnace slag: on-site hot modification

The iron element in electric arc furnace(EAF)slag is extremely difficult to recycle due to the low specific magnetic susceptibility of the RO phase(a solid solution of FeO,MgO,CaO,and MnO).Landfilling EAF slag is strictly forbidden for environmental consideration because of poisonous Cr^(6+) leaching.The original RO phase could be transformed to a spinel structure,whose specific magnetic susceptibility is much higher than that of other minerals,through hot modification,resulting in significantly increased iron recovery by magnetic separation.Precipitation of spinel crystals encloses chromium,such that iron and chromium could be recovered simultaneously.The chromium in obtained iron concentrates is considerably useful for stainless steel making rather than polluting the environment.As a result,recovering iron and chromium is truly beneficial for cleaner production.Hot modification of EAF slag should be conducted at 1500-1600ºC for at least 60 min to guarantee homogeneous liquid slag.The liquid slag was poured onto an iron mold to obtain modified slag(MS)through air quenching.MS was characterized by thermodynamic analysis,X-ray diffraction,and scanning electron microscopy combined with energy-dispersive spectroscopy to correlate the relationship between mineral structures and iron recovery.The iron recovery rate of MS first increased and then decreased with increasing modifier.It was less than 10%when the modifier addition amount was below 12 wt.%,but it increased rapidly as the modifier addition amount increased from 16 to 24 wt.%,mainly due to spinel formation.The highest iron recovery rate was 81.9%when the modifier amount reached 20 wt.%.Meanwhile,Cr^(6+) was enriched in the spinel phase but was not observed in other minerals.Industrial tests were performed on-site with the modifier ranging from 12 to 18 wt.%because additional heat was not provided during the tests.Results showed that MS with 18 wt.%modifier addition exhibited an iron recovery rate of 61.0%,much higher than that(34.6%)of the original slag.

Temperature Distribution of Iron Ore Pellet Bed in Grate

The temperature distribution of iron ore pellet bed in grate has a significant effect on pellet production and quality control, but the related work is scarce. A well-designed test was successfully carried out by means of tracking measurement and the temperature distribution and variation in pellet layers were obtained. The effects of blast tem- perature, blast velocity and oxidation reaction on the pellet layer temperature were studied. According to the analy- sis, the inlet air temperature in the up-draught drying zone （UDD） and blast temperature in the Preheating I （PH I） zone should be raised, and the length of the down-draught drying zone （DDD） should be properly increased.