Inspired by the demand of improving the riding comfort and meeting the lightweight design of the vehicle, an inerter-based X-structure nonlinear energy sink(IXNES) is proposed and applied in the half-vehicle system to...Inspired by the demand of improving the riding comfort and meeting the lightweight design of the vehicle, an inerter-based X-structure nonlinear energy sink(IXNES) is proposed and applied in the half-vehicle system to enhance the dynamic performance. The X-structure is used as a mechanism to realize the nonlinear stiffness characteristic of the NES, which can realize the flexibility, adjustability, high efficiency, and easy operation of nonlinear stiffness, and is convenient to apply in the vehicle suspension, and the inerter is applied to replacing the mass of the NES based on the mass amplification characteristic. The dynamic model of the half-vehicle system coupled with the IX-NES is established with the Lagrange theory, and the harmonic balance method(HBM) and the pseudo-arc-length method(PALM) are used to obtain the dynamic response under road harmonic excitation. The corresponding dynamic performance under road harmonic and random excitation is evaluated by six performance indices, and compared with that of the original half-vehicle system to show the benefits of the IX-NES. Furthermore, the structural parameters of the IX-NES are optimized with the genetic algorithm. The results show that for road harmonic and random excitation, using the IX-NES can greatly reduce the resonance peaks and root mean square(RMS) values of the front and rear suspension deflections and the front and rear dynamic tire loads, while the resonance peaks and RMS values of the vehicle body vertical and pitching accelerations are slightly larger.When the structural parameters of the IX-NES are optimized, the vehicle body vertical and pitching accelerations of the half-vehicle system could reduce by 2.41% and 1.16%,respectively, and the other dynamic performance indices are within the reasonable ranges.Thus, the IX-NES combines the advantages of the inerter, X-structure, and NES, which improves the dynamic performance of the half-vehicle system and provides an effective option for vibration attenuation in the vehicle engineering.展开更多
In order to improve the seismic performance of adjacent buildings,two types of tuned inerter damper(TID)damping systems for adjacent buildings are proposed,which are composed of springs,inerter devices and dampers in ...In order to improve the seismic performance of adjacent buildings,two types of tuned inerter damper(TID)damping systems for adjacent buildings are proposed,which are composed of springs,inerter devices and dampers in serial or in parallel.The dynamic equations of TID adjacent building damping systems were derived,and the H2 norm criterion was used to optimize and adjust them,so that the system had the optimum damping performance under white noise random excitation.Taking TID frequency ratio and damping ratio as optimization parameters,the optimum analytical solutions of the displacement frequency response of the undamped structure under white noise excitation were obtained.The results showed that compared with the classic TMD,TID could obtain a better damping effect in the adjacent buildings.Comparing the TIDs composed of serial or parallel,it was found that the parallel TIDs had more significant advantages in controlling the peak displacement frequency response,while the H2 norm of the displacement frequency response of the damping system under the coupling of serial TID was smaller.Taking the adjacent building composed of two ten-story frame structures as an example,the displacement and energy collection time history analysis of the adjacent building coupled with the optimum design parameter TIDs were carried out.It was found that TID had a better damping effect in the full-time range compared with the classic TMD.This paper also studied the potential power of TID in adjacent buildings,which can be converted into available power resources during earthquakes.展开更多
17(Cu-10Ni)-(NiFe2O4-10NiO) cermets were prepared by cold pressing and sintering in nitrogen atmosphere, and tested as inert anode for aluminum electrolysis at 960 °C for 10 and 40 h, respectively. Microstruc...17(Cu-10Ni)-(NiFe2O4-10NiO) cermets were prepared by cold pressing and sintering in nitrogen atmosphere, and tested as inert anode for aluminum electrolysis at 960 °C for 10 and 40 h, respectively. Microstructures and phase compositions of the as-sintered and post-electrolyzed samples were investigated. The impurity contents in the electrolyte and the cathode metal were detected in order to investigate the corrosion characteristic of the elements of Fe, Ni and Cu in the anode. A dense NiFe2O4 layer was observed on the surface of anode and thickened with prolonging the electrolysis time. In the newly formed dense ceramic layer, NiO phase disappeared as a result of being swallowed by NiFe2O4 phase, and the metal phase was oxidized during the electrolysis in which Cu element showed a higher dissolution rate than Fe and Ni elements. The formation process of the dense ceramic layer during the electrolysis was presented and explained by using the corrosion mode of the metal phase and the transformation mechanism from NiO phase to NiFe2O4 phase.展开更多
xCu/(10NiO-NiFe2O4) cermet and 1BaO-xCu/(10NiO-NiFe2O4) cermet(x=5,10,17) inert anodes were prepared as potential inert anodes for aluminum electrolysis and their corrosion resistance to traditional electrolyte ...xCu/(10NiO-NiFe2O4) cermet and 1BaO-xCu/(10NiO-NiFe2O4) cermet(x=5,10,17) inert anodes were prepared as potential inert anodes for aluminum electrolysis and their corrosion resistance to traditional electrolyte was studied with anodic current density of 1.0 A/cm2 in laboratory electrolysis.The substantial corrosion of metal Cu was observed,many pores appeared on the surface of anode and electrolytes infiltrated inside anodes during the electrolysis.The wear rates of 5Cu/(10NiO-NiFe2O4),10Cu/(10NiO-NiFe2O4),17Cu/(10NiO-NiFe2O4),1BaO-5Cu/(10NiO-NiFe2O4),1BaO-10Cu/(10NiO-NiFe2O4) and 1BaO-17Cu/(10NiO-NiFe2O4) are 2.15,6.50,8.30,4.88,4.70 and 4.48 cm/a,respectively.The addition of BaO to 10Cu/(10NiO-NiFe2O4) cermet and 17Cu/(10NiO-NiFe2O4) cermet is advantageous because BaO can effectively promote densification and thus improve corrosion resistance.But the addition of BaO to 5Cu/(10NiO-NiFe2O4) cermet is unfavorable to corrosion resistance because additive BaO at the grain boundary of anode accelerates possibly the corrosion of cermet.展开更多
A comparative study on the corrosion resistance of 17Ni/(NiFe2O4-10NiO) cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rate...A comparative study on the corrosion resistance of 17Ni/(NiFe2O4-10NiO) cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rates of NiFe2O4-based cermetanodes prepared in the vacuum and the atmosphere with oxygen content of 2×10^-3 (volume fraction) are 6.46 and 2.71 cm/a,respectively. Though there is a transition layer with lots of holes or pores, a densified layer is formed on the surface of anode due tosome reactions producing aluminates. For the anode prepared in the atmosphere with oxygen content of 2×10^-3, the thickness of thedensification layer (about 50 μm) is thicker than that (about 30 μm) formed on the surface of anode prepared in the vacuum. Thecontents of NiO and Fe(II) in NiFe2xO4-y-z increase with the decrease of oxygen content in sintering atmosphere, which reduces thecorrosion resistance of the material.展开更多
NiFe2O4-10NiO-based cermet inert anodes for aluminium electrolysis were prepared and their properties were investigated in a lab-scale electrolysis cell. The results show that the inert anodes exhibit good performance...NiFe2O4-10NiO-based cermet inert anodes for aluminium electrolysis were prepared and their properties were investigated in a lab-scale electrolysis cell. The results show that the inert anodes exhibit good performance during electrolysis in molten salt cryolite at 960 °C, but according to the analyses of phase compositions and microstructures through XRD, SEM/EDX and metallographic analysis, the metal in the anodes is preferentially corroded and many pores are produced on the anode surface after electrolysis. The preferential dissolution of Fe in the NiFe2O4 phase may lead to the non-uniform corrosion of NiFe2O4 grains. Moreover, a dense protective layer of NiFe2O4-NiAl2O4-FeAl2O4 is formed on the anode surface, which originates from the reaction of Al2O3 dissolved in the electrolyte with NiO or FeO, the annexation of NiFe2O4-NiAl2O4-FeAl2O4 to NiO and volume expansion. Thus, the dense NiFe2O4-NiAl2O4-FeAl2O4 layer inhibits the metal loss and ceramic-phase corrosion on the surface of the cermet inert anodes.展开更多
In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI(polyaniline)-WC(tungsten carbide) composite inert anodes were prepared on aluminum alloy substrate by...In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI(polyaniline)-WC(tungsten carbide) composite inert anodes were prepared on aluminum alloy substrate by double pulse electrodeposition(DPE) of PANI and WC particles with Pb2+ from an original plating bath.Thereafter,anodic polarization curves,cyclic voltammetry curves and Tafel polarization curves for the composite inert anodes obtained under different PANI concentrations in the original plating bath were measured,and the microstructural features were also investigated by scanning electron microscopy(SEM).The results show that Al/Pb-PANI-WC composite inert anode obtained under PANI concentration of 20 g/L in the original plating bath possesses uniform microstructures and composition distributions,higher electrocatalytic activity,better reversibility of electrode reaction and corrosion resistance in a synthetic zinc electrowinning electrolyte of 50 g/L Zn2+,150 g/L H2SO4 at 35 °C.Compared with Pb-1%Ag alloy,the overpotential of oxygen evolutions for the composite inert anode are decreased by 185 mV and 166 mV,respectively,under 500 A/m2 and 1000 A/m2.展开更多
LiFePO4/C was synthesized by high temperature solid-state method with cheap Fe2O3, LiH2PO4 and glucose as raw materials in absence of inert gas. The sample had ordered olivine-type structure other impurities character...LiFePO4/C was synthesized by high temperature solid-state method with cheap Fe2O3, LiH2PO4 and glucose as raw materials in absence of inert gas. The sample had ordered olivine-type structure other impurities characterized by the test of X-ray diffraction (XRD). The charge-discharge test showed the sample could demonstrate 120.5 mAh/g at 0.2C rate with good cyclic capability. The powder microeleetrode cyclic voltammetry test indicated that the redox process of the sample had good reversibility.展开更多
(Cu-Ni)/(10NiO-90NiFe204) cermet inert anodes containing metal Cu-Ni0, 5, 10, 15 and 20 wt pct were prepared and their corrosion resistance to Na3AlF6-Al2O3 melts was investigated. The results indicate that the co...(Cu-Ni)/(10NiO-90NiFe204) cermet inert anodes containing metal Cu-Ni0, 5, 10, 15 and 20 wt pct were prepared and their corrosion resistance to Na3AlF6-Al2O3 melts was investigated. The results indicate that the content of metal Cu-Ni has little effect on the steady-state concentration of Ni in the electrolyte and the values could not be used to effectively differentiate their corrosion resistance. The steady-state concentration of Fe decreases from 304×10^-6 to 168×10^-6 and that of Cu increases from 21×10^-6 to 71×10^-6 with the content of metal Cu-Ni increasing from 0 to 20 wt pct. Post-examination shows that metallic phase Cu-Ni is corroded preferentially during electrolysis and many pores are left at the anode surface. Considering the corrosion resistance and electrical conductivity, the cermet containing metal Cu-Ni 5 wt pct should be selected and studied further.展开更多
Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working co...Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working condition of an inert anode. To reduce its thermal stress, the effect of some parameters on the thermal stress distribution was investigated, including the anode height, the anode radius, the hole depth, the hole radius, and the radius of inner chamfer and outer chamfer. The results showed that in the actual working condition of an inert anode, there existed a large axial tensile stress near the tangent interface between the anode and bath, which was the major cause of anode breaking. Increasing the anode height and reducing the hole depth properly seemed to be beneficial for the stress distribution. With the increase of anode radius, the stress distribution became better first and then deteriorated, the reasonable value was between 0.045 to 0.06m. The hole radius had a significant effect on the stress and a smaller radius would reduce the thermal stress. The effect of the radius of the inner chamfer and the outer chamfer was less than other parameters.展开更多
The thermal stresses relaxation of Ni/NiFe2O4 system functionally graded cermet inert anode for aluminum electrolysis was optimally designed. The transient thermal stresses of the inert anode under complex boundary co...The thermal stresses relaxation of Ni/NiFe2O4 system functionally graded cermet inert anode for aluminum electrolysis was optimally designed. The transient thermal stresses of the inert anode under complex boundary condition during high-temp (955℃) electrolysis were calculated using the finite-element software ANSYS, the influence of different parameters on the distribution of the thermal stresses were analyzed. The results showed that, during the process of thermal shock, the thermal hoop tensile stress on the surface of the anode is very large, which is possibly the major cause of anode crack; when the radius of the anode is between 0.05-0.15m, a range that can be realized by recent manufacturing technology, the optimum composition distribution exponent p is 0.25; The hoop tensile stresses reduce with the decrease of anode scale and also decrease with the decrease of the convection coefficient between the electrolyte and the anode.展开更多
The microstructure evolution and electrolysis behavior of(Cu_(52)Ni_(30)Fe_(18))–x Ni Fe_2O_4(x=40wt%,50wt%,60wt%,and 70wt%)composite inert anodes for aluminum electrowinning were studied.Ni Fe_2O_4 was synthesized b...The microstructure evolution and electrolysis behavior of(Cu_(52)Ni_(30)Fe_(18))–x Ni Fe_2O_4(x=40wt%,50wt%,60wt%,and 70wt%)composite inert anodes for aluminum electrowinning were studied.Ni Fe_2O_4 was synthesized by solid-state reaction at 950°C.The dense anode blocks were prepared by ball-milling followed by sintering under a N_2 atmosphere.The phase evolution of the anodes after sintering was determined by scanning electron microscopy and energy-dispersive X-ray spectroscopy.The results indicate that a substitution reaction between Fe in the alloy phase and Ni in the oxide phase occurs during the sintering process.The samples were also examined as inert anodes for aluminum electrowinning in the low-temperature KF–NaF–AlF_3 molten electrolyte for 24 h.The cell voltage during electrolysis and the corrosion scale on the anodes were analyzed.The results confirm that the scale has a self-repairing function because of the synergistic reaction between the alloy phase with Fe added and the oxide phase.The estimated wear rate of the(Cu_(52)Ni_(30)Fe_(18))–50Ni Fe_2O_4 composite anode is 2.02 cm·a^(-1).展开更多
Arc sound is well known as the potential and available resource for monitoring and controlling of the weld penetration status,which is very important to the welding process quality control,so any attentions have been ...Arc sound is well known as the potential and available resource for monitoring and controlling of the weld penetration status,which is very important to the welding process quality control,so any attentions have been paid to the relationships between the arc sound and welding parameters.Some non-linear mapping models correlating the arc sound to welding parameters have been established with the help of neural networks.However,the research of utilizing arc sound to monitor and diagnose welding process is still in its infancy.A self-made real-time sensing system is applied to make a study of arc sound under typical penetration status,including partial penetration,unstable penetration,full penetration and excessive penetration,in metal inert-gas(MIG) flat tailored welding with spray transfer.Arc sound is pretreated by using wavelet de-noising and short-time windowing technologies,and its characteristics,characterizing weld penetration status,of time-domain,frequency-domain,cepstrum-domain and geometric-domain are extracted.Subsequently,high-dimensional eigenvector is constructed and feature-level parameters are successfully fused utilizing the concept of primary principal component analysis(PCA).Ultimately,60-demensional eigenvector is replaced by the synthesis of 8-demensional vector,which achieves compression for feature space and provides technical supports for pattern classification of typical penetration status with the help of arc sound in MIG welding in the future.展开更多
The NiFe2O4 inert anode is synthesized by high-temperature solid-state reaction method using NiO and Fe2O3 as main raw materials and adding MnO2 powder as additive. Archimedes method using water immersion technique is...The NiFe2O4 inert anode is synthesized by high-temperature solid-state reaction method using NiO and Fe2O3 as main raw materials and adding MnO2 powder as additive. Archimedes method using water immersion technique is used to measure the sintering performances of sampies. The static thermal corrosion rates of samples are measured by weight loss. SEM is employed for the observation of material microstructure, and phase structure of the sample surface after corrosion is determined by XRD. The experimental results indicate that a suitable MnO2 additive content is 2%, while the sintering performance is the best, and the static thermal corrosion rate is the lowest. Because of MnO2 dopant enriching at crystal boundary, the corrosion reaction of molten salt to crystal grain creates Mn2AlO4 phase, which is denser than NiFe2O4 phase, and prevents the cryolite molten salt to penetrate into the inert anode, thus reducing the corrosion.展开更多
ZnFe 2O 4 and ZnFe 2O 4 based materials were tested to obtain the electrical conductivity and corrosion resistance in melting bath for aluminum electrolysis. The results proved that adequate additives, such as Ni 2O 3...ZnFe 2O 4 and ZnFe 2O 4 based materials were tested to obtain the electrical conductivity and corrosion resistance in melting bath for aluminum electrolysis. The results proved that adequate additives, such as Ni 2O 3 CuO, Cu, ZnO and CeO 2 would increase the electrical conductivity, and the ZnFe 2O 4 based anodes with these additives were of good corrosion resistance. The current density on anode, the mole ratio of NaF/AlF 3 (MR) and the content of alumina in the bath effect the anode corrosion rate in different way.展开更多
Anesthetics are extremely important in modem surgery to greatly reduce the patient,s pain. The understanding of anesthesia at molecular level is the preliminary step for the application of anesthetics in clinic safely...Anesthetics are extremely important in modem surgery to greatly reduce the patient,s pain. The understanding of anesthesia at molecular level is the preliminary step for the application of anesthetics in clinic safely and effectively. Inert gases, with low chemical activity, have been found to cause anesthesia for centuries, but the mechanism is unclear yet. In this review, we first summarize the progress of theories about general anesthesia, especially for inert gas narcosis, and then propose a new hypothesis that the aggregated rather than the dispersed inert gas molecules are the key to trigger the narcosis to explain the steep dose-response relationship of anesthesia.展开更多
This paper presents the use of a computer method of the ventilation process simulation for the analysis of the flow distribution of air and gases in the area of wall mining work and the adjacent goaf.In workings and g...This paper presents the use of a computer method of the ventilation process simulation for the analysis of the flow distribution of air and gases in the area of wall mining work and the adjacent goaf.In workings and goaf,the complex issue of the formation of a gaseous atmosphere under variable ventilation conditions and an existing fire hazard level,with the possibility of feeding goaf with an additional carbon dioxide flux as the inertizing agent is considered.Some examples of the simulation of feeding goaf with carbon dioxide illustrating the different patterns of the distribution of the goaf atmosphere gases concentration,said distribution patterns being gas supply place dependent,have been presented.In addition,the impact of the additional sealing of goaf on the distribution level of the concentration of gases,the said sealing made from the wall side with chemical agents has also been considered.The capabilities of the VentGoaf computer simulation program,being the basis for our calculations,enable consideration of the use of the inert gases supplied to the goaf depending on: the location of the gas feeding the pipe outlet,tightness of the fire field,fire centre location,and spatial situation of the mined wall.It has been found that fire prevention elements,such as chemical sealing agents,are of great impact on the effectiveness of fire prevention.展开更多
The main aim of this study was to investigate liquation cracking in the heat-affected zone(HAZ)of the IN939 superalloy upon tungsten inert gas welding.A solid solution and age-hardenable filler metals were further stu...The main aim of this study was to investigate liquation cracking in the heat-affected zone(HAZ)of the IN939 superalloy upon tungsten inert gas welding.A solid solution and age-hardenable filler metals were further studied.On the pre-weld heat-treated samples,upon solving the secondaryγ′particles in the matrix,primaryγ′particles in the base metal grew to"ogdoadically diced cubes"of about 2μm in side lengths.The pre-weld heat treatment reduced the hardness of the base metal to about HV 310.Microstructural studies using optical and fieldemission scanning electron microscopy revealed that the IN939 alloy was susceptible to liquation cracking in the HAZ.The constitutional melting of the secondary,eutectic,and Zr-rich phases promoted the liquation cracking in the HAZ.The microstructure of the weld fusion zones showed the presence of fine spheroidalγ′particles with sizes of about 0.2μm after the post-weld heat treatment,which increased the hardness of the weld pools to about HV 350 and 380 for the Hastelloy X and IN718 filler metals,respectively.Application of a suitable solid solution filler metal could partially reduce the liquation cracking in the HAZ of IN939 alloy.展开更多
This study compared the microstructure and mechanical characteristics of AA6061-T6 joints produced using friction stir welding(FSW),friction stir vibration welding(FSVW),and tungsten inert gas welding(TIG).FSVW is a m...This study compared the microstructure and mechanical characteristics of AA6061-T6 joints produced using friction stir welding(FSW),friction stir vibration welding(FSVW),and tungsten inert gas welding(TIG).FSVW is a modified version of FSW wherein the joining specimens are vibrated normal to the welding line during FSW.The results indicated that the weld region grains for FSVW and FSW were equiaxed and were smaller than the grains for TIG.In addition,the weld region grains for FSVW were finer compared with those for FSW.Results also showed that the strength,hardness,and toughness values of the joints produced by FSVW were higher than those of the other joints produced by FSW and TIG.The vibration during FSW enhanced dynamic recrystallization,which led to the development of finer grains.The weld efficiency of FSVW was approximately 81%,whereas those of FSW and TIG were approximately 74%and 67%,respectively.展开更多
Super-clean and super-spherical FGH4095 superalloy powder is produced by the ceramic-free electrode inductionmelt inert gas atomization(EIGA) technique.A continuous and steady-state liquid metal flow is achieved at ...Super-clean and super-spherical FGH4095 superalloy powder is produced by the ceramic-free electrode inductionmelt inert gas atomization(EIGA) technique.A continuous and steady-state liquid metal flow is achieved at high-frequency(350 k Hz) alternating current and high electric power(100 k W).The superalloy is immersed in a high-frequency induction coil,and the liquid metal falling into a supersonic nozzle is atomized by an Ar gas of high kinetic gas energy.Numerical calculations are performed to optimize the structure parameters for the nozzle tip.The undesired oxidation reaction of alloying elements starts at 1000℃ with the reaction originating from the active sites on the powder surfaces,leading to the formation of oxides,MexOy.The role of active sites and kinetic factors associated with the diffusion of oxygen present in the atomization gas streams are also examined.The observed results reveal that the oxidation process occurring at the surface of the produced powders gradually moves toward the core,and that there exists a clear interface between the product layer and the reactant.The present study lays a theoretical foundation for controlling the oxidation of nickel-based superalloy powders from the powder process step.展开更多
基金Project supported by the National Natural Science Foundation of China (Nos. 12172153 and51805216)the China Postdoctoral Science Foundation (No. 2023M731668)the Major Project of Basic Science (Natural Science) of the Jiangsu Higher Education Institutions of China(No. 22KJA410001)。
文摘Inspired by the demand of improving the riding comfort and meeting the lightweight design of the vehicle, an inerter-based X-structure nonlinear energy sink(IXNES) is proposed and applied in the half-vehicle system to enhance the dynamic performance. The X-structure is used as a mechanism to realize the nonlinear stiffness characteristic of the NES, which can realize the flexibility, adjustability, high efficiency, and easy operation of nonlinear stiffness, and is convenient to apply in the vehicle suspension, and the inerter is applied to replacing the mass of the NES based on the mass amplification characteristic. The dynamic model of the half-vehicle system coupled with the IX-NES is established with the Lagrange theory, and the harmonic balance method(HBM) and the pseudo-arc-length method(PALM) are used to obtain the dynamic response under road harmonic excitation. The corresponding dynamic performance under road harmonic and random excitation is evaluated by six performance indices, and compared with that of the original half-vehicle system to show the benefits of the IX-NES. Furthermore, the structural parameters of the IX-NES are optimized with the genetic algorithm. The results show that for road harmonic and random excitation, using the IX-NES can greatly reduce the resonance peaks and root mean square(RMS) values of the front and rear suspension deflections and the front and rear dynamic tire loads, while the resonance peaks and RMS values of the vehicle body vertical and pitching accelerations are slightly larger.When the structural parameters of the IX-NES are optimized, the vehicle body vertical and pitching accelerations of the half-vehicle system could reduce by 2.41% and 1.16%,respectively, and the other dynamic performance indices are within the reasonable ranges.Thus, the IX-NES combines the advantages of the inerter, X-structure, and NES, which improves the dynamic performance of the half-vehicle system and provides an effective option for vibration attenuation in the vehicle engineering.
基金This research was funded by the Natural Science Research Project of Higher Education Institutions in Anhui Province(Grant No.2022AH040045)the Anhui Provincial Natural Science Foundation(Grant No.2008085QE245)the Project of Science and Technology Plan of Department of Housing and Urban-Rural Development of Anhui Province(Grant No.2021-YF22).
文摘In order to improve the seismic performance of adjacent buildings,two types of tuned inerter damper(TID)damping systems for adjacent buildings are proposed,which are composed of springs,inerter devices and dampers in serial or in parallel.The dynamic equations of TID adjacent building damping systems were derived,and the H2 norm criterion was used to optimize and adjust them,so that the system had the optimum damping performance under white noise random excitation.Taking TID frequency ratio and damping ratio as optimization parameters,the optimum analytical solutions of the displacement frequency response of the undamped structure under white noise excitation were obtained.The results showed that compared with the classic TMD,TID could obtain a better damping effect in the adjacent buildings.Comparing the TIDs composed of serial or parallel,it was found that the parallel TIDs had more significant advantages in controlling the peak displacement frequency response,while the H2 norm of the displacement frequency response of the damping system under the coupling of serial TID was smaller.Taking the adjacent building composed of two ten-story frame structures as an example,the displacement and energy collection time history analysis of the adjacent building coupled with the optimum design parameter TIDs were carried out.It was found that TID had a better damping effect in the full-time range compared with the classic TMD.This paper also studied the potential power of TID in adjacent buildings,which can be converted into available power resources during earthquakes.
基金Project (2005CB623703) supported by the National Basic Research Program of ChinaProject (50721003) supported by the National Natural Science Fund for Innovation Group of ChinaProject (2008AA030501) supported by the National High-Tech Research and Development Program of China
文摘17(Cu-10Ni)-(NiFe2O4-10NiO) cermets were prepared by cold pressing and sintering in nitrogen atmosphere, and tested as inert anode for aluminum electrolysis at 960 °C for 10 and 40 h, respectively. Microstructures and phase compositions of the as-sintered and post-electrolyzed samples were investigated. The impurity contents in the electrolyte and the cathode metal were detected in order to investigate the corrosion characteristic of the elements of Fe, Ni and Cu in the anode. A dense NiFe2O4 layer was observed on the surface of anode and thickened with prolonging the electrolysis time. In the newly formed dense ceramic layer, NiO phase disappeared as a result of being swallowed by NiFe2O4 phase, and the metal phase was oxidized during the electrolysis in which Cu element showed a higher dissolution rate than Fe and Ni elements. The formation process of the dense ceramic layer during the electrolysis was presented and explained by using the corrosion mode of the metal phase and the transformation mechanism from NiO phase to NiFe2O4 phase.
基金Project(2005CB623703)supported by the National Basic Research Program of ChinaProject(50721003)supported by the National Natural Science Foundation for Innovation Group of China+1 种基金Project(2008AA030501)supported by the National High-tech Research and Development Program of ChinaProject(201012200021)supported by the Basic Scientific Research Program of Central South University,China
文摘xCu/(10NiO-NiFe2O4) cermet and 1BaO-xCu/(10NiO-NiFe2O4) cermet(x=5,10,17) inert anodes were prepared as potential inert anodes for aluminum electrolysis and their corrosion resistance to traditional electrolyte was studied with anodic current density of 1.0 A/cm2 in laboratory electrolysis.The substantial corrosion of metal Cu was observed,many pores appeared on the surface of anode and electrolytes infiltrated inside anodes during the electrolysis.The wear rates of 5Cu/(10NiO-NiFe2O4),10Cu/(10NiO-NiFe2O4),17Cu/(10NiO-NiFe2O4),1BaO-5Cu/(10NiO-NiFe2O4),1BaO-10Cu/(10NiO-NiFe2O4) and 1BaO-17Cu/(10NiO-NiFe2O4) are 2.15,6.50,8.30,4.88,4.70 and 4.48 cm/a,respectively.The addition of BaO to 10Cu/(10NiO-NiFe2O4) cermet and 17Cu/(10NiO-NiFe2O4) cermet is advantageous because BaO can effectively promote densification and thus improve corrosion resistance.But the addition of BaO to 5Cu/(10NiO-NiFe2O4) cermet is unfavorable to corrosion resistance because additive BaO at the grain boundary of anode accelerates possibly the corrosion of cermet.
基金Project(51474238)supported by the National Natural Science Foundation of China
文摘A comparative study on the corrosion resistance of 17Ni/(NiFe2O4-10NiO) cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rates of NiFe2O4-based cermetanodes prepared in the vacuum and the atmosphere with oxygen content of 2×10^-3 (volume fraction) are 6.46 and 2.71 cm/a,respectively. Though there is a transition layer with lots of holes or pores, a densified layer is formed on the surface of anode due tosome reactions producing aluminates. For the anode prepared in the atmosphere with oxygen content of 2×10^-3, the thickness of thedensification layer (about 50 μm) is thicker than that (about 30 μm) formed on the surface of anode prepared in the vacuum. Thecontents of NiO and Fe(II) in NiFe2xO4-y-z increase with the decrease of oxygen content in sintering atmosphere, which reduces thecorrosion resistance of the material.
基金Project (2012FJ6123) supported by the Project of Science and Technology of Hunan Province,ChinaProject supported by Post-Doctoral Foundation of Central South University,China+1 种基金Project (CL12100) supported the Undergraduate Innovative Training of Central South University,ChinaProject (2282013bkso13) supported by Free Exploration Plan of Central South University,China
文摘NiFe2O4-10NiO-based cermet inert anodes for aluminium electrolysis were prepared and their properties were investigated in a lab-scale electrolysis cell. The results show that the inert anodes exhibit good performance during electrolysis in molten salt cryolite at 960 °C, but according to the analyses of phase compositions and microstructures through XRD, SEM/EDX and metallographic analysis, the metal in the anodes is preferentially corroded and many pores are produced on the anode surface after electrolysis. The preferential dissolution of Fe in the NiFe2O4 phase may lead to the non-uniform corrosion of NiFe2O4 grains. Moreover, a dense protective layer of NiFe2O4-NiAl2O4-FeAl2O4 is formed on the anode surface, which originates from the reaction of Al2O3 dissolved in the electrolyte with NiO or FeO, the annexation of NiFe2O4-NiAl2O4-FeAl2O4 to NiO and volume expansion. Thus, the dense NiFe2O4-NiAl2O4-FeAl2O4 layer inhibits the metal loss and ceramic-phase corrosion on the surface of the cermet inert anodes.
基金Project (51004056) supported by the National Natural Science Foundation of ChinaProject (KKZ6201152009) supported by the Opening Foundation of Key Laboratory of Inorganic Coating Materials, ChinaProjects (2011239, 2011240) supported by Analysis and Measurement Research Fund of Kunming University of Science and Technology,China
文摘In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI(polyaniline)-WC(tungsten carbide) composite inert anodes were prepared on aluminum alloy substrate by double pulse electrodeposition(DPE) of PANI and WC particles with Pb2+ from an original plating bath.Thereafter,anodic polarization curves,cyclic voltammetry curves and Tafel polarization curves for the composite inert anodes obtained under different PANI concentrations in the original plating bath were measured,and the microstructural features were also investigated by scanning electron microscopy(SEM).The results show that Al/Pb-PANI-WC composite inert anode obtained under PANI concentration of 20 g/L in the original plating bath possesses uniform microstructures and composition distributions,higher electrocatalytic activity,better reversibility of electrode reaction and corrosion resistance in a synthetic zinc electrowinning electrolyte of 50 g/L Zn2+,150 g/L H2SO4 at 35 °C.Compared with Pb-1%Ag alloy,the overpotential of oxygen evolutions for the composite inert anode are decreased by 185 mV and 166 mV,respectively,under 500 A/m2 and 1000 A/m2.
基金We are grateful for the financial support from the Natural Science Foundation of Hunan Province(Grant No.04JJ0388)and from Central South University.
文摘LiFePO4/C was synthesized by high temperature solid-state method with cheap Fe2O3, LiH2PO4 and glucose as raw materials in absence of inert gas. The sample had ordered olivine-type structure other impurities characterized by the test of X-ray diffraction (XRD). The charge-discharge test showed the sample could demonstrate 120.5 mAh/g at 0.2C rate with good cyclic capability. The powder microeleetrode cyclic voltammetry test indicated that the redox process of the sample had good reversibility.
基金financial support from National Basic Research Program of China(No.2005CB623703)National Natural Science Foundation of China(No.50474051).
文摘(Cu-Ni)/(10NiO-90NiFe204) cermet inert anodes containing metal Cu-Ni0, 5, 10, 15 and 20 wt pct were prepared and their corrosion resistance to Na3AlF6-Al2O3 melts was investigated. The results indicate that the content of metal Cu-Ni has little effect on the steady-state concentration of Ni in the electrolyte and the values could not be used to effectively differentiate their corrosion resistance. The steady-state concentration of Fe decreases from 304×10^-6 to 168×10^-6 and that of Cu increases from 21×10^-6 to 71×10^-6 with the content of metal Cu-Ni increasing from 0 to 20 wt pct. Post-examination shows that metallic phase Cu-Ni is corroded preferentially during electrolysis and many pores are left at the anode surface. Considering the corrosion resistance and electrical conductivity, the cermet containing metal Cu-Ni 5 wt pct should be selected and studied further.
基金supported by the National Key Basic Research and Development Programme of China(No.2005CB623703)the National Natural Science Foundation of China(No.50474051 and No.50374081).
文摘Inert anode has been a hot issue in the aluminum industry for many decades. With the help of FEA (finite element analysis) software ANSYS, a model was developed to simulate the thermal stress distribution working condition of an inert anode. To reduce its thermal stress, the effect of some parameters on the thermal stress distribution was investigated, including the anode height, the anode radius, the hole depth, the hole radius, and the radius of inner chamfer and outer chamfer. The results showed that in the actual working condition of an inert anode, there existed a large axial tensile stress near the tangent interface between the anode and bath, which was the major cause of anode breaking. Increasing the anode height and reducing the hole depth properly seemed to be beneficial for the stress distribution. With the increase of anode radius, the stress distribution became better first and then deteriorated, the reasonable value was between 0.045 to 0.06m. The hole radius had a significant effect on the stress and a smaller radius would reduce the thermal stress. The effect of the radius of the inner chamfer and the outer chamfer was less than other parameters.
基金This work was supported by the National Basic Research Program of China(No.2005CB623703)National Natural Science Foundation(No.5047405I)+1 种基金Hunan Provincial Natural Science Foundation of China(No.03JJY3080)Trans-Century Excellent Persons Cultivation Project of Ministry of Education of China(in 2002).
文摘The thermal stresses relaxation of Ni/NiFe2O4 system functionally graded cermet inert anode for aluminum electrolysis was optimally designed. The transient thermal stresses of the inert anode under complex boundary condition during high-temp (955℃) electrolysis were calculated using the finite-element software ANSYS, the influence of different parameters on the distribution of the thermal stresses were analyzed. The results showed that, during the process of thermal shock, the thermal hoop tensile stress on the surface of the anode is very large, which is possibly the major cause of anode crack; when the radius of the anode is between 0.05-0.15m, a range that can be realized by recent manufacturing technology, the optimum composition distribution exponent p is 0.25; The hoop tensile stresses reduce with the decrease of anode scale and also decrease with the decrease of the convection coefficient between the electrolyte and the anode.
基金financially supported by the Major Science and Technology Programs of CHALCO(ZB2013CBBCe1)the Zhengzhou Non-ferrous Metals Research Institute Co.Ltd.of CHALCO for supporting this work
文摘The microstructure evolution and electrolysis behavior of(Cu_(52)Ni_(30)Fe_(18))–x Ni Fe_2O_4(x=40wt%,50wt%,60wt%,and 70wt%)composite inert anodes for aluminum electrowinning were studied.Ni Fe_2O_4 was synthesized by solid-state reaction at 950°C.The dense anode blocks were prepared by ball-milling followed by sintering under a N_2 atmosphere.The phase evolution of the anodes after sintering was determined by scanning electron microscopy and energy-dispersive X-ray spectroscopy.The results indicate that a substitution reaction between Fe in the alloy phase and Ni in the oxide phase occurs during the sintering process.The samples were also examined as inert anodes for aluminum electrowinning in the low-temperature KF–NaF–AlF_3 molten electrolyte for 24 h.The cell voltage during electrolysis and the corrosion scale on the anodes were analyzed.The results confirm that the scale has a self-repairing function because of the synergistic reaction between the alloy phase with Fe added and the oxide phase.The estimated wear rate of the(Cu_(52)Ni_(30)Fe_(18))–50Ni Fe_2O_4 composite anode is 2.02 cm·a^(-1).
基金supported by Harbin Academic Pacesetter Foundation of China (Grant No. RC2012XK006002)Zhegjiang Provincial Natural Science Foundation of China (Grant No. Y1110262)+2 种基金Ningbo Municipal Natural Science Foundation of China (Grant No. 2011A610148)Ningbo Municipal Major Industrial Support Project of China (Grant No.2011B1007)Heilongjiang Provincial Natural Science Foundation of China (Grant No. E2007-01)
文摘Arc sound is well known as the potential and available resource for monitoring and controlling of the weld penetration status,which is very important to the welding process quality control,so any attentions have been paid to the relationships between the arc sound and welding parameters.Some non-linear mapping models correlating the arc sound to welding parameters have been established with the help of neural networks.However,the research of utilizing arc sound to monitor and diagnose welding process is still in its infancy.A self-made real-time sensing system is applied to make a study of arc sound under typical penetration status,including partial penetration,unstable penetration,full penetration and excessive penetration,in metal inert-gas(MIG) flat tailored welding with spray transfer.Arc sound is pretreated by using wavelet de-noising and short-time windowing technologies,and its characteristics,characterizing weld penetration status,of time-domain,frequency-domain,cepstrum-domain and geometric-domain are extracted.Subsequently,high-dimensional eigenvector is constructed and feature-level parameters are successfully fused utilizing the concept of primary principal component analysis(PCA).Ultimately,60-demensional eigenvector is replaced by the synthesis of 8-demensional vector,which achieves compression for feature space and provides technical supports for pattern classification of typical penetration status with the help of arc sound in MIG welding in the future.
基金This work was suppored by the National High Technical Reasearch and Development Programme of China(No.2001AA335010).
文摘The NiFe2O4 inert anode is synthesized by high-temperature solid-state reaction method using NiO and Fe2O3 as main raw materials and adding MnO2 powder as additive. Archimedes method using water immersion technique is used to measure the sintering performances of sampies. The static thermal corrosion rates of samples are measured by weight loss. SEM is employed for the observation of material microstructure, and phase structure of the sample surface after corrosion is determined by XRD. The experimental results indicate that a suitable MnO2 additive content is 2%, while the sintering performance is the best, and the static thermal corrosion rate is the lowest. Because of MnO2 dopant enriching at crystal boundary, the corrosion reaction of molten salt to crystal grain creates Mn2AlO4 phase, which is denser than NiFe2O4 phase, and prevents the cryolite molten salt to penetrate into the inert anode, thus reducing the corrosion.
文摘ZnFe 2O 4 and ZnFe 2O 4 based materials were tested to obtain the electrical conductivity and corrosion resistance in melting bath for aluminum electrolysis. The results proved that adequate additives, such as Ni 2O 3 CuO, Cu, ZnO and CeO 2 would increase the electrical conductivity, and the ZnFe 2O 4 based anodes with these additives were of good corrosion resistance. The current density on anode, the mole ratio of NaF/AlF 3 (MR) and the content of alumina in the bath effect the anode corrosion rate in different way.
基金supported by the Supercomputing Center of Chinese Academy of Sciences in Beijing,Chinathe Shanghai Supercomputer Center,China+3 种基金the National Natural Science Foundation of China(Grant Nos.21273268,11290164,and 11175230)the Startup Funding from Shanghai Institute of Applied Physics,Chinese Academy of Sciences(Grant No.Y290011011)"Hundred People Project"from Chinese Academy of Sciences"Pu-jiang Rencai Project"from Science and Technology Commission of Shanghai Municipality,China(Grant No.13PJ1410400)
文摘Anesthetics are extremely important in modem surgery to greatly reduce the patient,s pain. The understanding of anesthesia at molecular level is the preliminary step for the application of anesthetics in clinic safely and effectively. Inert gases, with low chemical activity, have been found to cause anesthesia for centuries, but the mechanism is unclear yet. In this review, we first summarize the progress of theories about general anesthesia, especially for inert gas narcosis, and then propose a new hypothesis that the aggregated rather than the dispersed inert gas molecules are the key to trigger the narcosis to explain the steep dose-response relationship of anesthesia.
基金a part of research projects(NN524 368237)Financed by the Ministry of Science and Higher Education
文摘This paper presents the use of a computer method of the ventilation process simulation for the analysis of the flow distribution of air and gases in the area of wall mining work and the adjacent goaf.In workings and goaf,the complex issue of the formation of a gaseous atmosphere under variable ventilation conditions and an existing fire hazard level,with the possibility of feeding goaf with an additional carbon dioxide flux as the inertizing agent is considered.Some examples of the simulation of feeding goaf with carbon dioxide illustrating the different patterns of the distribution of the goaf atmosphere gases concentration,said distribution patterns being gas supply place dependent,have been presented.In addition,the impact of the additional sealing of goaf on the distribution level of the concentration of gases,the said sealing made from the wall side with chemical agents has also been considered.The capabilities of the VentGoaf computer simulation program,being the basis for our calculations,enable consideration of the use of the inert gases supplied to the goaf depending on: the location of the gas feeding the pipe outlet,tightness of the fire field,fire centre location,and spatial situation of the mined wall.It has been found that fire prevention elements,such as chemical sealing agents,are of great impact on the effectiveness of fire prevention.
文摘The main aim of this study was to investigate liquation cracking in the heat-affected zone(HAZ)of the IN939 superalloy upon tungsten inert gas welding.A solid solution and age-hardenable filler metals were further studied.On the pre-weld heat-treated samples,upon solving the secondaryγ′particles in the matrix,primaryγ′particles in the base metal grew to"ogdoadically diced cubes"of about 2μm in side lengths.The pre-weld heat treatment reduced the hardness of the base metal to about HV 310.Microstructural studies using optical and fieldemission scanning electron microscopy revealed that the IN939 alloy was susceptible to liquation cracking in the HAZ.The constitutional melting of the secondary,eutectic,and Zr-rich phases promoted the liquation cracking in the HAZ.The microstructure of the weld fusion zones showed the presence of fine spheroidalγ′particles with sizes of about 0.2μm after the post-weld heat treatment,which increased the hardness of the weld pools to about HV 350 and 380 for the Hastelloy X and IN718 filler metals,respectively.Application of a suitable solid solution filler metal could partially reduce the liquation cracking in the HAZ of IN939 alloy.
文摘This study compared the microstructure and mechanical characteristics of AA6061-T6 joints produced using friction stir welding(FSW),friction stir vibration welding(FSVW),and tungsten inert gas welding(TIG).FSVW is a modified version of FSW wherein the joining specimens are vibrated normal to the welding line during FSW.The results indicated that the weld region grains for FSVW and FSW were equiaxed and were smaller than the grains for TIG.In addition,the weld region grains for FSVW were finer compared with those for FSW.Results also showed that the strength,hardness,and toughness values of the joints produced by FSVW were higher than those of the other joints produced by FSW and TIG.The vibration during FSW enhanced dynamic recrystallization,which led to the development of finer grains.The weld efficiency of FSVW was approximately 81%,whereas those of FSW and TIG were approximately 74%and 67%,respectively.
文摘Super-clean and super-spherical FGH4095 superalloy powder is produced by the ceramic-free electrode inductionmelt inert gas atomization(EIGA) technique.A continuous and steady-state liquid metal flow is achieved at high-frequency(350 k Hz) alternating current and high electric power(100 k W).The superalloy is immersed in a high-frequency induction coil,and the liquid metal falling into a supersonic nozzle is atomized by an Ar gas of high kinetic gas energy.Numerical calculations are performed to optimize the structure parameters for the nozzle tip.The undesired oxidation reaction of alloying elements starts at 1000℃ with the reaction originating from the active sites on the powder surfaces,leading to the formation of oxides,MexOy.The role of active sites and kinetic factors associated with the diffusion of oxygen present in the atomization gas streams are also examined.The observed results reveal that the oxidation process occurring at the surface of the produced powders gradually moves toward the core,and that there exists a clear interface between the product layer and the reactant.The present study lays a theoretical foundation for controlling the oxidation of nickel-based superalloy powders from the powder process step.