以低黏度聚对苯二甲酰对苯二胺(PPTA)为原料,工业浓硫酸为溶剂,采用干喷湿纺法制备对位芳纶,探讨了PPTA浆液的配制及其纺丝性能。结果表明:选择PPTA树脂比浓对数黏度(ηinh)为6.0 d L/g,浆液中PPTA质量分数为19.3%,对纺丝性能非常重要;...以低黏度聚对苯二甲酰对苯二胺(PPTA)为原料,工业浓硫酸为溶剂,采用干喷湿纺法制备对位芳纶,探讨了PPTA浆液的配制及其纺丝性能。结果表明:选择PPTA树脂比浓对数黏度(ηinh)为6.0 d L/g,浆液中PPTA质量分数为19.3%,对纺丝性能非常重要;控制PPTA树脂灰分含量小于100μg/g,浓硫酸中的杂质含量小于100μg/g,可以提高PPTA浆液的可纺性和纤维的强度;配浆螺杆温度分8区,设置温度前低后高,可以减少浆液的降解,浆液粘稠度均匀;配制的PPTA浆液在8 h内纺丝,所得纤维都有较高的断裂强度,大于18.3 c N/dtex。展开更多
Carbon fibers(CFs)are widely used in various cutting-edge fields,such as aerospace,military,automobiles,and sports,owing to their unique combination of excellent mechanical properties,good thermal stability,and lightw...Carbon fibers(CFs)are widely used in various cutting-edge fields,such as aerospace,military,automobiles,and sports,owing to their unique combination of excellent mechanical properties,good thermal stability,and lightweight.However,their inherent super-black appearance makes it difficult to satisfy the aesthetic/fashion requirements of the colorful world,and the flammability of CFs severely limits their practical utilization in high-temperature and other extreme environments.Herein,we fabricated full-color tunable colored CFs on a large-scale via atomic layer deposition,based on the monolayer film interference strategy.CFs exhibited brilliant colors and excellent environmental durability in extreme environments,such as intense ultraviolet(UV)irradiation,accelerated laundering,friction,high-temperature,and low-temperature treatments.Colored CFs also exhibited excellent fire-retardant performance that could withstand alcohol-lamp flame burning for 60 min.Our work provides insights into an innovative material/structural design that can help achieve rapid development of the CF industry and global carbon neutrality/sustainability.展开更多
采用Minitab软件对千吨级对位芳纶生产中聚合物比浓对数黏度对纤维断裂强度的影响进行分析。首先,对聚合物比浓对数黏度和纤维断裂强度的测量系统进行验证,得出测量系统的变异影响都是在可接受的范围;然后采集生产现场数据对聚合物比浓...采用Minitab软件对千吨级对位芳纶生产中聚合物比浓对数黏度对纤维断裂强度的影响进行分析。首先,对聚合物比浓对数黏度和纤维断裂强度的测量系统进行验证,得出测量系统的变异影响都是在可接受的范围;然后采集生产现场数据对聚合物比浓对数黏度对纤维断裂强度和纺丝成纤率的影响进行分析,得出纤维断裂强度和纺丝成纤率随着聚合物比浓对数黏度的增大而增大,但当聚合物比浓对数黏度达到一定值后成纤率下降,并找出了聚合物比浓对数黏度较佳控制范围为6.3-7.0 d L/g。展开更多
文摘以低黏度聚对苯二甲酰对苯二胺(PPTA)为原料,工业浓硫酸为溶剂,采用干喷湿纺法制备对位芳纶,探讨了PPTA浆液的配制及其纺丝性能。结果表明:选择PPTA树脂比浓对数黏度(ηinh)为6.0 d L/g,浆液中PPTA质量分数为19.3%,对纺丝性能非常重要;控制PPTA树脂灰分含量小于100μg/g,浓硫酸中的杂质含量小于100μg/g,可以提高PPTA浆液的可纺性和纤维的强度;配浆螺杆温度分8区,设置温度前低后高,可以减少浆液的降解,浆液粘稠度均匀;配制的PPTA浆液在8 h内纺丝,所得纤维都有较高的断裂强度,大于18.3 c N/dtex。
基金We thank Y.Huang from Tsinghua University for the help in characterizing colored CFs samplessupported by the National Natural Science Foundation of China(Grant Nos.51903008 and U1910209)+6 种基金Science and Technology Research Project of the Educational Commission of Hubei Province(D20211703)Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.2023433)Natural Science Foundation of Shanxi Province(Grant No.20210302124128)Open Foundation of State Key Laboratory of Bio-Fibers and Eco-Textiles from Qingdao University(Grant No.2020105)Hubei Key Laboratory of Digital Textile Equipment,Wuhan Textile University(Grant No.DTL 2022006)National Engineering Laboratory for Modern Silk,Soochow University(Grant No.SDGC2148)National Local Joint Laboratory for Advanced Textile Processing and Clean Production(Grant No.17).
文摘Carbon fibers(CFs)are widely used in various cutting-edge fields,such as aerospace,military,automobiles,and sports,owing to their unique combination of excellent mechanical properties,good thermal stability,and lightweight.However,their inherent super-black appearance makes it difficult to satisfy the aesthetic/fashion requirements of the colorful world,and the flammability of CFs severely limits their practical utilization in high-temperature and other extreme environments.Herein,we fabricated full-color tunable colored CFs on a large-scale via atomic layer deposition,based on the monolayer film interference strategy.CFs exhibited brilliant colors and excellent environmental durability in extreme environments,such as intense ultraviolet(UV)irradiation,accelerated laundering,friction,high-temperature,and low-temperature treatments.Colored CFs also exhibited excellent fire-retardant performance that could withstand alcohol-lamp flame burning for 60 min.Our work provides insights into an innovative material/structural design that can help achieve rapid development of the CF industry and global carbon neutrality/sustainability.
文摘采用Minitab软件对千吨级对位芳纶生产中聚合物比浓对数黏度对纤维断裂强度的影响进行分析。首先,对聚合物比浓对数黏度和纤维断裂强度的测量系统进行验证,得出测量系统的变异影响都是在可接受的范围;然后采集生产现场数据对聚合物比浓对数黏度对纤维断裂强度和纺丝成纤率的影响进行分析,得出纤维断裂强度和纺丝成纤率随着聚合物比浓对数黏度的增大而增大,但当聚合物比浓对数黏度达到一定值后成纤率下降,并找出了聚合物比浓对数黏度较佳控制范围为6.3-7.0 d L/g。
